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IEEE Guide For Selection of VRLA Batteries
IEEE Guide For Selection of VRLA Batteries
Stationary Applications
1. Scope
This guide describes methods for selecting the appropriate type of valveregulated, immobilizedelectrolyte,
recombinant leadacid battery for any of a variety of potential stationary float applications. Installation,
maintenance,sizing,andconsiderationofbatterytypesotherthanvalveregulatedleadacidbatteries,arebeyondthe
scopeofthisguide.Designofthedcsystemandsizingofthedcbatterycharger(s)arealsobeyondthescopeofthis
guide.
2. References
Thisguideshallbeusedinconjunctionwiththefollowingpublications:
IEEEStd1001992,TheNewIEEEStandardDictionaryofElectricalandElectronicsTerms(ANSI). 1
IEEEStd4851997,IEEERecommendedPracticeforSizingLargeLeadStorageBatteriesforGeneratingStations
andSubstations(ANSI).
IEEEStd11871996,IEEERecommendedPracticeforInstallationDesignandInstallationofValveRegulated
LeadAcidBatteriesforStationaryApplications.
IEEE Std 11881996, IEEE Recommended Practice for Maintenance, Testing, and Replacement of Valve
RegulatedLeadAcid(VRLA)BatteriesforStationaryApplications.
3. Definitions
Thefollowingdefinitionsapplyspecificallytothisguide.Forotherdefinitions,seeIEEEStd1001992.
5.1
absorbed electrolyte: Electrolyte in a VRLA cell that has been immobilized in absorbent
separators.
5.2
gelledelectrolyte: ElectrolyteinaVRLAcellthathasbeenimmobilizedbytheadditionofa
gellingagent.
5.3
immobilizedelectrolyte: ElectrolyteinaVRLAcellthatisretainedbyusingeithergelledor
absorbedelectrolytetechnology.
5.4
5.5
oxygenrecombinationefficiency: Theamountofoxygenultimatelyconvertedtowateratthe
negativeplatesexpressedasapercentageofthetotalamountofoxygenproducedatthepositiveplates:
1IEEEpublicationsareavailablefromtheInstituteofElectricalandElectronicsEngineers,445HoesLane,P.O.Box1331,Piscataway,NJ
088551331,USA.
O2 eff
5.6
valveregulatedleadacid(VRLA)cell:Acellthatissealedwiththeexceptionofavalvethat
opens to the atmosphere when the internal gas pressure in the cell exceeds atmospheric pressure by a
preselectedamount.VRLAcellsprovideameansforrecombinationofinternallygeneratedoxygenandthe
suppressionofhydrogengasevolutiontolimitwaterconsumption.
5.7
ventedcell:Acellinwhichtheproductsofelectrolysisandevaporationareallowedtoescapeto
theatmosphereastheyaregenerated.Thesecellsarecommonlyreferredtoasflooded.
5.8
VRLAcell:See:valveregulatedleadacid(VRLA)cell.
4. Technology overview
5.1
Water loss
Waterinaventedleadacidcellislostduringoverchargebyaprocessknownaselectrolysis.Inthisprocess,water
isconvertedtooxygenatthepositiveplatesandtohydrogenatthenegativeplates.Theoxygenandhydrogengases
areallowedtoventoutofthecellintotheatmosphere,resultinginthelossofwater.InVRLAcells,theoxygen
recombinationcyclelimitsthewaterloss.
5.2
Oxygen recombination
Inaperfectwatertooxygentowatercycle,alltheoxygenproducedatthepositiveplatesonfloatorover charge
wouldbetransportedtothenegativeplatesandconvertedbacktowater,withnowaterbeinglostfromthecell.This
isthebasisforVRLAcelltechnology(seeannexAformoredetails).
5.3
Theefficiencyoftheoxygenrecombinationcycledependsprimarilyontheabilitytotransporttheoxygengenerated
atthepositiveplatestothenegativeplates.Inventedleadacidcells,thetransportprocessisimpededbythebulk
liquidelectrolyte,andoxygenisliberatedtotheatmosphere.Themigrationofoxygenthroughliquidsulfuricacid
electrolyteisapproximately10000timesslowerthanitisthroughair[B1],[B2],[B3] 2.VRLAtechnologyprovides
voids(gaspassages)betweenpositiveandnegativeplatesthroughwhichoxygentransportisgreatlyenhanced.
5.4
Gelledelectrolytecellsaredesignedsuchthatvoidsdevelopinthegel.Thesevoidsserveaspassagesthroughwhich
oxygentransporttothenegativeplatesisenhanced.
5.5
Absorbedelectrolytecellsaredesignedwithanabsorbentseparatorthatisapproximately95%filledwithliquid
electrolyte.Theremainingvoidsprovideforoptimizedoxygentransportfrompositivetonegativeplates.
5.6
Hydrogen evolution
ItispossibletodesignVRLAcellsinwhich,undernormalfloatconditions,theoxygenrecombinationwilloperate
atvirtually100%efficiency.However,evenundernormalfloatconditions,somewaterwillbelostbyelectrolysis.
Therearereactionsthatoccuratthepositiveplateswhoseonlypossiblecorrespondingreactionatthenegativeplate
istheformationofhydrogengas.Themostfamiliarofthesereactionsiscorrosionoftheleadorleadalloypositive
gridtoleaddioxide,whichresultsinhydrogenevolutionatthenegativeplates.Thesereactionscannotbeprevented.
(SeeannexAformoredetails.)
5.7
The internal cell pressure caused by the evolved gases is regulated by a valve that allows them to escape
periodically.Thisistheoriginoftheterm valveregulated.VRLAvalvesoperateoverarelativelynarrowrange,
typicallywithinthelimitsof0.550psig,dependingupondesign,allowingtheescapeofunrecombinedgasesand
preventingthebackflowofairintothecell.
5.8
Catalysts
2ThenumbersinbracketsprecededbytheletterBcorrespondtothoseofthebibliographyinannexB.
ThefollowingtextwasadaptedfromaJimMcDowallpresentation:
Somebatterymanufacturersusecatalystsintheheadspacemainlytoreducewaterlossandcorrosion. Thisisa
relativelynewtechnology,andtimewillshowhowmuchvalueithas.Catalystsprobablyhelpovercomeproblems
withnegativeselfdischarge(iftheyexist),bringthepositivestoamorefavorablepolarizationlevel,andreduce
gridcorrosioninnormaloperation(whichwillreducewaterlossfromgridcorrosion.Catalystscannotcompletely
eliminatewaterloss(althoughtheymayhelpreduceit),norcantheyeliminatehydrogenevolution(althoughthey
mayreducetheamountofhydrogenlosttotheairundernormaloperationofthecell).Forthosechoosingtopaya
smallpremiumforthepotentialpromisesofthistechnology,theyneedtobeawarethatcatalystswillaffectthestart
andstoppointsandslopeoftemperaturecompensation(contactthebatterymanufacturerforrecommendedvalues).
Theeffect ofcellagingonpolarization,andthepotentialforpoisoningthecellareamongthepotentialissues
surroundingthecatalysttechnologywhichhavenotbeenfullyexplored.
Reactions
Bothtechnologiesundergothesamechemicalandelectrochemicalreactions.Theratesofsomeofthesereactions
aredifferent(see4.3).
5.2
Construction materials
MostofthematerialsusedinventedandVRLAcellsarethesame.Notableexceptionsareabsorbentseparatorsused
inabsorbedelectrolyteVRLAcellsandgellingagentsusedingelledelectrolyteVRLAcells.Also,floodedcelljars
(containers)aretypicallytransparentwhereasjarsforVRLAcellsareusuallyopaque.
5.3
Aging and failure mechanisms (Eddie Davis to provide additional subsections
on additionsal failure and aging modes [only those which are valid on newer models of
VRLA]. Some of these mechanisms that will be expanded include: seal/container/valve
failure, negative dishcarge/depolarization, soft shorts, loss of compression/bulging,
stratification, ripple current, etc. Eddie will also do some rewriting of this section)
Thefamiliarfailuremechanismsofpositiveplatecorrosionandgrowth,activematerialfailure,postsealleakage,
andjar/coversealleakageassociatedwithventedcellsarealsopresentinVRLAcells.However,inVRLAcells,the
effectsofleakageatthepostand/orjarcoversealsaremoresignificantthaninventedcells.First,suchleakagecan
contributetodryout(see5.3.1)andsecond,suchleakscanallowatmosphericoxygentoenterthecell,whichcauses
dischargeofthenegativeplates.
CAUTION
Electrolyteleakagemayleadtogroundpathsandpotentialfire/explosionhazards.
VRLAcellsaresusceptibletotwofailuremodesthatarenormallynotassociatedwithventedcells.Thesearedryout
andthermalrunaway.
Dryout
VRLA cells operate on a precise balance of electrolyte and active material to optimize capacity and oxygen
recombination.Ifthecellsarerelativelyfreeofoxidizableimpuritiesandthepositivegridcorrosionrateisnot
unreasonablyhigh(see4.6),verylittlewaterwillbelostthroughelectrolysis.Ifwaterislost,internalresistance
increasesandperformanceondischargedegrades.Positivegridcorrosionandwaterlossincreasewithincreasing
temperatures. Operation at voltages above the recommended float voltage will also accelerate water loss via
electrolysis.Anotherdryoutmechanismthatcanbesignificantatelevatedtemperaturesiswaterlossviadiffusion
through the jar and cover walls. Dryout bydiffusion ishighly dependent upon the selection ofjar and cover
materials.,thethicknessthereof,operatingtemperature,andrelativehumidityoftheexternalenvironment.
1
Thermal runaway
WhenaVRLAcellisoperatingonfloatoroverchargeinafullyrecombinantmode,almostalloftheovercharge
energyresultsinheatgeneration.Ifthedesignofthesystemandsitsenvironmentaresuchthattheheatproduced
canbedissipatedandthermalequilibriumcanbereached,thenthereisnothermalrunawayproblem.However,if
therecombinationreactiongivesrisetoarateofheatevolutionthatexceedstherateofheatdissipation,thebattery
temperaturewillriseandmorecurrentwillberequiredtomaintainthefloatvoltage.Theadditionalcurrentresultsin
stillmorerecombinationandheatgenerationthatfurtherraisesbatterytemperature,andsoon.Theneteffectcanbe
accelerateddryoutand/ormeltingofthebattery.Thispotentialproblemisfurtheraggravatedbyelevatedambient
temperaturesorbycellorchargingsystemmalfunctions.Thepossibilityofthermalrunawaycanbeminimizedby
useofappropriateventilationbetweenandaroundthecellsandbylimitingthechargeroutputcurrentandvoltage
suchasbyusingtemperaturecompensatedchargers.Inthegelledelectrolytesystem,thegelhasintimatecontact
with the plates and the container walls and provides better heat dissipation characteristics than the absorbed
electrolytesystem,butnotasgoodasthevented(flooded)system[B4].
7.2
Electrolyte concentration
Bydesign,absorbedelectrolyteVRLAcellshavelesservolumesofelectrolytethanventedcellsofequivalent
dimensions. This would normally result in lower longduration capacities for the absorbed electrolyte cells of
equivalentdimensions.Gelledelectrolytecellswillusuallyhavethesamevolumeofelectrolyteasventedcells.
However,thepresenceofthegelinterfereswithelectrolytediffusionandconvection,whichresultsinreducedhigh
ratecapacities.Inbothcases,theexpectedreductionsincapacitymaybepartiallycompensatedforbyincreasingthe
electrolyteconcentration(specificgravities).(Notethathigherspecificgravitiesincreasetherateofcorrosion;i.e.,
speedsupaging.)
7.3
Charging voltage
TheelectrolytespecificgravitythatistypicalofVRLAcellsmayrequirehigherfloatvoltages.Theactualfloat
voltagedependsuponthespecificgravityoftheelectrolytebeingused.Recommendedfloatvoltagesareprovided
bythebatterymanufacturers.
GarthCoreywillrewritethissectiontoincludeotherchargingregimesbesidesfloat.
7.4
7.5
BytheverynatureofthedesignsofVRLAcells,specificgravityreadingsandwateradditionsarenotpractical.
Consequently,thebatteriesareoftenreferredtoasmaintenancefree.However,thisistrueonlywithrespecttothe
electrolyte.Otherwise,VRLAbatterymaintenanceissimilartothatrequiredforventedbatteries,andwillrequire
specialprocedurestocompensatefortheinabilitytodeterminetheamountandconcentrationofelectrolyte.(See
IEEEStd11881996.)Duetotheirdesignandhistoricalreliability(seeSection5.10)VRLAbatteriesmayrequire
increasedmonitoringandtesting(seeIEEEstandards1188and1491).
7.6
Orientation in use
Unlikeventedleadacidcellswheretheonlypossibleorientationrequiresthatthecellcoverbefacingupward,
certain VRLA cell designs allow for operation in other orientations. Contact the manufacturer for specific
instructions.
7.7
Vented gas
InaVRLAcelloperatinginafullyrecombinantmode,therewillbeaslowbuildupofgases.Eventually,the
compositionofthisgaswillbeessentiallypurehydrogen.Whenthecellinternalpressureexceedsthevalverelease
pressure,thegaseswillbeventedintotheatmosphere.Adequateventilationmustbeprovidedinordertoprevent
buildupofhydrogengasinthearea.
CAUTION
WhenaVRLAcellischargedatvoltagesaboveitsrecombinantlimits,potentiallyexplosivemixturesofhydrogen
and oxygen are generated within the cell and released at rates similar to those of vented cells. Contact the
manufacturerforinformationongassingratesandrecombinationefficiencies.
7.8
Historical Reliability
ThissectiontobeprovidedbyEddieDavis
7.9
MuchhasbeenwrittenaboutthedrawbacksofVRLAbatteries. Howevertheydohaveadvantagesoverother
batterytypes(mostspecifically,ventedleadacidcells).Someoftheadvantagesarelistedbelow:
LowInitialCost Comparedtomanyothertechnologies(thisrefersnotonlytootherbatterytechnologies,
butalsoincludesothertypesofbackup,suchasflywheels,fuelcells,etc.),VRLAbatteriestypicallycostthe
least for equivalent energy supply levels. However, the total life cycle cost of ownership (including
maintenance,replacement,operatingcosts,etc.)mustbeconsidered. Manyapplications(especiallythosein
adverseoperatingconditions,likehightemperatureenvironments)shouldhavealifecoststudyperformedto
determinetheappropriatebatterytypebasedonlifecycleeconomics.
Compact Comparedtofloodedleadacidbatteries,VRLAsarerelativelycompact.Theycanbeplacedin
smaller"confined"(butventilated)spaces.Becauseofthewaytheyaremanufacturedandpackaged,VRLAs
canbemadeinsizesmuchsmallerthanthosetypicallyfoundforfloodedVLAcells.
NoWatering Becausetheydonotnormallyrequirewatering,VRLAscan"survive"withlessmaintenance
thanfloodedleadacidcells. However,thisdoesnotexcusetheuserfrommaintenanceasdefinedinIEEE
1188.Thosewhodon'tdomaintenanceopenthemselvesuptoasignificantlyincreasedriskoffailure.
Easier Installation VRLA batteries are typically less costly to install than flooded batteries, and can
typicallybeinstalledinlesstimethanequivalentlysizedfloodedbatteries.
"NonSpillable" (Transport and Placement) VRLA batteries that have passed the appropriate
qualificationtestscanbeclassifiedbytheU.S.Dept.ofTransportation(DOT)asUN2800Batteries,Non
Spillable. Althoughtheycanleakverysmallamountsofelectrolyte,theseVRLAsqualifiedasUN2800are
allowedtobetransportedbyplane.Theyarealsoallowedtobetransportedforrelativelyshortdistancesbyjust
aboutanyone(aspecialtransportcontractordoesn'thavetobehiredtovisit100cabinets[with48batteries
each]inan18wheelerandthentaketheusedbatteriestoarecyclingfaciltity;thesesmallbatteriescanbe
centralize them first). Because they are essentially "nonspillable", most of them can be placed in more
convenient spacesaving configurations (such as front terminal, or "horizontal"). By most interpretations,
VRLAsareexemptfromcostlyspillcontainmentmandatedbyFireCodes.
Asdefinedelsewhereinthisdocument(andothers),themajordisadvantagesofVRLAsareshownbelow.Notethat
thepoorenvironmentsVRLAsareplacedincontributegreatlytomanyofthese"disadvantages".
ThermalIssues VRLAbatteriesaresusceptibletopotentiallydestructiveanddangerousthermalrunaway.
Similartofloodedleadacidbatteries(butperhapsexacerbatedbythethermalrunawayphenomenon),VRLAs
have short lifetimesinhightemperature environments. Thereareothertechnologies(e.g.,NiCad)which
performmuchbetterinhightemperatureevironments.
ShortLife VRLAbatteries(evenwhenkeptinsimilarenvironments)havemuchshorteraveragelifetimes
thanfloodedleadacidbatteries,NiCads,andothercompetingtechnologies. (Failuremodesarediscussed
elsewhereinthisdocument.)
LowerReliability Duetothefactorsjustmentioned,useofVRLAbatteriestypicallylowersthereliability
ofanapplication(incomparisontofloodedleadacidbatteries,forexample).
7.1
Temperature
Elevated temperature operation will shorten VRLA battery life. As a general rule, prolonged use at elevated
temperatureswillreducethebatterylifebyapproximately50%forevery8 C(15 F)above25 C(77F).For
VRLAbatteries,optimalgasrecombinationisafunctionofoperatingtemperature. Therefore, batterycharging
voltagemusttaketemperatureintoconsiderationinordertomaximizebatterylife.Theadditionalissuesofpossible
dryoutandthermalrunawaywithVRLAbatteriesshouldbecarefullyassessedforelevatedtemperatureoperation.
Considerationshouldalsobegiventofailsafecurrentlimitsonchargersforelevatedtemperatureapplications.In
addition,someVRLAbatterymanufacturersrecommendtheuseoftemperaturecompensatedchargersforthose
applicationswheresignificanttemperaturevariationscanbeexpected. Monitoringoftemperature(bothambient
andbattery)canhelpwarnofpossibleproblems(seeIEEEStd.1491).
7.2
Charging limitations
Ingeneral,VRLAbatteries,becauseoftheirhigherelectrolytespecificgravities,willrequireahigherfloatvoltage
per cell. Therefore, charger capability and system voltage limitations must be considered. Some systems that
normallywouldhavebeenengineeredwith24ventedcellsmaybeengineeredwith23largerVRLAcells,thus
maintaining capacity while solving the float voltage issue. As mentioned in section 5.3.2, temperature
compensationofcharging,orothermethodsoflimitingrecharge current,shouldbestronglyconsidered forall
VRLAapplications.
GarthGreyandSamNormanhavevolunteeredtoaddtoandmodifythissectiontoallowforothercharging
regimesbesidesfloat.
7.3
Space limitations
7.4
Environment
ProperlydesignedandoperatedVRLAbatteriesemitlessgasthanventedbatteriesundernormalconditions.This
featureshouldbeconsideredinconjunctionwiththeenvironmentinwhichtheiruseisintended.Asalways,the
effectsofcellorequipmentmalfunctionmustalsobeconsidered.(SeeIEEEStd11871996andIEEEStd1188
1996.)
Humidity is another consideration for VRLAs. As mentioned in section 5.3.1, dryout is an issue with these
batteries.Humiditycanplayaminorroleinthisprocess.Someplasticsaremoreporousthanotherstodiffusionof
hydrogen(thesmallestmolecule).Withthemoreporousplastics,lowhumiditiescanspeedupthisverysmallrate
of diffusion. However, thisisgenerally aminorissue,and highhumiditiesare often not goodforelectronic
equipmentthatmaybeinthesamearea.
Otherenvironmentalconsiderationsincludeactiveorpassiveventialtionforgasmanagement(seeIEEEStd.1187
forhydrogenevolutionrates,plussection6.6below),thermalmanagement(seesection6.7),andtemperature(see
section6.1).
7.5
Life considerations
Batterylifeversussystemdesignlifeshouldalwaysbeconsideredintheselectionprocess.Ingeneral, VRLA
batteries are more sensitive to abusive conditions of temperature, voltage, and current than vented (flooded)
batteries. Also,historicalreliability,eveningoodenvironmentsshowsashorteraveragelifetimeforVRLAcells
(seeSection5.10).
7.6
Safety
Aswithallleadacidbatteries,adequateventilationmustbeprovidedforVRLAbatteries(neverinstallaVRLAina
sealedenvironment).Inaddition,itisstronglyrecommendedthatVRLAcellsbeequippedwithflamearrestor
devices.Electrically,VRLAbatteriesposethesamehazardsasventedbatteries.
VRLAplasticscanbeflameretardantornot(typicalflameretardancystandardsincludeUL94V0andLOI28).
Therearedrawbackstoflameretardantplastics(theyaretypicallysofter,etc.).Manyofthesedrawbackscanbe
overcomebycasedesignorcontainmentofthecase.
FormoreinformationonsafetyconsiderationsforinstallingandmaintainingVRLAbatteries,seeSection4ofIEEE
Stds.1187and1188,respectively.
7.7
Asnotedinsection6.1,VRLAbatteriesareparticularlysensitivetohightemperaturesandoverheating(whichcan
leadtothermalrunaway).Afewsimplemeasuresorselectionconsiderationscanreducetheriskofoverheatingand
thermalrunaway.
Chargingtechniquesandvoltagescanaffectbatterytemperature(seesection6.2)
Forced air cooling is the best thermal management vehicle. In installations without cooling, forced air
ventilationwillhelp.Asaminimum,cellsormonoblocksshouldbespacedatleast10mmaparttoallowfor
naturalconvection(theyshouldalsobespacedaparttoallowforforcedaircoolingorventilationairflow).
Choosebatterystandsortraysthatallowand/orforcethisspacing.Becausethebatteryalsolosesheatthrough
theposts,airspaceontopofthecellsisalsohelpful.
GelcellshavebetterthermaltransfertotheoutsidewallsofthebatterythanAGMcells(althoughAGMcells
haveotheradvantages,asnotedinsection6.9).
Formonoblocks,designsthatexposemoresurfaceareaofmorecellstotheouterwallsofthebatteryhave
betterheattransfer.Forexample,a2x3cellconfigurationina12Vmonoblockistypicallybetterthana1x6
configuration.
Homogeneityoftemperaturesacrossastring(typically,nomorethana3Cdifferenceshouldbeseenfromthe
hottesttocoolestcell/monoblockinastring)areaconsiderationwhendesigningventilation.
7.8
Maintenance considerations
Maintainability and replaceability of the battery must be considered when selecting the battery and it's
stands/cabinets/trays/racks.(SeealsoIEEEStd.1188.)
MostVRLAmaintenanceisdoneonorneartheterminalposts.Frontterminalbatteriesaretheeasiesttomaintain
inrelayracksorcabinets.Fortopterminalbatteriesintheseapplications,slideouttrays(ratedfortheseismiczone
inwhichtheyareinstalled)canhelp.(Withslideouttraysthereneedstobetopspacetoensurethatthereisno
inadvertentshortingofpostsorintercellcableswhenthetrayispulledout.)Ifslideouttraysarenotanoption,at
least100mm(ormoreifpossible)ofspaceshouldbeleftontoptoaccesstheterminalposts. Theactualtop
spacingwillagreewiththenumberinIEEEStd.1187
VRLAsareoftenchosenbecausetheywillfitinspacesthatfloodedbatterieswillnot.Spacingformaintenanceand
thermalmanagementwillhelptheissue,butbesurenottobuycells/monoblocksthatareveryuniqueinsize(sizeas
inheight,length,andwidth).Ifthatbatteryiseverdiscontinuedorfoundtohavemajorproblems,theusermaybe
introubleifitistheonlybatterysizethatwillphysicallyfit.
7.9
AGMandgelcelltechnologiesarebothused.Whichoneispickedhashistoricallydependedonwhattheindustry
typicallyusedhistorically.Thereshouldbemoreconcretecriteriafordecidingwhichtechnologyisbetterforthe
application(theybothhaveadvantagesanddisadvantages).SinceAGMsarethemostcommonandmostfamiliarto
mostusers,thefollowinglcommentswillfocusonwhatmakesgelcellsdifferent(andbetterorworse)thanAGMs
fromaperformanceperspective.
Gelcellswillnotsufferfromdecompression.AGMcellsdependoncontactofthemattewiththeplates.Ifthe
plasticcaseofaVRLAbattery"relaxes"or"bulges"toomuchduetogassing,heat,etc.,theAGMcellrunsthe
riskoflosingcompression(thiscontactbetweenthematteandtheplate),whichleadstoreducedperformance
and/orfailure.
Asmentionedintheprevioussectiononthermalmanagement,gelcellstendtoconductheatawayfromthe
platestotheoutsideofthebatteriesbetterthandoAGMcells,partlybecausetheyhavemoreelectrolyte.This
reduces(butdefinitelydoesn'teliminate)theriskofthermalrunaway.
Inthefirstyearormoreoflife,gelcellswilltendtorecombinelessefficientlythanAGMs,untiltheyhave
developedtheinternalfissures/cracksinthegelnecessaryforrecombinantgastransport.(Infact,gelcellswill
neverrecombineasefficientlyasaproperlydesignedAGMcell,allthewaythroughthelife.)Thismeansthat
they will gas more. That doesn't necessarily mean they will dry out sooner, since they start with more
electrolytethantheAGMcells.Thebuildingoftheinternalfissuresmaycauseinconsistentohmicreadingsin
thefirstyearorsooflifeofagelcell.ThismeansthatbaselineohmicreadingsrecommendedbyIEEEStd
1188maynotbeasvaluableforgelcellsastheyareforAGMcells.
GelcellshavehigherinternalresistancethanAGMs,simplyduetothefactthattheirelectrolyteisinamore
immobilizedform.Thismeansthatforsuperhighratedischargeapplications,theymaynotbethebestchoice.
Notallgelcellsaredesignedtobelaidinhorizontalorfrontterminalpositions.Consultthemanufacturer.
Thegelledelectrolytesystemmayprovidebetterdeepdischargerechargeability.
7.10
Ifthebatterywillcyclealot(inaphotovoltaicapplicationforexample),theuserwouldwanttosteerclearof
pureleadplategrids.Chooseabatteryspecifiedbythemanufacturerasacyclingtypebattery(forexample,
batterieswithleadantimonyplategridstendtocyclewell).Themanufacturerspublishdataontypicalcycles
expectedoutofbatteries.(Notethatmanyhighantimonycontentplatedesigns,whicharecommonlyknownas
leadantimony plates, may not work well in float applications. Lowantimony plate designs, which are
commonlyknownasleadselenium plates,maynot suffer from thisproblem,andmayworkwell inboth
applications. Consultthebatterymanufacturersforthebestplatedesigniftheapplicationrequiresfrequent
cycling.)
Pure lead grids function better in lower specific gravity designs than in higher specific gravity designs.
Althoughpureleadgridshavesuperiorlifeonfloat,asmentioned,theygenerallyarenotgoodforfrequent
cyclingordeepdischargecycling.
UPSapplicationsareoneexampleofapplicationsthattypicallyhaveahighdischargerate.Gridalloysandgrid
thicknessesareimportantfactorsforhighdischargerateapplications. Unlessyouwanttopaysignificantly
more,youmightwanttochooseabatterythatisratedinWatts(orkW)percell.Thistypicallysignifiesthatthe
manufacturerhasdesignedthatbatteryforhighdischargerateapplications.
BruceColehasofferedtoputthissection6.10inmoreofamatrixformat.
7.1
Parallel Strings
Usingparallelstringscangreatlyincreasethereliabilityofasystembymitigatingagainstthefailureofindividual
cellsorstrings. Forlongdurationdisharges,simplysplittingtherequiredamperehourreserveover2ormore
stringsisusuallysufficient.However,forhighratedischargeapplications,redundancyofstringsmaybeabetter
option.
Inaddition,parallelstringsimprovesmaintainability.Ifthestringsareinstalledwithdisconnects,oneoftheparallel
stringscanbeeasilydisconnectedforgreatersafetyinmaintenancewithoutseriouslycompromisingthebackup
abilityofthewholebatterysystem.
7.2
Typically, vented and VRLA batteries have different specific gravities and internal resistances (thus different
chargingcharacteristics). ThismeansthatVRLAsandventedcellsshouldneverbemixedinthesamestring.
Theoretically,VRLAbatterystringscanbeparalleledwithventedleadacidstrings.However,thisisnotusually
done,asthereisnotalotofexperiencewithit;plusdifferingnumbersofcells(typicallyfewer)mustusuallybe
usedintheVRLAstring,andit'sdifficulttomatchtheoptimumchargingvoltages/regimens.
7.3
Oversizing
IEEEStd.485hasbuiltinfactorsinthesizingcalculationstoallowforaging. Inaddition,510%additional
oversizingcanallowaveryquickrecharge(sincethefirst9095%ofchargecapacityisusuallyquicklyreturnedto
thebatterywithinadayorless,dependingonthechargersize;whilethefinal510%maytakedaystoweeksto
returntothebattery).