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SPM Chemistry Skema Set 1 Paper 1: Bahagian A
SPM Chemistry Skema Set 1 Paper 1: Bahagian A
SECTION A
BAHAGIAN A
1 (a)
(b)
(i)
(ii)
ZnCl2
Zn(NO3)2
1
1
(i)
(ii)
(iii)
(c)
(i)
(ii)
1
1
0.5 mol
1
From the chemical equation,
Daripada persamaan tindak balas, didapati :
Hence,
Maka,
0.5 mol of AgNO3 will produce 0.5 mol of NO2
0.5 mol AgNO3 akan menghasilkan 0.5 mol NO2
85 g / 170
Volume of NO2
Isipadu NO2
= 0.5 x 24
= 12 dm3
10
..
(a)
39
(b)
(i)
(ii)
(iii)
(c)
1
3
2.8
Group / kumpulan 1
Low density
Low melting and boiling points
Conduct electricity
Soft metal
[any one correct]
ketumpatan rendah
takat lebur/didih rendah
mengkonduksikan elektrik
logam lembut
[ Mana-mana satu betul ]
1
1
1
(d) (i)
2M + Cl2
2MCl
1
(ii)
ionic bond /Ikatan ion
Atomic size/ atomic
radius of N atom bigger than M
Saiz /Jejari atom N lebih besar berbanding M
Valence
electron of atom N further away from nucleus //Nucleus attraction towards
valence electron of N is weaker than M
Elektron valens atom N semakin jauh dari nukleus //
Daya tarikan nukleus terhadap elektron valen N lebih lemah
berbanding M
1
3 N atom easy to release electron.
Atom N mudah melepaskan elektron
1
10
(b)(i) Aluminium
1
(ii) Aluminium tends to donate electron //
Aluminium is more electropositive// Al is above Cu in ECS
Aluminium lebih cenderung menderma elektron//
Aluminium lebih elektropositif // Al lebih atas dalam SEK berbanding
kuprum
1
3+
(iii)
Al
Al
+ 3e
1
(c) (i)
copper plate becomes thicker// brown solid deposited
Kepingan kuprum menebal // Enapan perang
1
2+
(ii) Cu
+
2e
Cu
1
(d) 2Al + 3Cu2+
2Al3+
+ 3Cu
1
(e) Drawing arrow to show the movement of electron from Al to Cu
through external circuit.
Melukis anak panah menunjukkan pergerakan elektron
dari Al ke Cu melalui litar luar
1
(f)
(i)
Cu, Pb, Zn, Mg
1
(ii) 0.6 V
1
10
(a)
14.90,
15.10,
(b)
14.90
+ 15.10
3
(c)
pink to colourless /
(d)
2KOH
(e)
MasidVasid = 1
MalkValk
2
15.00
+ 15.00 cm3
H2SO4
1
=
15.00 cm3
2H2O
Masid x 15/1000 = 1
0.5 x 20/1000
2
Masid = 0.33 moldm-3
1
1
(f)
(i)
30.00 cm3
(ii)
5 (a) (i)
Mg + 2HCl
MgCl2 + H2
(ii)
(iii)
[step of calculation
Correct answer
(b)(i)
(ii)
Langkah pengiraan]
//
cm3s-1)
1
10
1
1
1
Or
Add potassium hexasionoferate(III) / potassium thiocianate
Dark blue precipitate / red blood solution formed.
Tambahkan larutan natrium hidroksida/larutan ammonia.
Mendakan hijau kotor terhasil.
Atau
Tambahkan larutan kalium heksasionoferat(III) / kalium tiosianat.
Mendakan biru tua / larutan merah darah terhasil.
(e) i)
ii)
x + 4(-2) = -1
x
=+7
1
10
SECTION B
BAHAGIAN B
2 (a)
[Can draw structural formula and name the corresponding isomer correctly.
Dapat melukis formula struktur dan menamakan isomer yang sepadan dengan
betul ]
Answer :
H H
H
I
I
I
H - C - C - C - OH
propan-1-ol / 1-propanol
I
I
I
H
H
H
H
H
I
I
H -C - C I
I
H
OH
(b)(i)
1
1
H
I
C - H
I
H
propan-2-ol / 2-propanol
1+1
1+1
3 Empirical formula is
formula empiric ialah CH2
[use the empirical formula to determine the molecular formula
gunakan formula empirik untuk menentukan formula molekul ]
4
(b)(iii)
(b)(iv)
5 C3H6 // CH3CHCH2
[can draw the structural formula and name the alkene correctly
Dapat melukis formula struktur dan menamakan alkena dengan betul]
6 structural formula is / formula strukur ialah :
H H
H
I
I
I
H- C - C = C - H
I
H
7 Name : propene / prop-1-ene
Nama : propena / prop-1- ena
[ can state the general formula of homologous series correctly
Dapat menyatakan formula am siri homolog dengan betul]
1
1
(c)
Answer / Jawapan :
8 general formula of homologous is CnH2n
Formula am siri homolog ialah CnH2n
[procedure
prosedur ]
1. Put 5 cm3 of alkene M and propane in two test tube
masukan 5 cm3 alkena M dan propana dalam dua tabung uji
2. drop/ add bromine water and shake
titis/ tambahkan air bromin dan goncang
[observation
pemerhatian ]
3. Brown colour of bromine water turns to colourless in test tube of alkene M
No change in test tube of propane
warna perang air bromin bertukar kepada tanpa warna dalam tabung uji
alkena M
1
1
1
1
1
(2)(d)
1. [functional diagram
gambarajah berfungsi ]:
water is shaded, rubber stopper outside the mouth of test tube, delivering
tube is not blocked, retort stand with clamp.
air berlorek, gabus diluar mulut tabung uji, salur penghantar tidak
dihalang, pengapit kaki retort,
1
1
2. [ label ] :
Alkene M gas, heat, porcelain chips, glass wool soaked with propanol
gas Alkena M, panaskan, serpihan porselin, kapas direndam propanol.
[ Procedur
prosedur ]
3. Heat the porcelain chips strongly / until glowing
panaskan serpihan porselin dengan kuat / sehingga membara
4. Warm the glass wool soaked with propanol
Hangatkan kapas yang direndam propanol
1
1
SECTION C
BAHAGIAN C
3
(a) Heat released when 1 mol of H+ ion reacts with 1 mol of OH- ion to form 1 mol of
water
Haba yang dibebaskan apabila 1 mol ion H+ bertindak balas dengan
1 mol ion OH- membentuk 1 mol air
11
(b)(i) Hydrochloric acid is strong acid, undergoes complete ionisation when
dissolve in water.
Ethanoic acid is weak acid, undergoes partial ionisation when
dissolve in water.
Some of the heat released is absorbed to break the bond in the acid molecule.
Asid hidroklorik adalah asid kuat, mengalami pengionan
lengkap apabila larut dalam air
1
Asid etanoik adalah asid lemah, mengalami pengionan separa
apabila larut dalam air
1
Sebahagian haba dibebas diserap untuk memutuskan ikatan
yang terdapat dalam molekul asid
13
(ii) x value is 57 kJ mol-1 [same as reaction 1]
sulphuric acid is strong acid, undergoes complete ionisation when dissolve in
water
reaction involved 1 mol of H+ and 1 mol of OH- /
H+ + OH- H2O
nilai x ialah 57 kJ mol-1 [sama seperti tindak balas 1]
1
Asid sulfurik adalah asid kuat, mengalami pengionan lengkap
apabila larut dalam air
1
Tindak balas melibatkan 1 mol H+ dan 1 mol OH- /
H+ + OH- H2O
1..3
apparatus:
Polystyrene cup, thermometer, measuring cylinder
Radas :
Cawan polistirena, termometer, silinder penyukat.
Procedure
Kaedah :
1 100cm3 of sodium hydroxide solution 2 moldm-3 is measured using
measuring cylinder and is added into polystyrene cup
100cm3 larutan natrium hidroksida 2 moldm -3 disukat menggunakan
silinder penyukat dan dimasukkan ke dalam cawan polistirena
2 initial temperature is recorded
Suhu awal dicatat
1
3 100cm3 of hydrochloric acid 2 moldm-3 is measured using measuring
cylinder
100cm3 asid hidroklorik 2 moldm-3 disukat dengan silinder
penyukat
1
4 initial temperature of acid is recorded
Suhu awal asid dicatat
1
5 hydrochloric acid is quickly poured into sodium hydroxide solution
Asid hidroklorik dituang dengan cepat ke dalam larutan natrium
hidroksida
1
6 the mixture is stirred
Campuran dikacau.
1
7 maximum temperature achieved is recorded
Suhu maksimum yang dicapai dicatat.
1
8 Step 1 to 7 is repeated using ethanoic acid.
Langkah 1 7 diulangi dengan asid etanoik.
1
Result
Keputusan :
Hydrochloric acid
Asid hidroklorik
Ethanoic acid
Asid etanoik
Initial temperature of
NaOH/oC
Suhu awal NaOH /oC
Initial temperature of
acid/oC
Suhu awal asid /oC
Maximum temperature/oC
Suhu maksima /oC
1
Calculation
Penghitungan :
Heat released
Haba dibebaskan = 200 x 4.2 x
No. of mol / Bilangan mol HCl / CH3COOH = / 0.2 mol
Heat of neutralisation
Haba peneutralan = 200 x 4.2 x kJ mol-1
0.2 x 1000
1
1
1
..13
20
(a)
Reinforced concrete
Consist of steel rod in concrete pillar
It can withstand high pressure / withstand compression
Does not corrode
Uses : to make construction outline, bridges, road / high buildings
Konkrit yang diperkukuhkan
terdiri daripada batang keluli dalam tiang konkrit
sifatnya tahan terhadap tekanan yang tinggi / tahan mampatan
tidak berkarat
kegunaanya : membuat rangka pembinaan, jambatan, jalan raya
/ bangunan yang tinggi
OR
ATAU
1
1
1
1
15
(b) Material
Dilute sulphuric acid, ammonia solution, phenolphthalein indicator
Bahan :
Asid sulfurik cair, larutan ammonia, penunjuk fenoftalein
Apparatus:
procedure/ method:
Prosedur / Kaedah :
1
2
3
5
6
7
(c) 1
2
3
4
5
1
1
1
1