Professional Documents
Culture Documents
Anic Chemistry - Nitrogen Containing Compounds
Anic Chemistry - Nitrogen Containing Compounds
Anic Chemistry - Nitrogen Containing Compounds
com
ORGANIC CHEMISTRY –II
5. NITROGEN CONTAINING COMPOUNDS
PREVIOUS EAMCET BITS
1. The structure of the compound formed, when nitrobenzene is reduced by lithium aluminium hydride
(LiA/H4) is (2008 E)
1) 2) NHOH
N N
H H
NH2
3) 4)
N N
Ans : 3
Sol:
NO2
+8[H] LiA/H2 N N
Azo benzene
2. Nitrobenzene undergoes reduction with Zn/alcoholic KOH to form a compound A. The number of
Sigma and Pi bonds in A, respectively, are (2008 M)
1) 17,6 2) 27,6 3) 27,8 4) 17,8
Ans : 2
Sol:
NO2
Zn+KOH(alc) N
2 +10[H] N +4H2O
H H
4. Which of the following reactions can produce aniline as the main product? (2006 E)
1) C6 H 5 NO2 + Zn / KOH 2) C6 H 5 NO2 + Zn / NH 4Cl
3) C6 H 5 NO2 + LiAlH 4 4) C6 H 5 NO2 + Zn / HCl
Ans : 4
Powered by 1myengg.com
Powered by myengg.com Organic Chemistry – II
Sol: Reaction
C6 H 5 NO2 + 6 ( H ) ⎯⎯⎯→
Zn / HCl
C6 H 5 NO2 + 2 H 2O
5. Which of the following compounds is soluble in benzene but almost insoluble in water?
(2005 E)
1) C6 H 5OH 2) CH 3CO2 H 3) CH 3CHO 4) C6 H 5 NO2
Ans : 4
Sol: Nitrobenzene is soluble in organic solvents like Benzene but insoluble in water.
6. Aniline is not the major product in one of the following reactions. Identify that reaction
(2003 E)
ZnCl2
1) C6 H 5OH + NH 3 0
2) C6 H 5 NO2 + Zn powder ⎯⎯⎯⎯⎯
alcoholic KOH
→
300 C
3) C6 H 5Cl + NH 3 ⎯⎯⎯
2000 C
CH 2O
→ High pressure 4) C6 H 5 NO2 + Fe + H 2O ⎯⎯ HCl
⎯→ CHO
Ans : 2
Sol:
NO2
Zn+KOH N
2 +10[H] N
Alconol
H H
Hydrazobenzene
C6 H 5 N 2Cl ⎯⎯⎯
HNO2
Cu2O
→ C6 H 5 NO2 + N 2 + HCl
(X) (Y)
9. What is the product obtained when nitrobenzene is reacted with HCl in the presence of Sn
(2001 M)
Powered by 2myengg.com
Powered by myengg.com Organic Chemistry – II
1) C6 H 5 N = NC6 H 5 2) C6 H 5 NH 2
3) C6 H 5 NH − NHC6 H 5 4) C6 H 5 NHOH
Ans : 2
Sol: When reduced in strongly acid medium (Sn + HCl) nitrobenzene gives aniline.
C6 H 5 NO2 + 6 [ H ] → C6 H 5 NH 2 + 2 H 2O
Azobenzene
DDDD
Powered by 3myengg.com