Table of The Simple Relationships Between The Basic Values Within An Electrolytic and Galvaic Cells in Respect To The Redox Half Equations

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Annode Oxidation REDuction

Gain of oxygen CAThode


Loss of hydrogen Loss of oxygen
Loss of 𝒆 Gain of hydrogen
+𝑒 in products Gain of 𝒆
Oxidation +𝑒 in reactants
StrongestReductant Reduction
Anode StrongestOxident
Corrodes Faster Cathode
𝒆 →→
Voltaic Cell Spontaneous
Negative Electrode Positive Electrode
HASLower E0 HASHigest E0
E0 x-1
Solid forms (plating)
←← 𝑃𝑜𝑠𝑖𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐶𝑎𝑡𝑖𝑜𝑛𝑠) 𝐴+
𝐴−𝑁𝑒𝑔𝑎𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐴𝑛𝑖𝑜𝑛𝑠) →→
Zn s |Zn(NO3 )2 aq ||Cu(NO3 )2 aq |Cu(s)
Electrolytic Cells Non Spontaneous
Positive Electrode Negative
0
Highest E Electrode
E0 x-1 Lowest E0
Becomes basic 𝑝𝐻 ↑ GOES AS PREDICTED
Becomes acidic 𝑝𝐻 ↓
Solid forms on electrode
+
𝐴 𝑃𝑜𝑠𝑖𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐶𝑎𝑡𝑖𝑜𝑛𝑠) →→
←← 𝑁𝑒𝑔𝑎𝑡𝑖𝑣𝑒 𝐼𝑜𝑛𝑠 (𝐴𝑛𝑖𝑜𝑛𝑠) 𝐴−
Cl=-1 Br=-1 H=+1 O=-2 Ag=+1
H2 O2 ∶ O = −1 CuH2 : H = −1
K Na Li Ba Ca Mg Al Zn Fe Ni Sn Pb H2 Cu Ag Hg
←strongest REDUCTANT weakest→
𝑤𝑜𝑛𝑡 𝑟𝑒𝑎𝑐𝑡 𝑤𝑖𝑡ℎ 𝑎𝑐𝑖𝑑 ← 𝐻2 → will react

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