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Soal-Soal Kimia Anorganik
Soal-Soal Kimia Anorganik
18.187 Drinking water is often disinfected with chlorine gas, which hydrolyzes to form
hypochlorous acid (HCIO), a weak acid but poweIful disinfectant:
Cl2(aq) + 2H2O(l) ----+ HCIO(aq) + H30+(aq) + CI-(aq)
The fraction of HOCI in solution is defined as
[HOCl]
[HOCI] + [OCI-]
(a) What is the fraction of HOCI at pH 7.00 (Ka of HCIO = 2.9 X 10- 8 )?
(b) What is the fraction at pH 10.OO?
14.165 Carbon tetrachloride is made by passing Cl2 in the presence of a catalyst through
liquid CS2 near its boiling point. Disulfur dichloride (S2Cl2) also forms, in addition to the
by-products SCl2 and CCl3SCl. How many grams of CS2 reacted if excess Cl2 yielded 50.0
g of CC4 and 0.500 g of CCI3SCl? Is it possible to determine how much S2Cl2 and SCl2
also formed? Explain.
14.167 P4 is prepared by heating phosphate rock [principally Ca3(P04)2] with sand and
coke: Ca3(P04)2(S) + SiO2(s) + C(s) -- CaSi03 (s) + CO(g) + P4(g) [unbalanced]
How many kilograms of phosphate rock are needed to produce 315 mol of P4, assuming
that the conversion is 90 % efficient?