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EdExcel A Level Chemistry Unit 7 Mark Scheme Jan 2000
EdExcel A Level Chemistry Unit 7 Mark Scheme Jan 2000
1.
(a)
(i)
(ii)
Kc =
NH 3 2
N 2 . H 2 3
moles at
start
moles at eq
[] at eq
N2
H2
NH 3
.........
given
.........
3.0
0.30
9.0
0.90
12
1.2
(1)
(1)
(iv)
(v)
(b)
(i)
1.22
= 6.6 /6.58 (1)
3
0.3 0.9
mol2 dm6 (1)
Mark (iii) consequentially on the values given for [ ] in part (ii)
Unit mark consequential.
Effect of T increase on K:
lowers its value(1)
Reason: reaction driven in endothermic direction (1)
Effect of P increase on K:
none(1)
Reason: Kc only altered by change in temperature / equilibrium
moves to maintain the value of Kc (1)
Kc =
Reactants (4NH 3 + 5O 2 )
Enthalpy
Hr or ()905.6 kJ mol 1
Correct levels
consequential on sign of
answer in (i) (1)
Labelled H line (1)
Products (4NO + 6H 2 O)
et
(c)
(i)
(ii)
(iii)
1
2
HSO 4
(1) H
NO 2
(1)
(1) NO 2+
or kekul form
(iv)
NO 2
+
(v)
H /H 2 SO 4
1
[22]
2.
(a)
(b)
k [H2O2] (1)
(i)
Rate =
(ii)
(iii)
et
(iv)
(c)
3.
(a)
(i)
(ii)
CH 3
H
C
(1)
CH 3
CH 2
CH 2
H
C
and
(b)
CH 3
CH 3
CHO
H
C
CH 3
CH 2
CH 2
(1)
CHO
C
CH 3
C
H
(i)
(ii)
Br Br
CH 3
Br Br
CH 2
CH 2
1
1
H
C
O
CH 3 H
(iii)
CH 3 H
(i)
(ii)
PCl5 (1) steamy/white/misty fumes / valid test for HCl gas (1)
or
Na(1) fizzes / gives gas that burns with a squeaky pop(1)
et
(e)
(i)
(ii)
(iii)
pH = 2.91
thus [H+] = 1.23 103 (mol dm3) (1)
Ka = [H+]2/[HA] or Ka = (1.23 103 )2 / 0.11(1)
= 1.38 105 mol dm 3(1)
3
[20]
et