SEKOLAH MENENGAH KEBANGSAAN DERMA,

01000 KANGAR,PERLIS
CHEMISTRY SPM 2015
PAPER 1
SOALAN ARAS TINGGI
1

The figure shows a symbol of an atom.

(Rajah menunjukkan simbol bagi suatu atom)

24

X
12
Which of the following is true about an ion formed from the atom?
(Antara berikut yang manakah benar tentang ion yang terbentuk daripada atom tersebut?)

A
B
C
D
2

Number of protons
(Bilangan proton)
10
12
12
12

Nucleon number
(Nombor nukleon)
24
24
20
24

Number of electrons
(Bilangan elektron)
12
10
10
12

The table shows the information for two types of particles.

(Jadual menunjukkan maklumat bagi dua jenis zarah.)
Particle
(Zarah)
J
K

Proton number
(Nombor proton)
8
15

Electron arrangement
(Susunan elektron)
2.8
2.8.8

Based on the information in the table, particle J and particle K are

(Berdasarkan maklumat dalam jadual, zarah J dan zarah K ialah)
A
B
C
D
3

inert gases (gas lengai)

negative ions (ion negatif)
atoms of metals (atom logam)
isotopes of the same element (isotop unsur yang sama)

Element X is below potassium in the Periodic Table. We can predict that

(Unsur X berada di bawah kalium dalam Jadual Berkala. Boleh diramalkan bahawa)
A
B
C
D

Element X is less electropositive than potassium

(Unsur X adalah kurang elektropositif daripada kalium)
The size of atom X is smaller than potassium
(Saiz atom X adalah lebih kecil daripada kalium)
Atom of element X has more valence electrons than potassium
(Atom unsur X mempunyai lebih banyak bilangan elektron valens daripada kalium)
Element X reacts more vigorously than potassium in oxygen
(Unsur X bertindak balas lebih cergas berbanding kalium dalam oksigen)

Element P has a proton number of 17. It can be deduced that

(Unsur P mempunyai nombor proton 17. Boleh disimpulkan bahawa)
A
B
C
D

it is located at Period 2
(ia berada di kala 2)
it has 17 valence electrons
(ia mempunyai 17 elektron valens)
it has three electrons in the outermost shell
(ia mempunyai tiga elektron di petala terluar)
it has three shells filled with electrons
(ia mempunyai tiga petala berisi elektron)

The diagram shows the electron arrangement of atom X

(Rajah menunjukkan susunan elektron atom X)

X
Which of the following atoms cannot form covalent bond with atom X?
(Antara atom berikut yang manakah tidak boleh membentuk ikatan kovalen dengan atom
X?)
A
B
C
D
6

Carbon (Karbon)
Sulphur (Sulfur)
Nitrogen (Nitrogen)
Magnesium (Magnesium)

The table shows the electron arrangement of atoms for five elements.
(Jadual menunjukkan susunan elektron bagi atom lima unsur)
Element
(Unsur)
U
V
W
X
Y

Electron arrangement
(Susunan elektron)
2.8
2.8.2
2.8.4
2.8.7
2.8.8.1

Which of the following pairs of elements will form a chemical compound with high melting
point and boiling point?
(Antara pasangan unsur berikut, yang manakah membentuk sebatian kimia dengan takat
lebur dan takat didih yang tinggi?)
A
B
C
D

U and
V and
X and
W and

W
Y
Y
X

The table shows the information of three voltaic cells.

(Jadual menunjukkan maklumat bagi tiga sel voltan.)
Voltaic cell
(sel voltan)

Electrodes
(elektrod)

Potential
difference/V
(beza
keupayaan/V)

Negative terminal
(Terminal negatif)

Zinc and magnesium

(Zink dan magnesium)

1.6

Magnesium

Iron and zinc

(Besi dan zink)

0.2

Zinc

Copper and magnesium

(Kuprum dan
magnesium)

2.6

Magnesium

What is the potential difference of the voltaic cell consisting of copper and iron electrodes?
(Berapakah beza keupayaan sel voltan yang terdiri daripada elektrod kuprum dan besi?)
A
B
C
D
8

0.8 V
1.0 V
1.8 V
2.4 V

The figure shows the apparatus set up for electrolysis of copper(II) sulphate solution using
carbon electrodes.
(Rajah menunjukkan susunan radas bagi elektrolisis larutan kuprum(II) sulfat
menggunakan elektrod karbon.)
A

Carbon electrodes
Copper(II) sulphate solution

Which of the following are true about the electrolysis?

(Manakah antara berikut adalah benar tentang elektrolisis tersebut?)
I
II
III
IV
A
B
C
D

Brown deposit is formed at the cathode

(Enapan perang terbentuk di katod)
Intensity of the blue solution decreases
(Keamatan warna biru larutan berkurangan)
Bubbles of greenish yellow gas is evolved at the anode
(Gas kuning kehijauan terbebas di anod)
Size of both electrodes increase
(Saiz kedua-dua elektrod bertambah)
I and II only
II and III only
II and IV only
I, III and IV only

10

Lead(II) nitrate can be prepared from the reaction between

(Plumbum(II) nitrat boleh disediakan daripada tindak balas antara)
I
II
III
IV

lead and nitric acid (plumbum dan asid nitrik)

lead(II) oxide and nitric acid (plumbum(II) oksida dan asid nitrik)
lead(II) carbonate and nitric acid (plumbum(II) karbonat dan asid nitrik)
lead(II) hydroxide and nitric acid (plumbum(II) hidroksida dan asid nitrik)

A
B
C
D

I and II only
II and IV only
II, III and IV only
I, II, III and IV

Equations below represent four stages of reactions in the manufacture of sulphuric acid by
the Contact Process.
(Persamaan di bawah mewakili empat peringkat tindak balas bagi penyediaan asid sulfurik
melalui Proses Sentuh.)
P:
Q:
R:
S:

2SO2 (g) + O2(g)

S(s) + O2(g)
H2S2O7(l) + H2O(l)
SO3(g) + H2SO4(aq)

2SO3(g)
SO2(g)
2H2SO4(aq)
H2S2O7(l)

Which of the following arrangements shows the correct sequence of reactions in the
process?
(Antara susunan berikut, yang manakah menunjukkan urutan tindak balas yang betul bagi
proses tersebut?)
A
B
C
D

11

P, Q, R, S
Q, P, R, S
P, S, Q, R
Q, P, S, R

An experiment is carried out to investigate the rate of reaction for the reaction between zinc
granules and hydrochloric acid to produce hydrogen gas.
(Satu eksperimen dijalankan untuk menyiasat kadar tindak balas bagi tindak balas antara
butiran zink dan asid hidroklorik untuk menghasilkan gas hidrogen)
Experiment
I
II

Substances
Excess zinc granules and 50 cm3 of 2 mol dm3 hydrochloric acid
(Butiran zink yang berlebihan dan 50 cm3 2 mol dm3 asid hidroklorik)
Excess zinc granules and 50 cm3 of 1 mol dm3 hydrochloric acid
(Butiran zink yang berlebihan dan 50 cm3 1 mol dm3 asid hidroklorik)

Which of the following graphs represents the reactions ?

(Antara berikut, graf yang manakah mewakili tindak balas itu ?

12

An ester with the formula C2H5COOCH3 can be produced from reaction between
(Ester yang berformula C2H5COOCH3 boleh dihasilkan daripada tindak balas antara)
A
B
C
D

C2H5OH and CH3COOH

CH3OH and C2 H5COOH
CH3OH and HCOOC2H5
C2H5OH and HCOOCH3

13

The figure shows the apparatus set up for an experiment to investigate electron transfer
through a distance.
(Rajah menunjukkan susunan radas bagi eksperimen untuk menyiasat pemindahan elektron
pada suatu jarak.)

Carbon P

Potassium bromide
(Kalium bromide)

Carbon Q
Chlorine water
(Air klorin)
Sulphuric acid
(Asid sulfuric)

Which of the following is true about the experiment?

(Antara berikut, yang manakah benar tentang eksperimen tersebut?
A
Bromide ions donate electrons (Ion bromida menderma elektron)
B
Rod Q is the negative terminal (Rod Q adalah terminal negatif)
C
Sulphuric acid allows the flow of electrons through it
(Asid sulfurik membenarkan pengaliran elektron melaluinya)
D
Electrons are transferred from rod Q to rod P through the external circuit
(Elektron mengalir dari rod Q ke rod P melalui litar luar)
14

The equation represents a redox reaction.

(Persamaan mewakili suatu tindak balas redoks)
Br2(g) + 2KI(aq)

I2(g) + 2KBr(aq)

The oxidation number of bromine changes from

(Nombor pengoksidaan bromin berubah dari)
A
B
C
D
15

0 to -1
0 to -2
2 to -2
-2 to 0

The diagram shows the energy profile of a reaction.

(Gambar rajah menunjukkan profil tenaga untuk satu tindak balas.)
Energy/kJ

263
W+X
142
Y+Z
50

Which of the following pairs shows the correct values of the activation energy and the heat
of reaction?
(Antara pasangan berikut, yang manakah menunjukkan nilai tenaga pengaktifan dan haba
tindak balas yang betul ?)

A
B
C
D
16

17

A
29
B
30
C
46
D
74
The charge of magnesium ion in MgX2 is +2. What is the charge of ion X?
(Cas bagi ion magnesium dalam MgX2 ialah +2. Apakah cas ion X?)
+1
+2
1
2

Which of the following hydrocarbons contains 81.82% carbon by mass?

[Relative atomic mass of H=1, C=12]
(Antara hidrokarbon berikut, yang manakah mengandungi 81.82% karbon mengikut jisim?
[Jisim atom relatif H=1, C=12])
A
B
C
D

19

Heat of reaction/kJ mol -1

(Haba Tindak balas/kJ mol -1)
-142
-92
-50
-142

The chemical formula of butanol is C4H9OH. Determine the relative molecular mass.
[Relative atomic mass of H=1, C=12, O=16]
(Formula kimia bagi butanol ialah C4H9OH. Tentukan jisim molekul relatif.)
[Jisim atom relatif H=1, C=12, O=16])

A
B
C
D
18

Activation energy/kJ
(Tenaga pengaktifan/kJ)
263
121
142
92

C2H2
C2H4
C3H6
C3H8

The equation represents the action of heat on calcium carbonate, CaCO 3.

(Persamaan di bawah mewakili tindakan haba ke atas kalsium karbonat, CaCO3.)

CaCO3 CaO + CO2

If 0.2 mole of calcium carbonate is heated until no further change, what is the mass of
calcium oxide, CaO produced?
[Relative atomic mass of C=12, O=16, Ca=40]
(Jika 0.2 mol kalsium karbonat dipanaskan sehingga tiada perubahan, berapakah jisim
kalsium oksida, CaO yang terhasil?)
([Jisim atom relatif C=12, O=16, Ca=40)]
A
B
C
D
20

5.6 g
11.2 g
16.8 g
22.4 g

The equation represents a neutralisation reaction.

(Persamaan mewakili satu tindak balas peneutralan)
2HNO3 + Ba(OH)2 Ba(NO3)2 + 2H2O
10.0 cm3 of barium hydroxide solution 0.1 mol dm -3 is titrated with nitric acid 0.1 mol dm 3
. If the initial reading of the burette is 10.00 cm3, what is the final reading of the burette?
(10.0 cm3 larutan barium hidroksida 0.1 mol dm-3 dititrat dengan asid nitrik 0.1 mol
dm 3
3
.Jika bacaan awal buret ialah 10.00 cm ,berapakah bacaan akhir buret?)
A
B
C
D

21

20.00 cm3
30.00 cm3
40.00 cm3
50.00 cm3

The equation shows the decomposition of a nitrate salt of metal X

(Persamaan menunjukkan penguraian garam nitrat bagi logam X)

2X(NO3)2

2XO

4NO2

O2

Calculate the volume of nitrogen dioxide,NO2 gas at room condition if

18.8 g of X(NO3)2 salt is heated.
(Hitung isipadu gas nitrogen dioksida, NO2 pada keadaan bilik jika 18.8 g garam X(NO3)2
dipanaskan)
[Relative atomic mass: X = 64 ; N = 14 ; O = 16. Molar volume = 24 dm3 mol-1 at room
conditions]
(Jisim atom relatif: X = 64 ; N = 14 ; O = 16. Molar volume = 24 dm3 mol-1 at room
conditions])
A
B
C
D
22

0.6 dm3
1.2 dm3
4.8 dm3
9.6 dm3

The diagram shows part of the structure of a polymer .

(Rajah menunjukkan sebahagian struktur polimer)

~C Cl

C C - C ~
H

Cl

Which is its monomer?

(Yang mana satu adalah monomernya?)
H

Cl

A
C= C

Cl

H C C H
H

H H

H C C C H
Cl

Cl
H

C = C C H
H
23

The table shows the volume of oxygen gas released from the decomposition of hydrogen
peroxide:
(Jadual menunjukkan isipadu gas oksigen yang terbebas daripada penguraian hidrogen
peroksida:)
Time/minute
(masa/minit)
Volume of gas/cm3
(Isipadu gas/ cm3 )

10

13

15

15

15

What is the average rate of decomposition of hydrogen peroxide for the first four minutes?
(Berapakah kadar penguraian hidrogen peroksida bagi empat minit yang pertama?)
A
B
C
D

2.50 cm3 min 1

3.75 cm3 min 1
6.00 cm3 min 1
15.00 cm3 min 1

24

The time taken for exactly 2 g of zinc powder to react completely with excess hydrochloric
acid is 5 minutes. What is the average rate of the above reaction ?
(Masa yang diambil untuk 2 g serbut zink bertindak balas lengkap dengan asid hidroklorik
berlebihan ialah 5 minit. Berapakah kadar purata bagi tindak balas di atas ?)
A
B
C
D

25

0.4 g
0.4 g
2.5 g
2.5 g

s 1
min 1
s 1
min 1

The equation represents the combustion reaction of ethanol with oxygen.

(Persamaan mewakili tindak balas pembakaran etanol dengan oksigen.)
C2H4 + 2O2

2CO2 + 2H2O

What is the volume of carbon dioxide gas given out when 20 cm3 of ethene is burnt
completely in excess oxygen?
(Berapakah isipadu gas karbon dioksida yang dibebaskan apabila 20 cm3 etena dibakar
dengan lengkap dalam oksigen berlebihan?)
A
B
C
D
26

20 cm3
30 cm3
40 cm3
60 cm3

The table shows the observation when mixtures of metals and metal oxides are heated
strongly.
(Jadual menunjukkan pemerhatian apabila campuran logam dan oksida logam dipanaskan
dengan kuat.)
Mixture

Observation

Metal P and metal Z oxide

Glowing (Membara)

Metal Q and metal R oxide

No change (Tiada perubahan)

Metal Q and metal T oxide

Glowing (Membara)

Metal R and metal Z oxide

No change (Tiada perubahan)

Which of the following arrangement represents the descending order of metal reactivity with
oxygen?
(Manakah antara berikut menunjukkan susunan menurun kereaktifan logam terhadap
oksigen?)
A
B
C
D

Z,P,T,R,Q
Z,R,Q,P,T
P,Q,T,R,Z
P,Z,R,Q,T

27

The diagram shows two metals each wound around an iron nail and placed in different
test tubes.
(Rajah menunjukkan dua logam yang telah dililit mengelilingi paku besi dan
dimasukkan ke dalam tabung uji berbeza)

The following observation is obtained after one week

(Pemerhatian berikut didapati selepas satu minggu)
Test Tube
Observation
I
Iron nail does not rust
(Paku besi tidak berkarat)
II
Iron nail rusted
(Paku besi berkarat)
Based on the above observation, the arrangement of metals E, F and iron in ascending
order of electropositivity is
(Berdasarkan pemerhatian di atas, susunan menaik keelektropositifan logam E, F dan
besi adalah)
A
B
C
D

F, iron, E
E, F, iron
E, iron, F
Iron, E, F

28

The energy profile for reaction between hydrochloric acid and sodium hydroxide is shown
below.
[Profil tenaga bagi tindakbalas antara asid hidroklorik dan natrium hidroksida ditunjukkan
di bawah]..
Energy
[tenaga]

HCl + NaOH
H = -57 kJmol-1
NaCl

+ H2O

The same amount of energy is released if hydrochloric acid is replaced by.

[Jumlah tenaga yang sama dibebaskan apabila asid hidroklorik digantikan oleh....]
A
B
C
D
29

sulphuric acid, H2SO4 (asid sulfurik)

nitric acid, HNO3, (asid nitrik)
carbonic acid, H2CO3, (asid karbonik)
ethanoic acid, CH3COOH , (asid etanoik)

Carbon burns in oxygen in a reaction as shown in the equation below.

(Karbon terbakar dalam oksigen seperti ditunjukkkan dalam persamaan dibawah)
C(s) + O2(g) CO2 (g)

H = -394 kJ mol-1

What is the mass of carbon that must be burnt completely to produce 78.8 kJ of heat?
(Berapakah jisim karbon yang mesti terbakar untuk menghasilkan 78.8 kJ haba?)
A
B
C
D
30

0.2 g
1.2 g
2.4 g
6.0 g

Which of the following can be used to cure headaches?

Antara berikut yang manakah dapat diguna untuk merawat sakit kepala?
A
Cortisone
B
Streptomycin
C
Paracetamol
D
Barbiturates

31 Diagram 6 shows the elements which are represented by letters J,Q,T and Z in the
Periodic Table.
J, Q, T and Z are not the actual symbols.
Rajah 6 di bawah menunjukkan unsur unsur yang diwakili oleh huruf J,Q,T dan Z
dalam Jadual berkala.
J, Q, T dan Z bukan symbol sebenar unsur.
1

Q
T

DIAGRAM 6
RAJAH 6
Which of the following are true about elements J,Q,T and Z?
Antara berikut, yang manakah benar tentang unsur J,Q,T dan Z?
I

Proton number increases in the order of J,Q,T and Z

Nombor proton bertambah dalam urutan J,Q,T dan Z
II Charges of J and Q ions are 2 while charges of T and Z ions are 3
Cas ion J dan Q ialah 2 manakala cas ion T dan Z ialah 3
III J and Q combine to form a compound with the formula JQ2
J dan Q bergabung membentuk sebatian dengan formula JQ2
IV Electronegativity decreases in the order of J,T and Z
Keelektronegatifan berkurang dalam urutan J,T dan Z
A
B
C
D

I and II only
I and IV only
III and IV only
I,III and IV only

32 Which of the following is not a natural polymer?

Di antara berikut, yang manakah bukan polimer semulajadi?
A
B
C
D

Protein
Protein
Cellulose
Selulosa
Polyethene
Polietena
Polyisoprene
Poliisoprena

33 When bromine water is added into iron(II) sulphate solution and heated, the green
solution changes to brown.
Which of the following conclusion is true about the reaction?
Apabila air bromine ditambahkan kepada larutan ferum(II) sulfat dan dipanaskan,
larutan hijau itu bertukar menjadi perang. Apakah kesimpulan yang boleh dibuat
daripada tindak balas itu?
A
B
C
D

Ferum(II) ions are reduced to ferum

Ion Ferum(II) diturunkan kepada logam Fe
Ferum(II) ions are oxidised to Ferum(III) ions
Ion Ferum(II) dioksidakan menjadi ion Ferum(III)
Bromine ions are oxidised to bromine molecules
Ion Bromida dioksidakan menjadi molekul Bromine
Sulphate ions are reduced to Sulphur dioxide molecules

Ion Sulfat diturunkan kepada molekul sulfur dioksida

34 The thermochemical equation below shows a neutralisation reaction.
Persamaan termokimia menunjukkan satu tindak balas peneutralan.
NaOH(aq) + HCl(aq) NaCl (aq) + H2O(l)

H = -57.0 kJmol-1

What is the heat change if 2.7g of water is produced?

Berapakah nilai perubahan tenaga haba apabila 2.7g air dihasilkan?
[Relative atomic mass : H,1 ; O,16]
[Jisim atom relatif : H,1 ; O,16]

A
B
C
D

-5.7 kJmol-1
-8.55 kJmol-1
-57.0 kJmol-1
-153.9 kJmol-1

35 A patient must finish the full course of antibiotics prescribed by the

doctor.
Which of the following statements is the best to explain this?
Seorang pesakit mesti menghabiskan kesemua dos lengkap antibiotik yang dibekalkan.Di
antara pernyataan berikut, yang manakah paling tepat menerangkan tujuan tersebut?
A
B
C
D

To prevent wastage
Untuk mengelakkan pembaziran.
To minimise the side effects
Untuk mengurangkan kesan sampingan
To improve the body immunity
Untuk memperbaiki daya tahan badan.
To prevent bacteria from becoming more resistant to the antibiotic.
Untuk mengelakkan bakteria daripada menjadi lebih rintang terhadap
antibiotik berkenaan.

36 The standard representation for carbon atom can be written as,

Perwakilan piawai bagi atom karbon boleh ditulis sebagai,

12
6

What is the number of valence electron for carbon atom?

Apakah bilangan elektron valens bagi atom karbon?

A
B
C
D

2
4
6
12

37 Which of the following gases have the highest mass at room temperature?
[Relative atomic mass : H, 1 ; C,12 ; O, 16 ; Ne, 20 ; S, 32 ; 1 mole of gas occupies a
volume of 24 dm3 at room temperature]
Antara berikut, gas yang manakah mempunyai nilai jisim yang paling tinggi pada
suhu bilik?
[Jisim atom relatif : H, 1 ; C,12 ; O, 16 ; Ne, 20 ; S, 32 ; 1 mol gas menempati isipadu
24 dm3 pada suhu bilik ]
A
B
C
D

6 dm3 of neon, Ne
6 dm3 of neon, Ne
9 dm3 of methane, CH4
9 dm3 of metana, CH4
72dm3 of hydrogen, H2
72dm3 of hidrogen, H2
3 dm3 of sulphur dioxide, SO2
3 dm3 of sulfur dioksida, SO2

38 The equation represents the decomposition of hydrogen peroxide solution.

Persamaan di bawah mewakili penguraian larutan hidrogen peroksida
2H2O2 (aq)

2H2O(I) + O2(g)

Which of the following can be used to determine the rate of this reaction?
Antara berikut yang manakah boleh digunakan untuk menentukan kadar tindak balas
I
Release of gas per unit time
Pembebasan gas per unit masa
II Change of colour intensity per unit time
Perubahan keamatan warna per unit masa
III Formation of precipitate per unit time
Pembentukan mendakan per unit masa
IV Increase in the mass of reactant per unit time
Penambahan jisim bahan tindak balas per unit masa
A
B
C
D

I only
III and IV only
I,II and III only
II,III and IV only

39 Elements X and Y form an ionic compound with a formula of X2Y3. What are the correct
electron arrangements of atom X and Y.
Unsur X dan Y membentuk sebatian ionik dengan formula kimia X2Y3. Apakah susunan
elektron yang betul bagi atom X dan Y?.

X
2.6
2.6
2.8.2
2.8.3

A
B
C
D

Y
2.8.3
2.8.2
2.8.3
2.6

40 Diagram 7 shows the set up of the apparatus to study the electroplating of an iron spoon
using electrolysis method.
Rajah 7 menunjukkan satu set radas untuk mengkaji penyaduran sudu besi menggunakan
kaedah elektrolisis.

Silver
Argentum

Iron spoon
Sudu besi

Silver nitrat solution

Larutan Argentum nitrate

DIAGRAM 7
RAJAH 7
Which of the following half equations represent the reactions that occur at the anode and
cathode?
Yang manakah antara berikut setengan persamaan yang mewakili tindak balas yang
berlaku di katod dan di anod.

A
B
C
D

Anode
Anod
4OH 2H2O + O2 + 4e
4OH 2H2O + O2 + 4e
Ag Ag+ + e
Ag Ag+ + e

2H+
Ag+
Ag+
2H+

Cathode
Katod
+ 2e
+ e
+ e
+ 2e

H2
Ag
Ag
H2

41 Table 3 shows solution X, Y, Z and W with their pH values.

Jadual 3 menunjukkan larutan X, Y, X dan W dan nila pH masing-masing.
Solution
Larutan
pH

11

TABLE 3
Which of the following solution reacts with magnesium to produce hydrogen gas?
Larutan manakah bertindak balas dengan magnesium menghasilkan gas hidrogen?
A
B
C
D

X
Y
Z
W

42 Reaction between a soluble salt A and sodium iodide solution will produce an insoluble
Salt, lead(II) iodide.
Tindak balas antara garam terlarutkan A dan larutan natrium iodida akan menghasilkan
garam tak larut, Plumbum(II) iodida.
A

Sodium iodide solution

Larutan natrium iodida

Lead(II) iodide
Plumbum(II) iodida

Which of the following substance is A?

Yang manakah antara berikut adalah A?
A
B
C
D

Lead(II) nitrate
Plumbum(II) nitrat
Lead(II) chloride
Plumbum(II) klorida
Lead(II) carbonate
Plumbum(II) karbonat
Lead(II) sulphate
Plumbum(II) sulfat

43 Table 4 shows the mass of sulphur trioxide formed at different temperatures during the
Contact Process.
Jadual 4 menunjukkan jisim sulfur trioksida yang terbentuk pada suhu berlainan semasa
Proses sentuh
Temperature/ oC
Suhu/ oC
Mass of sulphur
trioxide/kg
jisim sulfur
trioksida/kg

300

400

500

600

350

200

120

100

Time taken
masa

5 hours
5 jam

2 hours
2 jam

6 minutes
6 minit

9 minutes
9 minit

TABLE 4
JADUAL 4
What is the temperature to produce the highest rate of reaction in the process?
Berapakah suhu untuk menghasilkan kadar tindak balas tertinggi dalam tindak balas itu?
A
B
C
D

300oC
400oC
500oC
600oC

44 Diagram 8 shows the structural

formula of a hydrocarbon.
Rajah 8 menunjukkan formula struktur bagi satu hidrokarbon.

DIAGRAM 8
RAJAH 8
What is the name of the hydrocarbon?
Apakah nama hidrokarbon itu?
A

pent-2-ene
pent-2-ena
B 2-methylbut-2-ene
2-metilbut-2-ena
C 3-methylbut-2-ene
3-metilbut-2-ena
D 1,1-dimethylprop-1-ene
1,1-dimetilprop-1-ena
45 An experiment is carried out to study the rate of reaction between marble chips and
hydrochloric acid to produce carbon dioxide gas
Satu eksperimen dijalankan untuk mengkaji kadar tindak balas antara ketulan marmar
dan asid hidroklorik untuk menghasilkan gas karbon dioksida
Experimen
Eksperime
n

Substances
Bahan

Excess marble chips and 50.0cm3 of 2 mol dm-3 hydrochloric

acid
Ketulan marmar berlebihan dan 50.0cm3 2 mol dm-3 asid
hidroklorik

II

Exces marble chips and 100.0 cm3 of 1 mol dm-3

hydrochloric acid
Ketulan marmar berlebihan dan 100.0 cm3 1 mol dm-3 asid
hidroklorik

Which of the following graph represents the two experiments?

Antara graf berikut yang manakah mewakili dua eksperimen tersebut?

46

H2 + CuO Cu +
H2O
The oxidation number of
copper in the reaction
changes from
Numbor pengoksidaan
bagi kuprum dalam
tindak balas di atas
berubah daripada

A
B
C
D

2 to +1
1 to 0
+2 to +1
+2 to 0
47 Which of the following
statements about heat of
precipitation is not correct?
Manakah pernyataan
berikut mengenai haba
pemendakan adalah tidak
benar?

A
B
C

The heat change is always negative.

Perubahan haba tersebut adalah sentiasa negatif
It is the heat change measured when 1 mole of ionic crystal is formed.
Ia merupakan perubahan haba yang disukat apabila 1 mol hablur ionik
terbentuk.
It is the heat change measured when solutions containing the anion and
cation of the ionic compound are mixed together.
Ia merupakan perubahan haba yang disukat apabila larutan yang
mengandungi anion dan kation suatu sebatian ionik dicampurkan bersama.
It is the heat change measured when 1 mole of anion combines with 1 mole
of cation
Ia merupakan perubahan haba yang disukat apabila 1 mol anion
bergabung dengan 1 mol kation.

48 What is the purpose of adding azo and triphenyl compounds in foods?

Apakah tujuan mencampurkan sebatian azo dan trifenil dalam makanan?
A
B
C
D

To stabilise the dispersion of oil in water.

Untuk menstabilkan penyebaran minyak di dalam air.
To enhance the taste and flavour of foods
Untuk menambahkan rasa dan perisa makanan
To prevent the foods from being oxidised by the air
Untuk mengelakkan makanan daripada teroksida oleh udara.
To improve the appearance of foods by restoring their colours.
Untuk memperbaiki rupa makanan dengan memulihkan warna makanan
berkenaan

49 Table 5 shows the standard representation of element P, Q, R and S.

Jadual 5 menunjukkan perwakilan piawai bagi unsur P, Q R dan S.
13
6

14
6

14

7 R

16
8

TABLE 5
JADUAL 5
Which of the following pairs of element are isotopes?
Yang manakah antara pasangan unsur-unsur tersebut adalah isotop?
A
B
C
D

P and R
R and S
Q and R
P and Q

50 5g of calcium carbonate is added to excess hydrochloric acid. Calculate the volume of

carbon dioxide gas evolved at room temperature.
5g kalsium karbonat ditambahkan kedalam asid hidroklorik berlebihan. Tentukan
isipadu gas karbon dioksida yang terhasil pada suhu bilik.
[Relative atomic mass: C, 12 ; O, 16; Ca, 40; 1 mole of gas occupies a volume of 24
dm3 at room temperature]
[jisim atom relatif: C, 12 ; O, 16; Ca, 40; 1 mol gas menempati isi padu 24 dm3 pada
suhu bilik]
A
B
C
D

0.6
0.9
1.2
1.8

dm3
dm3
dm3
dm3

CHEMISTRY SPM 2015

PAPER 1
ARAS TINGGI
SET 2
1 X is element of group 17 in Periodic Table.
X ialah unsur kumpulan 17 dalam Jadual Berkala
Atom

Number of
Proton
Bilangan proton

Number of
Electron
Bilangan elektron

Number of
Neutron
Bilangan neutron

18

Which of the following is not true about X?

Antara berikut yang manakah tidak benar tentang unsur X?
A
B
C
D

X forms XX membentuk X2X is an oxidizing agent

X adalah agen pengoksidaan
X form a compound with carbon with formula of CX4
X membentuk sebatian dengan karbon berformula CX4
X reacts with magnesium to release hydrogen
X bertindak balas dengan magnesium membebaskan gas hidrogen

Table 6 shows the electron arrangement of atoms of elements V, W, X, Y and Z.

Jadual 6 menunjukkan susunan elektron atom-atom unsur V, W, X, Y dan Z.
Element
Electron Arrangement
V
2.8
W
2.8.2
X
2.8.4
Y
2.8.7
Z
2.8.8.1
TABLE 6
JADUAL 6
Which of the following pair of elements when combined will form a compound that
conducts
electricity in the molten state?
Manakah pasangan unsur berikut apabila berpadu akan membentuk satu
sebatian yang boleh mengkonduksikan arus elektrik dalam keadaan lebur?
A

V and X

B
C
D

W and Z
X and Y
Y and Z

Diagram 9 shows a Daniell cell.

Rajah 9 menunjukkan sebuah Daniell sel.

Porous pot
Pasu berliang
Copper
Kuprum

Zinc
Zink

Copper(II) sulphate solution

Larutan kuprum(II) sulfat

Zinc sulphate solution

Larutan zink sulfat

DIAGRAM 9
RAJAH 9
Which of the following is correct about the cell?
Antara berikut, yang manakah benar tentang sel itu?
A
B
C
D

The zinc electrode becomes thicker

Elektrod zink menjadi lebih tebal
The copper electrode dissolves in the solution
Elektrod kuprum larut dalam larutan
Electrons flow from zinc to copper through the external circuit
Elektron mengalir dari zink ke kuprum melalui litar luar
Zinc electrode is the positive terminal whereas copper electrode is the
negative terminal
Elektrod zink ialah terminal negative manakala elektrod kuprum ialah
terminal positif

4 Diagram 10 shows two volumetric flasks containing 2.0 moldm-3 of hydrochloric acid and
0.2 mol dm-3 hydrochloric acid.
Rajah 10 menunjukkan dua kelalang isipadu yang mengandungi asid hidroklorik 2.0 mol
dm-3 dan asid hidroklorik 0.2 mol dm-3.

100 cm3 hydrochloric acid

0.2 mol dm-3
100 cm3 asid hidroklorik
0.2 mol dm-3

50 cm3 hydrochloric acid

2.0 mol dm-3
50 cm3 asid hidroklorik 2.0
mol dm-3

DIAGRAM 10
RAJAH 10

What is the volume of 2.0 mol dm-3 hydrochloric acid needed to prepare 100 cm3 of
0.2 mol dm-3 hydrochloric acid?
Apakah isipadu asid hidroklorik 2.0 mol dm-3 yang diperlukan untuk menyediakan 100
cm3 asid hidroklorik 0.2 mol dm-3?
A
B
C
D

1.0 cm3
5.0 cm3
10.0 cm3
20.0 cm3

5 Sulphuric acid, H2SO4 reacts with lead(II) nitrate, Pb(NO3)2 to produce a white
precipitate lead(II) sulphate, PbSO4 as the equation below:
Asid sulfurik, H2SO4 bertindak balas dengan plumbum(II) nitrat untuk menghasilkan
mendakan putih, plumbum(II) sulfat, PBSO4 seperti persamaan di bawah:
H2SO4

Pb(NO3)2

PbSO4

2HNO3

What is the mass of lead(II) sulphate, PbSO4 obtained when 0.1 mol of lead(II) nitrate,
Pb(NO3)2 is used? [Relative Atomic Mass: Pb, 207; S, 32; O, 16]
Berapakah jisim plumbum(II) sulfat, PbSO4 , yang didapati apabila 0.1 mol plumbum(II)
nitrat, Pb(NO3)2 , digunakan? [Jisim Atom Relatif: Pb, 207; S, 32; O, 16]
A
B
C
D

15.15 g
30.30 g
25.50 g
12.75 g

6 Which of the following chemical fertilizer is the best fertilizer according to its percentage
of nitrogen content?
Di antara baja kimia berikut, yang manakah paling baik berdasarkan peratus
kandungan nitrogen?
(Relative atomic mass: N,14,Ca,40,O,16,H,1,S,32,P,31)
A
B
C
D

Calcium nitrate, Ca(NO3)2

Ammonium nitrate, NH4NO3
Ammonium sulphate, (NH4)2SO4
Ammonium dihydrogen phosphate, (NH4)H2PO4

7 Diagram 11 shows a part of the structure of a polymer chain formed by additional

polymerisation.
Rajah 11 menunjukkan sebahagian struktur rantai polimer yang terbentuk hasil
pempolimeran penambahan.

DIAGRAM 11
RAJAH 11
Which of the following is the monomer of that polymer.?
Antara berikut yang manakah monomer bagi polimer tersebut?
A

8 Diagram 12 shows a set up of the apparatus to study the transfer of electrons at a distance.
Which of the following half equations show the correct reactions at rod P and rod Q?
Rajah 12 menunjukkan susunan radas untuk mengkaji pemindahan elektron pada satu
jarak. Antara setengah persamaan berikut, yang manakah menunjukkan tindak balas
yang betul di rod P dan rod Q?

Carbon electrode
Elektrod karbon

Q
Bromine water
Air bromin

Potassium iodide solution

Larutan kalium iodida

Dilute sulphuric acid

Asid sulfurik cair

DIAGRAM 12
RAJAH 12
P

2I
2I
2Br
2Br

A
B
C
D

Br2 + 2e 2Br
2Br Br2 + 2e
2I I2 + 2e
I2 + 2e 2I

I2 + 2e
I2 + 2e
Br2 + 2e
Br2 + 2e

9 Substance Y shows the following properties.

Sebatian Y menunjukkan sifat-sifat berikut.
Solution Y produced a blue precipitate when sodium hydroxide
solution, NaOH was added.
Larutan Y menghasilkan mendakan biru apabila larutan natrium
hidroksida, NaOH ditambahkan.

Substance Y released a colourless gas which turns lime water

cloudy when heated.
Sebatian Y membebaskan gas tanpa warna yang mengeruhkan
air kapur apabila dipanaskan.

Which of the following is substance Y?

Yang manakah antara berikut sebatian Y?
A
B
C
D
10

11

Calcium oxide
Kalsium oksida
Copper(II) oxide
Kuprum(II) oksida
Calcium carbonate
Kalsium karbonat
Copper(II) carbonate
Kuprum(II) karbonat

Which of the following compounds is a soluble base?

A

Aluminium oxide

Copper(II) oxide

Iron(III) oxide

Sodium oxide

The pH scale below shows the position of five aqueous solutions P, Q, R, S and T, of
equal concentration.
P

7
pH Scale

14

What could the aqueous solutions be ?

12

13

sulphuric

ammonia

sodium

sodium

acid

acid

aqueous

chloride

hydroxide

What is the concentration of hydrogen ions in 0.05 mol dm-3 sulphuric acid?
A
0.025 mol dm-3
B

0.050 mol dm-3

0.100 mol dm-3

0.250 mol dm-3

Which of the following equations best represents the actual reaction between
hydrochloric acid and sodium hydroxide solution?
A

H+

OH-

H2O

H2

O2

H2O

2H+ +

O 2-

H2O

Na+ +

Cl-

NaCl

C
D
14

Ethanoic

The neutralization reaction between nitric acid and barium hydroxide solution is
shown in the equation below
2HNO3 + Ba(OH)2 Ba(NO3)2 + 2H2O
10.0 cm3 of 0.1 mol dm-3 barium hydroxide solution was titrated with 0.1mol dm-3
of nitric acid . What is the volume of the nitric acid?

15

40 cm3

30 cm3

20 cm3

10 cm3

Air polluted by sulphur dioxide was passed through the apparatus shown in the
diagram below.

Which of the following solutions could be used as Z to show the presence of

sulphur dioxide?
A

acidified potassium manganate(VII)

aqueous iron(II) sulphate

aqueous potassium iodide

limewater

16

The following scheme shows four stages in the conversion of sulphur to sulphuric
acid. In which stage is the catalyst used?

17

Which of the following mixtures of elements forms the most suitable alloy for
manufacturing of racing bicycle which is light and firm?

18

copper and nickel

iron and carbon

stanum and copper

aluminium and copper

Which of the following pairs shows the correct monomer for making the polymer?

B
C

19

2
0

2
1
X
Y

The followings are the properties of glass. Which of the followings are true?
I

low melting point.

II

they are good insulators of heat.

III

resistant to chemicals

IV
A

hard but brittle

I and II only

III and IV only

I, III and IV only

II, III and IV only

Compound A is an organic compound. When heated strongly, which of the following

gases is released?
A
Oxygen
B

Hydrogen

Carbon dioxide

Ethane

The chemical equation shows a chemical reaction that took place.

CH2CHCH2CH3 +H2 CH3CH2CH2CH3
CH2CHCH2CH3 +H2O CH3CH(OH)CH2CH3

X
A

Hydration

Y
Hydrogenation

2
2

2
3

2
4

Hydrogenation

Hydration

Substitution

Dehydration

Oxidation

Reduction

Which of the following is the IUPAC name for the structural formula
shown?

3-ethyl-4-methylheptane

4-methyl-2-ethylhexane

5-ethyl-3-methylheptane

2-ethyl-4-methylhexane

Which of the following is correct regarding the physical properties of pentene, C5H10?
A

Pentene is denser than hexene.

Pentene exists in the form of gas at room temperature

Complete combustion of pentene will produce 4 moles of carbon dioxide gas.

Pentene is insoluble in water but is soluble in organic solvent.

Which of the following best explains the statement below?

Combustion of hexene is sootier than that of hexane

A

Hexane molecule has more hydrogen atoms than hexene molecule.

The van der Waals forces between hexene molecules are stronger.

Percentage by mass of carbon in hexene molecule is higher than that in hexane

molecule.

D
2
5

2
6

The size of hexene molecule is larger.

In a reaction temperature will increase the rate of reaction because it will

A

lower the activation energy of the rection

increase the energy of particles involved in the reaction

decrease the effective collision of particles involved

increase the rate of collision among the particles

The table shows the volume of oxygen gas obtained at regular intervals for the
decomposition of hydrogen peroxide, H2O2
Time(min)
0
1.0
2.0
3.0
4.0
5.0

Volume of oxygen gas (cm3)

0
5.5
10.0
14.0
17.5
20.0

The everage rate of decomposition of hydrogen peroxide from the second minute to
the fourth minute is

2
7

17.5 cm3 min-1

12.5 cm3 min-1

3.75 cm3 min-1

4.17 cm3 min-1

The graph below shows the volume of gas produced against time for the reaction of
potassium carbonate and hydrochloric acid

The gradient of the graph decreases with time because

A
catalyst is not used

2
8

29

30

temperature of reaction decreases

volume of mixure decreases

concentration of hydrochloric acid decreases

Which of the following will increase the frekuency of collision?

I
II
III
IV
A

Use reactant with larger size

Increase the concentration of reactant
Increase the temperature of reaction
Remove the product of reaction
IV only

II and IV only

II and III only

I, III and IV only

Which of the following chemicals can oxidise chloride ions to chlorine?

A
Potassium manganate (VII)
B

Iron(III) sulphate

Aqueous bromine

Potassium

Which of the following is an oxidising agent?

A
Hydrogen gas
B

Potassium manganate(VIl)

Potassium Iodide

D
31

Ammonia
A patient claims that other people are reading his mind
and controlling his thoughts

Which of the following types of medicine is most appropriate in treating the

above symptoms
A Psychotherapeutic medicine
B Hormones
C Analgesic
D Antibiotics
32

A series of experiment was carried out to investigate the reactivity of

metals K Y and Z. The following results were obtained.
Mixture
X+ oxide of Y

Result
No reaction.

Y+ oxide of Z

Reaction occurred.

X + oxide of Z

Reaction occurred.

Which of the following is the correct sequence for the reactivity of the metals in
ascending order?
A
X,Y,Z

33

Z,KY

Y,Z,X

Y,X,Z

The figure bellows shows the energy profile diagram for a reaction between X and Y
to produce Z.

What is the heat of reaction?

A

E2 E1

E1 E2

E3 E1

E3 E2

34 Which of the following is an exothermic reaction?

35

The heating of hydrated copper(II) sulphate

The heating of sodium thiosulphate

Dissolving ammonium chloride in water

Rusting process

The figure below shows the change in the heat of combustion of a few alcohols.

Propanol ( C3H7OH )
Ethanol ( C2H5OH )
Methanol ( CH3OH )

Heat of
combustion
increases

The increase in the heat of combustion of alcohols as shown is due to

A
B
C
D

36

an increase in the sootiness of the alcohols when burnt

an increase in the reactivity of alcohols
an increase in the relative molecular mass
an increase in the carbon and hydrogen atoms per molecule of alcohol

Which of the following pairs regarding traditional medicines and their uses is
correct?

A
B
C

Traditional medicine
Eurycoma longifolia
Aloe vera
Garlic
Ginseng

Use
To relief asthmatic attack
To treat skin wounds
To treat stomach wind
To treat malaria

D
37

A mixture carbon powder is heated strongly as shown.

Carbon powder + oxide of metal L
Evaporating dish

Which of the following shows the arrangement of the metals in the reactivity series
in ascending order?

38

M, N, L

L, M, N

L, N, M

N, L, M

Which of the following is one of the possible products formed when palm oil is boiled in
concentrated sodium hydroxide solution ?
I Sodium chloride
II Glycerol
III Sodium palmitate
IV Sodium stearate
A

II and III only

I, II and III only

II, III and IV only

I, II, III and IV

39.

Calculate the volume of sodium hydroxide of concentration 0.5 mol dm -3 needed to

neutralise 25.0 cm3 sulphuric acid of concentration 0.20 mol dm-3.
Hitungkan isipadu larutan natrium hidroksida berkepekatan 0.5 mol dm -3 yang diperlukan
untuk meneutralkan 25.0 cm3 asid sulfurik 0.20 mol dm-3.
A
B
C
D

40.

10 cm3
20 cm3
25 cm3
50 cm3

Examples of salt which can be prepared by double decomposition are

Contoh-contoh garam yang dapat disediakan dengan kaedah penguraian ganda dua
adalah
I

Silver chloride
Argentum klorida
II Magnesium nitrate
Magnesium nitrat
III Barium sulphate
Barium sulfat
IV zinc carbonate
zink karbonat
A
B
C
D
41.

I and III
II and IV
I, II and III
I, III and IV

Which of the following reactions does not produce a salt?

Antara tindak balas di bawah, yang manakah tidak menghasilkan garam?
A Calcium carbonate and hydrochloric acid
Kalsium karbonat dan asid hidroklorik
B Copper(II) oxide and nitric acid.
Kuprum (II) oksida dan asid nitrik
C Zinc and hydrochloric acid
Zink dan asid hidroklorik
D Iron(II) nitrate and sulphuric acid
Ferum (II) nitrat dan asid sulfurik

42. A series of test is carried out on solution Y and the results are shown in Diagram 1.
Identify the substance present in solution Y.
Satu siri ujian telah dijalankan ke atas larutan Y dan keputusan nya d itunjukkan dalam
Rajah 1

/ Mendakan
perang

Mendakan putih
Diagram 1
Rajah 1
A Iron(II) sulphate
Ferum(II) sulfat
B Lead(II) sulphate
plumbum(II) sulfat
C Iron(III) nitrate
Ferum(III) nitrat
D Zinc carbonate
Zink karbonat
43.

Which of the following reactions does not produce a salt?

Antara tindak balas di bawah, yang manakah tidak menghasilkan garam?
A Calcium carbonate and hydrochloric acid
Kalsium karbonat dan asid hidroklorik
B Copper(II) oxide and nitric acid.
Kuprum (II) oksida dan asid nitrik
C Zinc and hydrochloric acid
Zink dan asid hidroklorik
D Iron(II) nitrate and sulphuric acid
Ferum (II) nitrat dan asid sulfurik

44.

Photochromic glass darkens on exposure to sunlight. The salt used to make photochromic
glass is
Kaca fotokromik menjadi gelap apabila didedahkan kepada cahaya matahari. Garam
yang digunakan untuk membuat kaca fotokromik ialah
A Lead(II) nitrate
plumbum(II) nitrat
B Silver chloride
Argentum klorida
C Copper(II) sulphate
Kuprum(II) sulfat
D Iron(II) sulphate
Ferum (II) sulfat

45.

Which of the following sulphate salt given below is soluble in water?

Di antara garam sulfat di bawah yang manakah larut dalam air?
A Barium sulphate
Barium sulfat
B Magnesium sulphate
Magnesium sulfat
C Lead(II) sulphate
plumbum(II) sulfat
D Calcium sulphate
Kalsium sulfat

46.

An alloy is harder than its pure metal because the foreign atoms in the alloy
Aloi adalah lebih keras daripada logam tulen kerana logam asing di dalam aloi
A increases the bond strength between the atoms.
menambah kekuatan ikatan di antara atom.
B increases the empty spaces between the atoms.
Menambah ruang kosong antara atom-atom
C react with the pure metal atoms to form a compound.
Bertindak balas dengan atom-atom logam tulin untuk membentuk sebatian
D reduces the ability of the atoms to slide across each other.
Mengurangkan kebolehan atom-atom untuk menggelongsor antara satu sama lain

47.

Choose the conditions applied in the Contact Process to get optimum yield.
Pilih keadaan-keadaan yang sesuai bagi Proses Sentuh supaya memperolehi hasil yang
maksimum
Temperature
Suhu

48.

450oC

500oC

450oC

500oC

Pressure
Tekanan

Catalyst
Mangkin

1 atmosphere Vanadium
(V) oxide
200
Vanadium
atmosphere (V) oxide
1 atmosphere Fine iron
powder
200
Fine iron
atmosphere
powder

The main element present in glass is

Unsur utama yang hadir dalam kaca adalah
A Lead
Plumbum
B Sodium
Natrium

C Silicon
Silicon
D Boron
Boron
49.

Ceramic is made from

Seramik di buat dari
A Silica, SiO2
Silika oksida, SiO2
B Cement
Simen
C Marble
Marmar
D Aluminosilicate hydrate
Aluminosilikat terhidrat

Tenaga

Diagram 2
Rajah 2
50. Diagram 2 shows the energy level for the reaction A + B
C. The activation energy for
the reaction is
Rajah 2 menunjukkan aras tenaga bagi tindak balas A + B
C. Tenaga pengaktifan
bagi tindak balas tersebut adalah
A
B
C
D

x
y
(x + y)
(y x)
CHEMISTRY SPM 2015
PAPER 1
SET 3
ARAS TINGGI

1.

Zinc reacts with hydrochloric acid according to the equation below:

Zink bertindak balas dengan asid hidroklorik seperti persamaan di bawah :
Zn(s) + 2HCl(aq)

ZnCl2(aq) + H2(g)

Which of the following graphs between volume (V) of hydrogen against time (t) is
correct?
Antara graf isipadu(V) hidrogen melawan masa(t) berikut berikut yang mana adalah
betul ?
A

Two experiments are carried out as follows:

Dua eksperimen telah dijalankan seperti berikut:
100 cm3 of 1.0 M HCl is added to 10g of marble chips at 30oC.
100cm3 HCl 1.0M telah ditambah dengan 10g cip marmar pada suhu
30o C
Experiment II : 50 cm3 of 1.0 M HCl 1.0 M is added to 10g of marble chips at 50oC.
Eksperimen II 50cm3 HCl telah 1.0 M ditambah ke 10g cip marmar pada 50o C.
Experiment I :
Eksperimen I

Which of the following graphs shows the volume of carbon dioxide (V) collected against
time (t) in both the experiments?
Antara graf-graf berikut, yang manakah menunjukkan isipadu karbon dioksida (V) yang
dikumpul melawan masa (t) bagi kedua-dua eksperimen
A

3.

Excess zinc metal is added to 50 cm 3 of 0.2 mol dm-3 of hydrochloric acid. The hydrogen
gas evolved is collected at 20 second intervals. The results are tabulated in Table 6:
Zink berlebihan telah ditambah ke 50 cm 3 of 0.2 mol dm-3 asid hidroklorik . Hidrogen gas
yang dibebaskan telah dikutip pada setiap 20 saat . Keputusan yang diperolehi direkokan
dalam Jadual 6
Time /seconds
0
Total volume of
0
3
H2/cm
Table 6

20
30

40
55

60
75

80
90

100
90

Jadual 6
What information can you obtain from the result of the experiment?
Apakah maklumat yang boleh diperolehi dari keputudan tersebut?
I

No hydrogen gas is given off at time 100 seconds.

Tiada gas hydrogen dibebaskan pada masa 100 saat.
II The average rate of reaction is 0.9 cm3 s-1.
Kadar purata tindak balas ialah 0.9 cm3 s-1.
III The total volume of hydrogen gas collected is 340 cm3.
Jumlah isipadu gas hydrogen terkumpul ialah 340 cm3.
IV The rate of release of hydrogen gas decreases with time.
Kadar pembebasan gas hidrogen berkurang dengan masa.
A
B
C
D
4.

The general formula of an organic substance that can decolourise the purple colour of
acidified potassium permanganate(VII) solution is
Formula am bagi satu bahan organik yang boleh menyahwarnakan larutan ungu kalium
manganat(VII) berasid adalah
A
B
C
D

5.

IV only
I and IV
I, II and IV
I, III and IV

CnH2n+1OH
CnH2n+1COOH
CnH2n
CnH2n+2

Which of the following pairs of substances are not isomers ?

Antara pasangan berikut yang manakan bukan isomer?
A Hexane and 2,3-dimethyl pentane
Heksana dan 2,3 dimetilpentana
B 1-butene and 2-methylpropene
1-butena dan 2-metilpropena
C Pentane and 2,2-dimethylpropane
Pentana dan 2,2-dimetilpropana
D 2-chloropentane and 3-chloropentane
2-kloropentana dan 3-chloropentana

6.

Pentyl propanoate is a food flavouring with apricot taste. This substance can be obtained
from the reaction between
Pentil propanoat adalah perasa makanan dengan rasa aprikot. Bahan ini boleh didapati
dari tindak balas antara
A
B
C
D

C3H7OH and C4H9COOH

C4H9OH and C2H5COOH
C5H11OH and C2H5COOH
C5H11OH and CH3COOH

7.

Concentrated
sulphuric asid
Asid sulfurik
pekat

Butene

Diagram 3
Rajah 3
Consider the conversion in Diagram 3 and identify the substance X.
Pertimbangkan pertukaran dalam Rajah 3 dan kenal pasti bahan X.
A 1-butanol
1-butanol
B 2-methylpropanol
2-metilpropanol
C Butanoic acid
Asid butanoik
D 2-methyl-2-butanol
2-metil-2-butanol
8.

W, X, Y and Z are four metals. Consider the reactions below involving these metals:
W,X, Y dan Z terdiri dari empat logam. Pertimbangkan tindak balas yang melibatkan
logam-logam tersebut di dibawah :
Z sulphate + X
Z sulphate + W
Y sulphate + W

Z + X sulphate
No reaction
Y + W sulphate

Arrange the metals W, X, Y and Z in decreasing order of reactivity.

Susun kereaktifan logam-logam W,X, Y dan Z mengikut tertib menurun.
A
B
C
D
9.

X, W, Z, Y
Y, W, Z, X
X, Z, W, Y
Y, Z, W, X

In which of the following compounds is the oxidation number of nitrogen the highest?
Antara sebatian-sebatian berikut ,yang manakah mempunyai nombor pengoksidaan yang
tertinggi bagi nitrogen ?
A
B
C
D

KNO2
NH4Cl
N2O
HNO3

10.

Magnesium ribbon, tin foil, copper foil and zinc foil are coiled around four different iron
nails. The metal pairs are then placed in a test tube containing aqueous sodium chloride
solution. Which of the test tubes will contain the highest concentration of iron(II) irons
after 2 days?
Pita magnesium, lingkaran stanum, lingkaran ferum dan lingkaran zink diikat pada paku
besi. Pasangan logam itu kemudian diletakkan di dalam tabung uji yang mengandungi
larutan natrium klorida. Antara tabung uji berikut yang manakah mengandungi kepekatan
ion ferum(II) yang paling tinggi selepas 2 hari.
A
B
C
D
11.

W
X
Y
Z

When a mixture of carbon and copper(II) oxide is heated strongly

Apabila satu campuran karbon dengan kuprum(II) oksida di panaskan dengan kuat
I

the oxide ion loses two electrons.

Ion oxida melepaskan dua elektron.
II the oxidation number of carbon increases from 0 to +4
nombor pengoxidaan karbon bertambah dari 0 kepada +4.
III the copper(II) oxide acts as the reducing agent.
Kuprum(II) oksida bertindak sebagai agen penurunan.
IV the copper(II) ion accepts two electrons
Ion kuprum(II) terima dua elektron.
A
B
C
D

I and III
II and IV
II, III and IV
I, II, III and IV

12.

When 25 cm3 of 0.25 mol dm-3 silver nitrate solution is added into 25 cm3 of 0.25 mol
dm-3 sodium chloride solution, the temperature of the mixture rises by 3oC. What is the
quantity of heat released in this experiment?
Apabila 25 cm3 of 0.25 mol dm-3 larutan argentum nitrat ditambah ke 25 cm 3 of 0.25
mol dm-3 larutan natrium klorida, suhu campuran tersebut meningkat sebanyak 3oC.
Apakah kuantiti haba yang dibebaskan di dalam eksperimen ini.
(Specific heat capacity of water = 4.2 J g-1 oC-1)
(Muatan haba tentu air = 4.2J g -1 o C -1 )
A
B
C
D

13.

25 x 4.2 x 3.0 J
25 x 4.2 x 0.25 x 3.0 J
50 x 4.2 x 3.0 J
50 x 4.2 x 0.25 x 3.0 J

The heat of neutralisation between hydrochloric acid and sodium hydroxide solution is
higher than the heat of neutralisation between ethanoic acid and sodium hydroxide solution
because
Haba peneutralan antara asid hidroklorik dan larutan natrium hidroksida adalah lebih
tinggi berbanding haba peneutralan antara asid etanoik dan larutan natrium hidroksida
kerana
A energy is needed to ionise the ethanoic acid.
tenaga diperlukan untuk mengionkan asid etanoik
B the reaction between ethanoic acid and sodium hydroxide solution is incomplete.
tindak balas antara asid ethanoik dan larutan natrium hidroxida adalah tidak lengkap

14.

hydrochloric acid is a mineral acid whereas ethanoic acid is an organic acid.

asid hidroklorik adalah asid mineral manakala asid etanoik adalah asid organic

hydrochloric acid and ethanoic acid have different pH values.

asid hidroklorik dan asid etanoik mempunyai nilai pH yang berbeza.

In an experiment to determine the heat of combustion of propane, when 2.4 g propanol is

completely burnt, the temperature of 500 cm3 of water increases by 38.5 oC. What is the
heat of combustion of propanol?
Dalam suatu eksperimen untuk menentukan haba pembakaran propane, apabila 2.4 g
propanol terbakar dengan lengkap suhu 500 cm3 air meningkatkan sebanyak 38.5oC.
Tentukan haba pembakaran propanol.
(Relative molecular mass of propanol=60, Specific heat capacity of water = 4.2 J/g oC)
(Jisim molekul relatif propanol=60, Muatan haba tentu air = 4.2 J / g o C )

15.

500 x 4.2 x 38.5 kJ/mol

2.4 x 60 x1000
60 x 4.2 x 38.5 kJ/mol
2.4 x 1000x 500
2.4 x 60 x 500 kJ/mol
4.2 x 38.5
60 x 500 x 4.2 x 38.5 kJ/mol
2.4 x 1000

The reaction between zinc and silver nitrate solution is represented by the equation:
Tindak balas antara zink dengan argentum nitrat diwakili dengan tindak balas berikut :
Zn(s) + 2AgNO3(aq)

2Ag(s) + Zn(NO3)2(aq)

H = -310 kJ mol-1

Which of the statements is true concerning the reaction above?

Antara pernyataan berikut yang manakah yang benar mengenai tindak balas di atas
[relative atomic mass of Ag = 108, Zn = 65]
[Jisim atom relatif Ag = 108, Zn = 65]
I

The zinc metal is oxidised.

Logam zink di oksidakan
II The temperature of the mixture increases during reaction.
Suhu camppuran meningkat semasa tindak balas
III When 10.8 g of silver is displaced, 31 kJ of heat is released.
Bila 10.8 g argentum disesarkan , 31 kJ haba dibebaskan
IV When 6.5 g of zinc is reacted, 31 kJ of heat is released.
Bila 6.5 g zink ditindak balaskan , 31 kJ haba di bebaskan
A
B
C
D
16.

I and II
III and IV
I, II and IV
II, III and IV

In which category of medicine is emphetamine grouped into?

Dalam kategori ubat yang manakah emfetamin dikelaskan?
A
B
C
D

Antibiotic
Analgesic
Hormone
Psychotherapeutic

17.

Picture 1
Gambar 1
Picture 1 shows some oil palm fruits. Saponification of oil palm produces
Gambar 1 menunjukkan buah kelapa sawit. Saponifikasi minyak kelapa sawit
menghasilkan
A one glycerol molecule and one soap molecule.
Satu molekul gliserol dan satu molekul sabun.
B one glycerol molecule and two soap molecules.
Satu molekul gliserol dan dua molekul sabun.
C one glycerol molecule and three soap molecules.
Satu molekul gliserol dan tiga molekul sabun.
D soap and water molecules.
Sabun dan molekul air.
18.

Which of the following food additive is correctly categorised?

Antara bahan tambah makanan berikut , yang manakah di kategorikan dengan betul?
I
II
III
IV
A
B
C
D

Food additive
Ascorbic acid
Carmoisine
Starch powder
Sodium
phosphate
I and III
I, II and IV
II, III and IV
I ,II ,III and IV

Category
Antioxidant
Colouring
Thickening agent
Food additive

19 The diagram shows the set up of the apparatus of a simple chemical cell.
Gambarajah menujukkan susunan alat radas untuk sebuah sel ringkas.
Electron flow
Electrode L

Electrode Y
Electrolyte

What are metals X and Y that produce the highest voltage of the cell?
Apakah logam X dan Y yang boleh menghasilkan voltan sel yang tertinggi?

A
B
C
D
20

Metal X
Logam X
Aluminium
Aluminium
Silver
Argentum
Magnesium
Magnesium
Zinc
Zink

Metal Y
Logam Y
Iron
Besi
Magnesium
Magnesium
Copper
Kuprum
Lead
Plumbum

The diagram represents the molecular formula of a carbon compound.

Gambarajah mewakili formula molekul suatu sebatian karbon.
CH3-CH2 -COOCH2CH2CH2CH3
What is the IUPAC name for the above carbon compound?
Apakah nama IUPAC untuk sebatian karbon di atas?
A
B
C
D

Ethyl propanoate
Etil propanoat
Propyl propanoate
Propil propanoate
Propyl butanoate
Propil butanoat
Butyl propanoate
Butil propanoat

21. The table shows the melting points and boiling points of substances S, T, U, V
and W
Substanc

Melting

Boiling point/

point/oC

- 182

- 162

- 23

77

- 97

65

41

182

132

290

Which substance exists as a gas at room temperature?

S only

S and T only

T and U only

Vand W only

22. The table below shows the proton number of elements M and N
Element
M
N

Proton number
3
17

Which is true of the compound formed between elements M and N?

Compound formula

23

Type of bond

MN

Ionic bond

MN

Covalent bond

M2N3

Ionic bond

M3N2

Covalent bond

Q
Dilute sodium chloride

In which set of the following pair of metals would electron flow in the direction as
in the diagram?

A
B
C
D

24.

Copper
Zinc
Copper
Zinc

magnesium
Magnesium
Iron
Lead

What is the number of atoms in 1 mole of ammonia, NH3?

Use the information that the Avogadro Constant 6.02 X 1023 mol-1

25

6.02 X 1023

2.408 X 1024

1.806 X 1023

1.2 X 1024

The chemical formula for glucose is C6H12O6. This shows that

I

the empirical formula for glucose is CH2O

II

each glucose molecule is made up of 6 carbon atoms, 12 hydrogen atoms and

6 oxygen atoms.

III

1 mol of glucose contains a total of 144 x 1023 atoms

IV

One glucose molecule has a mass of 180 times higher than the mass of 1
hydrogen atom

Use the information relative atomic mass for H =1,C =12 and O =16
Avogadro Constant = 6.02 X 1023 mol-1
A

I and II only

26

I, III and IV only

II, III and IV only

I, II, III and IV

What is the percentage by mass of nitrogen content in urea, CO(NH2) 2 ?

Use the information that the relative atomic mass of C = 12 , N =14, H=1
and O = 16
A

23.3 %

31.8 %

46.7 %

63.6 %

27
A meteorologist would like to release a weather balloon to the amosphere to
carry out carry out studies on the weather.
Between A, B, C and D in the Periodic Table shown below which is the most
suitable element to fill up the weather balloon?

28

The diagram shows the electron arrangement of a substance formed between two
atoms of Z.

Which of the following statements is true about the substance?

A

Consists of ions

Conduct electricity in molten state

29.

The compound has a low melting point

Dissolves in water

When 10 cm3 of 0.50 mol dm-3 NaOH is diluted with water to 100 cm 3 , the
concentration of NaOH solution is

30.

0.050 mol dm-3

0.10

mol dm-3

0.15

mol dm-3

0.20

mol dm-3

The reaction between lead (II) nitrate and potassium iodide solution is represented by
the equation below
Pb(NO3)2 (aq) + 2KI (aq) PbI2 (s) + 2KNO3 (aq)
25.0 cm3 of 1.0 mol dm-3 potassium iodide solution is mixed with 25.0 cm 3 of 1.0 mol
dm-3 lead (II) nitrate solution. What is the maximum mass of lead(II) iodide produced
in this reaction?
Use the information relative atomic mass for I = 127 and Pb = 207

31.

32

4.175 g

5.76 g

8.35 g

11.52 g

Which of the following is NOT a characteristic of ammonia?

A
Very soluble in water.
B
Has a pungent smell.
C
A white fume gas.
D
Alkaline gas.
1g of magnesium was allowed to react with 50 cm of sulphuric acid, 1 mol dm-.
Three experiments were conducted using three different sizes of magnesium. The
time taken to collect 20cm of hydrogen gas is as below.
Experiment

II

III

Time / s

16

25

Which of the following experiments show the arrangement of the size of magnesium
in decreasing order?

33

I, II, III

II, I, III

III, II, I

III, I, II

The diagram below is a structural formula of a polymer.

H

CH3

CH3

CH3

CH3

What is the structural formula of the monomer for the above polymer?
A
B
H

H
H

C
H
H

H
C

H
H

H
H

34

A compound with formula M2CO3 has a relative formula mass of 138.

What is the relative atomic mass of M ?
Use the information that the relative atomic mass of C = 12 and O = 16
A

39

69

78

110

35

Study the structural formula below:

H
H

H
H

H
H

H
H
H

Based on the IUPAC system, what is the name of the compound having this structural
formula?

36

2,4,4- trimethylpentane

2,4,4- trimethyloctane

2-ethyl-4-methylpentane

2,4-dimethylhexane

Butane has some similar characteristics with butene. The characteristics are
I
II

37

Exist as gas at room temperature.

Decolourise the purple colour of acidified potassium manganate(VII).

III

Cannot dissolve in water.

IV

Burn in excess air to produce a gas that turns limewater cloudy.

I and III only

II and IV only

I, III and IV only

I, II, III and IV

Two experiments were conducted to study the rate of reaction between excess
calcium carbonate and sulphuric acid as shown below.
Experiment
I
II

Sulphuric acid
25cm H SO4, 1 mol dm-
50cm H SO4, 0.5 mol dm -
2

Which of the following graphs best describes the results of the above
experiments?
Volume/cm3

Volume/cm3

II
II
I

time/s

time/s
Volume/cm3

B Volume/cm3

II

II
time/s

38

time/s
The relative atomic mass of metal Q is 7 and the relative atomic
mass of the metal W is 56
Which of the following conclusions can be drawn from the above statement?

39

1 mol of W has 8 times more atoms than 1 mol of Q

II

1 atom of W is 8 times heavier than 1 atom of Q

III

1 atom of W has the same number of protons with 8 atoms of Q

IV

56 g of W has the same number of atoms as in 7 g of Q

I and III only

II and IV only

I, II and III only

I, II, III and IV

The equation shows neutralization reaction between W hydroxide solution and nitric
acid.
W(OH)2 + 2HNO3 W(NO3)2 + 2H2O

20 cm3 of W hydroxide solution 0.5 mol dm -3 neutralized 20 cm3 of nitric acid. What
is the concentration of the nitric acid needed?

40

0.25 mol dm-3

0.50 mol dm-3

1.00 mol dm-3

2.00 mol dm-3

An esterification reaction is given as follows:

Propanoic acid + ethanol Q + H2O
What is the molecular formula of ester Q?
A
B
C
D

41

C3H7COOC2H5
C2H5COOC3H7
C2H5COOC2H5
C5H11COOH

Below are the symbols of element X and Z.

27
13

12
6

If elements X and Z combine together to form an alloy Q, what is the arrangement of

atoms in alloy Q?
A

B
Atom Z
Atom X

Atom X

Atom Z

D
Atom X

Atom Z

Atom Z
Atom D
X

42. The equation below represents the reaction to extract aluminium from aluminium

oxide.

2Al2O3

4Al +

3O2

What is the mass of aluminium that can be extracted from 51 g of aluminium

oxide ?
Given that relative atomic mass of Al = 27 and O = 16

43

6.75 g

13.5 g

27.0 g

54.0 g

Between these aqueous solutions, which will give the increasing number in pH value?
A

CH3COOH, HCl, NaOH, NaCl

HCl, NaCl, CH3COOH, NaOH

NaOH, NaCl, CH3COOH, HCl

HCl, CH3COOH, NaCl, NaOH

44. The table shows the number of electrons, proton number and number of neutrons for
particles X and Y.

Particle

Number of

Proton number

Number of

electrons
10

neutrons
8

Which of the following conclusions is correct for X and Y?

45

X is a positive ion

X and Y are isotopes

The mass of 1 mol of X is equals to 16g

Both X and Y are charged particles

The combustion of methane is as follows:

CH4 + 2O2

CO2 + 2H2O

If 100 cm3 of methane is burnt in excess air, what is the volume of carbon dioxide
gas given off at room conditions?
Given that 1 mol of gas occupies 24 dm3 at room conditions.

46

47

100 cm3

150 cm3

200 cm3

300 cm3

Which of the following are the properties of acid?

I

Changes the blue litmus paper to red

II

Reacts with metal to produce salt and hydrogen gas only

III

Reacts with metal oxide to produce salt and water only

IV

Reacts with metal carbonate to produce salt and carbon dioxide only

I and II only

II and III only

I, II and III only

I, II, III and IV

You were asked by your teacher to verify the cation and anion in a sample of
iron ( II ) chloride salt solution.
What substance can you use to verify the cation and anion?

A
B
C
D
48

Cation
Nessler reagent
Nessler reagent
Sodium hydroxide
Sodium hydroxide

Anion
Dilute nitric acid and silver nitrate
Dilute hydrochloric acid and barium chloride
Dilute nitric acid and silver nitrate
Dilute hydrochloric acid and barium chloride

The figure below shows the structural formula of a molecule of fat X.

O
C

CH2

O
C
O
C

CH

CH2

Which of the following is true about fat X?

I
Fat X can undergo hydrogenation reaction.
II

Fat X could be found much in plants or vegetables.

III

Increases the amount of cholesterol in blood.

IV
Fat X is an ester.
I and II
III and IV
I, II and IV
I, II, III and IV

A
B
C
D

49. The table below shows the melting and boiling points of substances P, Q, R and S.
[Jadual menunjukkan takat lebur dan takat didih bahan P, Q, R dan S. ]
Substance
[Bahan]

Melting point(C)
[Takat lebur]

Boiling point (C)

[Takat didih]

Which
of
the
following are true
P
-25
5
about the physical
state of the of
Q
10
140
substances P, Q, R
R
50
300
and S at room
S
350
2340
temperature ?
Yang manakah antara berikut adalah benar tentang keadaan fizik bahan P, Q, R dan S pada suhu bilik ?
I
II
III
IV

Substance [Bahan]
P
Q
R
S

Physical state [Keadaan fizik]

Gas[Gas]
Liquid[Cecair]
Solid[Pepejal]
Solid[Pepejal]

A I and III
B II and IV
C I, III and IV
D I, II, III and IV

50. Compound P and compound Q have the molecular formulae CH3OH and C2H5OH resperctively.
Which of the following reaction is true of both compounds?
[Sebatian P dan sebatian Q mempunyai formula molekul CH3OH dan C2H5OH masing-masing.
Tindak balas yang manakah antara berikut adalah benar untuk kedua-dua sebatian?]
A Produce esters when reflux with concentrated sulphuric acid.
[ Menghasilkan ester apabila direfluks dengan asid sulfurik pekat]
B Produce carboxylic acids when reflux with acidified potassium dichromate(VI).
[ Mehghasilkan asid karbosilik apabila direfluks dengan kalium dikromat(VI).]
C Produce alkenes when the vapour is passed through heated porcelain chips.
[Menghasilkan alkena apabila wap sebatian melalui serpihan porselin yang panas.]

D Produce the same amount of heat when undergo complete combustion.

[Menghasilkan jumlah haba yang sama banyak apabila mengalami pembakaran lengkap]

CHEMISTRY SPM 2015

SOALAN ARAS TINGGI
SET 4
1. The table below shows the results of two experiments carried out to investigate the rate of reaction of
magnesium with hydrochloric acid.

[Jadual di bawah menunjukkan keputusan dua eksperimen yang dijalankan untuk

mengkaji kadar tindak balas magnesium dengan asid hidroklorik.]
Experiment
[Eksperimen
]
I
II

Volume of hydrochloric acid/cm3

[Isipadu asid hidroklorik]

Concentration of hydrochloric acid/ mol dm-3

[Kepekatan asid hidroklorik]

50
100

1.0
0.5

Which of the following graphs show the volume of hydrogen gas liberated against time?
[Antara graf yang berikut, yang manakah menunjukkan isipadu gas hidrogen dibebaskan terhadap masa?]
A
Volume of gas /
cm3
[Isipadu gas]

Experiment II
Experiment I
Time / s

C
Volume of gas
/ cm3
[Isipadu gas]

Experiment I
Experiment II

Time / s

B
Volume of gas /
cm3
[Isipadu gas]

Experiment I
Experiment II

Experiment II

Volume of gas / cm
[Isipadu gas]

Experiment I

Time / s

Time / s

2. The formula for X oxide is X2O3 and its relative formula mass is 70. What is the relative atomic
mass of element X?
[Formula bagi oksida X ialah X2O3 jisim formula relatifnya ialah 70. Apakah jisim atom
relatif unsur X?]
[Relative atomic mass of O = 16 ]
[Jisim atom relatif O = 16 ]
A

B 11
C 24
D 27

3. Diagram 10 below shows the set up of an electrolytic cell and a chemical cell
[Rajah 10 di bawah menunjukkan susunan bagi sel elektrolisis dan sel kimia.]

Electrolytic cell
[ Sel elektrolisis]

Chemical cell
[Sel kimia]

DIAGRAM 10
Which of the following statements is common to both electrolytic cell and chemical cell?
Antara penyataan berikut yang manakah benar bagi kedua-dua sel?

A The energy changed is from electrical energy to chemical energy.

[Perubahan tenaga yang berlaku adalah dari tenaga elektrik ke tenaga kimia].
B The electrons flow from the negative electrode to the positive electrode.
[ Elektron mengalir dari elektrod negatif ke elektrod positif.]
C Reduction occurs at the anode and oxidation occurs at the cathode.
[Proses penurunan berlaku di anod dan proses pengoksidaan berlaku di katod]
D The more electropositive metal will becomes the anode in both cell
[Elektrod yang lebih elektropositif akan menjadi anod dalam kedua-dua sel]
4. Diagram 11 shows the atomic symbol for element M
[Rajah 11 menunjukkn simbol atom bagi unsur M.]
19

M
DIAGRAM 11

The nucleus of atom M contains

[Nukleus atom M mengandungi]
A 9 electrons and 19 neutrons
B 9 protons and 10 neutrons
C 9 electrons and 10 protons
D 9 protons and 19 neutrons

5. Diagram 12 shows the conversion of methanol into compound P and subsequently into compound Q.
[Rajah 12 menunjukkan penukaran metanol kepada sebatian P yang seterusnya kepada sebatian Q.]

Compound P
[Sebatian P]

CH3OH

Heat with acidified K2Cr2O7

[Panakan dengan K2Cr2O7
Berasid]

DIAGRAM 12

Which of the following may be compound Q?

[Yang manakah antara berikut ialah sebatian Q?]
A Methanoic acid [Acid metanoik]

Compound Q
[Sebatian Q]
reflux with C2H5OH and
concentrated H2SO4
[Refluks dengan C2H5OH dan H2SO4
Pekat]

B Methylethanoate [Metilletanoat]
C Ethylmethanoate [ Etilmetanoat]
D Ethylethanote [ Etilletanoat]

6. 12.4 g of P has reacted with 9.6 g of Q.

Which of the following represents the reaction?
[12.4 g P telah bertindakbalas dengan 9.6 g Q.
Yang manakah antara berikut mewakili tindakbalas tersebut?]
[Relative atomic mass of P= 31 , Q = 16]
[Jisim atom relatif P= 31 , Q = 16]
A
B
C
D

4P
2P
4P
4P

+
+
+
+

Q2
Q2
3Q2
5Q2

2P2Q
2PQ
2P2Q3
2 P2Q5

7. The following shows the chemical equation for the reaction between ammonia gas and hydrogen chloride
gas.
[Persamaan berikut mewakili tindakbalas antara gas ammonia dan gas hidrogen klorida.]
NH3 (g)

HCl(g)

NH4Cl (s)

500 cm of ammonia gas has reacted with excess hydrogen chloride gas at S.T.P.
What is the mass of ammonium chloride formed in the reaction?
[500 cm3 gas ammonia telah bertindakbalas dengan gas hidrogen khlorida pada S.T.P.
Berapakah jisim ammonium klorida terbentuk dalam tindakbalas itu?]
[Relative atomic mass of H=1, N=14 , Cl =35.5 ; 1 mol of gas occupies 22.4 dm3 at S.T.P]
[Jisim atom relative of H=1, N=14 , Cl =35.5 ; 1 mol gas menempati 22.4 dm3 at S.T.P]
A 22.4 x 1000
500 x 53.5
B 22.4 x 1000 x 53.5
500
C

500 ______
22.4 x 1000 x 53.5

D __53.5 x 500_

22.4 x 1000
8. 3.2 g of copper (II) oxide powder is reacted with excess dilute nitric acid.
What is the mass of copper (II) nitrate formed in the reaction?
[3.2 g serbuk kuprum(II) oksida ditindakbalaskan dengan asid nitrik cair yang berlebihan. Berapakah
jisim kuprum(II) nitrat yang terbentuk dalam tindak balas itu?]
[Relative atomic mass : N,14; O,16; Cu,64]
[Jisim atom relatif : N,14; O,16; Cu,64]
A 3.76 g
B 4.96 g
C 5.04 g
D 7.52 g
9. The following information is given.
Relative atomic mass of C =12; H=1; O = 16 and Na = 23
[ Jisim Atom Relatif C=12; H=1; O=16; Na=23 ]
One mole of ethane, C 2H 4 contains
[Satu mol etena, C 2H 4 mempunyai]
I the same number of molecules as 1 mole of methane, CH 4
[bilangan molekul yang sama dengan 1 mol metana CH 4 ]
II the same number of carbon atoms as 2 moles of sodium carbonate, Na 2CO 3
[bilangan atom karbon yang sama dengan 2 mol natrium karbonat, Na2CO 3]
III the same mass as 1 mole of carbon monoxide
[jisim yang sama dengan 1 mol karbon monoksida]
IV the same volume as 1 mole of hydrogen gas
[isipadu yang sama dengan 1 mol gas hidrogen]
A III and IV
B I , II and III
C II,III and IV
D I, II, III and IV
10. The thermochemical equation below represents the combustion of methane in excess oxygen.
[Persamaan termokimia berikut mewakili pembakaran metana dalam oksigen berlebihan]
CH4(g) + 2O2(g) CO2(g) + 2H2O(l)

H = -890 kJmol-1

Which of the following are true when 4.0g of methane was burnt in excess oxygen?
[Yang manakah antara berikut adalah benar apabila 4.0g of metana dibakar dalam oksigen
berlebihan?]
[Relative atomic mass: H,1;C,12;O,16;Molar volume of gas = 24 dm3 at room temperature]
[Jisim atom relative: H,1;C,12;O,16; Isipadau molar gas = 24 dm3 pada suhu bilik]
I

222.5 kJ heat was released

222.5 kJ haba terbebas

II 0.25 mol of oxygen is used

0.25 mol oksigen terhasil
III 6 dm3 of carbon dioxide was formed
6 dm3 karbon dioksida terbentuk
IV 4.5g of water was produced
4.5g air terbentuk
A
B
C
D

I and III only

II and IV only
II, III and IV only
I, II, III and IV

11. The table below shows the results of an experiment to study the displacement of metal from its
solution using other metals[ Jadual menunjukkan keputusan eksperimen untuk mengkaji penyesaran logam
dari larutan garamnya oleh logam yang lain]

Metal
[Logam]
W
Y
Z

Nitrate of W
[Nitrat logam W]

Nitrate of Y
[Nitrat logam W]

Nitrates of Z
[Nitrat logam W]
X
X
-

Which of the following statements is true about metals W,X and Y?

[ Antara berikut yang manakah benar tentang W,X dan Y?]
I.

W is more electropositive than Y

[W adalah lebih elektropositif dari Y.]

II. No reaction occurs between Z and nitrate of Y

[Tiada tindakbalas berlaku antara Z and Y nitrat. ]
III W is placed higher than Z in the electrochemical series
[W terletak lebih atas dari Z dalam siri elektrokimia]
IV The arrangement of metals W,Y and Z in descending order of electropositivity
is Z,W and Y.
[ Susunan logam dalam tertib keelektropositifan menurun ialah Z,W danY.]
A. I and III only
B. I and IV only
C. I,II and III only
D. I,II,III and IV
12. A student was provided with 2.40 g solid sodium hydroxide to prepare a standard solution of
0.12 mol dm-3 sodium hydroxide
[ Seorang pelajar telah dibekalkan sebanyak 2.40 g pepejal natrium hidroksida bagi menyediakan
satu larutan piawai natrium hidrksida 0.12 mol dm-3]
(Relative atomic mass : Na =23; O=16; H=1 )
(Jisim atom relatif : Na =23; O=16; H=1 )
The size of the volumetric flask required to prepare the solution is.
[Saiz kelalang volumetrik yang diperlukannya ialah untuk menyediakan larutan tersebut ialah]
A 200 cm3

B 250 cm3
C 500 cm3
D 1000 cm3
13. Diagram 13 shows the set up of apparatus for the titration of sodium hydroxide solution with
sulphuric acid.
[Rajah di bawah menunjukkan susunan radas bagi proses pentitratan larutan natrium hidroksida
dengan asid sulfurik.]

0.1 mol dm-3 of sulphuric acid

[Asid sulfurik 0.1 mol dm-3]

20 cm3 of 0.2 mol dm-3 sodium hydroxide and

phenolphthalein as an indicator
[20 cm3 larutan natriun hidroksida
0.2 mol dm-3 dan penunjuk fenolftalein]

DIAGRAM 13
What is the total volume of the solution in the conical flask at the end point of titration ?
[Berapakah jumlah isipadu larutan di dalam kelalang kon pada takat akhir pentitratan?]
A 20 cm3
B 30 cm3
C 40 cm3
D 50 cm3

14

When a mixture of 2-butanol, CH3CHOHCH2CH3 and concentrated sulphuric acid is

heated, gas X is produced. Which of the following is the molecular structure of X?
A
B
C
D

15

CH3CH=CHCH3
CH3CH=C(CH3)2
(CH3)2CHCH=CH2
CH3CH2CH=CH2

The diagram below shows the changes of the sulphur in Contact Process.
S

SO2

SO3

H2S2O7

Which of the following are the correct changes in the oxidation state of sulphur?

16

0
+4
+6
+6
A
0
+4
+6
+7
B
1
+3
+6
+8
C
1
+4
+6
+6
D
The following equation shows the formation of water

H2(g) + O2(g) H2O(l) , H = 287 kJmol

Which of the following is true regarding the above equation?
A
B
C
D
17

Activation energy for the reaction is high

If 1 mole of oxygen reacts 574 kJ of heat energy is absorbed
Combustion of 1 mole of hydrogen releases 287 kJ of heat energy
1 mole of water that is formed in the reaction received 287 kJ heat energy

A patient claims he always heard someone says something to him but he

didnt see anybody around him during the situation.
Which of the following medicines is most appropriate in treating the above symptoms or
disorders?
A
Chlorpromazine
B
Amphetamine
C
Tranquilisers
D
Barbiturates

18

Which of the following isotopes is used to detect leakage in a gas pipe?

A
Carbon 14
B
Cobalt 60
C
Sodium 24
D
Iodine - 131

19

34 g of ammonia consists of
[Relative molecular mass of ammonia = 17, Avogadro constant = 6.02 x 10 23 mol-1]
I
2 mole of nitrogen atoms
II
2 mole of ammonia molecules
III
1.204 X 1024 molecules
IV
5 mole of hidrogen atoms
A
B
C
D

20

I and II only
I, II and III only
II, III and Iv only
I, II, III and IV only

Profesional cyclists usually fill their bicycle tyres with gas X which makes the bicycle
lighter.

X
Y

W
Z

Which of the following elements X, Y, W and Z in the Periodic Table is suitable to be

used in bicycle tyres?
A
B
C
D
21

X
Y
W
Z

The diagram below shows the symbols of atoms D and E

27

16

D
13

E
8

Atom D reacts with atom E to form a compound. Calculate the relative molecular mass
for the compound formed.
A
B
C
D
22

23

21
43
102
113

Calculate the volume of sodium hydroxide of concentration 0.5 mol dm-3 needed to
neutralize 25.0 cm3 sulphuric acid of concentration 0.20 mol dm-3.
A
10 cm3
B
20 cm3
C
25 cm3
50 cm3
D
The table below shows the potential difference of three simple voltaic cells.
Cell

Pair of metal

I
II
III

Mg and Cu
Mg and Zn
Zn and Fe

Potential
difference(V)
3.0
1.5
0.5

Negative
terminal
Mg
Mg
Zn

What is the potential difference of a simple voltaic cell for pair of iron and copper ?
A
B
C
D
24

0.5 V
1.0 V
1.5 V
2.5 V

200 cm3 of 0.1 mol dm-3 sodium chloride solution reacts completely with excess silver
nitrate. Calculate the mass of precipitate produced.

[Relative atomic mass of: Ag, 108; Cl, 35.5]

A
B
C
D
25

2.78 g
2.87 g
3.78 g
3.87 g

The uses of substance X;

To clean metals.
To produce detergents.
To make paints.

What is substances X?
A
B
C
D
26

Nitric acid
Sulphuric acid
Ammonia
Ammonium sulphate

Graph represents the decomposition of 25 cm3 hydrogen peroxide of 0.5 mol dm-3 with
manganese(IV) oxide as a catalyst at a temperature of 30oC.

Which of the following experiments will produce graph II ?

Volume of
hydrogen peroxide / cm3
A
B
C
D

27

Temperature of

hydrogen peroxide/
mol dm-3
0.7
0.5
0.7
0.5

hydrogen peroxide / oC
30
30
30
20

Which of the following equations represents a redox reaction?

A
B
C
D

28

15
15
40
40

Concentration of

Pb(NO3)2(aq) + CuSO4(aq)
CH3COOH(aq) + NaOH(aq)
Mg(s) + CuSO4(aq)
C2H4(g) + 3O2(g)

PbSO4(s) + Cu(NO3)2(aq)
CH3COOH(aq) + H2O(l)
MgSO4(aq) + Cu(s)
2CO2(g) + 2H2O(l)

The diagram below shows the molecular formulae of two compounds A and B. Substance
X is formed when both compounds react with each other.

Compound B,
C2H5COOH

Compound A,
C2H5OH

Substance X

Which of the following set represents substance X?

C
H
H

Structural formula

A
H
C

Name

C
H

H
H Ethyl propanoate
H

B
H
C

Ethyl propanoate

C
H

C
H

H
H

Propyl propanoate

D
Propyl propanoate