Final Exam Worksheet

1. Name the elements that occur as diatomic molecules naturally.

H2, N2, O2, F2, Cl2, Br2, I2

2. List the strong acids.

HCl, HBr, HI, H2SO4, HNO3, HClO4, HClO3

3. List the polyatomic ions (with correct charges) that you are required to know.

CN-, CH3CO2-, CO32-, HCO3-, NO2-, NO32-, PO33-, PO43-, SO32-, SO42-, NH4+, H3O+, OH-, O22-,
O2-, I3-, SCN-, HSO3-, HSO4-, ClO-, ClO2-, ClO3-, ClO4-, MnO4-, CrO42-, Cr2O72-

4. What is the definition of a Lewis acid/base.

Lewis acid is an electron pair acceptor.

Lewis base is an electron pair donor.

5. What is the percentage by mass of N in the amino acid arginine (C6H14N4O2)?

32.17%

6. What is the mass, in grams, of 4.3 moles of copper (II) sulfate?

686.4g

7. What is the empirical formula of a compound that is 36.6% carbon, 6.9%

hydrogen, 32.0% nitrogen and 24.4% oxygen by mass?

C4H9N3O2

8. Balance the following equation using whole number coefficients.

3PbO + 2NH3  3Pb + N2 + 3H2O

9. 46.2 g of ethanol (C2H5OH) is burned in excess oxygen to produce carbon

dioxide and water. What is the mass of the water that is produced?

2497 g

10.How many oxygen atoms are in 96.2 g of insulin (C257H383N65O77S6)?

7.86 x 1023

11.What is a state function? Name some examples of things that are state
functions and things that are not state functions.

A state function is a property of a system that depends only on the current state of
the system not how the system got there. State functions: enthalpy, entropy, free
energy Not State Functions: heat, work

12. Calculate the enthalpy of the reaction

C2H5OH(l) + 3O2(g)  2CO2(g) + 3H2O(l)
given the following reactions and enthalpies of formation.
C2H5OH(l)  2C(s) + 3H2(g) + ½ O2(g) ΔHo = 228 kJ
CO2(g)  C(s) + O2(g) ΔHo = 394 kJ
H2(g) + ½ O2(g) H2O(l) ΔHo = -286 kJ
-1418 kJ

13. Acetylene gas burns in air with an extremely hot flame:

2C2H2(g) + 5O2(g)  4CO2(g) + 2H2O(g) ΔHo =
-2600kJ
It requires 15 kJ of heat to melt one mole of iron metal at 1535oC. How
much acetylene needs to be burned to melt 100 grams of iron?

0.538g

14. Identify the spectator ions in the following reaction:

Li2SO4(aq) + Ba(NO3)2(aq)  BaSO4(s) + 2LiNO3(aq)

Li+ and NO3+

15. What is the ground state electron configuration for strontium?

What are the values of the four quantum numbers?

[Kr] 5s2
n = 5 l = 0 ml=0 ms = -1/2

16. How many grams of hydrochloric acid would be dissolved in a 3L

flask to make a 1.25M solution?
136.7g
 17. What is the final temperature if a 43.7kg metal block (specific heat =
0.856 J/gK) at 750K is dropped into 125 kg H2O at 302K?

If you assume the water can superheat, the temperature will be 488K.

18. How much ice will melt if that same metal at 786K is dropped into ice
water containing 400kg H2O and 500kg ice at 273K?
All of it

19. 23.2g of steam (373K) is bubbled into a mixture of 500g of water and
523g of ice at 273K. How much of the ice will melt?

186.6g

20. What is the ΔHreaction in kJ for the following reaction:

Fe3O4(g) + CO(g)  3FeO(s) + CO2(g)
Standard enthalpies of formation:
Fe3O4(g) = -1117 kJ/mol
CO(g) = -110.5 kJ/mol
FeO(S) = -266.5 kJ/mol
CO2(g) = -393.7 kJ/mol

34.3 kJ

21. Using deBroglie’s equation (λ= h/mv), what is the wavelength in

m of a 173.4 g softball being thrown at 73 miles/hr?

1.17 x 10-37 m

22.For the following compounds/molecules/ions:

i) Draw the Lewis dot structure

ii) Name the VSEPR structure

iii) Find the Average bond order

iv) Draw resonance (if applicable)

v) State hybridization

vi) Polar/Non-polar?

a) CCl4

ii) Tetrahedral

iii) 1
 iv) N/A

v) sp3

vi) non-polar

b) XeF2

ii) Linear

iii) 1

iv) N/A

v) sp3d

vi) non-polar

c) SF6

ii) octahedral

iii) 1

iv) N/A

v) sp3d2

vi) non-polar

d) HF

ii) Linear

iii) 1

iv) N/A

v) N/A

vi) polar

e) NH3

ii) Trigonal pyramid

iii) 1

iv) N/A

v) sp3
 vi) polar

f) SO3

ii) Trigonal planar

iii) 4/3

iv) resonance

v) sp2

vi) non-polar

23.You make a new temperature scale (oN) that you choose the new freezing
point of H2O is -34oN and the new boiling point is 797oN. What would be the
new freezing and boiling points of ethanol (EtOH)? Ethanol freezing point:
-114.3oC boiling point: 78.4oC

Freezing point = -1028oN

Boiling point = 617.5oN

24.Two gases, H2O and OCl2, are confined in two flasks that are connected by a
tap. The H2O is in a 2.5L flask with a pressure of 4.8atm and the OCl2 is in a
5.3L flask with a pressure of 3.8atm before the tap is opened. Once the tap is
opened, the two gases mix and the reaction is able to go to completion. What
are the partial pressures of the three gases and the total pressure at the end
of the reaction? The temperature is constant.

H2O(g) + OCl2(g)  2HClO(g)

PH2O = 0 atm POCl2 = 1.04 atm PHClO = 3.08 atm Ptot = 4.12 atm

25.This single unit cell consists of three ions. The largest (X) on the corners, the
medium (Y) in the center and the smallest (Z) on the faces. What is the
lattice of the X and Y ions and what is the overall stoichiometry of this lattice?

Body centered cubic

Stiochiometry : XYZ3
26.Label the following phase diagram. (solid, liquid, vapor)

27.What are the temperatures and pressures associated with the following
points on the diagram?

a. Critical point b. Triple point c. Normal boiling point d. Normal

melting point

T: 825 T : 80 T: 310 T: 80

P: 1.5 P: .70 P: 1 P:1

28.What is the outcome as the following happens?

a. At 1.75atm., the temp rises from 90oC to 750oC. (SL)

b. At 100oC, the pressure increases from 0.50atm to 1.25atm. (VLS)

c. At 800oC, the pressure decreases from 1.50atm to 1.00atm. (LV)

solid Liquid

Vapor

29.What is
the molality of a 5.0% by mass aqueous solution of acetic acid (CH3CO2H)?
0.876 m

30.Rate the following intermolecular attractions from weakest to strongest?

a) London dispersion (1)

b) H-bonding (3)

c) Ionic bonding lattice (4)

d) Covalent bonding lattice (5)

e) Dipole-dipole (2)

31.Along the z- axis, state which orbitals (using s and all three possible p
orbitals) will combine to make σ and π bonds.

σ : s-s, s-pz, pz-pz π: px-px, py-py

32.According to the following equation at equilibrium and LeChatlier’s principle

H2(g) + I2(g)  2 HI(g) ΔH = positive

What happens when

a. H2 is decreased (shift left)

b. HI is increased (shift left)

c. Temperature is increased (shift right)

d. Volume is decreased (nothing)

e. Addition of a catalyst (nothing)

33.Acetic acid(CH3CO2H) is a weak acid monoprotic acid that is diluted with

water to make a 0.376 M solution. What is the pOH of the solution at
equilibrium? Ka = 1.74 x 10-5

pOH = 11.41

34.What is the equilibrium constant for the following reaction?

NO2(g) + CO(g)  NO(g) + CO2(g)

 [NO2] = 1.25M; [CO] = 0.75M; [NO] = .55M; [CO2] = 0.62M

Keq = 0.364

35.What kind of solution (acidic, basic, neutral) is made with the following salts>

a. LiI b. NH4Br c. KCl d. H3PO4

a. Neutral

b. Acidic

c. Neutral

d. Acidic