Professional Documents
Culture Documents
Brief Description of Urea Process
Brief Description of Urea Process
99.5% wt
10 ppm max
0.5% wt
Carbon di oxide:
CO2 (dry basis)
Inerts
H2
H2O
98.7% vol.min
0.5 % vol min
0.3% vol min
saturated
Utilities characteristics:
Cooling water:
Pressure (norm/degn)
Inlet temperature
Outlet temperature
Fouling factor
Electric power:
Alternating current
Direct current
11 KV 50Hz 3ph
3.3kV 50Hz 3ph
415 V 50Hz 3ph
115 V 1Ph
Service air:
Moister saturated
Pressure (norm/degn) 7 / 11 kg/cm2
Temperature 40 0C
Instrument air:
Pressure 7 / 11 kg/cm2
Temperature 40 0C
Type Oil free
0.2 s cm-1
0.02 s cm-1
0.01 ppm
0.1 ppm
0.5 ppm
7
Nitrogen:
Nitrogen plus noble gases
CO2
Water
Oxygen
Pressure (min/norm)
Temperature
99.6% vol
20 ppm max
20 ppm max
200 ppm max
5/7 kg/cm2
ambient
The reaction products from the reactor overflow to the stripper where the
unconverted carbamate is decomposed back into the constituents with the
help of the heat supplied by MP steam. The stripper is basically a falling film
exchanger with urea solution on the tube side and MP steam on the shell
side. The urea solution obtained at the bottom flows to MP section through a
level control valve.
The vapors from the stripper top enter the HP carbamate condenser along
with the carbamate solution from MP section. Here they condense to form
carbamate solution again and in the process releasing a large amount of heat
of condensation, which is utilized to generate the low-pressure steam on the
shell side. Vapors consisting mainly of inerts are sent from the carbamate
separator to the bottom of the MP decomposer to passivate the MP section.
2.Urea Purification
Urea purification takes place in two stages. One is known as MP section and
the other is known as LP section.
Medium Pressure section
Urea solution from the bottom of the stripper enters the MP decomposer.
During the expansion most of the remaining carbamate flashes forming the
NH3 and CO2 vapors, thereby concentrating the urea solution. The vapors
from the MP decomposer top flow to pre vacuum concentrator shell side and
from pre vacuum concentrator to MP condenser shell side. Prior to the entry
of the vapors in the pre vacuum concentrator the vapors get mixed with the
low concentration carbonate solution from the LP section. The partly
condensed gas mixture from MP condenser outlet goes to MP absorber where
the CO2 is stripped from the NH 3 vapors and the pure NH 3 vapors from the MP
absorber flow to the ammonia condenser. The solution at the bottom of the
MP absorber provides the suction for the HP carbamate pump. Ammonia
condenser has cooling water on tube side.
From ammonia condenser both vapor and liquid flow to the ammonia receiver
tank. The receiver tank receives fresh ammonia from the ammonia plant. The
inert gases saturated leaving the receiver enter the ammonia recovery tower.
Here ammonia is further condensed by direct contact with cold ammonia
from the battery limit. The inert with residual ammonia from the tower are
sent to MP inert wash tower via a condenser. The ammoniacal solution
collected at the bottom is recycled back to the MP absorber.
Low Pressure Recovery
The urea solution from MP decomposer bottom enters the LP decomposer
after expansion through a level controller. Consequently most of the residual
carbamate is decomposed and in the process urea solution gets
concentrated. The remaining carbamate is decomposed in falling film
exchanger, which is a part of LP decomposer.
The vapors from the LP decomposer enter the LP condenser where they get
cooled and liquefied. Prior to entry of LP off gases in LP condenser the vapors
get mixed with aqueous solution from wastewater section. The vapors thus
formed get condensed in LP condenser goes to carbonate solution tank from
where it is sent back to MP condenser. The inert gases in the tank contain
considerable amount of ammonia and thus are absorbed in cool condensate
before being sent to the vent stack.
The urea solution at the bottom of LP decomposer is sent to pre vacuum
concentrator through a level controller valve.
3.Urea concentration
Pre Vacuum concentrator
The urea solution from LP decomposer enters the pre vacuum concentrator,
which is an exchanger with urea solution from the LP section on tube side
and MP decomposer off-gases on the shell side. The MP decomposer offgases give their heat and the urea solution gets concentrated in the process.
The pre vacuum concentrator operates under vacuum and the vapors from
the top are condensed in the pre vacuum condenser. The vapors condensing
in the pre vacuum condenser are collected at the bottom in vacuum system
tank and the liquid is sent to the wastewater section.
The concentrated urea solution at the bottom is sent to the vacuum
concentrated section.
Vacuum concentration
The urea solution from the pre vacuum section bottom gets further
concentrated up to the concentration required for prilling in two vacuum
concentrators in series. The heat for concentrating the urea solution is
supplied by low-pressure steam. The vacuum is maintained in both the
stages with the help of ejectors and condensers. The urea solution from the
outlet of second vacuum concentrator has 99.7%(w/w) concentration and is
pumped to prilling section. The vapors from both the stages get condensed in
the condensers and are sent to the wastewater section.
4.Urea Prilling
The urea melt from the second vacuum concentrator is sent to the prilling
bucket. The urea melt comes out from the bucket in the form of liquid drops
and they fall along the prilling tower. The drops get solidified and cooled by
the countercurrent flow of air from the bottom of prilling tower. The solidified
urea melt drops known as urea prills, fall on the prilling tower bottom. These
prills are collected by a rotating scrapper and are sent to the bagging plant
with the help of belt conveyors. The heated air containing few ppm of NH 3 is
released from the top into the atmosphere.
=
=
=
=
=
510C
381C
219C
147C
160C
KS Network:
The steam is available at urea plant battery limit and is utilized to drive the
CO2 compressor turbine. It may be used to provide the MS steam in case of
failure of turbine extraction steam
HS Network:
This steam is available at the point battery limit and is utilized in hydrolyzer.
MS Network:
This steam is extracted from the CO2 compressor turbine and is de super
heated to make it saturated. This steam is utilized in the stripper and MP
decomposer.
LS Network:
This steam is produced in the HP carbamate condenser shell & is used in the
following equipments / systems:
1. LP decomposer