Chemistry Problems With Solution

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LYCEUM OF THE PHILIPPINES UNIVERSITY - CAVITE CAMPUS

COLLEGE OF ENGINEERING, COMPUTER STUDIES AND ARCHITECTURE


DEPARTMENT OF ENGINEERING

CHEMISTRY

SUBMITTED BY:
GERONIMO, CHRISTINE ERICKA E.
BSECE-501

SUBMITTED TO:
ENGR. ARNEL M. AVELINO

DATE:
DECEMBER 05, 2015

CHEMISTRY

1.) Book:

Science HS.com Chemistry III

Question: What volume will the gas occupy at 760mmHg pressure, if 200mL sample of hydrogen is
collected when pressure is 860mmHg?
Solution:

Given: P1

760mmHg

P2

860mmHg

V1

200mL

V2

P2V2

Find:

Soln: P1V1
V2
Answer:

2.) Book:

V2

176.74 mL

Science HS.com Chemistry III

Question: A 0.050 mole of hydrogen gas sample at a certain temperature and pressure occupies 4.0
L. How many moles of argon are there in a 2.0L container at that temperature and
pressure?
Solution:

Given: nH

0.050 mole

VH

4.0 L

VA

2.0 L

nA

Vm

Vm

80.2 L/mole

nVm

Find:

Answer:

0.025 moles

3.) Book:

Science HS.com Chemistry III

Question: Ascorbic acid (Vitamin C) cures scurvy and may help prevent the common cold. Find its
empirical formula if it is composed of 40.92% carbon, 4.58% hydrogen and 54.50%
oxygen.
NC

NH

NO

Answer:

4.) Book:

40.92g C x

3.407mol C 3.406

4.58g H x

4.54mol H 3.406

54.50g O x

3.406mol O 3.406

Empirical Formula

1(3)

4.54mol H
=

3.407mol C

1.33(3)

3.99 or 4

3.406mol O
=

1(3)

C3H4O3

Science HS.com Chemistry III

Question: What is the boiling point of a solution prepared by dissolving 2.50 g of biphenyl (C 12H10)
in 85.0g of benzene? The molecular weight of biphenyl is 154g.
Solution:

The molality solution is the number of moles of biphenyl dissolved in 1000g of benzene.
mol C12H10

1000g benzene

0.191

The molal boiling point elevation constant for benzene solution is 2.53C/m.
Tb

Kbm

(2.53C/m) (0.191m)

0.483C

The normal boiling point of benzene is 80.1C. The boiling point of the solution,
therefore, is:
80.1C + 0.5C
Answer:

80.6C

80.6C

5.) Book:

Science HS.com Chemistry III

Question: How much C6H12O6 is needed to prepare a 0.5m solution using 500g of water?
Solution:

Given:

Formula:

Soln:

mass solvent (H2O)

500g

molality of solution

0.5m

mass solute

mass solvent

molality

0.5 mole

mass solute

(0.50mole) (180g/mole) x

45g C6H12O6 can be dissolved in 500g of water


Answer:

6.) Site:

45 g

http://chemistry.about.com/od/workedchemistryproblems/a/phstrongacid.htm

Question: Hydrobromic Acid (HBr) is a strong acid and will dissociate completely in water to H +
and Br-. For every mole of HBr, there wo;; be 1 mole of H+, so the concentration of H+
will be the same as the concentration of HBr. (H+ = 0.025M).
Solution:

pH is calculated by the formula:


pH

- log (H+)

by entering the concentration found before:


pH

- log (0.025)

pH

- (-1.602)

pH

1.602

The pH pf a 0.025 M solution of Hydrobromic Acid is 1.602.


Answer:

pH

1.602

7.) Site:

http://chemistry.about.com/od/workedchemistryproblems/a/daltons-law-of-partialpressures.htm

Question: The pressure of a nitrogen (N), carbon dioxide (CO2), and oxygen (O2) is 150 kPa. What
is the partial pressure of oxygen if the partial pressures of the nitrogen and carbon dioxide
are 100kPa and 24kPa, respectively?
Solution:

Daltons Law of partial pressure states that:


PTOTAL

P1 + P2 + P3 + ... Pn

Therefore,

Answer:

8.) Site:

PTOTAL

Pnitrogen + Pcarbon dioxide + Poxygen

150kPa

100kPa + 24kPa + Poxygen

Poxygen

150kPa - 100kPa - 24kPa

Poxygen

26 kPa

http://chemistry.about.com/od/workedchemistryproblems/a/idealgasmoles.htm

Question: 6.2 liters of an ideal gas are contained at 3.0 atm and 37C. How many moles of this gas
are present?
Solution:

The ideal gas law states that:


PV

nRT

pressure

volume

number of moles of gas

gas constant (0.08 L atm/mol K)

absolute temperature in Kelvin

where:

Solution:
T

37C + 273 K

0.75 mol

310 K

Therefore, there are 0.75 mol of the ideal gas present in the system.
Answer:

0.75 mol

9.) Site:

http://www.spiritsd.ca/curr_content/chem30_05/4_solutions/practice/a2_2.htm

Question: A 0.750 L aqueous solution contains 90.0 g of ethanol, C 2H5OH. Calculate the molar
concentration of the solution in molL-1. (molar mass of C2H5OH
Solution:

Answer:

10.) Site:

Volume

Molarity

[C2H5OH ]

= 46.1 gmol-1)

0.750 L

90.0 g x

2.6 mol/L

2.60M

http://www.chemteam.info/Solutions/Molarity-probs11-25.html

Question: What volume (in mL) of 12.0 M HCl is needed to contain 3.00 moles of HCl?
Solution:
12.0 M = 3.00 mol / x
x = 0.250 L

This calculates the volume in liters. Multiplying the answer by 1000 provides the
required mL value:

0.250 L x (1000 mL / L) = 250. mL (note use of explicit decimal point to create three sig
figs)

Answer:

Volume

250 mL

11.) Book:

Science HS.com Chemistry III

Question: A process in which the form of certain properties of a substance change, but not its
chemical identity.
Answer:

12.) Book:

PHYSICAL CHANGE

Science HS.com Chemistry III

Question: A solution concentration which is equal to the number of equivalents of solute per liter of
solution.
Answer:

13.) Book:

NORMALITY

Science HS.com Chemistry III

Question: The attractive force existing between atoms or group of atoms that holds them together in
compounds and polyatomic ions.
Answer:

14.) Book:

CHEMICAL BOND

Science HS.com Chemistry III

Question: An oxide or hydroxide of a metal which gives hydroxide ions in solution and neutralizes
an acid to a salt and water.
Answer:

15.) Book:

BASE

Science HS.com Chemistry III

Question: The smallest particle of a pure substance which can exist by itself and carries all the
properties of that substance.
Answer:

ATOM

16.) Site:

http://antoine.frostburg.edu/chem/senese/101/glossary.shtml

Question: This law states that when two pure substances react to form a compound, they do so in a
definite proportion by mass. For example, when water is formed from the reaction
between hydrogen and oxygen, the 'definite proportion' is 1 g of H for every 8 g of O.
Answer:

17.) Site:

LAW OF DEFINITE PROPORTIONS

http://antoine.frostburg.edu/chem/senese/101/glossary.shtml

Question: A branch of chemistry that quantitatively relates amounts of elements and compounds
involved in chemical reactions, based on the law of conservation of mass and the law of
definite proportions.
Answer:

18.) Site:

STOICHIOMETRY

http://antoine.frostburg.edu/chem/senese/101/glossary.shtml

Question: The temperature at which the volume of an ideal gas* becomes zero; a theoretical coldest
temperature that can be approached but never reached.
Answer:

19.) Site:

ABSOLUTE ZERO

http://antoine.frostburg.edu/chem/senese/101/glossary.shtml

Question: The volume of a gas is directly proportional to its temperature in Kelvin, if pressure and
amount of gas remain constant.
Answer:

20.) Site:

CHARLES LAW

http://antoine.frostburg.edu/chem/senese/101/glossary.shtml

Question: A measure of energy dispersal. Any spontaneous change disperses energy and increases
entropy overall. For example, when water evaporates, the internal energy of the water is
dispersed with the water vapor produced, corresponding to an increase in entropy.
Answer:

ENTROPY

BOOK REFERENCE:

Carigo, V., Fernandez, C., & Nudo, L. (2002). Science HS.com Chemistry III. Quezon City: Bookman, Inc.

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