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Enthalpy Changes HW
Enthalpy Changes HW
ASSESSED HOMEWORK
Answer all questions
Max 64 marks
Name
..
Mark
../64
Paddington Academy
....%
Grade
1.
e n t h a lp y
r e a c tio n p a th w a y
[Total 3 marks]
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2.
(ii)
(iii)
Complete the enthalpy profile diagram for the combustion of butane. Label the
activation energy, Ea, and the enthalpy change, H.
e n th a lp y
C 4H
10
( g ) + 6 12 O 2 ( g )
p r o g r e s s o f r e a c t io n
[3]
[Total 6 marks]
3.
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4.
Write an equation, including state symbols, representing the standard enthalpy change
of formation of PbO.
..................................................................................................................................
[Total 2 marks]
5.
Alkanes are important hydrocarbons since they are used as fuels in homes and in
industry. It is important that the enthalpy changes involved in alkane reactions are
known.
(i)
(ii)
Write the equation, including state symbols, that accompanies the enthalpy
change of formation of hexane, C6H14(l).
[2]
(iii)
What conditions of temperature and pressure are used when measuring the
standard enthalpy change of formation?
temperature ...............................................................
pressure .........................................................
[1]
[Total 5 marks]
6.
Propane, C3H8, is a gas at room temperature and pressure. It is used in blow torches
to melt the bitumen needed to apply the felt to flat roofs.
Write the equation for the complete combustion of propane.
[Total 2 marks]
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7.
This question is about the relationship between bond enthalpies and enthalpy changes of
combustion.
Define the term bond enthalpy.
..................................................................................................................................
..................................................................................................................................
..................................................................................................................................
[Total 2 marks]
8.
There are several oxides of lead. This question is about the enthalpy changes that
occur during the reactions of some of these oxides.
(i)
(ii)
What are the standard conditions of temperature and pressure used in enthalpy
calculations?
.........................................................................................................................
[1]
[Total 3 marks]
9.
In the vapour state, hydrogen and iodine undergo the following reaction.
H2(g) I2(g)
2HI(g)
reaction 2.1
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10.
Enthalpy changes of reaction can be determined indirectly from average bond enthalpies
and standard enthalpy changes.
The table below shows the values of some average bond enthalpies.
(i)
bond
average bond
1
enthalpy /kJ mol
CH
+410
OH
+465
O=O
+500
C=O
+805
CO
+336
(ii)
The equation below shows the combustion of methanol, CH3OH, in the gaseous
state.
CH3OH(g) + 1O2(g) CO2(g) + 2H2O(g)
Using the average bond enthalpies in the table above, calculate the enthalpy
change of combustion, Hc, of gaseous methanol.
Hc = ............................................. kJ mol
[3]
[Total 4 marks]
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11.
Use the average bond enthalpies given in the table below to calculate a value for
the enthalpy change of combustion of methane, HC.
bond
CH
410
OH
465
O=O
500
C=O
805
HC = ...................................... kJ mol
[3]
(ii)
.........................................................................................................................
.........................................................................................................................
[1]
[Total 4 marks]
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12.
The equations for the combination of gaseous atoms of carbon and hydrogen to form
methane, CH4, and ethane, C2H6, are shown below.
1
H = 1652 kJ mol
H = 2825 kJ mol
[1]
(ii)
[2]
[Total 3 marks]
13. The Table below gives values for the standard enthalpy changes of combustion for the
first three alkanes.
(i)
alkane
formula
methane
CH4
890
ethane
C2H6
1560
propane
C3 H8
2220
-1
Hc /kJ mol
(ii)
As the chain length in the alkanes increases, the value of Hc becomes more
negative. Use your understanding of bond breaking and bond making to explain
this trend.
.........................................................................................................................
.........................................................................................................................
.........................................................................................................................
.........................................................................................................................
[2]
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(iii)
-1
Hc = ......................... kJmol
-1
[3]
[Total 7 marks]
14. Metal priming paints often contain red lead, Pb3O4. Red lead can be made by heating
PbO in the presence of air.
1
3PbO(s) 2 O2 (g) Pb3O4(s)
(i)
Use the H f values in Table below to calculate the standard enthalpy change for
the above reaction.
compound
H f /kJ mol1
PbO(s)
217
Pb3O4(s)
718
= ............................................... kJ mol
[3]
(ii)
= 10 kJ mol
H
Use the value of
for this reaction, together with the values of H f in the
table above, to calculate a value for the enthalpy change of formation of PbO2(s).
H f = .................................... kJ mol1
[3]
[Total 6 marks]
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15.
Enthalpy changes can be calculated using enthalpy changes of combustion. The table
below shows some values for standard enthalpy changes of combustion.
substance
Hc / kJ mol
C(s)
394
H2(g)
286
CH4(g)
890
Use these values to calculate the standard enthalpy change of the reaction below.
C(s) 2H2(g) CH4(g)
standard enthalpy change = ........................................... kJ mol
[Total 3 marks]
16.
(a)
Methane reacts with steam to produce carbon monoxide and hydrogen. The
equation for this process is given below.
CH4(g) + H2O(g) CO(g) + 3H2(g)
The table below shows the standard enthalpy changes of formation for CH4, H2O
and CO.
compound
(i)
Hf /kJ mol
CH4
75
H2O
242
CO
110
(ii)
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(iii)
Write the equation, including state symbols, that represents the standard enthalpy
change of formation for carbon monoxide, CO.
................................................................................................................
[2]
(iv)
Using the Hf values in the table above, calculate the enthalpy change for
the reaction of methane with steam.
CH4(g) + H2O(g) CO(g) + 3H2(g)
H = .............................................. kJ mol
[3]
(b)
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