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MRSM Chemistry Trial Paper 2 Marking Scheme
MRSM Chemistry Trial Paper 2 Marking Scheme
MRSM Chemistry Trial Paper 2 Marking Scheme
( )
tube without shaking it. A brown ring is formed inferred that nitrate ion is present
in the solution Z.
5. (a) the volume of carbon dioxide gas released per unit volume of time.
MV ( 0.1 ) (25)
(b) (i) n=
=
=0.0025 mol
1000
1000
(ii)
According to chemical equation, 2 mol of HNO3 will produce 1 mol of CO2.
Hence, 0.0025 mol of HNO3 will produce 0.00125 mol of CO2.
Vg
, V g =n m . v=0.00125 24=0.03 d m 3
m.v
(iii)
Volume of Carbon dioxide gas released (cm3)
n=
Time(s)
Formula that show simplest ratio of number of C atom and number of H atom in
benzene is 1:1
Molecular formula = C6H6
Formula that show actual number of C atom and number of H atom in benzene is
6:6
(ii) Methane, CH4. Empirical formula = CH4 molecular formula = CH4.
(b) (i)
Elements
Mass of 100g
Number of mole, n
Mole ratio
C
80g
80
=6.67
12
6.67
=1
6.67
H
20g
20
=20
1
20
=3
6.67
CH3
Empirical formula
molecular formula=( empirical formula )n
molecular formula=( CH 3 )n
30= [ 12+3( 1) ] n
30
=n
15
2=n
molecular formula=( CH 3 )2=C 2 H 6
(ii)
2C 2 H 6+7 O2 4 C O2 +6 H 2 O
J: alkene, CnH2n, n = 2, 3, 4, .,
4C
48
100 = 100 =82.7
C 4 H 10
58
4C
48
100 = 100 =85.7
Percentage of carbon by mass of butene =
C4 H8
56
Butene burns with more sootiness/produce more soot than butane because
butene has higher
percentage of carbon by mass than butane.
The presence of tin atom which has different size with copper atom
disrupt the orderly arrangement of atoms in copper. This reduce the ability of
layers of atom from sliding when force is applied. Hence, bronze is harder than
copper.
(b) (i) 2SO2 + O2 2SO3.
Sulphur dioxide gas is converted into sulphur trioxide gas by reacting sulphur
dioxide gas and oxygen gas under 4500C and presence of vanadium (V) oxide
Catalysts and pressure of 1 atmospheric pressure.
H2S2O7.
absorbed by concentrated sulphuric acid to form oleum
2H2SO4.
with water to form sulphuric acid.
mass
48 g
=
=1.5 mol
molar mass 32
Chemical equation: 1 mol of S will produce 1 mol of SO2. Hence, 1.5 mol of S
produce 1.5 mol of SO2.
Volume of Gas
3
n=
,Volume of Gas=1.5 24=36 d m
molar volume
(iii) S + O2 SO3
n=
Weak Acid
Ethanoic acid
Methanoic acid
Carbonic acid
2. a) the time taken to collect 10 cm3 of gas in Experiment I is longer because the large
marble chips has smaller total surface area that slow down the rate of reaction.
the time taken to collect 10 cm3 of gas in Experiment II is shorter because the
marble chips powder
has larger total surface area that increase the rate of reaction.
b) i) Manipulated Variable: Total surface area of marble chips
ii) Responding variable: Rate of Reaction/ Time taken to collect 10 cm3 of gas
iii) Constant variable: Concentration of hydrochloric acid/ Mass of marble chips/
Temperature of
hydrochloric acid
c) The smaller the particle size of a fixed mass of marble chips, the larger the total
exposed surface area, hence the higher the rate of reaction.
d) When marble chips is added into the hydrochloric acid, the shorter the time taken
to collect 10 cm3 of gas, the higher is the rate of reaction.
e) The higher the temperature of surrounding, the higher the rate of drying of clothes.
3)
Aim:
to differentiate/verify the identity of hexane and hexene using
bromine water
Problem statement:
How can hexane and hexene be differentiated/verified by using bromine
water or acidified potassium manganite (VII) solution?
Hypothesis:
Bromine water can be used to differentiate hexane and hexene which
hexene will decolourise brown bromine water but hexane will no change the
brown bromine water.
Or
Acidified potassium manganite (VII) solution can be used to differentiate
hexane and hexene which hexene will decolourise purple acidified potassium
manganite (VII) solution but hexane will not.
Manipulate Variable: hexane and hexene (type of hydrocarbon)
Responding Variable: The change in colour of brown bromine water/ the
change in colour of purple acidified potassium manganate
(VII) solution
Constant Variable: Volume of hexane and hexene, the addition of bromine
water or acidified potassium manganite (VII) solution
Materials: bromine water or acidified potassium manganite (VII) solution,
hexane, hexene
Apparatus: dropper, test tube,
Procedure:
1. 5 cm3 of hexane liquid is poured into a test tube.
2. A few drops of bromine water/ acidified potassium manganate (VII)
solution is added and well shaken.
3. Any change on colour of bromine water/ acidified potassium manganate
(VII) solution is observed and recorded in table.
4. Step 1-3 is repeated by replacing hexane with hexene liquid.
Tabulation of data:
Type of hydrocarbon
hexane
hexene
Observation