ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam

Material Safety Data Sheet

1 Identification of the substance / preparation and company
TPU/PU
Product InformationTPU/PU Series Screen Printing Ink
TPU/PU
Product NumberTPU/PU Series Screen Printing Ink
Information on Producer/Supplier Name, Addresses, Phone
+84-650-3629369

ZHINENG Chemical Co., Ltd. To 1, Tan Binh, Tan Hiep,Tan Uyen, Binh Duong, VN
+84-650-3629228
/ Emergency Phone / Fax +84-650- / +84-650-3629370
3629369
2 Composition / Information on Ingredients
Mixture
Chemical Characteristic Solvent-based polyurethane resin

Chemical Characteristic

()
Concentration/Percentage

Hazard Symbols

TPU (PU Resin)

20-30%

(Pigment)

0 50%

(Cyclohexanone)

100%

Add to make 100% total

3 Hazard Identification
Major Hazard Effect

Hazard Warnings for Health: Harmful if swallowed or inhaled or absorbed through the skin.
Irritation of skin, eyes and respiratory tract. Affects (central)
nervous system.

Hazard Warnings for Environment: Toxic to aquatic organisms.

Physical and Chemical Dangerous: Flammable liquid and Vapor.

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ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam
Special Harm:
Major State: Irritation or thermal burns of skin and eyes, headache, nausea, vomiting, diarrhea.
3 ()
Hazard Category: 3 (Flammable liquid)

4 First Aid Measures

Emergency and First Aid Procedures

Inhalation: Move to fresh air. Rest, half-upright position, loosen clothing. Practice artificial respiration
in case of difficulty in breathing. Get immediate medical attention.

Skin Contact: Wash off immediately with plenty of soap and water. Take all Contaminated clothing off
immediately. Seek medical advice.

Eye Contact: Rinse immediately with plenty off water. Always Seek medical advice.

Ingestion: Do not induce vomiting because of risk of aspiration. Rinse mouth with water. Seek medical
advice. Never give anything by mouth to an unconscious person.

Major Disease and Harm Effect: Affects central nervous system if under prolong and high concentration
on exposure. Damage to the liver and kidneys may occur.

First-Aid Personal Protection: Wear Protective gloves to prevent contact with the contaminated materials.

Prompt to Doctor: In small ingestions the gastrointestinal decontamination is not recommended. With
larger ingestions there is potential for systemic toxicity from gastrointestinal
absorption and decontamination is suggested.
5 Fire Fighting Measure

Suitable Extinguishing Media: Dry chemical, alcohol foam of carbon dioxide.

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ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam

Special Exposure Hazards: Carbon dioxide and carbon monoxide and toxic fumes may be generated
under high temperature. Fire exposed containers may explode. Above flash
point, vapor-air mixtures are explosive within flammable limits

Special Extinguishing Procedure: Keep up-wind to avoid fumes. Water spray may be used to keep fire
exposed containers cool. Keep run-off water out of sewers and water
sources. Dike for water control. Move container from fire if it can be
done without risk. If risk of water pollution occurs, notify appropriate
authorities.

Special Protection Equipment: In the event of a fire, wear full protective clothing and self-contained
breathing apparatus with full facepiece operated in the pressure demand
or other positive pressure mode.
6 Accidental Release Measures
1.
2.
Personal Protection: 1. Keep unnecessary and unprotected personnel from entering.
2. Wear appropriate personal protective equipment. Do not breathe vapors / dust.
1.
2.
3.
4.
Environmental Protection: 1. Ventilate area of leak or spill.
2. Keep away from sources of ignition - no smoking.
3. Prevent product from entering drains. Do not contaminate surface
water. Avoid subsoil penetration.
4. Report to the authorities if large leakage occurred.

Methods for Cleaning Up: Contain and recover liquid when possible. Use non-sparking tools and
equipment. Collect liquid in an appropriate container or absorb with an inert
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ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam
material (e. g., vermiculite, dry sand, earth), and place in a chemical waste
container. Do not use combustible materials, such as saw dust. Do not flush
to sewer!
7 Handling and Storage
1.

2.
3.
Handling: 1. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat,
sparks, flame, static electricity or other sources of ignition, they may explode and cause
injury or death. Containers of this material may be hazardous when empty since they retain
product residues (vapors, liquid).
2. Observe all warnings and precautions listed for the product.
3. Wear appropriate personal protective equipment. Avoid spilling, skin and eye contact. Do not
use contact lenses.
1.
2.
3.
4.
Storage: 1. Protect against physical damage. Store in a cool, dry well-ventilated location.
2. Away from any area where the fire hazard may be acute.
3. Containers should be bonded and grounded for transfers to avoid static sparks.
4. Storage and use areas should be No Smoking areas. Use non-sparking type tools and
equipment, including explosion proof ventilation.

8 Exposure Control / Personal Protection

Engineering Control: A system of local and/or general exhaust is recommended. Local exhaust ventilation
is generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area.

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ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam

/ /
25ppm () /
37.5ppm () /

LD501,535mg/kg () LC508,000ppm/4H ()
Control Factor
Cyclohexanone
TWA / STEL / CEILING25ppm (skin) / 37.5ppm (skin) / None
Biotic Index
LD50 oral rat Dose1535mg/kg LC50 inhalation rat Dose8000ppm/4H Cyclohexanone

Personal Protection Equipment

Respiratory Protection: Use a full-face piece positive-pressure or air-supplied

respirator or a respirator with organic solvent filter.

Hand Protection: Protective gloves made of rubber.

Eye Protection: Safety goggles or full face shield.

Skin & Body Protection: Suitable protective clothing, boots.

Hygiene Procedures: Wash at the end of each work shift and before eating, smoking. Promptly remove
any clothing that becomes contaminated. Contaminated clothing to be placed in
closed container until disposal or decontamination. Warn cleaning personnel of
chemical's hazardous properties.
9 Physical and Chemical Properties/Characteristics

AppearanceLiquid paste

FormLiquid

ColorDepend on item number

OdorTypical organic solvent odor

pH
pH valueAlmost neutral

/ 197C
Boiling Point/Boiling Range197C

Decomposition Temperature-

44C
( ) ( V )
Flash Point44C
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ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam
Test Method ( ) Open Cup ( X ) Close Cup
420C
Spontaneous Temperature420C

1.1% @ 100C ~ 9.4%

Explosive Limits1.1% @ 100C ~ 9.4%

4mmHg @ 20C
Vapor Pressure4mmHg @ 20C

3.38 (=1)
Vapor Density3.38 (Air=1)

0.98-1.2 ( = 1)
Specific Gravity0.98-1.2 (Water=1)

Solubility in WaterInsoluble in water

10 Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage .

Special Conditions of Hazardous Reaction: Strong oxidizing agent(cause fire).

Conditions to Avoid: Flame, static electricity, heat, ignition sources and incompatibles.
()
Incompatibility: Strong oxidizing agents (peroxides, nitrate). May cause spontaneous ignition and violent
reaction. May attack some plastics and rubber.

Hazardous Decomposition Products: Thermal decomposition may release acid fumes, smoke and carbon
monoxide.
11 Toxicological Information
Acute Toxicity

Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
High concentrations have a narcotic effect. Irritation effects normally prevent exposures high
enough to cause systemic effects.
,
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. May be absorbed
through the skin with possible systemic effects.

Eye Contact: Vapors may cause irritation. Contact may cause corneal injury.

Ingestion: May produce abdominal pain, nausea. Aspiration into lungs can produce severe lung damage
76

MSDS 2015/01/01

ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam
and is a medical emergency. Other symptoms expected to parallel inhalation
500mg()
20mg()
Local Effects: 500mg ( rabbit , skin ), Moderate irritation
20mg (rabbit, eyes), Serious irritation.
Sensitive:
Chronic: Prolonged or repeated exposure may cause skin rash or dermatitis. Damage to the liver and
kidneys may occur.

Exceptional Effect: Has shown teratogenic effects in laboratory animals
12 Ecological Information
/
Possibility of Environmental Impact/Move: Hazardous to water, Must not enter the waters drains or
ground.
13

Disposal Information: Seal the container tightly to prevent leak or spill. In case of incineration, follow
the disposal standard of industrial waste. Consign the disposal to the specialist of
industrial waste after clarifying that the goods are flammable waste oil.
14 Transport Information
1.DOT 49 CFR ()
2.IATA/ICAO 3()
3.IMDG 3()
International Transport Regulation1.DOT 49 CFRHazard Class: 3 Packing GroupIII
2. IATA/ICAOHazard Class: 3
3. IMDGHazard Class: 3
UN1915
The United Nations Number (Un-No): UN1915
1. 84
2.
3.
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MSDS 2015/01/01

ZHINENG CHEMICAL CO.,LTD.

TEL+84-650-3629369 FAX+84-650-3629370
Thua dat so 10, To ban do so 15, To 1, Kp Tan Binh, P.Tan Hiep, TX.Tan Uyen, Tinh Binh
Duong,Vietnam
Internal Transport regulation1. 84
2.
3.
Special Transport Way and Note: 15 Regulation Information

Apply Regulation

16 Other Information

Reference

Make Unit

NameZhineng Chemical Co., Ltd.

0650-3629369
/
Addresses/Phone: To 1, Tan Binh, Tan Hiep,Tan Uyen, Binh Duong, VN 0650-3629369

Make People

Professional PostPerson in charge

Make Date

2015/01/01

Document No.

100

Version

78

Bruce Ye
NameBruce Ye

Document type

MSDS 2015/01/01