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Thermoelectric Refrigeration: Comparision With Conventional Cooling System
Thermoelectric Refrigeration: Comparision With Conventional Cooling System
Thermoelectric Refrigeration: Comparision With Conventional Cooling System
1. INTRODUCTION :
Today one cannot refuse the use of refrigeration system in our life,
not only in kitchen but also in shops, industries and commercial
purposes.Todays compression refrigeration system has given very
good performance. But refrigerants (Chlorofluorocarbons,
Hydrochloroflorocarbons) used in this systems are hazardous to the
environment and human life, because they react with very useful gas ozone
(O3). Thus depletion of ozone layer is the main problem in front of us.
Thermo-electric refrigeration system can able to substitute vapor
compression refrigeration system for small-scale applicant and may result
as solution of the problem above discussed.
COMPARISION WITH CONVENTIONAL COOLING SYSTEM:
Thermo-electric cooling is described as a solid-state method of heat
transfer generated primarily through the use of dissimilar semiconductor
materials. To understand the cooling method, it is first necessary to know
how thermoelectric cooling systems differ from their conventional
refrigeration counterparts. Like conventional refrigeration, thermoelectric
obey the basic laws of thermodynamics. Both in result and principle, then,
thermoelectric cooling has much in common with conventional refrigeration
methods - only the actual system for cooling is different.
Perhaps the best way to show the differences in the two refrigeration
methods is to describe the systems themselves. In a conventional
refrigeration system, the main working parts are the evaporator, condenser,
and compressor. The evaporator surface is where the liquid refrigerant
boils, changes to vapor and absorbs heat energy. The compressor
circulates the refrigerant and applies enough pressure to increase the
temperature above ambient level. The condenser helps discharge the
absorbed heat into the ambient air. In thermo-electric refrigeration,
essentially nothing has changed. The refrigerant in both liquid and vapor
form is replaced by two dissimilar conductors. The cold junction (evaporator
surface) becomes cold through absorption of energy by the electrons as
they pass from one semiconductor to another, instead of energy absorption
by the refrigerant as it changes from liquid to vapor. The compressor is
replaced by a DC power source which pumps the electrons from one
semiconductor to another. A heat sink replaces the conventional condenser
fins, discharging the accumulated heat energy from the system. The
difference between the two refrigeration methods, then, is that a thermoelectric cooling system refrigerates without the use of mechanical devices,
except in the auxiliary sense, and without refrigerant.
Thomson effect:
It is reversible thermoelectric phenomenon. When a
current passes through a single conductor having temperature gradient has
exhibited.
2.4 Joulean effect: When the electric current passed through a
conductor, there is dissipation of electrical energy in the form of heat.
According to Joule it is related as
qj = I2R
Where I= current
R= electrical resistance
2.5 Conduction effect:
If the ends of any element are maintained at
different temperatures, there is heat transfer from hot end to cold
end & it is related by
Qcond = U (Th-Tl)
Where
U = overall conductance
Th=high temperature
Tl=low temperature
*Abram Ioffe and co-workers discovered that some semi-conductors
exerted a much stronger Peltier/Seebeck effect and developed thermo-
3. WORKING OF THERMO-ELECTRIC
REFRIGERATION:
As shown in figure 3 two different materials are connected by battery in
which P-type region is connected to the positive terminal and N-type to the
negative terminal.
If a current is passed trough them, the cooling is produced at one
junction and heat is produced at other junction. If T h is maintained at
ambient temperature, Tc will be lower at ambient temperature. It also to be
noted that which of the junction or ends will become cold or hot depends on
direction of flow of current.
From the analysis of all the effects it has been found thatcoefficient
performance of system is
COP= qc/energy supplied
= [ab I Tl-I2R/2-U (Th-Tl)]/ [ab (Th-Tl) I+I2R]
Where ab= Seeback constant
I = Current passed
R= Electrical resistance
U= Overall conductance
Th= High temperature
Tl= Low temperature
Assumptions made for COP equation are:
1. Heat transfer takes place through the semiconductor at the ends only.
2. No energy exchange between the conductors through space separating
them.
3. Properties such as conductivity resistance are invariant with temperature.
Theory of Operation
The semiconductor materials are N and P type, and are so named because
either they have more electrons than necessary to complete a perfect
molecular lattice structure (N-type) or not enough electrons to complete a
lattice structure (P-type). The extra electrons in the N-type material and the
holes left in the P-type material are called "carriers" and they are the
agents that move the heat energy from the cold to the hot junction.
Heat absorbed at the cold junction is pumped to the hot junction at a
rate proportional to carrier current passing through the circuit and the
number of couples. Good thermo-electric semiconductormaterials such as
bismuth telluride greatly impede conventional heat conduction from hot to
cold areas, yet provide an easy flow for the carriers. in addition, these
materials have carriers with a capacity for carrying more heat.
Heat Sinks
The design of the heat exchanger is a very important aspect of a
good thermo-electric system. The upper part of the diagram illustrates the
steady-state temperature profile across a typicalthermo-electric device from
the load side to the ambient. If the heat sink is not capable of rejecting the
required Qs from the given system, the temperature of the entire system will
rise and the cold junction temperature will increase. If the thermo-electric
current is increased to maintain the load temperature, the COP (Coefficient
of Performance) tends to decrease. Thus, a good heat sink contributes to
improve COP. Energy may be transferred to or from the thermo-electric
system by three basic modules: conduction, convection, and radiation. The
values of Qc and Q1 may be easily estimated; their total along with the
power input gives Qs, the energy the hot-junction heat sink must dissipate.
into the cabinet. Each face of the module would need approximately 10
degrees Kelvin temperature difference relative to either the refrigerated
cabinet or the external air before there is sufficient heat transfer by
convection in air. This larger temperature difference causes the coefficient
of performance to decline from approximately 1 to 0.5 or less because of
reverse thermal conduction in the module.
A liquid-liquid heat transfer system for the Peltier module usually
involves a liquid coolant which transfers heat from the module to the air by
a radiator. It is also possible to cool a process fluid directly without using a
radiator. This is a more efficient process but may involve problems of
corrosion or blockage inside the heat exchange tubes. A pump is required
to circulate the coolant and the radiator will probably require a fan, thus
raising the level of mechanical complexity of the system when compared to
direct air cooling. In most cases, water is used as the coolant because it is
readily available, non-corrosive and an efficient medium for heat transfer.
Brine is also used on the cold side of the module in order to prevent
blockage by freezing of the coolant.
The main advantage of using water-based cooling systems is that the
Peltier module can work at a temperature difference that is far closer to the
nominal temperature difference of the system. This is because the
convective heat transfer coefficient between water and a solid interface is
much higher than air for comparable flow conditions. The Peltier module is
then able to work at close to its optimum thermodynamic efficiency thus
reducing electricity consumption to practicable levels. Refrigeration is a
major source of electricity consumption and there is little purpose to
mitigate ozone destruction if in return, the greenhouse effect is intensified
by an increase in electricity demand. European Union (EU) legislation has
imposed limits on the amount of electricity that can be consumed annually
by an individual refrigerator inside EU countries. This legislation
necessitates either a high coefficient of performance from the refrigerating
system or very efficient thermal insulation on the refrigerator cabinet.
The maximum temperature difference between hot and cold side for
practical functioning by Peltier modules is approximately 70 degrees
Celsius. Larger temperature differences can be obtained by stacking the
Peltier modules where the waste heat from the coldest module is
conducted to the cold side of the warmer module. The disadvantage of this
method is the low COP so that it is mostly used for specialized
instrumentation applications.
5. DEVELOPMENT OF MATERIALS:
Since the beginning of the industrial revolution, humanity has
demanded an ever-increasing supply of energy.
TE devices are currently used in automotive seat coolers/heaters
(over 500,000/yr), in portable refrigerators that plug into an automobiles
cigarette lighter, and in chemical and nuclear generators in arctic regions
and space probes. Increasing the efficiency of TE materials has been the
primary goal of research in the field, and may allow penetration of the
economical and environmentally friendly technology. Thermo-electric might
then be coupled to any number of heat sources to extract electricity from
heat that would otherwise have been dissipated into the environment as
waste. Examples of potentially useful heat sources include fuel cells, the
steam generator systems inherent in all large power plants, solar collectors,
the shaded sides of solar cells, and automotive exhaust. A Japanese
elements found in the lower right corner of the periodic table group IIIB to
VIB.
Some materials and their figure of merits are as shown in chart.
2.
3.
4.
5.
7. APPLICATIONS:
One application in practical use is that of a drinking water cooler.
Although there may be variations by different manufacturers, the author
has observed and used one thermo-electrically cooled (and heated)
drinking water cooler that dispenses ice water. The thermoelectric module
cools a disk at the bottom of a holding tank well. In this well, there is a
focus beam that shines across the disk to a light sensor. The 120 volt
power supply has a switching circuit that detects the amount of light across
the disk. When ice forms on the disk and it builds to a thickness that
deflects some of the light, the power supply is switched off. With the current
stopped, some of the heat from the modules hot side heat exchanger will,
warm the disk to free the ice by conduction. The remainder of the heat is
dissipated to the atmosphere with a small fan. Once the ice breaks free, it
will float to the top of the holding tank, the light sensor will turn the power
supply back on, and a new block will be produced approximately every
hour.
8. FUTURE DEVELOPMENTS:
The two main issues in thermo-electric refrigeration are the development of
new materials with stronger Peltier effects and the application of these
materials to real engineering problems such as refrigeration and control of
process heat. The former issue is primarily the domain of physicists and
materials scientists who test a large number of materials looking for
crystalline structures which combine high electrical conductivity with low
thermal conductivity as well as a strong thermo-electric characteristic. The
latter issue is of greatest concern to mechanical engineering where
problems such as heat transfer between the module and cheap
manufacture of modules are of concern. For refrigeration, unlike airconditioning, the power consumption is relatively small, typically 50 Watts
which means that the number of modules and their cost is also small. This
means that the main issue for refrigeration is heat transfer between the
module and its external environment. The level of interest in these
engineering problems is intensifying as the efforts of physicists and
9. CONCLUSION:
From the all above discussion we can predict that thethermoelectric refrigeration is in experimental stage. Though it is so, today it is
being used in surgery for cooling the instrument used for extracting the
crystalline lens out of the eye.
There is problem from testing of thermo-electric refrigeratorthat by
using the heat pipe, we can achieve heat transfer rate 500 times more than
the conventional heat removal aids like fins etc.by evaporating the heat
pipe reverse heat transfer which occurs after the shutoff power supply can
be solved So it has been noticed that use of heat pipe will lead to improve
the performance of the thermo-electric module and ulmatly the refrigerator.
Thermo-electric refrigeration is likely to become a significant form of
domestic refrigeration within the medium term because of the need to avoid
refrigerating fluids that are hostile to the environment.
Precise control of temperature for better food preservation, low noise and a
reduced number of moving parts are also significant benefits of thermoelectric refrigeration.
The energy consumption of thermo-electric refrigeration can be reduced to
moderate levels with further improvements in the heat transfer between the
various stages of the refrigerating system.
Last but not least, I feel that though thermo-electric
refrigeration system is at experimental stage and have less application
today, in future it can become popular, convenient, reliable eco-friendly
alternative refrigeration system.