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Carbinol Functional
Carbinol Functional
Silicon-Based Technologies
for Coatings
CH 3
CH 3
CH 3
CH 3
|
|
|
|
R- Si - O (- Si - O )n (- Si - O )m -Si - R
|
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|
CH 3
CH 3
R
CH 3
Parts by Weight
219.7
263.2
17.6
17.6
481.9
1000
CH 3
Ingredients
Alberdingk Lux 399
Dow Corning 68 Additive
Ultralube D816
Acematt TS 100
DSX 300
Irgacure 500
Total
Parts by Weight
951.0
3.0
25.0
5.0
6.0
10.0
1000
By Donna Perry and Vicky James/Dow Corning Ltd., Barry, UK; and Gerald Witucki/Dow Corning, Midland, MI
86
A P R I L 2 0 0 5 / www.pcimag.com
5.0
4.0
3.0
2.0
1.0
0.0
Ca
Ca
AB
AB
A
AB
rb
in
ol
3
l2
no
rb
i
in
Ca
rb
Co
nt
ol
ro
0.5% add
1.0% add
0.5% add
1.0% add
ol
l2
in
Ca
rb
AB
A
Ca
A
AB
Ca
A
AB
rb
i
rb
i
no
no
ro
l1
nt
Figure 2/Mar resistance of ABA linear silicone carbinol fluid with (EO)1OH
functionality in UV solventless parquet lacquers.
Co
Mar resistance
Cratering
PA I N T & C OAT I N G S I N D U S T R Y
87
0.50
0.40
0.30
0.20
0.10
0.00
in
rb
Ca
A
AB
Ca
rb
in
ol
3
2
ol
ol
in
rb
Ca
A
AB
AB
A
0.5% add
1.0% add
Co
nt
ro
l
Coefficient of Friction
CH3
(CH3)3-Si-O-Si-O-Si-(CH3)3
(CH2)3
(EO)nR
88
A P R I L 2 0 0 5 / www.pcimag.com
Parts by Weight
40.0
10.0
20.0
5.0
10.0
30.0
800.0
20.0
45.0
980
Without Additive
2.5
1.5
5
id
flu
id
in
Ca
rb
ol
in
rb
Ca
ol
flu
flu
ol
in
rb
Ca
3
id
id
1
Ca
rb
in
ol
ol
flu
id
SP
in
rb
Ca
flu
l
ro
xa
ne
nt
lo
Co
isi
0.5
Tr
Cratering
PA I N T & C OAT I N G S I N D U S T R Y
89
0.9
0.5% add
1.0% add
5.0% add
0.7
0.5
Co
nt
Tr
ro
isi
l
lo
xa
ne
Ca
SP
rb
E
in
ol
flu
Ca
id
rb
1
in
ol
f
lu
Ca
id
rb
2
in
ol
flu
Ca
id
rb
3
in
ol
flu
Ca
id
rb
4
in
ol
flu
id
5
40
30
0.5% add
1.0% add
5.0% add
20
in
in
ol
ol
rb
Ca
Ca
Ca
rb
rb
in
in
ol
ol
1
rb
in
rb
Ca
Ca
SP
ne
xa
Tr
isi
lo
ol
l
ro
nt
Co
10
6
5
4
3
2
1
0
he
EO
ny
l
l
in
o
Ca
rb
in
ol
Ca
-P
rb
ro
Co
nt
M
Q
2.5% addition
5% addition
10% addition
Cratering
Figure 10/Appearance of carbinol functional silicone resins in waterborne airdrying parquet lacquer (Formulation 3).
5
4
3
2
1
0
he
n
ol
-P
in
rb
Ca
A P R I L 2 0 0 5 / www.pcimag.com
EO
yl
l
in
o
rb
Ca
ro
nt
Co
M
Q
2.5% addition
5% addition
10% addition
Cratering
90
Conclusions
Silicone additives have progressed enormously since
the first use of PDMS fluids in solventborne coatings.
New chemical structures and delivery forms promise
Reference
Acrylic binder alone
Carbinol 1
Carbinol 2
Carbinol 3
Carbinol 4
Carbinol 5
he
n
EO
yl
ol
in
-P
Ca
rb
in
ol
Ca
Co
rb
nt
ro
M
Q
Mar resistance
Figure 12/Mar resistance carbinol functional silicone resins in waterborne airdrying parquet lacquer (Formulation 3).
5
2.5% addition
4
5% addition
3
10% addition
2
1
0
EO
ny
ol
olP
rb
in
Ca
work. They would also like to thank UCB, Alberdingk Boley, BASF and
Rohm and Haas for their contributions to test formulations.
Ca
Gloss 85 deg
Donna Perry and Vicky James are technical service specialists for Dow
2.5% add
5% add
10% add
60
40
References
1. Owen, MJ, The Surface Activity of Silicones: A short
review, I&EC Prod. Res. Dev., 10 (1980), 97.
2. W.H. Pushaw III in Handbook of Coatings Additives
(L.J. Calbo, ed.), Marcel Dekker, Inc., New York, 1987,
p.271.
20
For further information contact, Donna.perry@dowcorning.com,
he
l-P
ino
Ca
rb
A P R I L 2 0 0 5 / www.pcimag.com
EO
ny
l
l
ino
rb
MQ
Ca
Co
nt
ro
92
Acknowledgements
Wieber and Mike Ferritto at Dow Corning Corporation and Katrin Lan-
he
rb
in
MQ
Co
nt
ro
l
C of F
Vicky.james@dowcorning.com, or Gerald.Witucki@dowcorning.com.
This paper was presented at the European Coatings Conference Parquet
Coatings III, which took place November 2004, in Berlin. Information is
available at Vincentz Network, amanda.beyer@coatings.de.