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Thermal Physics: Thermodynamic (Kelvin) Scale of Temperature: Theoretical Scale That
Thermal Physics: Thermodynamic (Kelvin) Scale of Temperature: Theoretical Scale That
Internal Energy: is the sum of the kinetic energy of the molecules due to its random
motion & the potential energy of the molecules due to the intermolecular forces.
Internal energy is determined by the values of the current state and is independent
of how the state is arrived at. Thus if a system undergoes a series of changes from
one state A to another state B, its change in internal energy is the same, regardless
of which path {the changes in the p & V} it has taken to get from A to B.
Since Kinetic Energy proportional to temp, and internal energy of the system = sum
of its Kinetic Energy and Potential Energy, a rise in temperature will cause a rise in
Kinetic Energy and thus an increase in internal energy.
If two bodies are in thermal equilibrium, there is no net flow of heat energy between
them and they have thesame temperature. {NB: this does not imply they must have
the same internal energy as internal energy depends also on the number of
molecules in the 2 bodies, which is unknown here}
Thermodynamic (Kelvin) scale of temperature: theoretical scale that
is independent of the properties of any particular substance.
An absolute scale of temp is a temp scale which does not depend on the property of
any particular substance (ie the thermodynamic scale)
Absolute zero: Temperature at which all substances have a minimum internal
energy {NOT: zero internal energy.}
T/K = T/C + 273.15, by definition of the Celsius scale.
Specific heat capacity is defined as the amount of heat energy needed to
produce unit temperature change{NOT: by 1 K} for unit mass {NOT: 1 kg} of a
substance, without causing a change in state.
c = Q / mT
Specific latent heat of vaporisation is defined as the amount of heat energy needed
to change unit mass of a substance from liquid phase to gaseous phase without a
change of temperature.
Specific latent heat of fusion is defined as the amount of heat energy needed to
change unit mass of a substance from solid phase to liquid phase without a change
of temperature
L = Q / m {for both cases of vaporisation & melting}
The specific latent heat of vaporisation is greater than the specific latent heat of
fusion for a given substance because
Boiling
Occurrence
Increase
slightly
Evaporation
On the surface,
at all temperatures
Increase
significantly
Decrease for remaining
liquid
U = W + Q