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Past Paper Chemistry 1st Year BISE Lahore 2013 Group 1
Past Paper Chemistry 1st Year BISE Lahore 2013 Group 1
Past Paper Chemistry 1st Year BISE Lahore 2013 Group 1
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Time : 20 Minutes
Marks : 17
GROUP-I
Note: You have four choices for each objective type question as A, B, C and D. The choice which
you think is correct, fill that circle in front of that question number with marker or pen on the Anwer
Book provided. Cutting or filling two or more circles will result in zero mark in that question.
Attempt as many questions as given in objective type question paper and leave others
Q1.
1. Which statement is not true?
(A) isotopes with even atomic massess are comparatively abundant
(B) isotopes with odd atomic massess are comparatively abundant
(C) isotopes even atomic massess and even atomic numbers are comparatively abundant
(D) isotopes with even atomic massess and odd atomic numbers are comparatively abundant
2. 27 g of Al will react completely with how much mass of O2 to produce Al2O3?
(A) 8g of oxygen
(B) 16g of oxygen
(C) 32g of oxygen
(D) 24g of oxygen
3. Solvent extraction method is particularly useful technique for separation when the product to be
separated is
(A) non-volatile or thermally unstable
(B) volatile or thermally stable
(C) non-volatile or thermally stable
(D) volatile or thermally unstable
4. Number of molecules in one dm3 of water is elose to
(A)
(B)
(C)
.
.
.
10
10
10
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2.
16
1) Low of conservation of mass has to be obeyed during stoichiometric calculation, give reason.
2) One mg of K2CrO4 has thrice the number of ions than the number of formula units when ionized
in water, justify.
3) How many molecules of water are there is l0g of ice?
4) Differentiate between adsorption chromatography and partition chromatography.
5) Give the importance of sublimation.
6) Explain Boyle's law with the help of ICMT.
7) SO2 is comparatively non ideal at 273 K but behave ideally at 327 0C.
8) Give two applications of plasma.
9) Ice occupies more space then water, give reason.
10)Water and ethanol can mix is all proportions, give reason.
11)ionic solids do not conduct electricity in solid state, give reason.
12)Diamond is insulator and hard, give reason.
3.
1)
2)
3)
4)
5)
6)
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a.
b.
c.
d.
e.
f.
g.
h.
i.
12
(SECTION-II)
(a) What is boiling point? What is the effect of external pressure on boiling point? Why the
temperature of a liquid remains constant at boiling point although heat is continuously
supplied?
4
3
(b) An ideal gas is enclosed in a container having volume 500 cm at S.T.P. Its mass comes
out to be 0.72g. What is the molar mass of this gas?
4
6.
(a) Explain the molecular orbital structures of following molecules on the basis of the MOT:
(i) N2 (Nitrogen)
(ii) 02 (oxygen)
4
(b) State first law of thermodynamics. Prove that AE = qv
4
7.
(a) State Dalton's law of partial pressure, also give its three applications.
(b) Describe Millikan's Oil Drop Method for the measurement of charge on electron.
8.
(a) Describe the construction and the working of standard hydrogen electrode.
4
(b) what is the percentage ionization of acetic acid in a solution in which 0.1 moles, of it has
been dissolved per dm3 of the solution?
(a) Give three statements of Raoult's law and also mention how Raoult's law helps in
determining the ideality of a solution.
4
(b) What is arrhenius equation? How it can be used to calculate activation energy of a
reaction?
4
9.
4
4
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(SECTION-III)
(Practical Part)
Note:(i) Attempt any THREE questions.
1) Write down standard sloution, chemical equation with mole ratio, indicator with end point,
procedure and supposed readings with calculations for Part A, B and C.
1,1,1,1,1
2) Write down material required, diagram and procedure for Part D and E.
1,1,3
3
3) The given solution contains 5.6 g of alkali metal hydroxide 'MOH' dissolved per dm .
5
Find out the atomic mass of metal 'M' Volumetrically.
4) Determine the % composition of 8 g mixture of KMnO4 and K2SO4 per dm3 by volumetric
method. (Molecular Mass of KMnO4 = 158)
5
3
5) 24.8 g of Na2S2O3. XH2O have been dissolved per dm . Find out the value of 'X' by volumetric
method. (Molecular Mass of Na2S203 = 158
5
6) Using mixture that them by using paper chromatographic method?
5
7) How you could prepare the crystals of benzoic acid form water by using crystallization method?
5