Professional Documents
Culture Documents
Mark Scheme: Advanced Extension Award Chemistry 6821
Mark Scheme: Advanced Extension Award Chemistry 6821
Mark Scheme: Advanced Extension Award Chemistry 6821
0: 08/05
abc
Mark Scheme
2005 examination - June series
Mark schemes are prepared by the Principal Examiner and considered, together with the
relevant questions, by a panel of subject teachers. This mark scheme includes any
amendments made at the standardisation meeting attended by all examiners and is the scheme
which was used by them in this examination. The standardisation meeting ensures that the
mark scheme covers the candidates responses to questions and that every examiner
understands and applies it in the same correct way. As preparation for the standardisation
meeting each examiner analyses a number of candidates scripts: alternative answers not
already covered by the mark scheme are discussed at the meeting and legislated for. If, after
this meeting, examiners encounter unusual answers which have not been discussed at the
meeting they are required to refer these to the Principal Examiner.
It must be stressed that a mark scheme is a working document, in many cases further
developed and expanded on the basis of candidates reactions to a particular paper.
Assumptions about future mark schemes on the basis of one years document should be
avoided; whilst the guiding principles of assessment remain constant, details will change,
depending on the content of a particular examination paper.
Further copies of this Mark Scheme are available to download from the AQA Website: www.aqa.org.uk
Copyright 2005 AQA and its licensors. All rights reserved.
COPYRIGHT
AQA retains the copyright on all its publications. However, registered centres for AQA are permitted to
copy material from this booklet for their own internal use, with the following important exception: AQA
cannot give permission to centres to photocopy any material that is acknowledged to a third party even for
internal use within the centre.
Set and published by the Assessment and Qualifications Alliance.
The Assessment and Qualifications Alliance (AQA) is a company limited by guarantee registered in England and Wales 3644723 and a registered charity
number 1073334. Registered address AQA, Devas Street, Manchester. M15 6EX.
Dr Michael Cresswell Director General.
Question 1
(1)
(1)
(b)
(1)
(c)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(a)
(d)
= 9.25 10-4;
= 4.625 10-4 ;
= 0.0346 g;
Question 2
0.5
(a)
(i)
Kp =
pH 2 x pO2
pH 2 O
(1)
H2O
Moles
1-0.05
H2
0.05
O2
0.025
Mole fraction
0.95/1.025
i.e. 0.927
0.05/1.025
i.e. 0.0488
0.025/1.025
i.e. 0.0244
(1)
5.61 kPa
0.556
(1)
2.80 kPa
0.0278
(1)
(ii)
(iii)
(b)
(i)
(1)
(1)
(1)
(1)
Reaction endothermic;
Kp increases as T increases;
(allow conseq to inverted Kp)
Kp unchanged with change in pressure;
(allow correct answers based on G and T S)
not suitable for the manufacture of hydrogen
reason e.g.
yield too small,
cost (of energy) to generate 3000K OR are too high;
k1 small hence activation energy high OR
k2 larger hence activation energy low;
k1 small because covalent bond must be broken;
k2 larger because ions of opposite charge attract;
(mark M2 and M3 separately)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(ii)
(1)
(1)
Kc
(1)
4
= k1/ k2;
= 2.50 10-5 / 1.39 1011 = 1.80 10-16 mol dm-3; (1)
(iv)
(c)
(i)
(1)
(1)
(1)
(1)
(1)
Ka
= 1.26 10-5;
+
[H ] = 3.55 10-3;
%
= 0.355% or 0.036 or 0.059% if all 6 water molecules are
considered;
Al3+ ions polarise co-ordinated water causing either release of ions or
O - H bonds weakened;
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
Question 3
(a)
CH2
Cl
NH 2
NH 2
H2C
H2 N
CH2
Co
H2C
H2 C
NH 2
NH 2
Co
CH2
H2 N
NH 2
Cl
Cl
Co
Cl
NH 2
H2 N
CH2
(1)
(b)
H2 N
Cl
H2 C
Cl
CH2
CH2
NH 2
NH 2
CH 2
CH2
(1)
(1)
(1)
F2 2F ;
Xe + F XeF ;
XeF + F2 XeF2 + F or XeF + F XeF2;
(1)
(1)
(1)
(1)
(i)
(iii)
XeF2
a diagram showing linear shape ;
three lone pairs around Xe;
..
..
F
Xe
(1)
(1)
..
XeF4
a diagram showing square planar shape;
two lone pairs around Xe;
..
(1)
(1)
Xe
F
..
XeF5-
(iv)
a diagram with five bond and two lone pairs around Xe;
bond angle = 72o;
allow lone pairs shown as or but bonds must be lines
penalise Xe F once only
CE = 0 if number of lone pairs incorrect in XeF2 and XeF4
(1)
(1)
[XeF]+[SbF6]-;
(1)
Xe
F :
SbF5 ;
(2)
(1)
F
(v)
(vi)
Xe
SbF5
(1)
(1)
(1)
(c)
M1
M2
M3
M4
M5
M6
M7
M8
M9
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
Question 4
(a)
Cl2 2Cl
(i)
(1)
(1)
(1)
(1)
CH3CH2CH2CH2Cl;
Ratio 3:2 for 1-chloro : 2 chloro from ratio of H atoms;
the reason must be justified
!
The radical CH3CHCH2CH3 is planar around C ;
Therefore attack from either side;
allow M2 only if M1 is given correctly
(1)
(1)
(1)
(1)
(2)
(1)
(ii)
(iii)
(iv)
(b)
(i)
CH3 CH2
..
CH3
CH3 CH2
C= O
CH3
C
CH3
CH3
CH3
CH3 CH2 C CH 3
O:
H
(1)
OH
(1)
(1)
(iii)
CH3CH2COOH
do not allow the name
CH3 CHO
(1)
OH
CH3 CH2 C CH 3
H
(1)
allow name
K2Cr2O7 / H+ or name but not KMnO4
(1)
CH 3 CH2 CCH
(1)
OH
CH 3 CH2
C CH2 CH3
(1)
CH3
(1)
(1)
(c)
H
A
CH2 = CH - C - COOH
CH 3
B/C/D
CH3
COOH
C C
C C
H
CH3
(1)
CH3
H
H
(1)
CH3
CH2 COOH
(1)
COOH
C C
CH2 CH3
(1)
COOCH 3
C C
H
(1)
10
CH3 COO
F
CH3 COOCH 2
C
CH3
or
H
C
or
H
H2C
H2C
OOCCH 3
(1)
C=O
O
CH 3
H
C
O
O
I
(1)
CH 3
(1)
CH 3
CH3
C=C=C
HO
C
C-H
or H - C
OH
O
CH 3 CH3
(1)
O
J
C
H2 C
CH 2
H2 C
CH2
(1)
11
10
Question 5
(a)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
Max 17
C
W
A
(1)
(1)
(1)
Max 3
12
(b)
M1
M2
M4
M5
M6
M7
M1
M2
M3
M3
M4
M5
M6
M1
M2
M3
M4
M5
M6
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
(1)
Max 17
QWC correct use of technical language in at least one section
written in sentences and all 3 examples considered
answers presented in a logical form in not less than 2 sections
C
W
A
(1)
(1)
(1)
Max 3
13