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1 s2.0 S0167577X14014542 Main
1 s2.0 S0167577X14014542 Main
Materials Letters
journal homepage: www.elsevier.com/locate/matlet
art ic l e i nf o
a b s t r a c t
Article history:
Received 5 June 2014
Accepted 2 August 2014
Available online 11 August 2014
This letter reports the UVVIS spectroscopic studies of novel one pot synthesized polyindole/poly(vinyl
acetate) (PIN/PVAc) composite lms chemically using an oxidant nickel nitrate. The surface morphology
of the prepared sample was analyzed through eld emission scanning electron microscope (FE-SEM),
which shows irregular, non-porous structure and spongy amorphous morphology. The UVVIS spectroscopy was performed to study optical parameters of PIN/PVAc composite lms. These polymeric
composite lms exhibited strong absorption below 250 nm with a well-dened absorption peak at
around 225 nm. The optical band gap energy values of the prepared samples range over 3.9245.146 eV.
However, the maximum optical conductivity of PIN/PVAc composite lm was found to be 2.92 108 s 1
at 350 nm.
& 2014 Elsevier B.V. All rights reserved.
Keywords:
UVVIS spectroscopic
Polymers
Polyindole/poly(vinyl acetate)
Composite lms
Spectroscopy
Polymeric composites
1. Introduction
2. Experimental
Corresponding author.
E-mail address: bhagatd@rediffmail.com (D.J. Bhagat).
http://dx.doi.org/10.1016/j.matlet.2014.08.003
0167-577X/& 2014 Elsevier B.V. All rights reserved.
252
1.6
9
25 wt%
30 wt%
1.4
35 wt%
40 wt%
1.2
Absorption
45 wt%
25 wt%
30 wt%
35 wt%
40 wt%
45 wt%
50 wt%
1.0
0.8
200
250
300
Wavelength (nm)
50 wt%
350
4.0
4.5
5.0
5.5
6.0
Fig. 1. (A) FE-SEM micrograph. (B) UVVIS spectrum. (C) Plot of h versus photon energy (eV).
Ah Egn
h
1=2
1
1
1
Ts
Ts
253
Fig. 2. (A) Plot of extinction coefcient versus photon energy. (B) Plot of refractive index versus wavelength.
nc
4
Acknowledgment
Authors are very much thankful to the Principal, Arts, Science and
Commerce College, Chikhaldara, for providing the necessary facilities.
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