CALCULATION SHEET FOR EMISSION OF SOLVENT

WITH NON CONDENSIBLE AT DEPRESSURIZATION

Project:

Cad. No.
Sheet. no.
Plant

Client:

Contract-No

Tag number of tank/Reactor

Charging solvent name

Formula

Operating temp.

Enter the solvent name

T

Enter the operating temp.

5
6

Qty. of solvent

Molecular wt of solvent

Mole of solvent

Qty. of monomer

W1

Hexane
C6H12O2
0

125

398.15

Enter the amount of solvent

kg/batch

3000

Enter the MW of solvent

kmol/kg

116.16

n1

kmol

25.826

W2

kg/batch

6600

MW1

10

Molecular wt

11

Mole of monomer

n2

12

Total no. of mole

13

Mole fraction of solvent

= n1/n

14

Mole fraction of Monomer

= n2/n

20

Vapor pressur

MW2

Enter the MW of monomer

kmol/kg

200

kmol

33.0

= n1+n2

Pvp

58.826
0.439
0.561
Pa

98389.462

21

Kpa

98.389

22

kg/cm2

1.0031

23

mmHg

737.98

24

Partial pressure of BA

25

Total volume of reactor

Vt

Enter the total volume of reacto

m3

12.75

26

Working volume

Vw

Enter the working volume of rea

m3

9.75

27

Free volume

Vf

= Vt-Vw

m3

Vf'

= Vf*35.3147

ft3

105.94

28
29

Doc. No.

Initial pressure

30
31
32

PP of nc component at initil pressu

33

Final pressure

34

PP of nc component at final pressu

35

Universal gas constatnt

36

Moles of volitile component

37

Mass of volitile component

323.99

P1

Enter the initial pressure

kg/cm2g

4.5

P1'

= P1+1.033

kg/cm2a

5.53

P1''

=(P1'*760)/1.033

mmHg

4070.75

mmHg

3746.75

Pnc1
Enter the final pressure

mmHg

760
436.01

Enter the gas constant

mmHg
mmHg.ft3
/ lbmole
0k
lb-mole
lb

21.5646

kg

9.7815

Pnc2
R
ni out

38
39

Latent heat of Butyle acetate

40

Heat loss during depressurize

Enter the latent heat

998.9
0.1856

kcal/kg

73.98

kcal

723.636

41

15.07.2013

REV

DATE

SS
DESCRIPTION

PREPARED BY

CHECKED BY

APPROVED BY

CALCULATION SHEET FOR EMISSION OF SOLVENT

WITH NON CONDENSIBLE AT FILLING THE EMPTY TANK/REACTOR
Project:

Doc. No.
Cad. No.
Sheet. no.
Plant

Client:

Contract-No

Tag number of tank/Reactor

5150-T-016A/B

Charging solvent name

Enter the solvent name

Blanketing medium in tank

Enter the blanketing media

Operating temp.

MTBE
Nitrogen

Enter the operating temp.

45

= T+273.15

318.15

Material filling time

Enter the filling time

Operating Pressure

Pt

Enter the operating temp.

Molecular wt of solvent

MW1
MW2

hr

36.39

mmHg

760

Enter the MW of solvent

lb mol/lb

87.6

Enter the MW of air/nitrogen

lb mol/lb

Molecular wt. of blanketing

10

Construction of raector/tank

Enter the constuction of equipment

Top-conical & bottom-flat

12

Diameter of reactor/tank

Enter the diameter of vessel/reactor

35

13

Height of reactor/tank

Enter the ht of vessel/reactor

14

Total volume of tank/reactor

Vt

16

Vapor pressur at operating temp.

P1

Enter the vapor pressure of solven mmHg

525

17

Vapor pressure of blanketing

P2

= Pt -P1

235

18

Universal gas constatnt

Enter the gas constant

19

Mole of solvent

n1

= (P1*Vt)/(R*T)

W1

= n1 * MW1

15

= Vt*35.3147

20
21

Emission rate of solvent

22

Mole of nitrogen/air

23
24

Emission rate of nitogen /air

25

Total emission rate

= W / n1
n2

= (P2*Vt)/(R*T)

W2

= n1 * MW2
= W / n2

28

19
m3

19269.75

ft3

680505.32

mmHg
mmHg.ft3
/ lbmole
0k
lb kmol

1124.183

kg

98478.402

kg/hr

2706.194

998.9

lb kmol

503.206

kg

14089.756

kg/hr

387.188

kg/hr

3093.382
87.483355526
4.3741677763

15.07.2013

REV

DATE

SS
DESCRIPTION

PREPARED BY

CHECKED BY

APPROVED BY

CALCULATION SHEET FOR EMISSION OF SOLVENT

WITH NON CONDENSIBLE AT SOLVENT CHARGING TO THE REACTOR
Project:

Cad. No.
Sheet. no.
Plant

Client:

Contract-No

Tag number of tank/Reactor

Charging solvent name

Enter the solvent name

Methanol

24% Ammonia

Blanketing medium in tank

Enter the blanketing media

Nitrogen

Nitrogen

Operating temp.

Enter the operating temp.

35

35

= T+273.15

308.15

308.15
0.25

Material filling time

Enter the filling time

Operating Pressure

Pt

Enter the operating temp.

Molecular wt of solvent

MW1

Molecular wt. of blanketing

MW2

10

Doc. No.

Charging qty of solvent-1

m1

hr

0.25

mmHg

760

760

Enter the MW of solvent

lb mol/lb

32.04

17.03

Enter the MW of air/nitrogen

lb mol/lb

28

28

kg

1500

1500

Enter the charging qty of solvent-

11
12

n1

3307

3307

103.21

194.18

13

Density of solvent-1

14

Vulume of solvent-1

V1

16

Vapor pressur at operating temp.

P1

Enter the vapor pressure of solven mmHg

209.69

28.33

17

Vapor pressure of N2/Air

P2

= Pt -P1

550.31

731.67

18

Universal gas constatnt

Enter the gas constant

998.9

998.9

19

Mole of solvent

n1

= (P1*Vt)/(R*T)

mmHg
mmHg.ft3
/ lbmole
0k
lb kmol

0.046

0.005

W1

= n1 * MW1

kg

1.464

0.091

kg/hr

5.854

0.365

lb kmol

0.120

0.138

kg

3.357

3.874

kg/hr

13.426

15.497

kg/hr

19.281

15.862

15

Enter the density of solvent-1

lb
lb mole

= Vt*35.3147

20
21

Emission rate of solvent

22

Mole of nitrogen/air

23
24

Emission rate of nitogen /air

25

Total emission rate

15.07.2013

REV

DATE

= W / n1
n2

= (P2*Vt)/(R*T)

W2

= n1 * MW2
= W / n2

DESCRIPTION

kg/m3

790

910

m3

1.899

1.648

67.05

58.21

ft3

SS

KJM

KJM

PREPARED BY

CHECKED BY

APPROVED BY

CALCULATION SHEET FOR EMISSION OF SOLVENT MIXTURE

WITH NON CONDENSIBLE WHEN CHARGING TO THE EMPTY
REACTOR/VESSEL

Doc. No.

Project:

Plant

Client:

Cad. No.
Sheet. no.
Contract-No

Tag number of tank/Reactor

Charging solvent name

Enter the solvent name

Methanol

Name of charging solvent-2

Enter the solvent name

TOLUENE

Blanketing medium in tank

Operating temp.

Enter the blanketing media

T

NITROGEN

Enter the operating temp.

20

= T+273.15

293.15

Operating Pressure

Pt

Enter the operating temp.

Material filling time

Enter the filling time

mmHg

760

hr

0.083

Molecular wt of solvent-1

MW1

Enter the MW of solvent

lb mol/lb

100.205

10

Molecular wt of solvent-2

MW2

Enter the MW of solvent

lb mol/lb

92.130

11

Molecular wt. of blanketing

MW3

Enter the MW of air/nitrogen

lb mol/lb

28

12

Charging qty of solvent-1

kg

1938.339

m1

Enter the charging qty of solvent-

13
14

n1

15

Density of solvent-1

16

Vulume of solvent-1

V1

17

Carging qty of solvent-2

m2

Enter the density of solvent-1

Enter the charging qty of solvent-

18
19

n2

20

Density of solvent-2

21

Vulume of solvent-2

V2

22

Mole fraction of solvent -1

Xi1

23

Mole fraction of solvent -2

Xi2

24

Total volume of solvent added

Vt

25
26

Vapor press. of solvent-1 at op. te

VP1

27

Partial pressure of solvent-1

PP1

28

Vapor press. of solvent-1 at op. te

VP2

29

Partial pressure of solvent-1

PP2

30

Partial pressure of blanketing

PP3

31

Universal gas constatnt

32

Mole of solvent

33
34

Emission rate of solvent

35

Mole of solvent

36
37

Emission rate of solvent

38

Mole of nitrogen/air

39
40

Emission rate of nitogen /air

41

Total emission rate

Enter the density of solvent-2

lb

4273.30

lb mole

42.646

kg/m3

682.71

m3

2.839

kg

2454.07

lb

5410.300

lb mole

58.725

kg/m3

864.406

m3

2.839
0.42
0.58

= V1+V2

m3

5.678

= Vt*35.3147

ft3

200.52

Enter the vapor pressure of solven mmHg

35.55
14.96

Enter the vapor pressure of solven mmHg

21.84
12.65

= Pt -PP1-PP2

Enter the gas constant

n1

= (PP1*Vt)/(R*T)

W1

= n1 * MW1
= W1 / t

n2

= (PP2*Vt)/(R*T)

W2

= n1 * MW2
= W2 / t

n3

= (PP3*Vt)/(R*T)

W3

= n1 * MW2
= W3 / t

mmHg
mmHg.ft3
/ lbmole
0k
lb kmol

732.39
998.9
0.010

kg

1.026

kg/hr

12.315

lb kmol

0.0087

kg

0.798

kg/hr

0.009

lb kmol

0.502

kg

14.043

kg/hr

168.515

kg/hr

180.84

42

15.07.2013

REV

DATE

DESCRIPTION

SS

KJM

KJM

PREPARED BY

CHECKED BY

APPROVED BY

DOC NO.
CAD NO.
SHEET NO
PLANT
CONTRACT NO.

PROJECTCLIENT :
NOTE : Enter the value in green cell
Sr. No. Description

Symbol Formula

Unit

Tag number of exchanger

Name of vapor escaping from heat exchanger

Enter the solvent name

Blanketing medium in tank

Enter the blanketing media

Vaporisation rate

kg/hr

26

Density of inlet vapor

kg/m3

1.50

HEPTANE
NITROGEN

6
7
8
9

m3/hr
Operating temp of vapor

10
11

Molecular weight of condensible

Inlet pressure of vapor

12

Universal gas constatnt

13
14
15
16
17

Amount of nitrogen flowing

Operating pressure of system
Vapor pressure of condensible
Calculation for Non-condensible
flow rate
Design Factor

18
19
20
21
22

Design air leakage rate

23
24
25
26
27
28
29
30
31
32

Molecular weight of NC
Calculation for Condensible flow
rate
Ratio of condensible to non condensible
Mass flow rate of condensible fluid
Total mass flow rate goes to vacuum sys
Volumetric flow rate of condensible
Volumetric flow rate of non condensible
Total volumetric flow rate
Calculation for Evacuation time

To
MWc
Pi
R

ft3/hr
0
Enter the value of operating temp.
C
0
= T0 + 273.15
K
Enter the value of molecular
kg/kmol
weight
Enter the value of initial pressure
mmHg(a)
mmHg.ft3/
Enter the gas constant
lbmole 0k

17
600
5
278.00
100.21
760.00
998.90
1.6424

Po
Pv

Enter the value of operating press

Enter the value of vapor pressure

F
Wnc

Enter the value of design factor

mmHg(a)
mmHg(a)

15.430
3.5

=Wnc * F

kg/hr

Enter the value of molecular

weight
=Wnc / MWnc

kg/kmol
kmol/hr

28.013
0.0000

R
Wc
nc
Wt
Qc

=(Pv/(Po-Pv))*(MWc/MWnc)
=R * Wnc
=Wc / MWc
=Wc + Wnc
= (nc* R * To) / Po

kg/hr
kmol/hr
kg/hr
m3/hr

-3.5771
0.0000
0.0000
0.0000
#DIV/0!

Qnc
Qt

=( nnc*R*To) / Po
=Qc+Qnc

m3/hr
m3/hr

#DIV/0!
#DIV/0!

MWnc
nnc

33
34
35
36
37

11.05.2012

ISSUED FOR APPROVAL

SS

KJM

JJS

REV

DATE

DESCRIPTION

PREPARED

CHECKED

APPROVED