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Referat Oil Spills
Referat Oil Spills
Referat Oil Spills
D. DINU
Course:
<<MARINE POLLUTION I>>
Student:
Ana Maria Stan
Marine Spills
Recognition of spilt oil at sea or on the
shoreline may be the first indication of an oil
spill. Depending on the quantity and type of
oil involved, a clean-up response may have to
be organised for removing the oil and
protecting sensitive areas nearby.
The fate of spilt oil depends on a number of
factors, such as the amount of oil spilled; its
initial physical and chemical characteristics;
the prevailing weather and sea conditions; and whether the oil remains at
sea or comes ashore.
Once spilled at sea, the natural tendency for the oil will be to spread,
break up and become dissipated over time. This dissipation is a result of a
number of chemical and physical processes acting on the spilt oil. These
processes are collectively referred to as weathering.
In considering the fate of spilled oil at sea and potential clean-up and
response techniques, the persistence of the oil in the environment should
be taken into account.
A variety of models exist which may be used to aid in decision making
processes and forecasting the likely locations the oil may strand. Models
Dissipation does not occur immediately. The time this takes depends on a
series of factors, including the amount and type of oil spilled, the weather
conditions and whether the oil stays at sea or is washed ashore.
Sometimes, the process is quick and on other occasions it can be slow,
especially in sheltered and calm areas of water.
A number of models are available for predicting the trajectory and
dispersion of oil spills at sea. These can serve as a useful guide to
understanding how a particular oil is likely to behave and help in assessing
the scale of the problem which a spill might generate.
Weathering Process
Most of the weathering processes, such as evaporation, dispersion,
dissolution and sedimentation, lead to the disappearance of oil from the
surface of the sea, whereas others, particularly the formation of water-inoil emulsions ("mousse") and the accompanying increase in viscosity,
promote its persistence. The speed and relative importance of the
processes depend on factors such as the quantity and type of oil, the
prevailing weather and sea conditions, and whether the oil remains at sea
or is washed ashore. Ultimately, the marine environment assimilates
spilled oil through the long-term process of biodegradation.
The eight main processes that cause an oil to weather are described below
and summarised in the following diagram.
Figure 1: Fate of oil spilled at sea showing the main weathering processes
Spreading
As soon as oil is spilled, it starts to spread out
over the sea surface, initially as a single slick.
The speed at which this takes place depends
to a great extent upon the viscosity of the oil.
Fluid, low viscosity oils spread more quickly
than those with a high viscosity. Nevertheless,
slicks quickly spread to cover extensive areas
of the sea surface. Spreading is rarely uniform
and large variations in the thickness of the oil
are typical. After a few hours the slick will
begin to break up and, because of winds,
wave action and water turbulence, will then form narrow bands or
windrows parallel to the wind direction. The rate at which the oil spreads is
also determined by the prevailing conditions such as temperature, water
currents, tidal streams and wind speeds. The more severe the conditions,
the more rapid the spreading and breaking up of the oil.
Evaporation
Lighter components of the oil will evaporate to the atmosphere. The
amount of evaporation and the speed at which it occurs depend upon the
volatility of the oil. An oil with a large percentage of light and volatile
compounds will evaporate more than one with a larger amount of heavier
compounds. For example, petrol, kerosene and diesel oils, all light
products, tend to evaporate almost completely in a few days whilst little
evaporation will occur from a heavy fuel oil. In general, in temperate
conditions, those components of the oil with a boiling point under 200C
tend to evaporate within the first 24 hours. Evaporation can increase as
the oil spreads, due to the increased surface area of the slick. Rougher
seas, high wind speeds and high temperatures also tend to increase the
rate of evaporation and the proportion of an oil lost by this process.
Dispersion
Waves and turbulence at the sea surface can cause all or part of a slick to
break up into fragments and droplets of varying sizes. These become
mixed into the upper levels of the water column. Some of the smaller
droplets will remain suspended in the sea water while the larger ones will
tend to rise back to the surface, where they may either coalesce with
other droplets to reform a slick or spread out to form a very thin film. The
oil that remains suspended in the water has a greater surface area than
before dispersion occurred. This encourages other natural processes such
as dissolution, biodegradation and sedimentation to occur.
The speed at which an oil disperses is largely dependent upon the nature
of the oil and the sea state, and occurs most quickly if the oil is light and
of low viscosity and if the sea is very rough. These factors led to the
complete dispersion of the oil spilled from the BRAER (Shetland Islands,
United Kingdom, 1993).
The addition of chemical dispersants can accelerate this process of natural
dispersion.
Emulsification
An emulsion is formed when two liquids
combine, with one ending up suspended in the
other. Emulsification of crude oils refers to the
process whereby sea water droplets become
suspended in the oil. This occurs by physical
mixing promoted by turbulence at the sea
surface. The emulsion thus formed is usually
very viscous and more persistent than the
original oil and is often referred to as chocolate
mousse because of its appearance. The formation of these emulsions
causes the volume of pollutant to increase between three and four times.
This slows and delays other processes which would allow the oil to
dissipate.
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Oils with an asphaltene content greater than 0.5% tend to form stable
emulsions which may persist for many months after the initial spill has
occurred. Those oils containing a lower percentage of asphaltenes are less
likely to form emulsions and are more likely to disperse. Emulsions may
separate into oil and water again if heated by sunlight under calm
conditions or when stranded on shorelines.
Dissolution
Water soluble compounds in an oil may dissolve into the surrounding
water. This depends on the composition and state of the oil, and occurs
most quickly when the oil is finely dispersed in the water column.
Components that are most soluble in sea water are the light aromatic
hydrocarbons compounds such as benzene and toluene. However, these
compounds are also those first to be lost through evaporation, a process
which is 10 -100 times faster than dissolution. Oil contains only small
amounts of these compounds making dissolution one of the less important
processes.
Oxidation
Oils react chemically with oxygen either breaking down into soluble
products or forming persistent compounds called tars. This process is
promoted by sunlight and the extent to which it occurs depends on the
type of oil and the form in which it is exposed to sunlight. However, this
process is very slow and even in strong sunlight, thin films of oil break
down at no more than 0.1% per day. The formation of tars is caused by the
oxidation of thick layers of high viscosity oils or emulsions. This process
forms an outer protective coating of heavy compounds that results in the
increased persistence of the oil as a whole. Tarballs, which are often found
on shorelines and have a solid outer crust surrounding a softer, less
weathered interior, are a typical example of this process.
Sedimentation/Sinking
Some heavy refined products have densities
greater than one and so will sink in fresh or
brackish water. However sea water has a
density of approximately 1.025 and very few
crudes are dense enough or weather
sufficiently, so that their residues will sink in
the marine environment. Sinking usually
occurs due to the adhesion of particles of
sediment or organic matter to the oil. Shallow
waters are often laden with suspended solids
providing favourable conditions for sedimentation.
Oil stranded on sandy shorelines often becomes mixed with sand and
other sediments. If this mixture is subsequently washed off the beach back
into the sea it may then sink. In addition, if the oil catches fire after it has
been spilled, the residues that sometimes form can be sufficiently dense
to sink.
Biodegradation
Sea water contains a range of micro-organisms or microbes that can
partially or completely degrade oil to water soluble compounds and
eventually to carbon dioxide and water. Many types of microbe exist and
each tends to degrade a particular group of compounds in crude oil.
However, some compounds in oil are very resistant to attack and may not
degrade.
The main factors affecting the efficiency of biodegradation, are the levels
of nutrients (nitrogen and phosphorus) in the water, the temperature and
the level of oxygen present. As biodegradation requires oxygen, this
process can only take place at the oil-water interface since no oxygen is
available within the oil itself. The creation of oil droplets, either by natural
or chemical dispersion, increases the surface area of the oil and increases
the area available for biodegradation to take place.
Combined processes
The processes of spreading, evaporation, dispersion, emulsification and
dissolution are most important during the early stages of a spill whilst
oxidation, sedimentation and biodegradation are more important later on
and determine the ultimate fate of the oil. To understand how different oils
change over time whilst at sea, one needs to know how these weathering
processes interact. To predict this, some simple models have been
developed based on oil type. Oils have been classified into groups roughly
according to their density - generally, oils with a lower density will be less
persistent. However some apparently light oils can behave more like heavy
ones due to the presence of waxes. Although simple models cannot predict
the changes an oil undergoes very precisely, they can provide clues about
whether an oil is likely to dissipate naturally or whether it will reach the
shoreline. This information can be used by spill responders to decide upon
the most effective spill response techniques and whether such techniques
can be initiated quickly enough.
Persistence of Oil
The concept of persistence in relation to oil spills probably originated after
the TORREY CANYON incident in 1967. This is the time when discussions
first arose regarding various new measures to protect the marine
environment and to manage marine oil spills, particularly in relation to
liability and compensation. Generally, persistent oils contain a
considerable proportion of heavy fractions or high-boiling material. They
do not dissipate quickly and will therefore pose a potential threat to
natural resources when released to the environment. Such threats are
evident in terms of impacts to wildlife, smothering of habitats and oiling of
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Models
Modelling of the likely fate and behaviour of oil once spilled can follow a
number of different approaches. These range from a simple vector
calculation, to estimate the probable twodimensional trajectory of the
centre point of a slick, to sophisticated computer models of the movement
and distribution of the oil in three dimensions with the concurrent
predictions of the change in properties as the oil weathers. The main
properties which affect the fate of spilled oil at sea are specific gravity (its
density relative to pure water - often expressed as API* or API gravity);
distillation characteristics (its volatility); viscosity (its resistance to flow);
and pour point (the temperature below which it will not flow). In addition
the wax and asphaltene content influence the likelihood that the oil will
mix with water to form a water-in-oil emulsion. Oils which form stable oilin-water emulsions persist longer at the water surface.
Density
Examples
GroupI
Gasoline, Kerosene
GroupII
0.8 - 0.85
GroupIII
0.85 - 0.95
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Environmental Impact
The exact nature and duration of any impacts from an oil spill depend on a
number of factors. These include the type and amount of oil and its
behaviour once spilled; the physical characteristics of the affected area;
weather conditions and season; the type and effectiveness of the clean-up
response; the biological and economic characteristics of the area and their
sensitivity to oil pollution. Typical effects on marine organisms range
across a spectrum from toxicity (especially for light oils and products) to
smothering (heavier oils and weathered residues). The presence of toxic
components does not always cause mortality, but may induce temporary
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effects like narcosis and tainting of tissues, which usually subside over
time. Some typical oil impacts are described below.
Plankton
The importance of plankton in primary productivity of the oceans and as a
temporary home for the eggs and larvae of fish, shellfish, sea bed and
shoreline organisms is well known, but is there evidence of widespread
harm to these functions from spills which subsequently translates into long
term damage? Laboratory studies have demonstrated toxic and sub-lethal
effects on the plankton caused by oil, and there is little doubt that there is
potential for widespread impact. Unfortunately, plankton is extremely
difficult to study reliably because they are amongst the most variable of
marine communities in space and in time. The presence of oil on open
water is also patchy and transient, making it difficult to establish where
and when the plankton might have been exposed to the oil. Whilst the
possibility of long-term effects can not be excluded, there is no indication
that oil-induced losses of eggs and larval stages cause a significant decline
in adult populations.
Seabirds
Seabirds are amongst the most
vulnerable inhabitants of open waters
since they are easily harmed by floating
oil. Species that dive for their food or
which congregate on the sea surface are
particularly at risk. Although oil ingested
by birds during attempts to clean
themselves by preening may be lethal,
the most common cause of death is from
drowning, starvation and loss of body
heat following fouling of plumage by oil.
Cleaning and rehabilitation after oiling is often attempted, but for many
species it is rare for more than a fraction of oiled birds to survive cleaning
and rarer still for those that survive to breed successfully after release.
Penguins are an exception and are much more resilient than most other
birds. When handled properly, the majority are likely to survive the
cleaning process and rejoin breeding populations.
Bird mortality occurs during most spills and in some major spills breeding
colonies have been seriously depleted. Some species react to colony
depletion by laying more eggs, breeding more frequently or younger birds
joining the breeding group. These processes can assist recovery, although
recovery may take several years and will also depend on other factors like
food supply. Whilst it is common for short and medium term loss to occur
in populations, there is scant evidence of spills causing long-term harm to
populations, or of a spill tipping a marginal colony into permanent decline.
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Sea Mammals
Whales, dolphins and seals in the open
sea do not appear to be particularly at
risk from oil spills. Marine mammals
such as seals and otters that breed on
shorelines are, however, more likely to
encounter oil. Species which rely on fur
to regulate their body temperature are
the most vulnerable since, if the fur
becomes matted with oil, the animals
may die from hypothermia or
overheating, depending on the season.
Shorelines
Shorelines, more than any other part of
the marine environment, are exposed to
the effects of oil as this is where it
naturally tends to accumulate. However,
many of the animals and plants on the
shore are inherently tough since they
must be able to tolerate periodic
exposure to pounding waves, drying
winds, high temperatures, rainfall and
other severe stresses. This tolerance also
gives many shoreline organisms the
ability to withstand and recover from oil spill effects.
Rocky and sandy shores exposed to wave action and the scouring effects
of tidal currents tend to be resilient to the effects of a spill as they usually
self-clean quite rapidly. Rocky shores exposed to wave action are often
quoted as those which recover most rapidly, and there have been many
cases in which this was true. A typical example of impact on this habitat is
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Recovery
Natural Recovery
Marine organisms have varying degrees of natural resilience to changes in
their habitats. The natural adaptations of populations of animals and
plants to cope with environmental stress, combined with their breeding
strategies, provide important mechanisms for coping with the daily and
seasonal fluctuations in their habitats and for recovering from predation
and other stochastic events.
Some natural phenomena can be highly destructive. The short-term power
of hurricanes and tsunamis can easily be appreciated, as can the damage
they cause. The cyclical El Nio phenomenon has major long-term
consequences for marine organisms, seabirds and marine mammals
throughout the entire Pacific Ocean. Organisms suffer under such
onslaughts, but after what is often severe disruption and widespread
mortality, the marine populations re-establish themselves over a period of
time and this process constitutes natural recovery.
An important reproductive strategy for
many marine organisms is the
production of vast numbers of eggs and
larvae which are released into the
plankton and are widely distributed by
currents. This mechanism has evolved
to take maximum advantage of
available space and resources in marine
habitats and to deal with e.g. predation.
In some cases, only one or two
individuals in a million actually survive through to adulthood.
A less common reproductive strategy that is generally restricted to longlived species that do not reach sexual maturity for many years is to
produce relatively few, well-developed, offspring. These species are better
adapted to stable habitats and environments and as a result, their
populations are likely to take much longer to recover from the pressures of
localised mortality e.g. the effects of an oil spill.
Whilst there may be considerable debate over what constitutes recovery,
there is a widespread acceptance that natural variability in systems makes
getting back to the exact pre-spill condition unlikely, and most current
definitions of recovery focus on the re-establishment of a community of
plants and animals which are characteristic of the habitat and are
functioning normally in terms of biodiversity and productivity.
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Restoration
Removal of bulk oil contamination either through natural processes or a
well-conducted clean up operation is the first stage of the recovery and
restoration of a damaged environment. Dependent on the scale and nature
of the spill, for many marine habitats, the clean up operation is all that is
necessary to promote natural recovery, and there is little further that can
be done to speed up this process.
However, in some cases, especially in circumstances where habitat
recovery would otherwise be relatively slow, the clean up operation can be
followed by further measures which help restore a habitat structure. An
example of such an approach following an oil spill would be to replant an
area of salt marsh or mangrove after the bulk oil contamination has been
removed. In this way erosion of the area would be minimised and other
forms of biological life would be encouraged to return.
A salt marsh impacted by an oil spill before (left) and after (right)
replanting
Post-spill Studies
The short-term effects of oil spills on many marine species and
communities are well known and predictable, but concerns are often
raised about possible longer-term ("sub-lethal") population effects.
Extensive research and detailed post-spill studies have shown that many
components of the marine environment are highly resilient to short-term
adverse changes, including oil spills, and as a result even a major oil spill
will rarely cause permanent effects.
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above the sea surface are more likely to become contaminated by floating
oil, whereas submerged nets, pots, lines and bottom trawls are usually
well protected provided they are not lifted through an oily sea surface.
However, they may sometimes be affected by dispersed or sunken oil.
Less common is mortality of stock, which can be caused by physical
contamination or close contact with freshly spilled oil in shallow waters
with poor water exchange.
A common cause of economic loss to
fishermen is interruption to their activities by
the presence of oil or the performance of
clean-up operations. Sometimes this results
from a precautionary ban on the catching
and sale of fish and shellfish from the area,
both to maintain market confidence and to
protect fishing gear and catches from
contamination. Cultivated stocks are more at
risk from an oil spill: natural avoidance
mechanisms may be prevented in the case of captive species, and the
oiling of cultivation equipment may provide a source for prolonged input of
oil components and contamination of the organisms. Cultured seaweed
and shellfish are particularly vulnerable in tidal areas where they may
become contaminated with oil as the tide drops.
It is almost always necessary to make a thorough investigation of the
status of a fishery and alleged effects of a spill, in order to determine the
real impacts. This will often require scientifically rigorous sampling and
analytical techniques which are capable of documenting the damage and
providing proof that any damage observed has been caused by the oil in
question. Nevertheless, separating spill effects from other factors which
affect fisheries is frequently problematic. Wild stocks of commercial
species are in decline in many parts of the world because of over-fishing,
industrial pollution, destruction of coastal habitats and other natural
factors such as increasing sea temperature. Similarly, mariculture is often
ravaged by disease or suffers from the accumulation of its own wastes.
Therefore, in order to make the best assessment of damages attributed to
contamination by oil it is necessary to make comparisons of post-spill
recovery results with the conditions which pre-existed the spill or with
control areas outside the affected area.
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Return to top
Historically, vegetable oils have been considered relatively benign, nontoxic and therefore of limited concern to the environment. However, this
generalisation has been demonstrated to be incorrect. Previous experience
has shown that both chronic and acute pollution incidents can lead to
deleterious effects. This awareness has led to the reclassification of many
vegetable oils as category Y (hazardous) products under Annex II of the
MARPOL Convention with associated limitations on their carriage.
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(Note, the appearance and characteristics of the oil are dependent on a number of factors, such as
the degree of processing, see above)
Response Techniques
With the tendency of some vegetable oils to polymerise and form solid
lumps, the most appropriate response technique is that of containment
and recovery. Ideally, these floating lumps should be removed from the
water surface before they have a chance to accumulate sediment and sink
and before they are able to reach the shoreline.
Response techniques applied during previous incidents involving a spill of
vegetable oil include the use of conventional boom for containment,
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About HNS
The volume of chemicals transported by sea is increasing but remains
significantly lower than the seaborne trade in oil. In addition recent ITOPF
experience shows that spills of bunker fuel from all types of ship are at
least as likely to occur as loss of cargo oil from a tanker. Consequently
chemical spills occur at a much lower frequency than spills of oil. However,
the consequence of a chemical spill can be more wide reaching than that
of oil and there is growing international awareness of the need for safe and
effective contingency arrangements for chemical spills. The wide variety of
chemicals transported, their varying physical and chemical properties, the
different ways in which they behave in the environment and the potential
for effects on human health mean that response to chemical spills is not as
straightforward as for oil.
What are Hazardous and Noxious Substances (HNS)?
Human Health Aspects
Effects on Marine Resources
Fate of Chemicals in the Marine Environment
Chemical Response Strategies
Explosive
Toxic
Corrosive
Reactive
Bulk Liquids
Gases
Solids in bulk
1. Identification
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2. Hazard(s) identification
3. Composition/ingredients
4. First-aid measures
5. Fire-fighting measures
8. Exposure controls/personal
protection
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This easily accessible and simple guide provides an important first step in
evaluating the severity of a spill.
MARPOL
The MARPOL Convention is the main international convention covering
prevention of pollution from the shipping industry. Within MARPOL are two
annexes that are directly relevant to HNS:
Annex II
MARPOL Annex II contains regulations for bulk liquid cargos that may
cause environmental pollution if lost at sea. Within the annex are four
categories that are graded depending on the hazard the bulk liquid
presents to marine resources, human health and amenities.
Category X liquid substances which are deemed to present a major
hazard to either marine resources or human health, and therefore justify
the prohibition of the discharge into the marine environment.
Category Y liquid substances which are deemed to present a hazard to
either marine resources or human health or cause harm to amenities or
other uses of the sea and therefore justify a limitation on the quality and
quantity of the discharge into the marine environment.
Category Z liquid substances which are deemed to present a minor
hazard to either marine resources or human health and therefore justify
less stringent restrictions on the quality and quantity of the discharge into
the marine environment.
Category OS these other substances are deemed to fall outside of
categories X, Y, and Z and are deemed to present no harm to marine
resources, human health, amenities or other uses of the marine
environment.
Annex III
Annex III deals with the provisions for the
prevention of pollution by harmful
substances carried by seas in packaged
form. As part of these regulations, any
compounds that are environmentally
harmful (known as marine pollutants) must
be clearly marked and labelled as a marine
pollutant (see Figure 1) to distinguish them
from less harmful cargos.
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Properties
evaporate immediately
evaporate immediately
float, evaporate rapidly
evaporate rapidly, dissolve
float, evaporate
float, evaporate, dissolve
F
FD
DE
D
SD
S
float
float, dissolve
dissolve rapidly, evaporate
dissolve rapidly
sink, dissolve
sink
floater
floater/dissolver
dissolver/evaporator
dissolver
sinker/dissolver
sinker
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chain)
level.
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