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Red Imported Fire Ant Treatments and Surface Water Regulatory Issues
Red Imported Fire Ant Treatments and Surface Water Regulatory Issues
Davis, CA
May 5, 2000
Outline
Introduction
Introduction
Monitoring Plan
Insecticides
Surface Water Regulatory Issues
Results & Discussion
Conclusions
Monitoring Program
Offsite Movement
Insecticide Concentration
Aquatic Toxicity
Dissipation study
Turf, Soil, Water
Assessing Mitigations
Other Organophosphates
Dimethoate
Fonofos
Malathion
Methidathion
Methyl parathion
Phosmet
Bifenthrin (Talstar)
Chlorpyrifos (Dursban, Lorsban)
Diazinon
Fenoxycarb (Award)
Hydramethylnon (Amdro)
Pyriproxyfen (Distance)
Physico-Chemical Properties
Pesticide
Sol.
Koc
Bifenthrin
0.1
302,000 345
FD
Chlorpyrifos
1.4
12,000
Diazinon
60
1,800
30
Fenoxycarb
5.7
2,600
36
Hydramethylnon
0.9
360,000 55
Pyriproxyfen
0.4
34,000
56
86
R. Trout (ppb)
D.Magna (ppb)
Bifenthrin
0.15
0.16
Chlorpyrifos
1.7
Diazinon
2600
0.96
Fenoxycarb
1600
400
Hydramethylnon
160
1140
Pyriproxyfen
325
400
Malathion
170
1.8
TMDL Process
Total Maximum Daily Load
Regional Water Quality Control Board
Numeric Standards
Diazinon and Chlorpyrifos
Insecticide Concentration
Toxicity to Ceriodaphnia dubia
Urban vs. Nurseries
Regulatory Issues
Concentration (ppb)
7
bifenthrin
chlorpyrifos
5
diazinon
dimethoate
fonofos
malathion
m. parathion
2
90
80
70
60
50
4
3
40
30
20
10
0
Jun-99 Sep-99 Oct-99 Dec-99 Jan-00 Feb-00
Month
m. parathion
malathion
fonofos
diazinon
chlorpyrifos
bifenthrin
% mortality
bifenthrin
chlorpyrifos
Concentration (ppb)
100
Mortality of C. dubia (%)
Concentration (ppb)
fonofos
diazinon
bifenthrin
m. parathion
diazinon
dimethoate
malathion
m. parathion
3
2
1
0
May- Jun99
99
Sep99
Oct99
Dec99
Jan00
Feb00
Marshburn Slough
100
90
80
70
60
50
40
30
20
10
0
3
m. parathion
malathion
fonofos
dimethoate
diazinon
chlorpyrifos
bifenthrin
% mortality
Concentration (ppb)
Concentration (ppb)
bifenthrin
chlorpyrifos
diazinon
malathion
0
Feb-00
Month
Marshburn Slough
diazinon
chlorpyrifos
bifenthrin
% mortality
0
Feb-00
100
90
80
70
60
50
40
30
20
10
0
2
Concentration (ppb)
Concentration (ppb)
malathion
chlorpyrifos
diazinon
dimethoate
fonofos
malathion
0
Mar- Apr- May- Jun- Sep- Oct- Dec- Jan- Feb99 99 99 99 99 99 99 00 00
Bonita Creek
malathion
fonofos
Concentration (ppb)
100
90
80
70
60
50
40
30
20
10
0
dimethoate
diazinon
chlorpyrifos
% mortality
diazinon
malathion
Westcliff Park
Bonita Creek
80
% mortality
70
60
50
40
30
20
10
0
3
Concentration (ppb)
100
malathion
90
diazinon
2
Concentration (ppb)
Concentration (ppb)
chlorpyrifos
diazinon
methidathion
0
Dec-99
Jan-00
Feb-00
100
90
80
70
60
50
40
30
20
10
0
0
Dec-99
Jan-00
malathion
fonofos
methidathion
diazinon
chlorpyrifos
% mortality
Feb-00
Concentration (ppb)
diazinon
dimethoate
malathion
Concentration (ppb)
malathion
dimethoate
diazinon
%mortality
0
Apr-99 May-99
Jun-99
Sep-99
Oct-99
Month
Dec-99
Jan-00
Feb-00
100
90
80
70
60
50
40
30
20
10
0
Concentration (ppb)
Westcliff Park
Month
diazinon
90
malathion
chlorpyrifos
80
% mortality
70
60
50
40
1
30
20
diazinon
Concentration (ppb
malathion
100
chlorpyrifos
10
0
0
Jun-99
Sep-99
Oct-99
Dec-99
Jan-00
Feb-00
Arroyo
Oso Trabuco
Creek
22
Concentration
Concentration (ppb)
(ppb)
Concentration (ppb
bifenthrin
fenoxycarb
bifenthrin
hydramethylnon
fenoxycarb
pyriproxyfen
hydramethylnon
chlorpyrifos
chlorpyrifos
diazinon
diazinon
fonofos
dimethoate
malathion
fonofos
11
malathion
00
Mar- Mar- Apr- Apr- Apr- Apr- May- Jun- Sep- Oct- Dec- Jan- FebMar- Mar- Apr- Apr- Apr- Apr- May- Jun- Sep- Oct- Dec- Jan99
99
99
99
99
99
99
99
99
99
99
00
00
99
99
99
99
99
99
99
99
99
99
99
00
Feb00
Concentration (ppb)
100
90
80
70
60
50
40
30
20
10
0
malathion
fonofos
diazinon
chlorpyrifos
pyriproxyfen
hydramethylnon
fenoxycarb
bifenthrin
% mortality
Concentration (ppb)
2
3
chlorpyrifos
diazinon
fonofos
malathion
0
Apr99
Mar- Mar- Apr- Apr- Apr- Apr- May- Jun- Sep- Oct- Dec- Jan- Feb99
99
99
99
99
99
99
99
99
99
99
00
00
May99
Jan00
Feb00
Concentration (ppb)
malathion
fonofos
diazinon
chlorpyrifos
% mortality
Conclusions
All RIFA insecticides were detected
Single detects: hydramethylnon,
pyriproxyfen, fenoxycarb
Nurseries: Bifenthrin, Diazinon,
Chlorpyrifos, (Malathion), (Dimethoate)
<3 ppb
Urban: Diazinon, Malathion, Chlorpyrifos
<1 ppb
Acknowledgment
Calif. Dept. of Food & Agriculture
Center for Analytical Chemistry
Pest Detection/Emergency Project
Conclusions (continued)
Toxicity to C. dubia
Nursery sites:
10 attributable to Diazinon, Chlorpyrifos, Bifenthrin,
Malathion, Dimethoate, Fonofos
1 unknowns
Kgoh@cdpr.ca.gov
(916) 324-4072
830 K Street
Sacramento, CA 95814
www.cdpr.ca.gov
10