Solutions

1
FIITJEE
JEE(Main)-2015
ANSWERS, HINTS & SOLUTIONS
CRT III
(Main)
ALL INDIA TEST SERIES
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AITS-CRT-III-PCM(Sol)-JEE(Main)/15
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
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8.
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10.
11.
12.
13.
14.
15.
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28.
29.
30.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
1.
Td t Mv Mu and
T d t Mv
TA
u
2
Tdt
2.
Let equivalent resistance between A and B is R.

V
i
iR V, iR
i
3
3
V 2i
R2
3 3
Tdt
v2
u2 3Mg
TA new Mg M
Mg M
l
4l
2
TA old Mg
u
v
R1
R1
A
i i
R2
B
R 2R2
2V
3
R1 4
R2 3
iR1
3.
Conserving angular momentum

3mR2
mvR
3mR 2
2
2v 3R

6R
4.
Let at any time a charge q flows through the circuit. The

circuit is as shown
2RC
Time constant ( )
3
2C
4V
5.
4CV
1
3
3t
e 2RC
VM
IM1
1
R 1L
1C
VM
Similarly, IM2
1
R 2L
2 C
and IM2 are n times less than resonance current amplitude,

2
Since, both IM1
3
IM1 IM2
VM
or
6.
VM
1
1
R2 1L
R2 2L
2C
1
1
1L
2L
1C 2 C
or
12LC 1 1 22LC
1C
2 C
or
or
12LC(1 2 ) (1 2 ) 0
1 12LC 0
12
0 12
f0
1 T
2l
1
02
LC
df0 1 dT
f0
2 T
f0 2 15
T
100 150 Hz.
21
7.
W PdV and P V
9.
The object distance for the mirror

20
15
30 cm
4
/ 3
For mirror,
1 1 1

v u f
1
1
1
v 60 cm
v 30 20
The distance from water surface equals 60 15 = 45 cm
12.
Least count =
Pitch
Number of divisions on circular scale
1mm
0.01mm 0.001 cm
100
Zero error = 0.03 mm
Measurement = 3.76 ( 0.03) = 3.79 mm
13.
a
a
rcm i j (considering A to be origin AD to x-axis and AB to be y-axis)
2
2
a
a
Li mrcm v cm m i j v 0 (2i 4 j)
2
2
mav k
= mav (2k k)
0
4
m
ma2 ma2
a2
L f (a2 a2 ) m
2
2
12
6
From conservation of angular momentum about point A
L f Li
2
ma2 mav 0
3
3v
0
2a
3v a
3v0
a
v cm
0
2a 2 2 2
2
14.
If V0 be volume of the gas at C, P0 V0 3RT0

W = 3R(2T0 )ln 2 P0 V0
= 6RT0 ln 2 3RT0
= 3RT0 [2 0.693 1]
= 3RT0 [1.386 1]
= 1.16RT0
15.
mv 0R = I + mvR
v
= mR2 mvR
R
v0
=
2
1
= mv 02
2
v
Ki
Kf =
=
v2
1
1
1 v
1
mv 2 I2 m 0 mR2 02
2
2
2 2
2
4R
1
mv 20
4
1
So Wf = mv 02
4
16.
Initial current in R3 , ii
Final current if
E
R1 R 3
R2
E
R2R3
R2 R3
R1
R2 R3
R2E
R1 (R2 R3 ) R2R3
if
R1R3
R1 R 3
R2
As if ii , so current in the resistor R3 will decrease.
5
17.
vy
dy
1
dx
3 vx
So v x v y 3
v 2x v y2 v 02
3v 2y v 2y v 02
v0
2
3v 0
vx
2
vy
So y e
3v 0
3v 0
2
y e1
18.
If the string is pulled down by distance x, it is equivalent that a mass of x is removed from the
upper end of the string and is connected to the lower end
So Wg U Ui Uf
GM(x) GMx
RL
R
1
1
= GMx
R
R
L
K
amax = 2A =
A
m
If mass and amplitude both are doubled maximum acceleration will not change.
Wg
19.
20.
Resultant wave amplitude is given by

A = A12 A 22 2A1A 2 cos(1 2 )
Value of cos(1 2) lies between 1 and 1
Hence A1 A2 A A, + A2
24.
If three waves meet in same phase then the resultant amplitude will be algebraic addition of all
three amplitudes
R = 3A
A Amplitude of superimposed wave
R Amplitude of resultant wave
than I = 9I0 as [I R2]
25.
If process starts and ends on same isotherm then product of P and V must be constant hence
process a, b, d will be on same isotherm.
26.
mix
n1Cp1 n2Cp2
n1Cv1 n2Cv 2
7
5
2 R 1 R
2
2 19
=
5
3
13
2 R 1 R
2
2
6
27.
1 1
R(Z 1)2 2 2
K
1 2
l
1 1
R(Z 1)2 2 2
K
1 2
Solving (i) and (ii) Z = 9
.....(i)
....(ii)
28.
= A( 1) Slope of line will be A.
30.
x =
(SS1 + S1O) (SO) =
2
2

d
2D 1
1
2
2D
2
2 D2 d2 2D
d =
D
2
7
Chemistry
1.
2.
3.
PART II
SECTION A
In gas phase inductive effect play a key role.
n
Geometrical isomers = 8 = 2
3
Optical isomer = 8 = 2 = 8
= 16
Due to bulky effect.
4.
OH
O
O
O
H
OH
OH
O
H
OH
Tautomerise
5.
Birch reduction.
6.
3o carbocation is more stable.
7.
: CCl2 intermediate.
8.
CH3 CHO 2CuO CH3 COOH Cu2O

Re d ppt.
9.
D
D
D
D O
D
D
8
10.
OH
O
C
O
Polymerisation
NH
11.
It is belong to f-block Lu element.
12.
IP4 IP5 required more energy, So IVA group elements.
Mg
17.
3NaOH + 2O3 2NaO3 + NaOH.H2O(s) +
B.A
H
Mg
16.
Nylon-6
Caprolactum
15.
(CH2)5
1
O2
2
Cl2O, ClO2 , F2 O, Br2O

110
118
105
112
19.
(II) and (IV) have unpaired electron.
20.
H2S CdSO4 CdS
Yellow ppt
21.
22.
Let 1 mole of mixture has x mole N2O4

2 27.6 = x(92) + (1 x) 46
x = 0.2
2p
3p
3d
m
1
1
1
s
1/ 2 1/ 2 1/ 2
% by weight 10 d 36.5 10 1.2
12 M
M.w
36.5
36.5 1000
1000
m
15.7 m
36.5 100 36.5 63.5
23.
24.
ClO3 ClO4 2e x 2 oxidation

x = 5,
x=7
e ClO3 ClO2 x 1 reduction

x = 5, x = 4
M
EW M
2
25.
Ideal gas has no force of attraction and has negligible volume. Hence it cant be liquefied at any T
and P.
9
26.
H = nxCp T
PV
n
0.05
RT
Cp = Cv + K
Cp = 20.794 JK
r 1
For reversible adiable TV
T2 V2r 1
cons tan t
T1V1r 1
r = 1.66 for argon

T2 = 189.85 k
T = 110.15
Thus H = 0.05 20.794 110.15) = 114.52 J
27.
CH3 COCH3
CH3CH3 g CO g
At t 0
At t t
150
150 x
0
x
0
x
x
1
150 x 3
x = 75 mm.
28.
Mg OH2
Mg 2OH
s
2s
4s3 = 8.9 1012,

s = 1.3 104 m
[OH] = 2 1.305 104
pOH = 3.58832
pH = 10.4168
29.
1 mole of A will form 2 moles of B and C after completion of reaction when 75%. A converted into
B and C then total no. of moles
0.5 2 1.5 3.5 moles
30.
Along one body diagonal 2X atoms from 2 corners, one Y particle (at the centre of cube) will be
removed.
1 15
So effective no. of X particle in a unit cell = 4 2
8
4
And effective no. of Y particle in a unit cell = 4 1 = 3
15
X:Y
:3
4
5:4
10
Mathematics
1.
PART III
SECTION A
.. (1)
+ = p
is a root of equation
xn + 1 + (x + 1)n = 0
Again since
n
1 1 0
n
n
n
+ + ( + ) = 0
n + n = ( + )n = (p)n
From equation (1) and (2), we get
n
n
n
n
p = (p) p = (p)
n
n n
n
p = (1) p (1) = 1
n is an even integer
2.
.. (2)
From the figure, OM is bisector of angle BOP of triangle OBP

O (observer)
250 OB
50
OP
2
2
300 x
5
x
25x2 x2 = (300)2
300 m
24x2 = (300)2
300 300
x2
3250 25 25 6
24
x 25 6.
x m
A
1
3.
P
50 m
M
250 m
P 101 10 2 10 2 10 2 ..
2
1
1
1
10 2
1 1 1
1 2 3 .....
2 2 2
P 10
=
102 100
log0.01P = log0.01(100) = 1
4.
ax 2 b
ax 2b x ab
2
Consequently, for all x > 0
x
x
1
y 2
ax b 2x ab 2 ab
n
5.
x =
0.1 1 C1 2 C2 3 C3 n Cn
1 n C1 n C2 n Cn
r n Cr =
r 0
r r
n 1
Cr 1
r 1
n Cr
r 0
n n 1Cr 1
r 1
n
n Cr
n2n 1 n
=
2
2n
r 0
11
6.
n!
Greatest coefficient is
q!
m r
q 1!
15!
3! 4!
ln = 15 and m = 4, q = 3 and r = 37
15 = 4 3 13
7.
Two triangles may have equal areas

f is not one-one
Since each positive real number can represent area of a triangle
f is onto
8.
Area of PAB =
9.
32
sin 2
(PAB)min when 2
2

4
h = OC cosec = 4 2
P(0, h)
C
Equation of chord joining and is
x
y

cos
sin
cos
a
2 b
2
2
+ = 3
x
y
cos
0
a
2 b
It passes through the centre (0, 0)
10.
Ordinate of the point of intersection of the line
x y
m and the hyperbola, given by
a b
2y
x y x y 2y
a b a b b 1 i.e. m m b 1
i.e. y
b 1 m2
2m
Similarly ordinate of the point of intersection of the line

y
x y
m and the hyperbola is given by
a b
b m2 1
2m
Sum of the ordinates is zero
11.
Let P(x1,y1 ) , Q(x 2 , y 2 ) be the given points on y 2x 2

y1 2x1 2 and y 2 2x2 2
OP i = projection of OP on x-axis = x1 = 1 y1 = 2
and OQ i = projection of OQ on x-axis = x2 = 2 y2 = 16
OP i 2j , OQ 2i 16j
OQ 4OP 6i 8i
OQ 4OP 6i 8j 10
12
12.
The point B is (q, p) and the point C is (p, q) mid-point of AC is (0, 0)
13.
The point Q is (2, 1)

Image of P(1, 2) in the line x 2y + 1 = 0 is given by
x 1 y 2 4
1
2
5
9 2
Ordinate of the point are ,
5 5
Since this point lies on QR
Equation of QR is 3x y 5 = 0
+=2
14.
Let (, 3 ) be any point on x + y = 3

Equation of chord of contact is x + (3 )y = 9
i.e. (x y) + 3y 9 = 0
The chord passes through the point (3, 3) for all values of
15.
Equation of the two circles be (x r)2 + (y r)2 = r2 i.e. x2 + y2 2rx 2ry + r2 = 0 where r = r1 and
r2 condition of orthogonally gives 2r1r2 + 2r1r2 = r12 r22
4r1r2 = r12 r22 , circle passes through (a, b)
a2 + b2 2ra 2rb + r2 = 0
i.e. r2 2r(a + b) + a2 + b2 = 0
4(a2 + b2) = 4(a + b)2 2(a2 + b2)
a2 4ab + b2 = 0
16.
y2 6 x
2
Equation of directrix x = 0
3 3
Let coordinate P be t 2 , 3t
2
2
Coordinate of M are (0, 3t)

MS 9 9t 2
3 3
MP t 2
2 2
2
9
3 3
2
9 + 9t = t 2 1 t 2
2
2
4
4 = 1 + t2
Length of side = 6
17.
yy1 = 2a(x + x1)

2a
x2 = 4by = 4b x x1
y1
2
y1x 8ab x 8ab x1 = 0
D = 0 gives xy = 2ab
13
18.
Equation of the tangent to the ellipse at P(5 cos , 4 sin ) is
x cos y sin
1
5
4
It meets the line x = 0 at Q(0, 4 cosec )

Image of in the line y = x is R(4 cosec , 0)
Equation of the circle is x(x 4 cosec ) + y(y 4 cosec ) = 0
2
2
i.e. x + y 4(x + y) cosec = 0
Each member of the family passes through the intersection of x2 + y2 = 0 and x + y = 0
i.e. The point (0, 0)
19.
Equation of normal at (13 cos , 5 sin ) of
x2
y2
1
169 25
13 sin
x 13cos it passes through (0, 6) then cos (15 + 72 sin ) = 0
5 cos
5
cos = 0, sin
24
5
sin1
24
y 5 sin
21.
Given, f(x) = (x 1)(x 2)(x 3)(x 4)

Consider the interval [1, 2]
Since, f(x) is a polynomial function, it is continuous in [1, 2] and differentiable in (1, 2)
Also, f(1) = 0 = f(2)
By Rolles theorem these exists a point x = c in (1, 2) such that f(c) = 0 i.e. these exists a root of
f(x) = 0 in the interval (1, 2) which is positive
Similarly, two positive roots of f(x) = 0 exist in the open interval (2, 3) and (3, 4)
Hence, the three roots of f(x) are positive
22.
f(x) g(y) + f(x) g(y) = g(y)

(f(x) + f(x)) g(y) = g(y)
g' y
f(x) + f(x) =
= constant
g y
Put y = 0
g' 0
g0
.. (1)
1
1
Now from equation (1), we get f(x) + f(x) = 1 and
g' y
g y
g(y) = ey
23.
10
24.
Total number of numbers without restriction two numbers have all the digits equal
Hence, the required number of numbers = 25 2 = 30
25.
Given 7a 9b = 0 b =
C1
10
C2
10
C3
10
C4 10 45 120 210 385
7
a
9
So, the number of pairs (a, b) can be (9, 7), (18, 14) (27, 21) and (36, 28)
4
4
Required probability = 39
C2 741
14
26.
Two numbers are selected from {1, 2, 3, 4, 5, 6}

n(S) = 6 5 (as one by one with out replacement) favourable events = minimum of the two
numbers is less than 4
n(E) = 6 4
As for the minimum of the two is less then 4, we can select one from {1, 2, 3, 4} and other from
{1, 2, 3, 4, 5, 6}
n E 24 4
Required probability =
n S 30 5
dx
cosec 2 x
sin2 x cot x cot x dx

sin4 x cot x
Put cot x = t2
cosec2 x dx = 2t dt
2
2t
= dt = 2t + c = 2 cot x c =
c
t
tan x
28.
Let a = 2x, b = 3x 1, c = 1
a3 + b3 + c3 = 3abc
1
2
Now, a3 + b3 + c3 3abc = a b c a b factorizing and get a + b + c = 0 as a b c
2
Hence, the given equation is; 2x 3x 1 1 = 0
By trial x = 1 and 2 are solution of this
Now, 2x = 3x 1 + 1 has no other solution
Number of real solution exactly two
29.
2 sin2 5 sin + 2 > 0

1
sin
( 1 sin 1)
2
5
0, , 2
6
6
30.
Let h(x) = f2(x) + (f(x))2

h(x) = 2x(f(x))2 g(x)
x = 0 is the point of maximum
dx
27.

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1

ALL INDIA TEST SERIES

Let equivalent resistance between A and B is R.

Conserving angular momentum

Let at any time a charge q flows through the circuit. The

and IM2 are n times less than resonance current amplitude,

Since, both IM1

The object distance for the mirror

If V0 be volume of the gas at C, P0 V0 3RT0

Resultant wave amplitude is given by

= A( 1) Slope of line will be A.

(SS1 + S1O) (SO) =

3o carbocation is more stable.

CH3 CHO 2CuO CH3 COOH Cu2O

It is belong to f-block Lu element.

IP4 IP5 required more energy, So IVA group elements.

3NaOH + 2O3 2NaO3 + NaOH.H2O(s) +

Cl2O, ClO2 , F2 O, Br2O

(II) and (IV) have unpaired electron.

H2S CdSO4 CdS

Let 1 mole of mixture has x mole N2O4

ClO3 ClO4 2e x 2 oxidation

e ClO3 ClO2 x 1 reduction

For reversible adiable TV

r = 1.66 for argon

4s3 = 8.9 1012,

From the figure, OM is bisector of angle BOP of triangle OBP

Two triangles may have equal areas

Equation of chord joining and is

Ordinate of the point of intersection of the line

Similarly ordinate of the point of intersection of the line

Let P(x1,y1 ) , Q(x 2 , y 2 ) be the given points on y 2x 2

and OQ i = projection of OQ on x-axis = x2 = 2 y2 = 16

The point B is (q, p) and the point C is (p, q) mid-point of AC is (0, 0)

The point Q is (2, 1)

Let (, 3 ) be any point on x + y = 3

Coordinate of M are (0, 3t)

yy1 = 2a(x + x1)

Equation of the tangent to the ellipse at P(5 cos , 4 sin ) is

It meets the line x = 0 at Q(0, 4 cosec )

Equation of normal at (13 cos , 5 sin ) of

Given, f(x) = (x 1)(x 2)(x 3)(x 4)

f(x) g(y) + f(x) g(y) = g(y)

Now from equation (1), we get f(x) + f(x) = 1 and

C4 10 45 120 210 385

Two numbers are selected from {1, 2, 3, 4, 5, 6}

sin2 x cot x cot x dx

2 sin2 5 sin + 2 > 0

Let h(x) = f2(x) + (f(x))2

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