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NT611 Term Project Presentation
NT611 Term Project Presentation
Presented By:
Rishabh Tripathi
Roll No. 15115262
Phd, NET
IIT Kanpur
INTRODUCTION
Natural Uranium is 99.3% U238 with U235 the only fissile nucleas being 0.7%
To improve concentration of U235 to appreciable amounts necessary to be used as efficient fuel in nuclear power
plants enrichment is necessary
Grades of Uranium
a.) Slightly Enriched Uranium (SEU) U235 conc. is between 0.9% to 2% - fuel for PHWR
b.) Low Enriched Uranium (LEU) U235 conc. < 20% , mostly in the range of 3-5% - fuel for LWR
c.) Highly Enriched Uranium (HEU) U235 conc. > 20% - Weapons grade or used in fast neutron reactors /
submarines
ENRICHMENT TECHNIQUES
Separation / Enrichment Techniques and Processes
Old Processes
New Processes
GASEOUS DIFFUSION
rate of diffusion
1
Mol.Wt.
MU
(rate of diffusion)1
M2
=
(rate of diffusion)2
M1
MU
238
235
It uses a cascade of separation chambers (STAGES) with semi-permeable membrane as diffusion barrier
to cause partial enrichment of natural isotopic mixture as feed by differential separation by diffusion also
termed as 'effusion'. Degree of separation depends on relative Molecular weights of components.
DESCRIPTION
rateU
235
rateU
238
i=
MU
238
MU
235
352
=1.005
349
x p (1 x t )
=overall
x t (1 x p )
x ip (1x ti )
x ti (1x tp)
= for Stage i
Here xp & xt are the product and waste tail mass fractions respectively .
NU
v (1x i )
, v=
x i (1v)
N U + NU
x i= feed concentration at stage i
N i =molar flow rate of isotope
=
235
235
238
DESIGN LAYOUT
Product Stream (U235)
Depleted Phase fr
om above stagecv
STAGE 2
DIFFUSER STAGE
P,xp
p2
BARRIER (Membrane)
FEED (U235 = 0.72)
F,xf,xi
p1
STAGE 1
T,xt
STAGE 2'
Enriched Phase fr
om Below stagecv
CASCADE OF 3 STAGES
MATERIAL BALANCE
Overall
Overall
Component Balance
F =P+T
Component Balance
Fx f = Px p+Tx t
Feed to Product Ratio
t i+1+ pi 1 = p i+t i
F x p x t
=
P x f xt
T x p x f
=
P x f x t
i1
i
i
t i+1x i+1
t + pi1x p = pix p +t ix t
t i+1 xip1 x it
=
p i1 xit +1 x it
when i =0 ,t 0= f 0 =F
CASCADE LAYOUT
ENRICHED PRODUCT STREAM (P, xp)
Stage n
Np = sum(1:n)
ENRICHING SECTION
Stage 2
Stage 1
FEED (F , xf)
Stage 1
Stage 2
STRIPPING SECTION
Nw = sum(1:m)
Stage m
GAS CENTRIFUGE
> A gas centrifuge is a device that performs isotope separation of gases. A centrifuge relies on the principles of
centrifugal force accelerating molecules so that particles of different masses are physically separated in a gradient
along the radius of a rotating container. A prominent use of gas centrifuges is for the separation of uranium-235
from uranium-238.
> The gas centrifuge process uses a large number of rotating cylinders in series and parallel formations. Based on
the principle of Buoyant density centrifugation . It uses the concept of buoyancy to separate molecules in gas or
solution. Also known as density gradient centrifugation.
> In addition, if one creates a thermal gradient in a perpendicular direction by keeping the top of the rotating
column cool and the bottom hot, the resulting convection current carries the lighter molecules to the top while the
heavier ones settle at the bottom, from which they can be continuously withdrawn.
> The Zippe-type centrifuge is a gas centrifuge designed to enrich the rare fissile uranium isotope Uranium-235
out of the mixture of isotopes found in naturally-occurring uranium compounds. The isotopic separation is based
on the slight difference in mass of the isotopes.
DESCRIPTION
Separation factor () for gas centrifuge is given as
x (1x t )
= p
=e
x t (1 x p )
(M U M U ) (Rc r )
2RT
238
235
M U M U =3 g / g mole
238
235
Hence separation factor for Gas centrifugation process for U Isotopes is bigger than that for gaseous diffusion
process
The Total length of Gas centrifuge to carry out fuel enrichment is given as
Rc
)
r
H =
V ( x)
Do ( 1)2
2ln(
DESIGN LAYOUT
U-238 Movement
U-235 Movement
A GAS CENTRIFUGE
U-238 Movement
U-235 Movement
HEAT ADDITION
ZIPPE CENTRIFUGE
Advantages
-Lesser Power Consumption as compared to gaseous diffusion process. Only 2-2.5% of Total power consumption
of gaseous diffusion plant
-Continuous process, higher yields, less separative work units
-Higher separation efficiency
-Lower scale of operation
-Height of column independent of absolute radius of centrifuge bowl
Drawbacks
- Despite large separation factor the no. of units required is large for a given peripheral velocity
- Longer centrifugation columns are needed for low rotational speeds for a given degree of separation
COST ANALYSIS
a.) SEPARATIVE WORK UNITS (SWU)
Proportional to the total input (energy / machine operation time) and to the mass processed..
The same amount of separative work will require different amounts of energy depending on the efficiency of the separation
technology. A function of the concentrations of the feedstock, the enriched output, and the depleted tailings (xf, xp and xt).
OLD TECHNOLOGIES
A.) Mass Diffusion Separation of isotopes is effected through diffusion of the light isotope (U235) of the feed
gas mixture into a condensable vapor (steam or some separating agent vapor) at higher rate than diffusion of
the heavy isotope (U238). Separation efficiency lower than gaseous diffusion process.
B.) Thermal Diffusion - This process utilizes the transfer of heat across a thin liquid or gas to accomplish isotopic
separation. Lighter U235 Molecules diffuse towards a hot surface , Heavier U238 Molecules diffuse towards
a cold surface.
C.) Electromagnetic Isotope Separation Metallic U235 is vaporized , and then ionized to positively charged ions.
Cations are accelerated and are separated under the effect of electromagnetic field. Device known as Calutron
and used for Fuel Enrichment. High Energy cost.
Drawbacks
- Low Separation Efficiency, High Input Energy Cost, Low Productivity
- High Volume of Radioactive Waste
NEW TECHNOLOGIES
NEW SEPARATION / ENRICHMENT TECHNIQUES
A.) Laser Isotope Separation (SILEX Separation of Isotopes by Laser Excitation ; AVLIS Atomic Vapor Laser
Isotope Separation ; MLIS Molecular Laser Isotope Separation)
- U235 atoms in UF6 gas is preferentially excited by lasers and selectively ionized and isotopes separated
under the effect of magnetic field
B.) Aerodynamic Nozzle Process - Uses H2 or He gas as diluent or Carrier gas for UF6 gas stream. Passed through
nozzle at supersonic speed with enhanced centrifugal forces acting on high velocity gas stream . The light
fraction obtained thus gets enriched in U235 isotope while the heavier fraction gets depleted.
Advantages
- Low Energy Inputs , Lower Capital Costs and Lower Tails Assays
- Higher Separation Factor as compared to previous technologies, High Energy Efficiency and Low Volume of
Radioactive Waste.
CONCLUSION
ENRICHMENT
TECHNIQUE
GASEOUS
DIFFUSION
55 - 65
33 - 40
2-3
GAS
CENTRIFUGE
10 - 12
40 - 50
90 - 93
LASER ISOTOPE
SEPARATION
2-3
6-7
OTHERS
25 - 30
5-6
REFERENCES
a.) OECD Nuclear Energy Agency (2010). Nuclear Energy Today. OECD Publishing.
b.) Raymond L. Murray "Introduction to Nuclear Engineering" Chap. 3 Pg 70 85. 2 nd Edition Prentice Hall India
c.) Manson Benedict and Thomas Pigford "Nuclear Chemical Engineering Chap. 12-14 Pg 626 914. 2 nd Edition
McGraw- Hill Publications
d.) Glassstone Samuel Elements of Nuclear Reactor Theory Chap. 2-4 Pg 16-60. Ninth Edition Prentice Hall
Publications
THANK YOU
Q&A