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Air Pollution
Air Pollution
Air pollution is responsible for major health effects. Every year, the health of countless
people is ruined or endangered by air pollution.
Many different chemicals in the air affect the human body in negative ways. Just how sick
people will get depends on what chemicals they are exposed to, in what concentrations, and
for how long. Studies have estimated that the number of people killed annually in the US
alone could be over 50,000.
Older people are highly vulnerable to diseases induced by air pollution. Those with heart or
lung disorders are under additional risk. Children and infants are also at serious risk.
Because people are exposed to so many potentially dangerous pollutants, it is often hard to
know exactly which pollutants are responsible for causing sickness. Also, because a mixture
of different pollutants can intensify sickness, it is often difficult to isolate those pollutants that
are at fault.
Many diseases could be caused by air pollution without their becoming apparent for a long
time. Diseases such as bronchitis, lung cancer, and heart disease may all eventually appear in
people exposed to air pollution. Air pollutants such as ozone, nitrogen oxides, and sulfur
dioxide also have harmful effects on natural ecosystems. They can kill plants and trees by
destroying their leaves, and can kill animals, especially fish in highly polluted rivers.
Causes of air pollution:
There are many different chemical substances that contribute to air pollution. These
chemicals come from a variety of sources.
Among the many types of air pollutants are nitrogen oxides, carbon monoxides, and organic
compounds that can evaporate and enter the atmosphere.
Air pollutants have sources that are both natural and human. Now, humans contribute
substantially more to the air pollution problem.
Forest fires, volcanic eruptions, wind erosion, pollen dispersal, evaporation of organic
compounds, and natural radioactivity are all among the natural causes of air pollution.
Usually, natural air pollution does not occur in abundance in particular locations. The
pollution is spread around throughout the world, and as a result, poses little threat to the
health of people and ecosystems.
Though some pollution comes from these natural sources, most pollution is the result of
human activity. The biggest causes are the operation of fossil fuel-burning power plants and
automobiles that combust fuel. Combined, these two sources are responsible for about 90%
of all air pollution in the United States.
Some cities suffer severely because of heavy industrial use of chemicals that cause air
pollution. Places like Mexico City and Sao Paulo have some of the most deadly pollution
levels in the world.
Large scale
industrial releases with
serious acute effects are fortunately rare but you might recollect some events such as in
Bhopal (India). Various smaller scale events occur such as leaks from road tankers, or fires in
warehouses and factories. Special local environmental exposures can arise for example in
communities exposed to drifting pesticide sprays containing say, organophosphates. Some
natural phenomena such as volcanic eruptions can present serious risks to health. Fortunately
they are rare but can be catastrophic. According to a servey following are some statistics
about the air quality and health
In developing countries 0.5 1.0 million people die as a result of exposure to urban air
pollution
30 40 % of asthma
20 30 % all respiratory diseases
Air pollutants:
Sulfur dioxide
Nitrogen oxides
Ammonia
Carbon monoxide
Volatile Organic Compounds (VOCs)
Ozone
Persistent Organic Pollutants (POPs)
Airborne particles
Toxic metals
Radioactive pollutants
General Overview and Characteristics:
Air pollutants are generally defined as substances of gaseous, solid or liquid nature emitted
into the atmosphere by both natural and anthropogenic (human-caused) sources, that are
capable of causing harm to the environment in general, and living organisms in particular.
In other words, these pollutants are the agents that change the normal functioning of the
atmosphere and have an negative impact on all life forms including animals and plants.
General Characteristics:
Possibly one of most important characteristics of these pollutants is their trans boundary
nature. They know no borders and they can travel long distances from their source of origin
to the places that are not related to them in any shape or form.
An excellent example of that is the Arctic Haze, a visible reddish brown haze found above the
Arctic mainly in winter months and caused by pollutants in the air travelling from global
sources thousands of miles away, specifically from Asia.
This contributes to warming the Arctic faster than any other region in the world, causing the
sea ice to melt and destabilizing the environment.
Pollutants in the air can also be of primary or secondary nature.
Primary air pollutants are the ones that are emitted directly into the atmosphere by the
sources (such as power-generating plants).
Secondary air pollutants are the ones that are formed as a result of reactions between primary
pollutants and other elements in the atmosphere, such as ozone.
Transformation and Deposition
Once in the air, primary pollutants may undergo chemical reactions with other elements and
become part of different compounds, and thus transforming into secondary pollutants.
There are two ways for primary and secondary pollutants to be removed from the atmosphere
(this process is called deposition).
The first one is wet deposition. It works as follows. Pollutants make way into clouds or other
precipitation and then get deposited on to the surface of the Earth by way of rain (specifically,
acid rain).
The second one is dry deposition, during which pollutants are deposited directly on to the
surface of the Earth and vegetation, such as plants and trees of tropical rainforests.
Important Pollutants
Among the most important pollutants are sulphur dioxide (SO2), nitric oxide (NO), ozone,
volatile organic compounds (VOCs).
In fact, you may be surprised to learn that just one Siberian city in Russia Norilsk
produces 1% of the total global emissions of sulfur dioxide. In 2007, Norilsk was considered
to be one of the most polluted places on Earth.
Natural Sources of Sulfur Dioxide Emissions:
There are also significant sulfur emissions generated by natural sources.
The main natural sulfur emissions come in the reduced forms of sulfur compounds such as
Hydrogen sulfide (H2S)
Carbon disulfide (CS2)
Carbonyl sulfide (COS)
And in the organic forms of:
Methyl mercaptan (CH3SH)
Dimethyl sulfide (DMS) (CH3SCH3)
Dimethyl disulfide (DMDS) (CH3SSCH3)
Most of these compounds get oxidized to sulfur dioxide or to sulfate aerosols in the
atmosphere. Marine phytoplankton produce dimethyl sulfide (DMS) which is then oxidized
to SO2 in the atmosphere; decay processes in soil and vegetation produce H2S (as one of
sulfur compounds); and SO2 is emitted into the atmosphere by volcanoes. Around 90% of all
natural sulfur emissions come in the form of DMS. Most recently the natural sources have
been by far surpassed by anthropogenic sources. Natural sources have been estimated to
produce around 24% of all sulfur dioxide emissions, whereas human-caused emissions made
up around 76%.
Effects of Sulfur Dioxide Emissions
Sulfur dioxide found in the air produces following effects (20, 21):
Irritates eyes, nose, throat
Damages lungs when inhaled
As part of acid rain:
Acidifies lakes and streams
Destroys plant and fish life in lakes and streams
May deplete mineral nutrients in the soil
May cause reduction of forest and agricultural yields
Corrodes metals
Damages surfaces of buildings
Nitrogen Oxides
Author Andrew Farmer points out that oxides of nitrogen are produced by combustion of all
fossil fuels including coal- and gas-fired power stations and motor vehicles. Whereas fuel
itself can produce some nitrogen (for example, oil and coal contain around 0.5 1.5% of
nitrogen, and natural gas contains less than that), most of nitrogen oxides' production comes
from the reaction of atmospheric nitrogen and oxygen within the combustion chamber.
The two main nitrogen oxides are nitric oxide (NO), or nitrogen monoxide, and nitrogen
dioxide (NO2) the sum of which is equal to NOx. Nitric oxide (NO) is a colorless gas.
Nitrogen dioxide (NO2) is a gas of reddish-brown color with a distinct sharp, biting odor.
Combustion of fuels always produces both NO2 and NO. But almost 90% of the NOX
combustion product is in the form of NO which is then oxidized to nitrogen dioxide (NO2) in
the air. Therefore, only a small percentage of NO2 found in the atmosphere is directly emitted
there in this form. The rest has been formed as a result of chemical reactions in the
atmosphere itself.
Anthropogenic Sources of Nitrogen Oxide Emissions
Road transport (motor vehicles) is by far the largest contributor of nitrogen emissions (in
contrast, it contributes a very small proportion to sulfur dioxide emissions, as discussed
above).
Vegetation
Biomass burning
Effects of Ammonia Emissions
Exposure to very high concentrations of gaseous ammonia in the air may result in lung
damage and even death.
Carbon monoxide (CO):
Carbon monoxide is a colorless, odorless gas which is highly toxic to humans.
The combustion of carbon-based fuels produces carbon dioxide (CO2). But not all such
combustion is complete, and this leads to the production of carbon monoxide (CO).
Motor vehicles and industry are among the largest anthropogenic sources of carbon monoxide
emissions.
Effects of Carbon Monoxide Emissions
Carbon monoxide is the most common type of fatal poisoning in many countries around the
world.
Exposures to carbon monoxide may lead to (40):
Toxicity of the central nervous system and heart
Severe effects on the baby of a pregnant woman
Headaches and dizziness
Problems with getting oxygen supplied to some body parts which may be lifethreatening.
Volatile Organic Compounds (VOCs):
Volatile organic compounds (VOCs) are defined as organic compounds which easily
evaporate and enter the atmosphere. VOCs may include a wide range of organic air
pollutants, from pure hydrocarbons to partially oxidized hydrocarbons to organic compounds
containing chlorine, sulfur, or nitrogen.
Historically, the definition of VOCs did not include methane compounds (non-methane
VOCs: NMVOCs) since the atmospheric concentration of methane was considered to be a
stable natural background. But it was ultimately recognized that methane is also an
anthropogenic air pollutant that comes from intensive animal and rice production.Though
some of these compounds can have direct toxic effects, they have been grouped together
because of their role in ozone formation.
Anthropogenic Sources of Volatile Organic Compounds
The major anthropogenic sources of VOCs include;
Solvent Use (including paints, adhesives, aerosols, metal cleaning and printing)
Road transport (emissions from fuel / petroleum use)
Production processes
Extraction and distribution of fossil fuels
For example, in the UK the biggest emissions of NMVOCs are due to solvent use and road
transport. Jeremy Colls points out those substantial NMVOC emissions occur during the
following processes;
Painting (evaporation of solvents)
Oil production (flaring and venting of gas)
Oil refining (flaring and fugitive emissions)
Distribution of oil or refinery products (evaporation from storage, displacement losses
when venting tanks)
Dry cleaning (final drying of clothes)
Production of alcoholic drinks (breweries and distilleries)
Arable farming (crop growing, silage manufacture, sludge spreading)
Volcanoes
Forest fires
Living vegetation
Effects of Airborne Particles
Particles less than 10 m in diameter are of biggest concern to human and animal health as
they can be easily inhaled and get trapped in the respiratory system.
Jeremy Colls also notes that particles of this size have very low gravity-related sedimentation
rates and may therefore remain in the atmosphere for days before being washed out by rain or
attached to vegetation or buildings.
Airborne particles may cause;
Asthma
Lung cancer
Cardiovascular problems
Kathmandu Pollution
Exposure to carbon monoxide may lead to ;
Toxicity of the central nervous system and heart
Headaches, dizziness, nausea and unconsciousness
Loss of vision
Decreased muscular coordination
Abdominal pain
Severe effects on the baby of a pregnant woman
Impaired performance on simple psychological tests and arithmetic; loss of judgment
of time
In cases of prolonged exposure to high CO concentrations, unconsciousness,
convulsions and death would occur
Carbon monoxide pollution effects are exacerbated in weaker people, specifically in those
with heart and lung diseases.
Ozone Effects:
Ozone (O3) is a poisonous gas with a sharp and cold odor.
It can be found in the stratosphere where it occurs naturally and plays a beneficial role by
protecting the Earth from ultraviolet sunlight; and in the troposphere where it occurs naturally
and also forms part of the human-caused photochemical smog.
It is of course the tropospheric ozone that we are interested in as an important air pollutant.
The chemical reaction between nitrogen oxides and volatile organic compounds (VOCs) in
the presence of sunlight results in the photochemical smog; the tropospheric ozone is an end
product of this reaction and a component of the smog itself.
Santiago Smog
Because the photochemical smog requires a lot of sunshine to form, it occurs mostly in sunny
and heavily polluted places, such as Los Angeles, Mexico City and even Athens. Ozones
main victim within the human body is its respiratory system. Once in the lungs, ozone
burns through cell walls. The immune system fails to protect the lungs because ozone pushes
the defensive cells back. As cellular fluid starts seeping into the lungs, breathing becomes
rapid, shallow and painful.
Exposure to ozone over long periods of time leads to a stiffening of the lungs and a reduced
ability to breathe. As an example, a study conducted in California in the 1980s shows that
children living in ozone-polluted areas have smaller than normal lungs and adults lose up to
75% of their lung capacity.
So, exposure to the tropospheric ozone may cause;
Burning nose and watering eyes
Tightening of the chest
Coughing, wheezing and throat irritation
Rapid, shallow, painful breathing
Susceptibility to respiratory infections
Inflammation and damage to the lining of the lungs
Aggravation of asthma
Fatigue
Cancer
Ammonia Effects:
Ammonia is a colorless, pungent, hazardous caustic gas composed of nitrogen and hydrogen.
Though ammonia is used for different applications in many sectors, agriculture is its largest
consumer and producer. Livestock farming, animal waste and fertilizer application are the
biggest sources of atmospheric ammonia emissions within the agricultural sector. Gaseous
ammonia is a dangerous air pollutant. Breathing in large amounts can cause death.
So, ammonia pollution effects are;
On the respiratory system:
Ammonia Fertilization
Australia, c. 1975
Nose & throat irritation and burns (their severity increasing with the increased
ammonia concentrations)
Swelling of the throat and airways; airways destruction
Pulmonary edema
Chronic lung disease
Cough
Asthma
Lung fibrosis
Inhaling large amounts of ammonia can be fatal
On the skin & eyes :
Skin burns
Skin conditions, ex. dermatitis
Burning sensation in the eyes
Ulceration & perforation of the cornea (can occur months after exposure); blindness
Cataracts & glaucoma
Volatile Organic Compounds:
Volatile organic compounds (VOCs) are defined as organic compounds which easily
evaporate and enter the atmosphere.
VOCs are important pollutants for two reasons.
first, they are precursors
to the formation of ozone
(which is part of the
photochemical smog);
second, they include
compounds which are
carcinogenic and
mutagenic in their own right.
Typical VOCs include
propane, benzene, ethanol,
methanol, ether, carbon
tetrachloride
and
vinyl
chloride;
substances
such as petrol and resins
contain many individual
VOCs, and many others are
produced
during
combustion
processes.
Toxicity of some VOCs
and ensuing health effects are
no doubt issues of
serious concern.
For example, exposure to benzene and 1,3-butadiene is a suspected cause of around 10% of
leukemia incidence in the UK.
Exposure to toluene another dangerous VOC may lead to the dysfunction of the central
nervous system resulting in behavioral problems, memory loss and disturbance of the
circadian rhythm (toluene is also suspected to cause cancer.
Some other VOCs, ex. carbon tetrachloride and PCBs, are believed to produce abnormal
changes in fetus development and consequently lead to birth defects. Carbon tetrachloride
also leads to liver damage.
Vinyl chloride causes Raynaud's phenomenon (spasms in the small arteries that cause the
extremities to become pale and cold, as well as painful), necrosis of the small bones of the
hand, liver damage and a rare, highly malignant tumor of the liver.
and fainting long-term exposure to high levels can increase the risk of cardiovascular diseases
and cancer
Let us summarize some effects of VOCs on human health: