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Solid-Liquid Equilibrium
Solid-Liquid Equilibrium
=
Defining the ratio, / as :
=
(, )
( , ) ( , )
( , )
(, )
INTRODUCTION
(1)
(3)
Keywords-eutectic temperature, eutectic composition, solidliquid equilibrium, thermal analysis, naphthalene, diphenylamine
I.
(2)
(4)
(, )
( , )
( , )
(, )
(5)
(
)
(6)
2.
Diphenylamine,
g
Naphthalene,
g
3.75
0.75
3.75
1.875
3.75
3.75
3.75
7.5
3.75
3.75
3.75
0.75
M6 + 0.75 naphthalene
3.75
1.2525
M7 + 1.2525
naphthalene
Mixture preparation
M1 + 0.75 g
diphenylamine
M2 + 1.875 g
diphenylamine
M3 + 3.75 g
diphenylamine
M4 + 7.5 g
diphenylamine
1 1
(
)
1
1 = 1 exp
2 2
(
)
2
(7)
(8)
Temperature, Kelvins
340
330
320
310
300
290
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
x(1)
Figure 1. SLE curve for the naphthalene (1) - diphenylamine (2) system at 101.325 kPa (constructed from experimental data)
2
,2
,2
) = exp
1
,1
,1
(9)
naphthalene
diphenylamine
, C
80.2
52.9
, C
Experimental
0.306026561
27
Theoretical
0.360001299
32.21532052
deviation
14.99293 %
1.707896 %
REFERENCES
[1]
[2]
[3]
[4]
[5]
[6]
APPENDIX
Appendix A. Pure-Species Properties
Diphenylamine
Naphthalene
Density (g/cm3)
1.2
1.16
53
80.2
169.22244
128.17052
+
% =
100%
Appendix C. Cooling Curves
Mixture 1
Temperature (deg C)
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
Time (s)
200
250
300
Mixture 2
Temperature (deg C)
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
200
250
Time (s)
Mixture 3
Temperature (deg C)
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
100
200
300
400
Time (s)
500
600
700
Mixture 4
Temperature (deg C)
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
100
200
300
Time (s)
400
500
Mixture 5
Temperature (deg C)
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
200
Time (s)
250
300
350
400
250
300
350
400
250
300
350
400
Mixture 6
Temperature (deg C)
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
200
Time (s)
Mixture 7
Temperature (deg C)
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
200
Time (s)
Mixture 8
Temperature (deg C)
100.0
80.0
60.0
40.0
20.0
0.0
0
50
100
150
200
Time (s)
250
300
350
400