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Topper 8 116 4 2 Chemistry 2015 Questions Up201506182058 1434641282 7559 PDF
Topper 8 116 4 2 Chemistry 2015 Questions Up201506182058 1434641282 7559 PDF
Total Marks: 70
General Instructions:
1. All questions are compulsory.
2. Answers to the two sections are to be written in the same answer book.
3. Figures at the right hand side indicate full marks.
4. Write balanced chemical equations and draw neat and labelled diagrams, wherever
necessary.
5. Use of logarithmic table is allowed.
6. Answer to every question much be started on a new page.
SECTION - I
Q. 1 Select and write the most appropriate answer from the given alternatives for
each sub-question:
[7]
(i) p-type semiconductors are made by mixing silicon with impurities of
(a) germanium
(b) boron
(c) arsenic
(d) antimony
(ii) Amongst the following identify the criterion for a process
(a) G<0
(b) G>0
(c) Stotal=0
(d) S<0
(iii) Colligative property depends only on in a solution.
(a) Number of solute particles.
(b) Number of solvent particles.
(c) Nature of solute particles.
(d) Nature of solvent particles.
(iv) The change of how many coulomb is required to deposit 1.0g of sodium metal
(molar mass 23.0g mol1) from sodium ions is
(a) 2098
(b) 96500
(c) 193000
(d) 4196
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l A t
(b) K ln
t A o
(c) K
At
2.303
log10
t
A o
l A t
(d) K ln
t A o
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Al(s)
166V
Cu(s)
034V
Cl(aq)
136V
Ni(s)
026V
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SECTION - II
Q. 5 Select and write the most appropriate answers from the given alternatives for
each sub-question:
[7]
(i) Identify the product 'D' in the following sequence of reactions:
Alc.
HBr
Na
H3C - CH2 - CH2 Cl
'B'
'C'
'D'
KOH
Ether
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(a) 2, 2-dimethylbutane
(b) 2, 3-dimethylbutane
(c) hexane
(d) 2, 4-dimethylpentane
Which of the following complexes will give a white precipitate on treatment with a
solution of barium nitrate?
(a) [Cr(NH3)4SO4]Cl
(b) [Co(NH3)4 Cl2]NO2
(c) [Cr(NH3)4Cl2]SO4
(d) [CrCl2(H2O)4]Cl
What is the geometry of chromate ion?
(a) Tetrahedral
(b) Octahedral
(c) Trigonal planar
(d) Linear
Primary and secondary nitroalkanes containing H atom show property of
(a) chain isomerism
(b) tautomerism
(c) optical isomerism
(d) geometrical isomerism
In phenol carbon atom attached to OH group undergoes
(a) sp3 hybridisation
(b) sp hybridisation
(c) sp2 hybridisation
(d) no hybridisation
Identify the strongest acid amongst the following:
(a) Chloroacetic acid
(b) Acetic acid
(c) Trichloroacetic acid
(d) Dichloroacetic acid
Which of the following vitamins is water soluble?
(a) A
(b) D
(c) E
(d) B
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