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General Organic Chemistry (GOC)
General Organic Chemistry (GOC)
electrophile is a/an
Lewis base
Lewis acid
electron deficient species
Both A and B
Answer. B
5.
Answer. A
7. In isopentane the number of secondary carbon atom is
A. 1
B. 2
C. 3
D. 0
Answer. A
8. Carbocation (carbonium ion) is
A. a set of carbon atoms
B. an electrophile
C. a free radical
D. a nucleophile
Answer. B
9. Carbonium ions contain only ___electrons around the carbon core.
A. 2
B. 6
C. 5
D. 9
Answer. B
10.Carboxylic acids are isomeric with
A. Amines
B. Esters
C. Aldehydes
D. acid anhydrides
Answer. B
11.Two or more compounds having the same number and kind of atoms and
same molecular weight are called
A. Isobars
B. Isotones
C. Isomers
D. Isochors
Answer. C
12.The process of separating a racemic mixture into optical isomers is known as
A. Dissolution
B. Isomerisation
C. Resolution
D. Pasteurization
Answer. C
13.Sulphur trioxide is
A. a Lewis base
B. a base
C. nucleophile
D. an electrophile
Answer. D
14.In neopentane the number of primary carbon atoms are
A. 4
B. 5
C. 2
D. 1
Answer. A
15.Which of the following type of isomerism is found in the members of the
same homologous series?
A. Functional isomerism
B. Position isomerism
C. Metamerism
D. None of these
Answer. C
16.Hetrolytic fission results in the formation of
A. Electrophile
B. free radicals
C. electrophile and nucleophile
D. electrons
Answer. C
17.In acetylene C-C-H bond angle is
A. 144 degree
B. 180 degree
C. 90 degree
D. 96 degree
Answer. B
18.The forces between the molecules of a non-polar compounds are
A. Van der Walls forces
B. ionic bonding
C. hybrid forces
D. dipole forces
Answer. A
D. carboxylic acids
Answer. C
20.Diethyl amine and methylk propylamines are
A. metamers
B. tautomers
C. dynamic isomers
D. optical isomers
Answer. A
21.The number of possible metamers of pentonone are
A. 5
B. 1
C. 3
D. 6
Answer. C
22.The tetrahedral nature of the carbon was given by
A. Vant Hof
B. Lewis
C. Le Bell and Vant Hof
D. None of the above
Answer. C
23.Decomposition of a compound by the action of heat is known as
A. decomposition
B. knocking
C. smelting
D. pyrolysis
Answer. D
24.The most volatile amongst the following is
A. p-nitrophenol
B. m-nitrophenol
C. o-nitrophenol
D. none of these
Answer. A
Answer. B
26.A nucleophile is a
A. Lewis base
B. Lewis acid
C. neither a Lewis acid nor a Lewis base
D. both A & B
Answer. A
27.Chain isomers difer w.r.t.
A. position of substituent
B. position of functional group
C. chemical efect
D. root word
Answer. D
28.Alcohols are isomeric with
A. ketones
B. ethers
C. amines
D. acids
Answer. B
29.The total no. of possible isomers of ethane are
A. 10
B. 20
C. 4
D. Infinite
Answer. D
30.Which of the following carbonium ions is the most stable?
A. triphenyl methyl
B. diphenyl methyl
C. benzyl
D. All the above
Answer. A
31.Liquids whose molecules are held together by hydrogen bonds are called
A. associated liquids
B. aprotonic solvents
C. primary liquid
D. hydrated liquids
Answer. A
50.Which of the following molecules does not contains any secondary hydrogen
atom?
A. n-Pentane
B. neo-Pentane
C. neo-Hexane
D. iso-Pentane
Answer. B
51.Diastereomers are a pair
A. stereoisomers that cannot be separated from each other
B. stereoisomers that are not minor image of each other
C. stereoisomers that have identical chemical properties
D. stereoisomers that are minor image of each other
Answer. B
52.Which of the following have zero dipole moment?
A. 2 methyl propane
B. trans-2-butene
C. cis-2-butene
D. butane-1
Answer. B
53.All
A.
B.
C.
D.
Answer. C
54.The IUPAC name of allylene is
A. Propyne
B. Propene
C. 2-Butyne
D. 1-Butyne
Answer. C
Answer. D
62.Homolytic Fission is :
A. Symmetrical
B. Unsymmetrical
C. Both
D. None
Answer. A
63.Alcohols are resistant to oxidation :
A. Primary
B. Secondary
C. Tertiary
D. All
Answer. C
64.When alcohol is dehydrated ar 140 C the produxt obtnd is :
A. Ethane
B. Diethyl ether
C. Iodoform
D. None
Answer. B
65._____ are formed in homolytic bond fission :
A. Free radicals
B. Ions
C. Both A & B
D. None
Answer. A
66.The factors which favor homolytic fission are :
A. Electro negativity diference is less or zero
B. Gaseous state
C. Light & Electricity
D. All of the above
Answer. D
A.
B.
C.
D.
Nucleophile to electrophile
Electrophile to nucleophile
Source to sink
Both A & C
Answer. D
69.Which of the following is nucleophile :
A. Cl
B. H2O
C. NH3
D. All
Answer. D
70.In tertiary Alcohols one C having OH group is attached to mainly how many
more C :
A. 1
B. 2
C. 3
D. 4
Answer. C
71.In combustion of methane the amount of energy released is :
A. 891 kJ/mol
B. 892 kJ/mol
C. 893 kJ/mol
D. None
Answer. A
72.Which of the following is electrophile :
A. Cl2
B. ClC. Br2
D. Both A & C
Answer. D
73.Out of the following which reacts with alkanes in presence of ultra violet
rays :
A. Chlorine
B. Bromine
C. Iodine
D. Flourine
E. Both A & B
F. Both C & D
G. All
Answer. E
74.The step in which chlorine free radical reacts with methane and a methyl free
radical is obtained is termed as :
A. Initiation
B. Propagation
C. Termination
D. None
Answer. B
75.Combustion of alkanes is highly ____ so it requires ____ for initiation :
A. Endothermic & nothing
B. Exothermic & nothing
C. Endothermic & flame
D. Exothermic & spark
Answer. D
76.Which of the following reaction is not synthetically important :
A. Free radical reaction of alkanes
B. Halogenation of alkanes
C. Both A & B
D. None
Answer. C
77.During dehydrohalogenation of alkyl halides the hydrogen is removed from
the C which is attached to :
A. R
B. X
C. R or X
D. None
Answer. A
B. 180 C
C. 140-170 C
D. All of the above
Answer. D
80.The catalytic hydrogenation of alkenes is at 1-5 atm pressure and giving
120kJ/mol per double bond and giving ______ compound :
A. Unsaturated
B. Saturated
C. Depends upon given conditions
D. None
Answer. B
81.The catalysts used for catalytic hydrogenation of alkenes are :
A. Pt,Pd,NiAl2O3
B. Pt, Pb, Raney Nickle
C. Pt,Pd,Ni
D. None
Answer. C
82.For hydration of ethene the intermediate compound is :
A. Methyl hydrogen sulphate
B. Ethyl Hydrogen Sulphate
C. Ethyl hydrogen Nitrate
D. None
Answer. B
83.For hydration of alkanes the optimum temperature is :
A. 140 oC
B. 100 oC
C. 80 oC
D. None
Answer. B
84.As
A.
B.
C.
D.
Answer. B
85.1% dilute alkaline KMnO4 solution is a :
A. Strong oxidizing agent
B. Mild oxidizing agent
Answer. C
88.Butene can have:
A. Geometrical isomerism
B. 2-position isomers
C. Both A & B
D. All structural isomers
Answer. C
89.Geometrical isomerism is shown by :
A. Alkanes
B. Alkenes
C. Alkynes
D. Both A & C
Answer. B
Answer. B
92.Oxidation of alkenes in presence of hot KMnO4 solution the products obtained
can be :
A. Ketones
B. Carboxylic acids
C. Carbon dioxide
D. All
Answer. D
93.All
A.
B.
C.
D.
Answer. D
94.Difused or delocalized electron cloud is formed by overlapping of :
A. one 2py & one 2pz orbitals
B. Both 2pz orbitals
C. Any 2 orbitals
D. None
Answer. B
95.The stability of benzene ring is compared with :
A. Cyclohexene
B. 1,3 cyclohexadiene
C. 1,3,6 cyclohexatriene
D. None
Answer. D
96. In
A.
B.
C.
D.
Answer. D
97.During halogenation, nitration, Friedal crafts reactions of benzene the
direction of reaction is :
A. Benzene ring to electrophile
B. Electrophile to benzene ring
C. Benzene ring to nucleophile
D. Nucleophile to benzene ring
Answer. A
98.The acylation of benzene ring produces :
A. Methy benzene
B. Ethyl Benzene
C. Acetophenone
D. Alky Benzene
Answer. C
99.Which of the followoing are electrophile :
A. AlCl3
B. FeBr3
C. H2SO4
D. Both a & b
E. All
Answer. E
100.
102.
There is another site present on alkyl halides on which nucleophile can attack
during B-Elimination reaactions :
A. a-H
B. b-H
C. a-C
D. b-C
Answer.
42-The rate of E1 reactions depend upon :
a)The concentration of substrate
b)Conc. Of nucleophile
c)Conc of substrate as well as nucleophile
d)None
43-Which one of the following is not a nucleophile :
a)H2O
b)H2S
c)BF3
d)NH3
44-The benzene molecule contains :
a)Three double bonds
b)two double bonds
c)One double bond
d)Delocalized pi electron charge
45-During nitration of benzene active nitrating agent is :
a)NO3
b)NO2+
c)NO2d)HNO3
46-Formula of chloroform is :
a)CH3Cl
b)CCl4
c)CH2Cl2
d)CHCl3
47-Optimum temperature for the fermentation is :
a)25-35 oC
b)35-45 oC
c)15-25 oC
d)None
48-The product obtained after re-Distilation of 95% alcohol in presence of CaO
is called :
a)rectified spirit
b)Absolute alcohol
c)Methyleted spirit
d)None
49-For denaturation of alcohol which can be used :
a)Methanol
b)Ethanol
c)Pyridine
d)Acetone
e)All
f)All except ethanol
50-When NH3 reacts with alcohol then the catalyst used is :
a)ZnCl2
b)ThO2
c)Pyridine
d)None
51-Which reaction is correct :
b)Butanone
c)Acetophenone
d)None
60-The IUPAC name of (CH3)2 CH CH2 OH is :
a)2,3methyl 2 propanol
b) 2,4methyl 2 propanone
c) 1,3ethyl 3 propanol
d) 2,3methyl 1 propenol
61-In industry for preparation of formaldehyde the optimal conditions are :
a)Pt-Asbestos
b)300oC
c)Both
d)None
62-Acetaldehyde is prepared in the laboratory by the oxidation of ethyl
alcohol with :
a)Alkaline sodium dichromate solution
b)Acidfied KMnO4 Solution
b)Alkaline KMnO4 Solution
d)None
63-Acidified aqueous hydrolysis of acetaldehyde cyanohydrin gives :
a)2-Hydroxypropanoic acid
b)Lactic acid
c)alpha hydroxyl acid containing one C more than starting aldehyde or ketone
d)All
64-Which one of the following is a good source of Cyanide ion :
a)HCN
b)KCN
c)NH4CN
d)LiCN
65-Tryosine has ____ taste :
a)Sweet
b)Sour
c)Cheese
d)None
66-Which of the following pair of amino acids have sec. amino group :
a)Glycine & Proline
b)Histidine & Glutamic acid
c)Lysine & valine
d)Proline & Histidine
67-The acidic character of amino acid is due to :
a)COOH
b)COOb)NH2
c)NH3+
68-The catalyst used in the reaction of a-bromoacid with ammonia is :
a)K
b)P
c)Li
d)H
69-During strecker synthesis the intermediate compound obtained is :
a)Ammonium ion
b)Ammonium Chloride
c)Ammonium nitrile
d)None
70-There is a peptide molecule which is said to have molecular mass
11,312,it is termed as :
a)Polypeptide
b)Protein
c)Both a & b
d)None
71-Addition polymerization is catalyzed by :
a)Thermal decomposition of organic peroxides
b)Photochemical decomposition of organic peroxides
c)Both
d)None
72-Condensation polymerization involves the removal of :
a)Water
b)Methanol
c)Ethanol
d)All
e)Both a & b
73-Polysterene is used in :
a)Pipes
b)Gramophone records
c)Clothing
d)Cosmetic bottles
74-Plyamide resisns include :
a)Nylon -6,9
b)Nylon -3,6
c)Nylon -9,9
d)Nylon- 6.6
75-Glucose is also termed as :
a)Dextrose
b)Grape Sugar
c)Blood Sugar
d)All
e)Both b & c
76-Amylopectin has glycosidic linkages as :
a)1,2
b)1,4
c)1,2 & 1,4
d)1,4 & 1,6
77-Woody trees are generally ___% celloluse :
a)10%
b)20%
c)30%
d)40%
e)None
78-The saponification number for glycerol triplemitate is :
a)206
b)208
c)210
d)212
79-In DNA the sugar is :
a)1-Deoxyribose
b)2-Deoxribose
c)3-Deoxyribose
d)None
80-The acid chloride strength is of the order of :
a)CH3COOCl > CH3COOCl2 > CH3COOCl3 > CH3COOCl4
b) CH3COOCl < CH3COOCl2 > CH3COOCl3 < CH3COOCl4
c) CH3COOCl < CH3COOCl2 <CH3COOCl3 <CH3COOCl4
d) CH3COOCl <CH3COOCl2 ,CH3COOCl3 > CH3COOCl4
(Acetic acid, HC2H3O2 Ka = 1.8?10?5
Chloroacetic acid, HC2H2ClO2 Ka = 1.4?10?3
Dichloroacetic acid, HC2HCl2O2 Ka = 5.5?10?2
Trichloroacetic acid, HC2Cl3O2 Ka = 3.0?10?1 )
81-The steps for the formation of ester are :
a)3
b)4
c)5
d)None
82-In reaction with SOCl2 which two atoms get polarized due to presence of
Chloride ion :
is oxidized :
a)One
b)Two
c)Three
d)Four
91-During oxidation of unsymmetrial ketones the carbonyl group goes with:
a)Larger alkyl group
b)Smaller alkyl group
c)Separates
d)None
92-Formula for tollen?s reagent is :
a)Ag(NH3)2
b)AgNH3
c)AgNH2OH
d)[Ag(NH3)2]OH
93-In tollen?s test alongwith silver mirror we get :
a)H2O
b)NH3
c)Both
d)None
94-Fehling solution is :
a)An alkaline solution containing cupric tartrate complex ion
b) An acidic solution containing cupric tartrate complex ion
c) An alkaline solution containing cupric citrate complex ion
d)None
95-Formalin is :
a)40% formaldehyde in 50 % water
b) 30% formaldehyde in60 % water
c) 20% formaldehyde in 70 % water
d) 40% formaldehyde in 52 % water
96-Acetone reacts with HCN to form a cyanohydrin,it is an example of :
a)Electrophilic addition
b)Nucleophilic addition
c)Nucleophilic substitution
d)Electrophilic substation
97-Oxalic & Malonic acids are also called as :
a)Propanedioic and Etahnedioic acid
b)Ethanedioic and Propanedioic acid
c)Both
d)None
98-Pthalic acid has how many benzene rings :
a)1
b)2
c)3
d)4
99-Ethanol forms formic acid by forming an intermediate product of :
a)Aldehyde
b)Ethanal
c)Methanal
d)None
100-Tollen?s reagent is a :
a)Strong oxidizing agent
b)Mild oxidizing agent
c)Weak oxidizing agent
d)None
101-Alkanenitriles will give corresponding carboxylic acids on reaction with :
a)Acids
b)Alkalies
c)Both
d)None
102-When carboxylic acids are obtained from oxidation of primary alcohols
then the intermediate producs formed are:
a)Ketones
b)Aldehydes
c)Can be both of the above
d)None
103-When H atom of carboxylic acids is involved in the reactions then one
thing will must be formed :
a)Hydrogen gas
b)H2O
c)Respective Salts
d)All
104-During protonation of carboxylic acid in formation of an ester the
carboxylic acid at as :
a)Electrophile
b)Nucleophile
c)Can act as both
d)None
105-The correct formulae for ester is :
a)CH3COOC2H5
b) CH3COC2H5
c) CH3COOC2H5O
d) CH2COOC2H5
106-The third step of esterification is :
a)Protonation of carboxylic acids
b)Attack of alcohol
c)Elimination of H+
d)Hydrogen ion transfer
107-The formula for acetamide is :
a)CH3COONH2
b) CH3COONH3
c) CH3CONH2
d) CH3COONH
108-Which one of the following is a strong acid :
a)Phenol
b)Ethanoic acid
c)ChloroEthanoic acid
d)Alcohol
109-The Abbreviation for glutamic acid is :
a)Gla
b)Gly
c)Ala
d)None
110-Which of the following is a non-polar amino acid :
a)Glycine
b)Alanine
c)Valine
d)All
111-Carboxylate ion gives the ____ character to amino acid :
a)Acidic
b)Basic
c)Neutral
d)None
112-Which of the following are required for Strecker?s synthesis :
a)HCN
b)Amine
c)Formaldehyde
d)Both a & c
e)All
113-The compound formed due to addition of CN is called :
a)Amide
b)Amine
c)Imine
d)Nitrile
114-The unsaturated amino acids are :
a)Histidine
b)Glycine
c)Lysine
d)None
b)Tertiary
c)Secondary
d)Primary
132-The sequence of amino acids combined in a peptide chain is refered to
as :
a)Primary Structure
b)Secondary structure
c)Tertiary Structure
d)None
133- Main type of secondary structure of proteins are :
a)Alpha Helix
b)Beta Strand
c)Both
d)None
134-Hydrophobic interactions are present in ___ of proteins:
a)Primary structure
b)Secondary structure
c)Tertiary structure
d)None
135-____ also considered as primary building blocks :
a)Fatty Acids
b)Glycerols
c)Sterols
d)Both a & b
e) All
136-The polyunsaturated glycerides would have ___ M.P & B.P :
a)High
b)Medium
c)Low
d)None
137-Sterols,Vitamin D and terpenes are termed as :
a)Compund lipids
b0Associated lipids
c)Derived lipids
d)Both b & c
e)All
138-The rate of deterioration depends upon ___ of fats or oils :
a)Saturation
b)Unsaturation
c)Both
d)None
139-The quantity in miligrams(mg) taken for identification of characteristic of
fat or oil per specific given amount of fat or oil is of :
a)Acid Number & Iodine Number
b)Saponification number and iodine number
a)100
b)100000
c)10000
d)10
149-Which clogs the gills of a fish :
a)Mg
b)Ca
c)Al
d)None
150-The ozone layer is ___ high :
a)15-40 km high
b)25-28 km high
c)30 km high
d)All
Answer Key :
1-a
2-c
3-b
4-a
5-d
6-b
7-d
8-d
9-c
10-a
11-d
12-e
13-b
14-d
15-c
16-a
17-d
18-d
19-b
20-c
21-b
22-b
23-b
24-b
25-b
26-c
27-c
28-b
29-b
30-b
31-d
32-d
33-b
34-d
35-d
36-a
37-c
38-e
39-e
40-b
41-b
42-a
43-c
44-d
45-b
46-d
47-a
48-b
49-f
50-b
51-a
52-d
53-a
54-a
55-d
56-d
57-b
58-b
59-b
60-a
61-d
62-d
63-d
64-b
65-c
66-d
67-b
68b
69c
70b
71c
72e
73d
74-d
75-d
76-d
77-e
78-b
79-b
80-c
81-b
82-b
83-a
84-c
85-b
86-a
87-b
88-b
89-a
90-a
91-b
92-d
93-c
94-a
95-d
96-b
97-b
98-a
99-b
100-b
101-c
102-b
103-c
104-b
105-a
106-d
107-c
108-c
109-b
110-d
111-b
112-d
113-d
114-a
115-b
116-d
117-d
118-a
119-c
120-a
121-c
122-b
123-d
124-b
125-a
126-a
127-a
128-d
129-a
130-b
131-b
132-a
133-c
134-c
135-e
136-c
137-d
138-b
139-c
140-e
141-a
142-b
143-c
144-a
145-a
146-d
147-c
148-b
149-c
150-b