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Documents MSDSVendors 2015 June 02-23-18!33!271 PM
Documents MSDSVendors 2015 June 02-23-18!33!271 PM
ChemWatch Company
Chemwatch: 4143-99
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified
uses
Reagent.
Chelating agent [~Regeant ~]
Sigma-Aldrich
12 Anella Avenue Castle Hill 2154 NSW Australia
+61 2 9841 0555; 1800 800 097
+61 2 9841 0500
www.sigma-aldrich.com
ausmail@sial.com
Not Available
Emergency telephone
numbers
Other emergency
telephone numbers
Not Available
Flammability
Toxicity
Body Contact
Reactivity
Chronic
1
1
0
1
2
0 = Minimum
1 = Low
2 = Moderate
3 = High
4 = Extreme
Poisons Schedule
GHS Classification
Max
[1]
Legend:
Not Applicable
Skin Sensitizer Category 1, Carcinogen Category 2, Chronic Aquatic Hazard Category 4
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex
VI
Label elements
Continued...
Chemwatch: 4143-99
Page 2 of 8
SIGNAL WORD
WARNING
Hazard statement(s)
H317
H351
H413
P280
P281
P261
P302+P352
P333+P313
%[weight]
Name
699012-90-3
>98
Mixtures
See section above for composition of Substances
Eye Contact
Skin Contact
Inhalation
Ingestion
Continued...
Chemwatch: 4143-99
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Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
result
Fire Fighting
Fire/Explosion Hazard
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water courses.
Use water delivered as a fine spray to control fire and cool adjacent area.
Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible
(circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause fires
and / or dust explosions.
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended
in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including
secondary explosions).
Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive
mixture with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the
fine grinding of the solid are a particular hazard; accumulations of fine dust (420 micron or less) may burn rapidly and
fiercely if ignited - particles exceeding this limit will generally not form flammable dust clouds; once initiated, however,
larger particles up to 1400 microns diameter will contribute to the propagation of an explosion.
Minor Spills
Major Spills
Safe handling
Continued...
Chemwatch: 4143-99
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Other information
Suitable container
Storage
incompatibility
Material name
TEEL-1
TEEL-2
TEEL-3
TRIS(ETHYLENEDIAMINE)NICKEL(II)
CHLORIDE HYDRATE
Not Available
Not Available
Not Available
Not Available
Ingredient
Original IDLH
Revised IDLH
tris(ethylenediamine)nickel(II)
chloride hydrate
Not Available
Not Available
Exposure controls
Appropriate
engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and
ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Recommended material(s)
Respiratory protection
Continued...
Chemwatch: 4143-99
Page 5 of 8
CPI
Particulate. (AS/NZS 1716 & 1715, EN 143:000 & 149:001, ANSI Z88 or
national equivalent)
Required Minimum
Protection Factor
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES
P1
Air-line*
PAPR-P1
-
up to 50 x ES
Air-line**
P2
PAPR-P2
up to 100 x ES
P3
Air-line*
Air-line**
PAPR-P3
100+ x ES
Physical state
Divided Solid
Relative density
(Water = 1)
Not Available
Odour
Not Available
Partition coefficient
n-octanol / water
Not Available
Odour threshold
Not Available
Auto-ignition
temperature (C)
Not Available
pH (as supplied)
Not Applicable
Decomposition
temperature
Not Available
Not Available
Viscosity (cSt)
Not Applicable
Melting point /
freezing point (C)
Initial boiling point
and boiling range (C)
Molecular weight
(g/mol)
170
Not Available
Evaporation rate
Taste
Not Available
Not Applicable
Explosive properties
Not Available
Not Available
Not Available
Oxidising properties
Not Available
Surface Tension
(dyn/cm or mN/m)
Not Available
Volatile Component
(%vol)
Negligible
Flammability
Solubility in water
(g/L)
Vapour density (Air =
1)
309.9
Miscible
Not Applicable
Negligible
Gas group
Not Available
pH as a solution (1%)
Not Available
VOC g/L
Not Available
Not Applicable
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of
hazardous reactions
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
Continued...
Chemwatch: 4143-99
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Hazardous
decomposition
products
See section 5
Inhaled
Ingestion
The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced following
exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and
that suitable control measures be used in an occupational setting.
Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may
incur further disability if excessive concentrations of particulate are inhaled.
If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper
screenings should be conducted on individuals who may be exposed to further risk if handling and use of the material result
in excessive exposures.
Accidental ingestion of the material may be damaging to the health of the individual.
Nickel is not well absorbed orally. Excretion in the urine is complete after about 4-5 days.
Nickel salts cause vomiting, following ingestion as a result of the irritant effects.
Skin Contact
The material is not thought to produce adverse health effects or skin irritation following contact (as classified by EC
Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that
suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful
effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Eye
Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may cause
transient discomfort characterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also
result.
Chronic
There has been concern that this material can cause cancer or mutations, but there is not enough data to make an
assessment.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general
population.
There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared
to the general population.
Nickel causes a skin sensitisation which may produce a chronic eczema.
tris(ethylenediamine)nickel(II)
chloride hydrate
Legend:
TOXICITY
IRRITATION
Not Available
Not Available
1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
TRIS(ETHYLENEDIAMINE)NICKEL(II)
CHLORIDE HYDRATE
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's
oedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of
the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune
reactions.
Acute Toxicity
Carcinogenicity
Skin
Irritation/Corrosion
Reproductivity
Serious Eye
Damage/Irritation
STOT - Single
Exposure
Respiratory or Skin
sensitisation
STOT - Repeated
Exposure
Mutagenicity
Aspiration Hazard
Legend:
CMR STATUS
Not Applicable
Continued...
Chemwatch: 4143-99
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Persistence: Water/Soil
Persistence: Air
Bioaccumulative potential
Ingredient
Bioaccumulation
No Data available for all ingredients
Mobility in soil
Ingredient
Mobility
No Data available for all ingredients
Product / Packaging
disposal
NO
Not Applicable
"Not Applicable"
National Inventory
Status
Australia - AICS
Canada - DSL
China - IECSC
Europe - EINEC /
ELINCS / NLP
Japan - ENCS
Korea - KECI
Continued...
Chemwatch: 4143-99
Page 8 of 8
Philippines - PICCS
USA - TSCA
Legend:
Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not
exempt from listing(see specific ingredients in brackets)
end of SDS