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31 03 2
31 03 2
GRAND TEST-7
Time : 9:00 AM to 12.00 Noon
Date: 31-03-13
Main_GT-7(31/03/13)
Page 2
Main_GT-7(31/03/13)
CHEMISTRY
1.
1) Al 3 Ba 2 Na
3) Fe CN 6
2.
PO 4 3 SO 4 2 Cl
4) Al 3 Ba 2 Na
1) 1.344
3.
2) 3.584
3) 0.64
4) 1.584
The equivalent conductivity of a monobasic acid at infinite dilution is 348ohm 1cm 2eq 1
. If the resistivity of the solution containing 15g acid (M.Wt-49) in 1 lit is 18.5 ohm
cm, what is the degree of dissociation of acid ?
1) 50.7%
2) 60.4%
3) 25.35%
4) 40%
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Main_GT-7(31/03/13)
4.
5.
3) 45 K .Cal mole 1
4) 90 K .Cal mole 1
An impure sample of NaCl weighing 2 grams was dissolved in water and excess of
AgNO 3 solution was added. The weight of precipitate formed was 0.287g. The
2) 5.85%
3) 25%
4) 2.85%
The density of an ionic crystal is 2.75g cm 3 and edge length of unit cell is 660 pm.
The formula weight of ionic compound is 119. The number of unit cells present in
23.8 g of the ionic compound is
1) 1.2046 10 23
2) 3.01110 22
3) 6.023 10 22
4) 1.2046 10 22
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Main_GT-7(31/03/13)
7.
N
NaOH for
5
complete neutralization. Calculate the original weight of the organic compound taken.
1) 2 gm
2) 1.4 gm
3) 4 gm
4) 20 gm
8.
9.
1) CH 3CHO
The velocity of electron is 2.2 10 6 m sec 1 . If the uncertainty in its velocity is 0.1% the
uncertainty in its position is
1) 2.63 10 10 m
2) 26.3Ao
3) 26.3 nm
4) 2.63nm
Page 5
Main_GT-7(31/03/13)
10.
PCl 5 g
PCl 3 g Cl 2 g ; Kp
Kp
2) x
Kp P
Kp P
3) x K p P
Kp
4) x K P
p
12.
2) a, b, c, d
O2
Ore CN H 2
O
1) X Ag CN 2
3) X Au CN 2
Zn
3) b, c, d
4) a, c, d
Zn CN
;Y
4
Zn CN
;Y
2) X Ag CN 4
Zn CN
;Y
4) 1 and 3
Page 6
Main_GT-7(31/03/13)
13.
5 NO 2
Co NH
3
2)
1) Co NH 3 4 Cl 2
3) cis CrCl 2 ox 2
4)
14.
Co NH
3
The
5 SO 4
equilibrium
is optically active
Br and Co NH 3
constant
2 NOCl g 2 NO g Cl 2 g .
5 Br
for
Given
the
following
reaction
H 0 77.2 KJ mole 1
at
400K
is
S 0 122 JK 1 mole 1
log1.95 0.292
1) K c 1.995 10 4 2) K c 5.105 10 3 3) K c 2.5 10 4
15.
4) 1.95 10 4
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Main_GT-7(31/03/13)
16.
17.
2) a, b, c
3) a, c, d
4) a, b, c, d
The osmotic pressure of 0.1M solution of MgCl 2 at 300K is 4.92 atm. The percentage
ionization of the salt is
1) 20%
18.
2) 39%
3) 49%
4) 69%
A salt X on heating liberate one coloured gas and another coloureless gas. Both the
gases are paramagnetic. The salt Xmay be
1) NaNO3
19.
2) KNO3
3) Na2CO3
4) LiNO3
2) 1
a
RTV
3) 1
Pb
RT
RTV
4) 1 a
Page 8
Main_GT-7(31/03/13)
20.
In which of the following arrangements the order is not correct according to the
property indicated against it ?
1) O 2 F Na Mg 2 Al 3 (ionic radii)
2) F Cl Br I (Electron gain enthalpy)
3) B C O N (First ionization enthalpy)
4) SiO 2 P2O 5 SO3 Cl 2O 7 (acidic nature)
21.
22.
2) NO
3) Cl 2
23.
1) 4.62 10 2 M min 1
2) 2.3110 3 M min 1
3) 2.88 10 3 M min 1
4) 6.93 10 4 M min 1
Which of the following is wrong statement.
1) I 2O5 is a very good oxidizing agent and is used in the estimation of carbon
monoxide.
2) ClO 2 is used as bleaching agent for paper pulp and textiles.
3) When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric
chloride.
4) The inter halogen compound XX 1 hydrolysis as follows.
XX 1 H 2O HX HOX 1 [when X = larger halogen]
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24.
25.
A carbonyl compound X with molecular formula C 5 H 10O gives negative tollens and
iodoform tests and is reduced to n pentane by Zn Hg & HCl . The compound X is
1) 1 pentanol
26.
2) pentanal
3) 2-pentanone
4) 3-pentanone
Three organic compounds A, B & C liberates H 2 gas when react with Na metal.
Compounds A and B reacts with Tollens reagent but not C . A decolourises
bromine water. But not B. Then A is
O
1)
H 3C
CH3
3) CH CH
2)
HCOOH
4) CH 3 C C CH 3
Page 10
Main_GT-7(31/03/13)
27.
Which of the following sequence of reagent is the good means to furnish the
conversion
R CH 2OH R CH 2 NH 2
0
(d) Cu / 300 C; NH 3 ; LiAlH 4
1) a, b, c, d
28.
29.
2) a, b, c
3) b, c, d
4) c, d
Incorrect pair
1) Biuret test Protein
The number of chiral centres present in gluco pyranose and fructo furanose are
1) 4 and 5
2) 5 and 4
3) 4 in each
4) 5 in each
30.
Conc.HNO 3 Conc.H 2 SO 4
C 6H 6
Br2 , Fe
60 C
Br2 , Fe
Conc.HNO 3 Conc.H 2 SO 4
X Major
Y Major
2) Functional isomers
3) Chain isomers
4) Positional isomers
Page 11
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PHYSICS
31.
a
1 e bt . Then
b
The horizontal distance x and the vertical distance y of a projectile at time t w.r.t
point of projection are given by x at and y bt 2 ct where a, b and c are constants.
Then
1) The speed of the projectile 1 second after it is fired is a 2 b 2 c 2
1/2
1 c
2) The angle with the horizontal at which the projectile is fired is sin
a
1/2
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33.
Two blocks A and B are connected to each other by a string and a spring of force
constant k , as shown in fig. The string passes over a frictionless pulley as shown. The
block B slides over the horizontal top surface of a stationary block C and the block A
slides along the vertical side of C both with the same uniform speed. The coefficient of
friction between the surfaces of the blocks is . If the mass of block A is m . The mass
of block B is
1)
34.
2)
3) m
4) m
2) X rays
Page 13
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35.
A smooth uniform rod of length L and mass M has two identical beads of the
negligible size, each of mass m , which can slide freely along the rod. Initially the two
beads are at the centre of the rod and the system is rotating with angular velocity 0
about its axis perpendicular to the rod and passing through its mid point (see Fig).
There are no external forces. When the beads reach the ends of the rod, the angular
velocity of the system is
1)
M 0
M 3m
2)
M 0
M 6m
3)
M 6m 0
M
4) 0
Page 14
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36.
The track shown in Fig ends in a circular track of radius r with centre at O. A small
solid sphere of mass m rolls from rest without slipping from a point A at a height
h 6r from the level ground. The speed of the sphere when it reaches a point B at
Sphere
m
h 6r
O
B
r
1) 10gr
37.
2)
50
gr
7
3)
22
gr
7
4) Zero
A ball is dropped downwards to hit the ground at time t=0. After 1 second another ball
is dropped downwards from the same point. The distance between them after 3
seconds is
1) 25 m
2) 20 m
3) 50 m
4) 9.8 m
Page 15
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38.
A J tube , shown in the figure, contains a volume V of dry air trapped in arm A of the
tube. The atmospheric pressure is H cm of mercury. When more mercury is poured in
arm B, the volume of the enclosed air and its pressure undergo a change. What should
be the difference h in mercury levels in the two arms so as to reduce the volume of
air to V / 2 ? (See Fig)
1) H cm
39.
2) H / 2 cm
3) 2H cm
4) H / 3 cm
A liquid is kept in a vertical cylindrical vessel with upper end is open to atmosphere.
When the vessel is rotated about its axis, the liquid rises at its sides. If the radius of the
vessel is 0.05 m and the speed of rotation is 2 revolutions per second, the difference in
the heights of the liquid at the centre and at the sides of the vessel will be (take
g 10 ms 2 and 2 10 )
1) 2 cm
ICON Srs & LT_JEE-MAIN
2) 4 cm
3) 1 cm
space for rough work
4) 8 cm
Page 16
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40.
The centre of a ring of mass m and a sphere of mass M of equal radius R, are at a
distance 8 R apart as shown in Fig. The force of attraction between the ring and the
sphere is
1)
41.
2 2 GmM
27 R 2
8R
2)
GmM
8R 2
3)
GmM
9R 2
4)
2 GmM
9 9R 2
2) 1/ 2, 1/ 2 and 5 / 2
3) 1/ 2, 1/ 2 and 3 / 2
4) 1/ 2, 1/ 2 and 3 / 2
Page 17
Main_GT-7(31/03/13)
42.
The ends of a rod of length l and mass m are attached to two identical springs as
shown in fig. The rod is free to rotate about its centre O. The rod is depressed slightly
at end A and released. The time period of the resulting oscillations is
l
2
l
2
1) 2
43.
m
2k
2) 2
2m
k
3)
2m
3k
4)
3m
2k
A cube of wood supporting 200 g mass just floats in water. When the mass is
removed , the cube rises by 2 cm. What is the side of the cube ?(Given density of
water= 1g / cm3 )
1) 10 cm
2) 20 cm
3) 30 cm
4) 40 cm
Page 18
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44.
y 4a
3 3
y 3a
P
ya
2 2
1
O
2 ^
2) j
0
1) Zero
45.
3 ^
3) j
0
^
4) j
0
A photon and electron have same de-Broglie wavelength. Given that v is the speed of
electron and c is the speed of light; E e , E p are the kinetic energies of electron and
photon respectively. p e , p h are the momenta of electron and photon respectively.
Then which of the following relation is correct.
Ee
1) E
p
v
2c
Ee
2) E
p
2c
v
pe
3) p
h
c
2v
pe
2c
4) p v
h
Page 19
Main_GT-7(31/03/13)
46.
1) 1 T
47.
3)
2) 1 T
1 T
T
4)
1 T
T
48.
2) 300 J
3) 600 J
r
4) 1200 J
1) 40 NC 1m 2
49.
2) 50 NC 1m 2
3) 60 NC 1m 2
4) Zero
A metal wire of sonometer is held on two knife edges with tension 100N. The wire
vibrating with its fundamental frequency and a vibrating tuning fork together produce
5 beats per second. The tension in the wire is then reduced to 81N. When the two are
excited, beats are heard at the same rate. What is the frequency of the fork ?
1) 90 Hz
2) 95 Hz
3) 100 Hz
4) 105 Hz
Page 20
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50.
For the circuit shown in fig., which of the following statements is true ?
S1
S3
V1 30V
S2
V 2 20V
C 2 3 pF
C 1 2 pF
Two pendulums of length 121 cm and 100 cm start vibrating. At some instant the two
are at their respective mean positions and in the same phase. After how many
vibrations of the shorter pendulum, the two will be again in phase at their mean
positions for the first time?
1) 10
52.
2) 11
3) 20
4) 21
A potential difference of 600 V is applied across the plates of a parallel plate capacitor.
The separation between the plates is 3 mm. An electron projected into the space
between the plate and parallel to the plates, with a velocity of 2 10 6 ms 1 moves
undeflected between the plates. The magnitude of the magnetic field between the
capacitor plates is
1) 0.1 T
2) 0.2 T
3) 0.3 T
4) 0.4 T
Page 21
Main_GT-7(31/03/13)
53.
For a certain thermocouple, if the temperature of the cold junction is 0 0 C , the neutral
temperature and temperature of inversion are 285 0 C and 570 0 C respectively. If the
cold junction is brought to 10 0 C , then the new neutral and inversion temperature are
respectively
54.
55.
When an electron jumps from the fourth orbit to the second orbit, one gets the
1) second line of Paschen series
56.
W1
5 Rnt
2)
n W 2 W1
5 Rt
3)
W1
Rnt
4)
n W 2 W1
Rt
e
10 7
r
2)
e
10 7
2r
3)
e
10 7
2
r
4)
2e
10 7
2
r
Page 22
Main_GT-7(31/03/13)
57.
58.
Dd
4)
2
Dd
Dd
3)
Dd
D2
2) 2
d
For a transistor, the current amplification factor 0.9 . This transistor is connected in
common emitter configuration. When the base current changes by 0.4 mA , the change
in collector current will be
1) 36 mA
59.
2) 9 mA
3) 4 mA
4) 3.6 mA
Interference pattern is obtained with two coherent light sources of intensity ratio n . In
I
max
I min
60.
2 n
2)
n 1
3)
n 1
4)
2 n
n 1
The kinetic energy of the most energetic photo electrons emitted from a metal surface
is doubled when the wavelength of the incident radiation is reduced from 1 to 2 .
The work function of the metal is
hc
1) 2 2 1
1 2
ICON Srs & LT_JEE-MAIN
hc
2) 21 2
1 2
hc
3) 1 2
1 2
hc
4) 1 2
1 2
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MATHEMATICS
61.
If the algebraic sum of the perpendicular distances from the points (3, 1), (-1, 2) and
x2 1 x 1 x 2
4
3
2
(1, 3) to a variable line is zero, and 2 x 3 3 x 2 x 4 mx nx px qx r be an
x 4 4x 3 2x 5
identity in x then the variable line always passes through the point:
1). (m, r)
62.
2). (-r, m)
3). (r, m)
4). (2r, m)
where n N , Then
Page 24
Main_GT-7(31/03/13)
L1 : y x 10 0,
2) 3x 3 y 40 0
3) 3 x 3 y 40
4) 3 y 3 x 40
64. The number of ordered pairs (x,y) satisfying the equation sin x sin y sin( x y ) and
x y 1 is
1) 4
65.
2) 6
3) 8
4) 2
In the figure, OABC is a square of side 8 cm, then the equation of the smallest circle is:
2) ( x 4) 2 ( y 4)2 2 1
1) ( x 4)2 ( y 4) 2 4
3) ( x 4) 2 ( y 4) 2 2 1
4) ( x 4) 2 ( y 4) 2 2 2 2
66. If [cot1x]2 + (cot1x)2 2[cot1x]2 (cot1x) 2, where [.] denotes greatest integer x
& (.) denotes least integer x, the value of x satisfying will be
1)
4
2) Cot1
3) cot 1
space for rough work
4) cot 2
Page 25
Main_GT-7(31/03/13)
67.
The value of Lt
nk
n k 1
1) 1 sin 4 1 cos 4 1
4
68.
16
16
cos
4k
equals
n
2) 1 sin 4 1 cos 4 1
4
16
3) 1 1 sin 4
16
4) 1 1 cos 4
16
16
Two 8 faced dice (numbered from 1 to 8) are tossed. The probability that the product
of two counts is a square number, is
1)
69.
70
1
8
7
32
3)
3
16
4)
3
8
2) x 2 y3 y cos 2x C
3) x 2 y 2 ysin 2x C
4) x 2 y 2 ycos 2x C
The probability that a randomly chosen 3 digit in number has exactly 3 factors is
1).
71.
2)
2
225
2).
7
900
3).
7
300
4).
1) 4
3) 5 1
2) 5
3
500
z 1 i z 2 3i is
4) 0
Page 26
Main_GT-7(31/03/13)
72.
1
4
1
2
2
2
Let g x f 2x 1 f 1 x x R, where f " x 0x R , g(x) is necessarily
1)
73.
2 2
,
3 3
2)
2
,0
3
2
,
3
3) 1,1
4) [1,1]
74.
2) 3
3) 4
4) 5
6037 is
1) 79 73
2) 5(76 )
3) 10(7 6 )
4) 77
4
75.
(
p 1
7
)
q
is equal to
q 1
1)
1 i 3
2
2)
1 i 3
2
3)
1 i 3
2
4)
1 i 3
2
Page 27
Main_GT-7(31/03/13)
76.
If Z1 and Z 2 are complex numbers such that 15Z1 13Z 2 13Z1 15Z 2 Z1 Z 2
2) 934
2) 3
3) 1
1
1
1 l
1 l
cos
cos
, b tan
m
4 2
4 2
If a tan
1) a b
79.
4) 943
x y z x y z x y z x y z
x y . y x 2 y z .z y 3 z x . x z
If
then z y x z y x
log x
log y
log z
y .z
z x
x .y
1) 1
78.
3) 439
2m
l
2) a b 2 m l
l
4) 0
then
3) a b
2
2
2l
4) a b 2 l m
m
l
80.
2)
5 3
2
3) 10 3
4) 10
2) 4
3) 5
4) 1
Page 28
Main_GT-7(31/03/13)
81.
The figure shows two regions in the first quadrant. A t is the area under the curve y =
sin x
from 0 to t and B(t) is the area of the triangle with vertices O, P and M(t,0).
A t
equals.
t 0 B t
Lt
P t,sin t 2
B t
O
II
1)
82.
1
3
1
2
3)
2
3
4)
3
5
83.
2)
2) 2
3) 3
4) 4
Consider the curve Max x y , x y 2 . Let f(x) be given by the part of the curve
1/2
Page 29
Main_GT-7(31/03/13)
1) 4
2)
1
4
3)
3
2
4)
14
8
84.
6k
The sum 3k 2k 3k 1 2k 1
k 1
1) 1
2) 2
3) 3
4) 4
85.
If I
x 20
x sin x 5cos x 2
dx , then I equals
87.
If x cos ycos
10
8
1) 1
2) 2
3) -1
4) 0
Let P(x) be a polynomial with degree 2012 and leading co-efficient unity such that
P(0)=2011, P(1)=2010, P(2)=2009,.P(2011)=0 then the value of P(2012)= n a
where n and a are natural numbers then value of n a
1) 2013
2) 2012
3) 2011
4) 2010
Page 30
Main_GT-7(31/03/13)
88.
Let Sn 'S2n 'S3n are the sums of n, 2n, 3n terms of an arithmetic progression, then
S
3n
2n
is equal to
n
1) 1
89.
2) 3/2
3) 2
4) 3
A plane is such that the foot of perpendicular drawn from the origin to it is (2, -1, 1).
The perpendicular distance of the point (1,2,3) from the plane is (in units)
1)
90.
3
2
2)
1
2
1/2
The equation x 3 4 x 1
3)
1/2
3
2
x 8 6 x 1
4)
1/2 1/2
3
2
1). no solution
Page 31