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Material Safety Data Sheet

Part I Identification of the substance and details of the supplier
Trade Name

Gardolene D 6757

Company Name

Shanghai Chemetall Chemicals Co., Ltd

Address

Kang An Road No.628 KangQiao Industrial Zone Pu Dong

Shanghai

Post code

201315

Email

Jeff.chou@chemetall.com.cn

Fax

021-58120583

Emergency Telephone

021-58121367

Technical Instruction code

100047

Compile date

Sept 2013

National

Emergency

0532-83889090

Telephone
Part II Composition/information on ingredients
Compound
Trade Name
Hazardous components

Mixture

Gardolene D 6757
7788-97-8

Trivalent Chromium

1 10.0%

7664-38-2

Phosphate acid

2.50 - 10.00 %

Part III Summarize of harmfulness

Sort of the harmfulness

Toxic, potential threats to human body or environments

Invasion routes

Inhalation, skin exposure, eye contact, ingestion

Health hazard

Carcinogenic, toxic if swallowed, ambustion, irritability if skin

exposure

Environment hazard

Souce of water and soil may be polluted caused by leakage. Harmful

for aquatic organism.

Risk of explosion and

Not burn, not explode

burning
Part IV First Aid Measures
Skin exposure

Washing with plenty of water

Eye contact

Washing with flowing water for several minutes and go to hospital

Inhalation

Supply fresh air, go to hospital if not comfortable

Ingestion

Drink plenty of water, close to fresh air and go to hospital

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Part V fire protection

Hazardous

No hazardous components decomposed

characteristic
Hazardous combustion

No

products
Method of extinguishing

CO2, fire fighting powder or hydraulic giant, use hydraulic giant

and extinguishant
Notes for fire fighting

when big fire or foaming agent for preventing alcohol.

People for fire-fighting should equipped with safety device, cooling
the extinguisher with water exposed in fire, and avoid waste water
flowing into drainage.
Part VI emergency processing for leakage

Emergency processing

Dress safety device. People with no safety device should evacuate.

This product should not flow into drainage or other water body.
Adsorb leaked material with adsorbates (sand, bergmeal, acid
adsorbates, normal adsorbates. Use neutralizer.
Part VII handling and storage

Notices for operation

Special prevention measures are not needed when proper used.

Wear safety devices when operating, and avoid skin and eyes
contact. Eyewash equipments should be installed in working place,
and smoking and ingestion are forbidden in operation area.

Notices for storage

Keep containers sealed and avoid the product drying.

Part VIII Exposure control/Individual protection

Maximum

allowable

CAS-No.

Chemical name

concentration
ml/m3

concentration
7664-38-2

Phosphate acid

Monitoring method

No applicable data

Engineering control

No applicable data

Respiratory

Needless, respiratory system is needed if fog formed.

system

protection
Eyes protection

Wear sealed safety glass

Body protection

Wear work clothes

Hand protection

Wear neoprene gloves

Other protection

No
Part IX physical and chemical properties

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Appearance and color

Appearance: liquid

PH value20

<2

Melting point

No suitable data

Boiling point

No suitable data

Relative densitywater=1

About 1.2g/ml

Relative Vapor densityAir=1

No suitable data

Saturated vapor pressurehPa

No suitable data

color: green

(20)
Heat of combustionKJ/mol

No suitable data

Critical pressureMPa

No suitable data

octanol/water

log

partition

No suitable data

coefficient
Flash point

No suitable data

Ignition temperature

No suitable data

Upper explosive limit%V/V

No risk of explosive

Lower explosive limit%V/V

No risk of explosive

Solubility

Completely soluble

Main application

Pretreating agent for metal surface

Other

physical

and

chemical

No suitable data

properties
Part X stability and reactivity
stability

Stable under recommended storage conditions

Decomposition product

No decomposition if used as directed

Part XI toxicological information

Acute toxicity

No suitable data

Subacute chronic toxicity

No suitable data

thrill

Cause severe burns

Cause serious eye damage

sensitization

May cause an allergic skin reaction

mutagenicity

No suitable data

teraogenicity

No suitable data

carcinogenicity

May cause cancer

other

No suitable data
Part XII ecological information

Ecological toxicity

Do not flush into surface water or sanitary sewer system.

Avoid subsoil penetration.

biodegradability
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No suitable data
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Abiotic biodegradability
Bio-concentration

No suitable data
or

No suitable data

bio-cumulation
Other adverse effects

No suitable data
Part XIII Disposal consideration
hazardous waste

Product
Waste

disposal

industrial soild wastes

Disposal after neutralization, disposal of as hazardous waste in

measures

compliance with local and national regulation.

Waste code

Do not flush into surface water or sanitary sewer system.

Do not disposal of as hazardous waste into sewer before dilution
or neutralization.
Part XIV Transport information

Dangerous

goods

number
UN number

UN

Packing mark
Packing group

III

Packing method

Plastic drum

Transport announcement

Prevent high temperature solarization, Loading should be in strict

accordance with dangerous cargo loading list according to
<dangerous cargo transportation regulation> released by ministry
of railways. Packaging should be intact when start shipment. Make
sure the containers not leaked, not collapse, not fall, not
breakdown. Products should not be transported with fire goods,
strong

base

Transportation

goods,
cars

metal,

should

edible

be

chemical

equipped

with

products.
emergency

processing equipments. Solarization, raining and high temperature

should be protected during transportation. During transportation,
cars should drive under regulated routes and dont stop in
residential area and congested area.
Part XV laws and regulations
Laws

and

information

regulation

Dangerous chemical products safety control regulation(issued by

the State Council on 26

th

January 2002) rules about using

chemical products in working place(No.423released by ministry of

labor[1996]), and made relative regulations aiming at the safety
use, production, storage, transportation, loading of the risk
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chemical products. The category and label of the normal risk

th

chemical products put this matter in the 8 acid corrosive product.

Risk goods trade name list(GB12268-2005);poisonous materials
trade name list(GA 58-93);Occupational health standards of the
Peoples Republic of China occupational exposure limit of the
harmful factors in working place(GBZ2.1-2007).
Part XVI other information
references

<chemicals

safety

data

sheet

compile

regulation>GB16483-2008
Fill time

Sept 2013

Fill department

Shanghai Chemetall

Data auditing departments

Shanghai Chemetall

modification illustration

No suitable data

Other information

No suitable data

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