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Chemical Equilibrium Chem17
Chemical Equilibrium Chem17
F.G. QUEZON
INSTITUTE OF CHEMISTRY, COLLEGE OF SCIENCE
UNIVERSITY OF THE PHILIPPINES, DILIMAN QUEZON CITY, PHILIPPINES
DATE PERFORMED: JANUARY
INSTRUCTORS NAME: IRINA
9, 2013
DIANE CASTANOS
SUMMARY OF RESULTS
Iron(II)-Silver Ions System
Reaction
2+
3Fe + Fe(CN)6 Fe(III)Fe(II)(CN)6Fe3+ + 6SCN- Fe(SCN)2+
Ag+ + Cl- AgCl(s)
Copper-Ammonia System
Reactants
Cu2+
+ NH3
+ excess NH3
+ HCl
Results
Prussian blue precipitate (Fe2+ is present)
Blood red solution(Fe3+ is present)
White precipitate (Ag+ is present)
Drop
1
8
2
Color
Light blue
Dark blue
Dark blue
Light blue
Chromate-Dichromate System
CrO42Cr2O72-
H2SO4
Solution turned orange
2CrO42- + 2H+ Cr2O72- +
H2O(l)
No visible reaction
NaOH
No visible reaction
Solution turned yellow
Cr2O72- + 2OH- 2CrO42+ H2O(l)
Shift
Right
Right
Light yellow orange
Color
Carnation pink
Blue violet/lavender
Cu(OH) 2 . This precipitate would be dissolved upon the addition of excess ammonia.
This would result to the blue complex, Cu(NH 3 )42+.
Upon addition of HCl, the blue complex returns to being the light blue
solution, the one that contained the blue precipitate, Cu(OH) 2 . This is because the
H+ ion reacts with the ammonia in the copper complex to form ammonium ions that
cannot react with copper to form the complex. The hydroxide ion reacts with the
copper (II) ion instead and copper(II) hydroxide is formed again.
Cu(NH3 )42+ + H+ Cu(OH) 2(s) + NH4+ (8)
Compared to the number of ammonia drops needed to form the copper (II)
complex, the number of drops of HCl needed to decolorize the solution is relatively
smaller. In the experiment, A total of 9 drops were needed to form the Cu(NH 3 )42+,
however, only 2 drops of HCl was needed to decolorize it. This is because the first
few drops of NH3 are used to form Cu(OH)2. Excess NH3 is needed to form the
complex. On the other hand, with HCl, results are almost immediate since at the
first drop, the H+ from HCl already reacts with NH3 to form NH4+ . Irresponsible
addition of concentrated HCl could lead to errors since only a small amount of acid
is needed for the reaction. An accidentally added extra drop of the acid could cause
the end solution to be colorless instead of light blue. Careful monitoring of drops of
acid added should be done to avoid such errors.
The third part of the experiment is the chromate-dichromate system. The
chromate solution is color yellow while the dichromate solution is color orange.
Upon addition of the acid, H2SO4 the chromate solution changed color from yellow to
orange. The balanced equation for this reaction is:
2CrO42- + 2H+ Cr2O72- + H2O(l) (9)
Sulfuric acid is used for the reaction because sulfuric acid is a strong acid. The fact
that it ionizes completely is useful since only the hydrogen ions of the acid are
needed in the reaction. It is also a diprotic acid meaning it can donate two hydrogen
atoms to the reaction, which is the amount of hydrogen atoms needed. Upon
addition of the base, NaOH, the dichromate solution changed color from orange to
yellow. The balanced reaction for this is:
Cr2O72- + 2OH- 2CrO42- + H2O(l) (10)
When joined with sulfuric acid, the chromate in the yellow chromate solution
accepted the protons donated by the acid. This results in the formation of
dichromate in an orange dichromate solution. On the other hand, the addition of
sodium hydroxide in the orange dichromate solution caused the dichromate to
donate its protons and form chromate in a yellow chromate solution. However, when
sulfuric acid is added to dichromate, the solution is shifted to the side of the
reaction favoring the production of more dichromate ions, thus the solution remains
orange. Same goes for the addition of sodium hydroxide in chromate. The reaction
is shifted to the side favoring production of more chromate ions, thus the yellow
color remains. It is shown here that dichromate is stable in acidic conditions while
chromate is stable in basic conditions.
The next part of the experiment is on iron(III)chloride and thiocyanate. The
balanced equation for this reaction is:
Fe3+ + SCN- Fe(SCN)2+ (11)
Upon addition of more Fe3+, the solution turned a darker shade meaning more of the
product was being produced. Equilibrium shifted to the right to consume the
additional Fe3+ and maintain equilibrium. The same happened upon the addition of
SCN-. The solution turned darker which suggested that more of the product was
being formed, therefore equilibrium also shifted to the right to consume the
additional SCN-. The next case is the addition of saturated NaCl solution. This causes
equilibrium to shift to the left. This is because the Cl - reacts with some Fe3+ leaving
less for the reaction with SCN- to form Fe(SCN)2+ . To maintain equilibrium, some of
the product needs to be consumed, thus the equilibrium shifts to the left which is
the reactant side.
The last part of the experiment is the Co2+ system. The balanced reaction for
this is:
[Co(H2O)6]2+ + 4 Cl- CoCl42- + 6H2O(l) (12)
In the reaction, Co2+ is pink while CoCl42- is blue. The solution is pink at first because
of the presence of Co2+, however, when the temperature of the solution is raised,
the equilibrium shifts to the right which causes the formation of CoCl 42- which is
blue. The forward reaction is an endothermic one since the temperature raise
causes the formation of more products. With addition of HCl, though, it is shown
that the both products and reactants are present because of the lavender color of
the resulting solution.
UW Madison-Department of Chemistry.
http://www.chem.wisc.edu/deptfiles/genchem/sstutorial/ Text13/Tx135/tx135.html
(accessed Jan 12, 2013).