Professional Documents
Culture Documents
Restricted MaterialsREV - 2006
Restricted MaterialsREV - 2006
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
Danielle Boils
474052
Rev. Level:
Date:
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1 of 28
T3
02/06/2006
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19
20
21
22
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I- MISSION
To help ensure sustainable worldwide environmental stewardship, as well as employee and customer safety, this
specification list identified materials whose use is either prohibited or restricted because of national or international
regulations, health or environmental concerns. They require special consideration and continuing awareness in the
manufacture, use and disposal of Whirlpool products.
SCOPE
The Whirlpool Restricted Materials List includes those materials that experience has shown are of special
significance. The RML clarifies requirements regarding materials (chemical compounds and substances0 FOR
Whirlpool products. Further, more stringent requirements for the product or constituent materials can be specified in
the individual technical description (e.g., products which when used will come into contact with foodstuffs). This RML
reflects those materials that have been of concern in the past and those that are most obvious as potential concerns
in the future. It also reflects the fact that close attention to the choice of materials can have far reaching significance
in terms of product safety, reliability, consumer product acceptance, end-of-life disposal costs and the environment.
Whirlpool and its suppliers of parts, components, and materials must all comply with the requirements of
this Specification.
NOTES AND DEFINITIONS:
PRC: process; the material may be used in Whirlpool manufacturing processes.
PRT: product (part, component, material, or appliance)
CAS REGISTRY NUMBER- Materials are referenced by their universally recognized chemical abstract service
number (CAS number), in most cases, and acronyms will only be used after the full name of the substance has been
listed. This number is not to be confused with the Whirlpool designated category rating described below. Rather than
include each and every member of a class of compounds, the term multiple will be used to avoid listing the entire
class: for example, the CAS number will be listed for cadmium, but multiple will be used instead of listing all
cadmium salts or compounds of cadmium. Blank spaces in the list suggest the material is not suspected as a
concern or the material rating will be addressed at a later date.
CATEGORIES OF RESTRICTED MATERIALS
1.
Materials Prohibited.
2.
Materials that are being used for a limited time for a specific use with a specific phaseout schedule.
3.
Materials which must be used, or result from use, because there is no acceptable alternative. Extra
precautions must be taken or extra awareness must be used to prevent negative impact. This could
include material confinement or concentration limits. This also includes materials that are being used
for evaluation only.
4.
Materials that are not presently regulated but are a possible target for future regulation or concern.
The use of these materials should be monitored closely with strict adherence to review schedules.
CHANGES IN ENGINEERING MATERIALS - It is strongly recommended and encouraged that any change in
material (being contemplated in product design or manufacture) should result in the use of only materials with the
same or lower risk. For example, if a category 3 material being used is going to be replaced with another material on
this RML, the replacement material should be in category 3 or 4, not in category 2. In addition, changes in materials
should not make any requirement of landfill disposal more restrictive.
RESTRICTED MATERIAL - A material that could reasonably be expected to be an important consideration in the
manufacture, use or disposal of a Whirlpool appliance. Such a material could appear on this list because of legal
restrictions or as a result of Whirlpool policy.
REVIEW SCHEDULE Whirlpool will update this RML Specification from time to time, possibly on a quarterly basis.
Suppliers must check the website to ensure compliance with the most recent RML Specification.
GES00084
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3 of 28
CATEGORIES - Identified materials are divided into categories respective to the Whirlpool regions: USA &
CANADA, LAR, WE, MEX, and ASIA. It is to be noted that the Global category is for materials that are used in
Whirlpool products that are marketed globally. The regional ranking of a material in a specific region can be
different from that in other regions or globally due to regional exemptions. For example, a material ranked 3 in USA
& CANADA can be ranked 1 in GLOBAL because, while being produced in the USA, Whirlpools product will be
distributed beyond the USAs borders. Therefore, the strictest regulations in application in the other regions will
apply.
PROCEDURES
A complete materials evaluation must include referral to all documents that apply. FPA submittals must include
a certification document of compliance with this RML Specification.
Purchase of raw materials or semi-manufactured products must comply with the RML. FPA submittals must
include a certification document of compliance with this RML Specification.
The Whirlpool Chemistry, Materials and Analytical Sciences department may be available to help.
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
4 of 28
LAR
PDT
PRC
WHR ASIA
PDT
CAS NUMBER
PRC
1- Chloro-1,1,2,2,3,3,hexafluoropropane
(HCFC 226)
1,1 - Dichloro- 1,2,2,2tetrafluoroethane (CFC
114)
1,1,1,2- Tetrachloro-2fluoroethane (HCFC
121)
1,1,1-Trichloro-2,2,2
trifluoroethane ( CFC
113)
1,1,1-Trifluoro-3chloropropane (HCFC
253)
1,1,2- Trichloro-1,2,2trifluoroethane (CFC
113)
1,1,2,2- Tetrachloro-1fluoroethane (HCFC
121)
1,2 - Dichlor-1,1difluoroethane (HCFC
132b)
1,2 - Difluoro- 1,1,2,2tetrachloroethane (CFC
112)
1,2- Dichlor- 1,2difluoroethane (HCFC
132a)
1,2- Dichloro- 1,1,2,2tetrafluoroethane ( CFC
114)
1,2- Dichloro-1,1,2trifluoroethane (HCFC
123 )
1,2 Dichloroethane
422-55-9
374-07-2
354-11-0
354-58-5
460-35-5
76-13-1
354-14-3
1649-08-7
76-12-0
431-06-1
76-14-2
354-23-4
107-06-2
1,2 Dichloroethylene
75-35-4
3 a,b
3 a,b
3 a,b
3 a,b
354-21-2
106-99-0
1
507-55-1
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
5 of 28
LAR
PDT
PRC
WHR ASIA
PDT
CAS NUMBER
PRC
1,3,3-Trichloro-1,1,2,2,tetrafluoropropane
(HCFC 224)
1,4-Dioxane
1.1 Dichloroethane
76-11-9
306-83-2
615-05-4
95-80-7
2,4,5-trimethylanilline
2-amino-4-nitrotoluene
99-55-9
2-amino-azotoluene
97-56-3
75-88-7
90-04-0
2-naphtylamine(2-aminonaphtalene)
91-59-8
1d
1d
1d
1d
91-59-8
3,3 Dichlor-1,1,1,2,2pentafluoropropane
(HCFC 225ca)
3,3'- dichlorobenzidine
91-94-1
3,3'- dimethoxybenzidine
119-90-4
3,3'- dimethyl-4,4'
diaminodiphenylmethane
838-88-0
422-54-8
123-91-1
1
7-53-43
137-17-7
422-56-0
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
6 of 28
LAR
PDT
PRC
WHR ASIA
PDT
CAS NUMBER
PRC
3,3'- dimethylbenzidine
4- amino azobenzene
4,4' diaminodiphenylmethane
107-77-9
101-14-4
4,4'- oxydianiline
101-80-4
4,4'- thiodianiline
139-65-1
4-aminodiphenyl
92-67-1
4-chloroaniline
106-47-8
95-69-2
3 a,b
3 a,b
3 a,b
3 a,b
107-13-1
Ammonia
7664-41-7
3h
7440-36-0
3hl
1309-64-4
Acrylonitrile
Aromatic amines
Asbestos ( amosite )
Asbestos ( anthophylite )
119-93-7
1
60-09-3
multiple
7440-38-2
1, p
1, p
1332-21-4
1, p
1, p
12172-73-5
1, p
1, p
Asbestos ( chrysotile )
1, p
1, p
12001-29-5
Asbestos ( crocidolite )
1, p
1, p
12001-28-4
Asbestos ( tremolite )
1, p
1, p
14567-73-8
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
WE
MEX
PRC
PDT
PRC
PDT
PRC
7 of 28
LAR
PDT
PRC
WHR ASIA
PDT
Barium, insoluble
compounds
Barium, polyvinyl
chloride stabilizers
Benzene
Benzidine
Beryllium ( in copper)
Beryllium compounds
Bitumens, extracts of
steam or air refined.
Boron, soluble
compounds
Bromodiphenyl ethers
(Deca)
Bromodiphenyl ethers
(Penta, Octa)
1L
1f
2,c,q
2,q
7440-43-9
Cadmium compounds
1c
1c
1c
2,c,q
2,q
multiple
Carbon disulfide
Carbon monoxide
Carbon tetrachloride
Carcinogenic
substances
CFC - 11
(Trichlorofluormethane)
multiple
multiple
71-43-2
92-87-5
7440-41-7
multiple
1, p
PRC
Asbestos (actinolite )
1, p
CAS NUMBER
3j
see
reference
12
Multiple
75-15-0
630-08-0
56-23-5
see
reference
12
75-69-4
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
USA
& CANADA
WE
MEX
PRC
PDT
PRC
PDT
PRC
PDT
PRC
8 of 28
LAR
PDT
WHR ASIA
PRC
PDT
CAS NUMBER
PRC
CFC 12(Dichlorodifluorometha
ne)
CFC 111
354-56-3
CFC 211
135401-875
CFC 212
76564-99-3
CFC 213
60285-54-3
CFC 214
2268-46-4
CFC 215
76-17-5
CFC 216
661-97-21
CFC 217
CFC-113 (1,1,1,2Tetrachloro-2-2difluoroethane)
CFC-114 (1,2-Dichloro1,1,2,2tetrafluoroethane)
CFCs see Annex I
(CHLOROFLUOROCAR
BONS )
Chlorinated paraffins
waxes
1
1
1
1
1
1
1
1
422-86-6
76-11-9
76-14-2
1b
1b
1b, l
1b
2837-89-0
431-78-8
354-25-6
75-68-3
Chloro- 1,1,1,2tetrafluorethane
(HCFC 124)
Chloro- 1,1,1,3,3,3hexafluoropropane
(HCFC 226)
Chloro-1,1,2,2
tetrafluorethane
(HCFC 124)
Chloro-1,1difluoroethane
(HCFC 142b)
Chloroform
Chloropentafluoroethane
(CFC 115)
1
1
1
1
1
1
1
1
75-71-8
63449-39-8
67-66-3
1
76-15-3
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
9 of 28
LAR
PDT
PRC
WHR ASIA
PDT
CAS NUMBER
PRC
Chlorotetrafluorethane
( HCFC 124)
63938-10-3
Chlorotrifluoromethane
(CFC 13)
75-72-9
Chromium (VI)
compounds
3c,g
Copper
Copper soluble
compounds
1b
Cyanides,
Potassium/Sodium
Cyclopentane
3k
3k
3k
Di-2-ethylhexyl phthalate
1b
1b
1b
Dibutyltin-compounds
(DBT) see note n at end
of table
Dichlorodifluoromethane
(CFC 12)
1n
multiple
75-71-8
Dichlorofluoromethane
(HCFC 21)
75-43-4
Dichlorotetrafluorethane
(CFC 114)
1320-37-2
Dioctyltin- compounds
(DOT)
26401-97-8
Dioxins (TBDD-PBDD)
Epichlorohydrin
Ethyl acrylate
Ethylene glycol
3,q
2,q
7447-40-3
2,c,q
2,q
multiple
7440-50-8
3j
1b
multiple
151-508/143-33-9
287-92-3
1b
117817
multiple
3h
3 a,b
3 a,b
Ethylene glycol
monobutyl ether
Ethylene glycol
monoethyl ether
51594-55-9
3 a,b
3 a,b
140-88-5
3
1
107-21-1
111-76-2
110-80-5
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
10 of 28
LAR
PDT
WHR ASIA
PRC
PDT
CAS NUMBER
PRC
Ethylene glycol
monoethyl ether acetate
111-15-9
Ethylene glycol
monomethyl ether
109-86-4
Ethylene glycol
monomethyl ether
acetate
Fibrous glass (Glass
wool) (Respirable fibers)
110-49-6
Flammable materials
Fluorides
Formaldehyde
3k
multiple
multiple
3e
3e
3e
3e
50-00-0
Formic acid
64-18-6
HFC 245-ca
HFC 356-mff
HFC 365-mfc
2317-91-1
1717-00-6
75-45-6
811-97-2
460-73-1
407-59-0
406-58-6
Hydrofluoric acid
7664-39-3
Isobutane
3k
3k
Isophorone diisocyanate
Isopropyl alcohol
1
3b
75-28-5
4098-71-9
67-63-0
2,c,q
2,q
multiple
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
1
1
PRC
WE
MEX
PDT
PRC
3 b,c
PDT
PRC
11 of 28
LAR
PDT
PRC
WHR ASIA
PDT
CAS NUMBER
PRC
2,c,q
2,q
multiple
multiple
Lithium, Soluble
Compounds
7439-97-6
Mercury compounds
multiple
Methyl bromide
Methyl alcohol
67-56-1
78-93-3
108-10-1
Methylene bis-phenyl
isocyanate (MDI)
Methylene chloride
Mineral fibers
multiple
7439-98-7
Monobutylin-compounds
(MBT)
Monochlorodifluormetha
ne ( HCFC 22)
75-45-6
Monochloromonofluorom
ethane (HCFC 31)
593-70-4
Monooctyltincompounds (MOT)
3091-25-6
Mutagenic and
Teratogenic substances
3b
3b
3b
3b
Nickel compounds
1m
1m
3
1
3
1
74-83-9
3
1
101-68-8
1
75-09-2
see
reference
12
7440-02-0
3
multiple
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
PRC
WE
PDT
MEX
PRC
PDT
PRC
12 of 28
LAR
PDT
WHR ASIA
PRC
PDT
3
CAS NUMBER
PRC
N-Nitroso amines
o-toluidine ( 2-aminotoluene)
95-53-4
p-cresidine (2 methoxy5-methylaniline)
120-71-8
Pentachlorophenol salts
and esters
Perchloroethylene
(1,1,2,2Tetrachloroethene)
Perfluoropolymers
octanoic acid salts
Perfluoropolymers such
as Teflon
9002-84-0
Phosphate esters
3d
3d
3d
3d
multiple
multiple
79-947/92-52-4
1
1
Polybrominated
dibenzofurans (PBDF)
Polybrominated
biphenyls (See annex II)
Polybrominated diphenyl
ether, decabromo
isomer. Rohs exception
Polybrominated diphenyl
ether, octabromo isomer.
(See annex II)
Polybrominated diphenyl
ether, pentabromo
isomer technical (See
annex II)
Polychlorinated
biphenyls (PCBs)
Polychlorinated triphenyl
2b
multiple
87-86-5
127-18-4
1163-19-5
32536-52-0
32534-81-9
1L
1L
11126-42-4
9002-86-2
Polyvinylchloride (PVC)
1336-36-3
Selenium
7782-49-2
Selenium compounds
multiple
Silica, crystalline
crystabolite
14464-46-1
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
PRC
USA
& CANADA
PDT
WE
MEX
PRC
PDT
PRC
PDT
PRC
13 of 28
LAR
PDT
WHR ASIA
PRC
PDT
3
CAS NUMBER
PRC
Silica, crystalline
tridymite
15468-32-3
Silica, precipitated (
amorphous )
1313-98-2
Tellurium
4g
3g
13494-80-9
Tellurium compounds
multiple
Tetrabutyltin-compounds
(TeBT)
Tin
7440-31-5
Tin compounds
multiple
108-88-3
Toluene
2
3
2
1
Tributyltin compounds
(TBT)
Trichloroethane
Trichloroethylene
Trichlorofluoromethane
(CFC 11)
Tri-cresyl phospates,
ortho isomer prohibited
Tricyclohexyltincompounds (TcyT)
13121-70-5
Triphenyltin
compounds (TPhT)
76-87-9
Vanadium
3a
3a
Toluene diisocyanate
(TDI)
14808-60-7
584-84-9
multiple
1
79-00-5
79-01-06
75-69-4
1330-78-5
-7440
7440-62-2
3a
3a
75-01-04
1330-20-7
DESCRIPTION
THE SUBJECT MATTER SHOWN HEREON IS DISCLOSED IN CONFIDENCE TO THE EXTENT THAT IT IS
ORIGINAL WITH WHIRLPOOL. DISCLOSURE TO OTHER PARTIES, EXCEPT IN FILLING WHIRLPOOL ORDERS IS
GES00084
PAGE
GLOBAL
PDT
USA
& CANADA
WE
MEX
14 of 28
LAR
WHR ASIA
CAS NUMBER
PDT
PRC
PDT
3b
multiple
7440-66-6
PRC
PDT
PRC
PDT
PRC
Zinc compounds
3b
PDT
PRC
PRC
GES00084
PAGE
15 of 28
GES00084
PAGE
16 of 28
Footnotes
-
a.
b.
Prohibited above permissible exposure levels in water and food or other means of
ingestion.
c.
d.
Results from Cooking product components (Fibrous glass binder, plastics, etc.
Consumers Institutes concentration limits to be fulfilled)
Permitted if concentration in landfill disposed residue does not exceed 500 mg/Kg
Non-food applications
The use of these materials (classified in Directive 93/101) may be possible only by
approval Development Dept. responsibles
Flame retardants
Used in WER for PVC coating stabilizer 1-3%. Whirlpool has Food grade certification for
this
4aminodiphenyl
(pxenylamina)
Dimethyl carbamoyl
Chloride
4,4 methylene dianiline
Beta-naphthylamine
3,3 - dichlorobenzidine
Nitrosamine
4-nitrodifenil
Vinyl cyclohexane dioxide
Propane Sultone
Lead
Epichlorohydrin
Beta propiolactone
Phosphorus
Hexamethylphosphoramid
e
Thallium
Bis(chloromethyl)ether
4,4methylene bis (2
chloroaniline)
GES00084
PAGE
17 of 28
art.1,inc.II: it prohibits, nationwide, the spreading of all types of fibers among which
asbestos/amiante of the chrysotile variety.
art.1, inc.III: it prohibits, nationwide, the sales of bulky powder fibers, among which
asbestos/amiante.
art.7: it states that in all work sites where employees are exposed to asbestos/amianto
of the crisotila variety [...] the tolerance limits established in pertinent laws and
regulations shall be observed, and where there are no such laws and regulations, they
will be established based on the exposure control criteria recommended by national or
international institutions, scientifically acknowledged.
art.10: the transportation of asbestos and of natural and artificial fibers is considered
highly risky.
Conama resolution 05/85 - Pentachlorophenol It regulates use and commercialization
GES00084
PAGE
18 of 28
III-LEGISLATIVE REFERENCES
1. Directive 76/464 of the Council, d.d. May 4, 1976, concerning pollution deriving from the exhaust of harmful
substances into the water environment of the Union, granted by Legislative Decree no. 133/92 whose main
object concerned industrial exhausts of harmful substances into water. This directive, on considering necessary,
by Member Countries, a general and immediate action in order to safe the whole water environment of the
Union, established two groups of harmful substances. First list includes substances, which are treated as
primary importance for their toxicity, persistence and bioaccumulation; second list includes substances whose
negative effects can be restricted only in some places and conditions: nevertheless their discharge must be
minimized.
2. Directive 76/769 and following changes, concerning the approximation of legislative, regulation, administrative
disposition of the Member Countries concerning the restriction to put on the market and to use relevant quantity
of some particular substances and harmful compounds: therefore the substances foreseen by this Directive
have to be forbidden.
3. Directive 78/319 of the Council, d.d. March 20, 1978, concerning toxic and noxious wastes, lists some
substances that are toxic and noxious for the health and for the environment and that if they are present in some
special wastes make the same toxic and noxious. This Directive defines the national laws fix limit concentration
for each substance and for this we have taken into consideration the Italian law that is the Delibera of Comitato
Interministeriale on July 27, 1984.
4. Directive 82/501 of the Council, d.d. June 24, 1982, concerning the risks of considerable accidents related to
some activities.
5. Directive 83/477 of the Council, d.d. September 19, 1983, on worker protection against risks that may occur to
workers during an asbestos exposure.
6. Directive 76/403 of the Council, d.d. April 6, 1976, concerning the polychlorobiphenyls and polychlorotriphenyls
disposal.
7. Regulation no. 3952/92 of the Council, d.d. December 30, 1992, that modifies the Council Regulation no. 594/91
concerning substances that deplete the ozone layer.
8. German Ordinance in Respect of Dangerous Substances, come into force in 1986, fixes concentration levels of
5 polychlorinated dibenzodioxins and of 3 polychlorinated dibenzofurans.
9. German Incident Ordinance, d.d. September 1st. 1991, fixes concentration levels of TBDD, PBDD and PBDF.
10. German Dioxine Ordinance aims at prohibiting compounds which contain dioxins and furans and it applies to 17
chlorinated and 8 brominated dioxins and furans with threshold values around 1 ppb.
11. Directive 93/101 of the Commission, d.d. November 11, 1993, bearing the 20th adjustment to the technical
progress of the Directive 67/548 of the Council concerning the approximation of the legislative, regulation,
accounting dispositions concerning the classification, packaging and labeling of harmful substances, where the
same are classified as toxic (t), very toxic (t+), explosive (E), noxious (N), irritant (Xi), inflammable (F), corrosive
(C).
12. California Proposition 65
13. Canadian Environmental Protection Act
14. Clean Air Act
40 Code of Federal Regulations, Section 61.01
15. Clean Water Act
40 Code of Federal Regulations, Section 116.4
16. Consumer Product Safety Commission
Code of Federal Regulations
Banned Hazardous Substances for Consumer Use
Products Requiring Special Labeling
1500.17
1500.14
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172.01
28. Directive 2002/93/EC of the European Parliament and of the Council (ROHS and WEEE, 2004)
29. OJ No. L144, 4.6.1997, p 19 as amended by Directive 2002/65/EC (OJ No. L271, 9.10.2002, p 16).
30. The application of Directive 2002/95/EC of the European Parliament and of the Council on the Restriction of the
Use of Hazardous Substances in Electrical and Electronic Equipment (OJ No. L37, 13.2.2003 p.19) as amended
by Commission. Decision 2005/618/EC establishing the maximum concentration values for certain hazardous
substances in electrical and electronic equipment (OJ No. L214, 19.8.05, p. 65) was extended to the European
Economic Area from 8th November 2003 by virtue of Decision 147/2003 of the EEA Joint Committee.
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Chromium exists in two common forms Cr(III) & Cr(VI). Cr(VI) is carcinogenic. Chromium compounds have been
used as colorants for plastics. See sections below (Annex II and drinking standards)
Mercury is highly toxic. Long-term exposure to the metal may be fatal. Inhalation may lead to liver, kidney and CNS
damage. Danger of cumulative effects. Harmful by ingestion and by skin contact. See sections below (Annex II and
drinking standards)
Arsenic is very toxic and may be fatal if inhaled, swallowed or absorbed through the skin. This is a known human
carcinogen, which may cause reproductive disorders.
Nickel may cause allergic reactions for people sensitive to it. The DHHS has determined that nickel and certain
nickel compounds may reasonably be anticipated to be carcinogens. However, the EPA MCL of 0.1 ppm was
remanded in 1995.
Copper is harmful if swallowed or inhaled and causes irritation to skin, eyes and respiratory tract. It affects the liver
and kidneys and chronic exposure may cause tissue damage.
Aluminum is not classified by the EPA as a human carcinogen. It is not considered toxic, but contact may cause
irritation with redness and pain. Persons with pre-existing skin disorders or eye problems or impaired respiratory
function may be more susceptible to the effects of the substance. Aluminum hydroxide is widely used as an
inorganic flame retardant in plastics due to low cost and ease of incorporation into manufacturing process.
Iron may cause irritation if inhaled. Ingestion of extremely large oral dosages may produce gastrointestinal
disturbances.
Calcium is a typical nontoxic filler material for plastic, which may include precipitated calcium carbonates and
ultrafine ground calcium carbonate or Dolomite CaMg(CO3)2.
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V-Annex I
HCFC Montreal Protocol and United States Phase-out Schedules
Montreal Protocol
Year to be Implemented
% Reduction in
Consumption, Using the
Cap as a Baseline
2004
35.0%
2010
65.0%
2015
90.0%
2020
99.5%
2030
100.0%
United States
Year to be Implemented
Implementation of HCFC
Phase-out through Clean
Air Act Regulations
2003
No production and no
importing of HCFC-141b
2010
No production and no
importing of HCFC-142b
and HCFC-22, except for
use in equipment
manufactured before
1/1/2010 (so no
production or importing
for NEW equipment that
uses these refrigerants)
2015
No production and no
importing of any HCFCs,
except for use as
refrigerants in equipment
manufactured before
1/1/2020
2020
No production and no
importing of HCFC-142b
and HCFC-22
2030
No production and no
importing of any HCFCs
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Interpretation
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In these Regulations
electrical and electronic equipment means equipment which is dependent on electric currents or
electromagnetic fields in order to work properly and equipment for the generation, transfer and measurement of
such currents and fields falling under categories set out in Annex 1A to Directive 2002/96/EC on waste electrical and
electronic equipment(c) and designed for use with a voltage rating not exceeding 1,000 volts for alternating current
and 1,500 volts for direct current;
enforcement authority shall be construed in accordance with regulation 10; hazardous substance means
lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls or polybrominated diphenyl ethers in
quantities exceeding the maximum concentration value levels set out below
0.1% by weight in homogenous materials for lead;
0.1% by weight in homogenous materials for hexavalent chromium;
0.1% by weight in homogenous materials for mercury;
0.1% by weight in homogenous materials for polybrominated biphenyls:
0.1% by weight in homogenous materials for polybrominated diphenyl ethers; and
0.01% by weight in homogenous materials for cadmium; and
producer means any person who, irrespective of the selling technique used, including by means of distance
communication according to Directive 97/7/EC(a) on the protection of consumers in respect of distance contracts:
(i) manufactures and sells electrical and electronic equipment under his own brand;
(ii) resells under his own brand equipment produced by other suppliers, but for these purposes a reseller
shall not be regarded as the producer if the brand of the producer appears on the equipment, as provided
for in (i); or
(iii) imports or exports electrical and electronic equipment on a professional basis into a member State,
Norway, Iceland or Liechtenstein(b).
Applications of lead, mercury, cadmium and hexavalent chromium, which are exempted from the
requirements of Article 4(1)
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MCLG1
(mg/L)2
0.006
MCL or TT1
(mg/L)2
0.006
07
0.010
as of 01/23/06
7 MFL
7 million
fibers per
liter
2
Beryllium
0.004
0.004
Cadmium *
0.005
0.005
Chromium (total)
0.1
0.1
Copper
1.3
TT8;
Action Level=1.3
0.2
0.2
4.0
4.0
Lead
zero
TT8;
Action
Level=0.015
Mercury
(inorganic)
Nitrate (measured
as Nitrogen)
Nitrite (measured
as Nitrogen)
Selenium
0.002
0.002
10
10
0.05
0.05
Thallium
0.0005
0.002
Organic Chemicals
Contaminant
MCLG1
(mg/L)2
MCL or
TT1
Acrylamide
zero
(mg/L)2
TT9
Benzene
zero
0.005
Benzo(a)pyrene (PAHs)
zero
0.0002
Carbofuran
0.04
0.04
Carbon
tetrachloride
Chlorobenzene
zero
0.005
0.1
0.1
1,2-Dibromo-3chloropropane (DBCP)
o-Dichlorobenzene
zero
0.0002
0.6
0.6
p-Dichlorobenzene
0.075
0.075
1,2-Dichloroethane
zero
0.005
1,1-Dichloroethylene
0.007
0.007
cis-1,2-Dichloroethylene
0.07
0.07
trans-1,2Dichloroethylene
Dichloromethane
0.1
0.1
zero
0.005
1,2-Dichloropropane
zero
0.005
Di(2-ethylhexyl) adipate
0.4
0.4
Di(2-ethylhexyl)
phthalate
Dioxin (2,3,7,8-TCDD)
zero
0.006
zero
0.000000
03
Epichlorohydrin
zero
TT9
Ethylbenzene
0.7
0.7
Hexachlorobenzene
zero
0.001
Hexachlorocyclopentadi
ene
Polychlorinated
biphenyls (PCBs)
Pentachlorophenol
0.05
0.05
zero
0.0005
zero
0.001
Styrene
0.1
0.1
Tetrachloroethylene
zero
0.005
Toluene
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1,2,4-Trichlorobenzene
0.07
0.07
1,1,1-Trichloroethane
0.20
0.2
1,1,2-Trichloroethane
0.003
0.005
Trichloroethylene
zero
0.005
Vinyl chloride
zero
0.002
Xylenes (total)
10
10
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*: In Europe the limit is 100mg/kg of product (ppm), but the limits set in Holland are stricter. When Cadmium is
added as a pigment to a plastic product the amount of cadmium is of the order of several thousands. For cadmium
in products in contact with food, the limits are generally lower. However, to comply with regulation rules both
requirements have to be fulfilled.
National Secondary Drinking Water Regulations (Source EPA)
National Secondary Drinking Water Regulations (NSDWRs or secondary standards) are non-enforceable guidelines
regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration) or aesthetic effects
(such as taste, odor, or color) in drinking water. EPA recommends secondary standards to water systems but does
not require systems to comply. However, states may choose to adopt them as enforceable standards.
Contaminant
Aluminum
Chloride
Copper
Fluoride
Foaming Agents
Iron
Manganese
Nickel
pH
Silver
Sulfate
Total Dissolved Solids
Zinc
Secondary Standard
0.05 to 0.2 mg/L
250 mg/L
1.0 mg/L
2.0 mg/L
0.5 mg/L
0.3 mg/L
0.05 mg/L
0.1 mg/L
6.5-8.5
0.10 mg/L
250 mg/L
500 mg/L
5 mg/L
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VIII-LIST OF CHANGES
July 2005
REVISION T:
January 2006
REVISION T3
:
Headers:
Whirlpool Materials Regulations has been replaced by Whirlpool Materials Specifications
The GES00084 as well as EN474052 number has been added
The acronym "RML" has been added
Pages 1 to 3: text has been edited
Reference to Page 16 in table of materials has been replaced by reference to page 19
Page 16: Legislative references 29 and 30 have been added to take into acount RoHS directives updates
Page 18:notes in Portuguese (relevant to Brazil region only) replaced by English version
Annex II text in 1st paragraph has been edited
The following statement has been added to the headers: : This RML supercedes and replaces any
previously issued RML
Page 22 covering maximum concentration allowed and definition of homogeneous materials for RoHS purposes
has been added