Professional Documents
Culture Documents
Stages of Site Investigation
Stages of Site Investigation
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5.1
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Table 5.1
Field Screening Instruments
INSTRUMENT
APPLICABILITY
ADVANTAGES
DISADVANTAGES
Flame Ionization
Detector (FID)
Detects organic
gases and vapor in
air, soil, and waste;
useful in
determining areas of
concern
Photo Ionization
Detector (PID)
Detection is non-specific;
requires experience; not effective
in humid or cold weather;
affected by electrical sources;
does not respond to methane;
depends on lamp eV; does not
respond to any compound with a
higher ionization potential than
its probe (probes with varying
ionization potentials are
available); detects in the ppm
range
Portable Gas
Chromatograph
(GC)
Detects organic
gases and vapor in
air, soil, and waste
X-Ray
Fluorescence
(XRF)
Field detection of
arsenic, antimony,
barium, cadmium,
chromium, copper,
iron, lead, mercury,
nickel, selenium,
and zinc
Rapid analysis of
metals; user can
analyze an unlimited
number of samples to
generate data of known
quality (with lab
confirmation) meeting
QA level 2; can use a
generic calibration
model for locating
points for further lab
analysis
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INSTRUMENT
APPLICABILITY
ADVANTAGES
DISADVANTAGES
Field Detection
Kits
Detects specific
compounds, or
specific properties,
in soil, waste, and
water (e.g., PCB or
pesticide kits; Haz
Cat kits for
examining
parameters such as
reactivity, pH,
flashpoint,
ammonium,
chlorine, cyanide,
sulfides)
Real-time Aerosol
Monitor
(RAM)/mini RAM
Real-time detection
of particulate matter
in air
Detector Tubes
Qualitative air
monitoring for
specific vapors
Easy to operate;
available for many
different compounds;
gives direct reading of
vapor concentration;
widely available
Monitor Gas
Monitor
Detection of various
specific gases (e.g.,
H2S, HCN, NO2 )
Needs no experience;
passive; simple
audible alarm if
concentrations of the
gas rises above TLV;
widely available
Radiation Meter
Detection of alpha,
beta, and gamma
radiation
Allows immediate
detection of radioactive
materials; direct
reading; widely
available; needs little
experience to operate;
audible detection mode
Combo meter
(CGI, O2, H2S)
Detection of
combustible gas
(CGI), O2, and H2S,
in air
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INSTRUMENT
APPLICABILITY
ADVANTAGES
DISADVANTAGES
Mercury Vapor
Analyzer
Analysis of mercury
vapor in air
Conductivity
Meter
Screening of
groundwater
Immediate detection of
potentially-impacted
groundwater; high
conductivity is an
indication of possible
contamination
Used to determine
particulate and/or
VOC type, size, and
quantity
Personal air
sampling
Many sampling
scenarios for VOC and
particulates
Notes:
H2S=hydrogen sulfide
HCN=hydrogen cyanide
NO2=nitrogen dioxide
HCl=hydrogen chloride
Cl2=chlorine gas
O2=oxygen
TLV=threshold limit value
TWA=time weighted average
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Away from source areas, a limited number of indicator parameters may be selected
for analysis (e.g., lead, PAHs) based on the suspected hazardous substances.
Although approved sampling and laboratory methods must be used for all offsite
laboratory analysis, this approach will result in significant cost savings over a full
chemical analysis of each sample.
The USEPA recommends analysis of at least 10% of the screening samples at an
offsite laboratory to evaluate MDLs and the potential bias of screening methods
(USEPA, 1991). The samples chosen for analysis should be representative of
locations at which hazardous substances were detected by the field screening
instruments. If no contaminants were detected by the field screening instruments,
the samples submitted for laboratory analysis should be a random selection of
several media.
To meet screening objectives, USEPA quality assurance/quality control (QA/QC)
objective level 1 (QA1) is appropriate (USEPA, 1991). The QA1 objective applies
when a large amount of data are needed quickly and relatively inexpensively, or
when preliminary screening data is not required to be chemical or concentration
specific. QA1 requirements are used with data from field analytical screening
methods to prepare a quick, preliminary assessment of site contamination.
Examples of QA1 objectives include:
!
!
!
!
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The scope of work should define the methods that will be used to conduct the
investigation (a geophysical survey, leachate sampling, test pits, soil borings,
monitoring wells, etc.); the media that will be sampled (soil, groundwater, sediment);
the sampling locations and quantities; and the analytical parameters for laboratory
analysis. Detailed information on the application of these technologies is provided
in subsequent parts of this chapter.
5.4.2 PREPARATION OF A WORK PLAN DOCUMENT
A formal work plan document should be developed and should include: 1.) the
scope of the investigation; 2.) investigation methods; 3.) sampling locations; 4.)
analytical parameters; 5.) quality assurance procedures, 6.) a cost estimate; 7.) the
project schedule; and 8.) project deliverables.
The work plan document should identify field and management personnel, and their
duties and responsibilities. However, it should be remembered that, while it is
essential to have a well-defined plan, a good scope of work is flexible and may be
revised during the investigation, if appropriate.
5.4.3 PREPARATION FOR INITIAL SITE INVESTIGATION
Prior to conducting the site investigation, several preparatory steps, discussed
below, must be undertaken. They are essential to the success of the investigation
and should be considered carefully before commencing field activities.
5.4.3.1 Obtaining Site Access
In order to conduct field activities, it will be necessary to obtain site access from all
affected property owners. This may include adjacent property owners, if access to
the site affects adjacent sites. Due to potential legal issues, it is recommended that
written permission be obtained from each affected property owner. An example of
a typical access agreement is presented in Appendix C.
5.4.3.2 Obtaining Utility Clearance
The locations of aboveground and underground utility corridors should be
determined using several sources of information.
These sources can be
summarized as follows:
! Site Inspection: Visual inspection of the site may reveal sewer lines and other
buried utilities, and above ground power lines that may interfere with field
activities (i.e., drill rig)
! Utility Companies: Water, electric, and gas companies will provide detailed
information on locations of buried utilities.
! Current Site Owner(s): Blueprints or other detailed site diagrams, current
and historical, may be available from the current site owner(s).
! Miss Dig Utility Alert: In Michigan, a utility locating service known as Miss
Dig Utility Alert (800-482-7171) will mark all the known utility lines for a site.
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!
!
!
!
Laboratory SOPs are obtained from the laboratory selected to perform the analysis,
and usually are based on published procedures from sources such as USEPA or the
American Society for Testing and Materials (ASTM).
In addition, a Quality Assurance Project Plan (QAPP) should be prepared and
approved prior to the start of field investigation activities. The QAPP summarizes
the project objectives and outlines the data quality objectives for the investigation.
An example outline of a QAPP is included in Appendix E.
5.4.3.7 Preparation of a Cost Estimate
Using the scope of work, a detailed cost estimate should be prepared. The cost
estimate provides information for the site manager to prepare budgets and cost
control procedures. A detailed cost estimate should include costs for the following
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items:
!
!
!
!
!
!
This section focuses specifically on the use of statistical methods in the selection
of sampling locations from which the samples will be subjected to trace chemical
analysis. The choice of the most appropriate sampling approach is important; the
methods
include judgmental, random, stratified random, systematic grid,
systematic random, search, and transect sampling. A sampling plan may combine
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two or more of these approaches. Table 5.2 summarizes several types of statistical
sampling designs.
This section is not intended to be an exhaustive treatment of this exceedingly
complex topic. Many important areas have not been included, namely determining
the number of sampling locations, specifying the specific location of samples, and
procedures for detecting outliers. During the planning stage of an investigation it
is crucial to involve a qualified statistician so that appropriate statistical methods
are selected.
5.6.1.1 Judgmental Sampling
Judgmental sampling is the subjective selection of sampling locations at a site and
is typically based on: 1.) historical information; 2.) visual inspection; and 3.) the
professional judgement of the sampling team. Judgmental sampling is conducted
to identify contaminants present at areas having the highest concentrations (i.e.,
worst-case conditions). It has no randomization associated with the sampling
strategy, precluding any statistical interpretation of the sampling results.
5.6.1.2 Random Sampling
Random sampling is the arbitrary collection of samples within defined boundaries
of the area of concern. Random sample locations are selected using a random
procedure (e.g., using a random number table). The arbitrary selection of sampling
points requires each sampling point to be selected independent of the location of all
other points, and results in all locations within the area of concern having an equal
chance of being selected. This randomization is necessary in order to maintain
statistical validity.
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Table 5.2
Summary of Sampling Designs
TYPE OF SAMPLING
DESIGN
Haphazard sampling
Judgmental sampling
Multistage sampling
Cluster sampling
Systematic sampling
Search sampling
Because most approaches assume that the site is homogeneous with respect to the
parameters being evaluated (i.e., the contamination does not contain major patterns
or trends) other methods must be considered. The higher the degree of
heterogeneity, the less the random sampling approach will adequately characterize
true conditions at the site. Therefore, since hazardous waste sites are very rarely
homogeneous, other statistical sampling approaches may provide more suitable
means of subdividing the site into homogeneous areas, and thus would be more
appropriate than random sampling. Figure 5.2 presents an example of a random
sampling design.
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Figure 5-4
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10%
0.97
20%
0.95
30%
0.92
40%
0.88
50%
0.85
20%
30%
40%
50%
60%
70%
80%
90%
100%
0.95
0.88
0.92
0.85
0.83
0.87
0.78
0.75
0.85
0.80
0.71
0.77
80%
0.75
0.62
90%
0.72
100%
0.70
0.55
0.45
0.56
0.35
0.54
0.75
0.72
0.45
0.66
0.0
0.0
0.21
0.0
0.0
0.06
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.04
0.0
0.0
0.0
0.08
0.18
0.0
0.03
0.0
0.1.0
0.24
0.37
0.07
0.12
0.08
0.06
0.03
0.0
0.30
0.45
0.15
0.29
0.50
0.08
0.12
0.18
0.32
0.51
0.21
0.27
0.27
0.38
0.54
0.41
0.38
0.44
0.58
0.77
0.50
0.54
0.63
0.80
70%
0.66
0.65
0.69
0.82
60%
0.72
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
BLOCK GRID
S
S=length of short axis
0.97
0.95
TRIANGULAR GRID
Example 1: Suppose the block grid method is chosen with a grid spacing of 25
feet. The decision maker is willing to accept a 5 percent chance of missing an
elliptical hot spot. Using Table 5.3, there would be a 95 percent probability of
locating an elliptical hot spot with L equal to 80 percent of the grid spacing chosen
and S equal to 50 percent of the grid spacing chosen. Therefore, the smallest
elliptical hot spot which can be located would have a long axis L= 0.80 x 25ft = 20ft,
and a short axis S = 0.50 x 25ft. = 12.5ft.
Example 2: If 1.) a triangular grid with a 25 foot grid spacing is chosen, 2.) the
approximate shape of the hot spot is known, 3.) L is approximately 15 feet or 60
percent of the grid spacing and 4.) S is approximately 10 feet or 40 percent of the
grid spacing, then, there is approximately a 15 percent chance of missing a hot spot
of this size and shape. Figure 5-6 presents an example of a search sampling design.
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Figure 5-6
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Figure 5-7
JUDGMENTAL RANDOM
STRATIFIED
RANDOM
IDENTIFY
SOURCES
2A
DELINEATE THE
EXTENT OF
CONTAMINATION
2B
CONFIRM
CLEANUP
1C
1D
Notes:
1--Preferred Approach
A--Should be used with field analytical screening
2--Acceptable Approach
B--Preferred only where known trends are present
3--Moderately Acceptable Approach C--Allows for statistical support of clean up verification if sampling over entire site
4--Least Acceptable Approach
D--May be effective with composting technique if site is presumed to be clean
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5.7
THE GEOPHYSICAL SURVEY
Geophysical surveys include a wide range of physical measurements and can
assist in: 1.) defining hydrogeologic conditions; 2.) selecting sampling locations;
3.) identifying the locations of buried waste and underground storage tanks; 4.)
estimating quantities of waste; and 5.) tracing conductive plumes (Benson et. al.
1988). The methods are non-invasive and usually lead to increased project
efficiency and cost effectiveness. These physical measurements are based on the
physics of electromagnetic fields, electric current flow, magnetics, seismic wave
propagation, gravitational attraction, and radioactive properties.
! Natural Site Conditions - Terrain and ground cover will influence the rate
of collection and geophysical sampling locations. In some instances, grid
lines will need to be physically cleared before the survey can commence.
Soil type(s) and depths to groundwater need to be considered when selecting
the appropriate geophysical method. Drilling records will aid in interpreting
the survey results.
! Cultural Features - Cultural features (i.e., fencing, power lines, and surface
metal) can create undesirable noise (i.e., interference) in the geophysical
measurements. These cultural features can interfere with electric,
electromagnetic, and magnetic measurements. Vibrations from busy
roadways, industrial complexes, or mining operations can also interfere
with seismic data collection. The presence of these features should be
considered when assessing the viability of data collection.
! Survey Objectives - The objectives of the geophysical survey should be
clearly defined and may include: 1.) defining hydrogeologic conditions, 2.)
defining the extent of fill, 3.) locating buried metallic objects (i.e., drums or
underground storage tanks), or 4.) locating trenches. Defining the
objectives of the survey is vital to a properly designed survey.
! Waste Type(s) - Waste or fill material present in the survey area will
influence selection of the geophysical method. Some waste types may not
be detected by the proposed geophysical method. Other waste types can
interfere with the assessment of hydrogeologic conditions at the site.
! Survey Grid Size and Positioning - The survey grid must be accurately
laid out and linked to permanent features so that locations of interest or
concern can be relocated after the survey has been completed. The line and
station spacing of the grid will depend on the target size, estimated depth
of buried material, contrast in physical properties between the target and
host material, and the selected geophysical method. The orientation of the
survey grid relative to the target should also be considered.
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magnitude with good electrical conductors (i.e., buried metals). Measuring the
in-phase signal, therefore, identifies the presence of buried metals. The EM
technique is an excellent reconnaissance tool for tracking certain contaminant
plumes, locating buried metal, detecting pit and trench locations of bulk waste,
as well as locating buried metallic utility lines.
The EM method does not require direct ground contact, therefore, data acquisition
is rapid. The EM instrument is carried over the site as data is recorded. A one-ortwo person field crew is usually sufficient to conduct the field survey. EM survey
results are typically portrayed as profile lines or contour maps.
Table 5.5
Comparison of Five Geophysical Survey Methods
METHOD
USES
1.
Electromagnetic
2.
3.
4.
Magnetic
1.
2.
GPR
1.
2.
3.
4.
5.
DC Resistivity
1.
2.
Seismic
1.
2.
3.
PROS
CONS
Defining hydrogeologic
conditions
Locating buried waste
Tracking conductive
plumes
Locating buried metallic
objects
1.
2.
3.
1.
Mapping
near
surface
stratigraphy
Locating trenches
Locating buried metallic
objects
Underground utility
locations
Location of voids
1.
2.
High resolution
Picture Like Graphic
Display
1.
2.
Defining
hydrogeologic
conditions
Tracing conductive plumes
1.
2.
1.
Mapping stratigraphy
Mapping
water
table
(refraction technique)
Locat ing
lat e r al
discontinuities (reflection
technique)
1.
2.
4.
2.
3.
4.
1.
1.
Good resolution
Good depth of exploration
2.
3.
2.
2.
1.
2.
3.
5.7.1.2 Magnetics
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properties between the metal and surrounding soils. GPR has also been used to
map non-aqueous phase liquids floating on the water table. Data acquisition is
conducted by dragging an antenna across the ground. A two person crew is
typically required.
5.7.1.4
DC Resistivity
DC Resistivity is the direct current (DC) resistivity method which has been
developed to determine lateral and vertical variations in the earths resistivity.
Resistivity surveys are conducted by inserting electrodes into the earth. DC or low
frequency alternating current (AC) is injected into the earth through electrodes.
Other electrodes measure the potential difference (voltage). The potential
measured is a function of the location and geometry of the source electrodes
relative to the potential electrodes.
Conduction of electric current is primarily through water in the pore spaces and
by clay minerals in the soil and rock. Factors controlling earth resistivity are: 1.)
the porosity of the medium; 2.) the amount of pore water; 3.) the concentration of
dissolved solids in the pore water, and; 4.) the clay content of the soil or rock.
Cultural features that are conductors such as metal fencing, railroad tracks,
buried metal pipelines, and heavily salted roadways, will alter the measured
resistivity values and should be avoided.
There are two main types of resistivity surveys: sounding and profiling. A
sounding survey (also known as electrical drilling) has the electrode array expand
over a common center point. A sounding survey delineates depth and thickness
of layers of variable resistivity. The resistivity sounding method is intended for
use in uniformly horizontal-layered geologic conditions, but can yield useful
information in complex geological environments. A profiling survey (also known
as electric trenching) maintains a constant electrode spacing as the array moves
laterally across the site. Profiling surveys are performed when mapping lateral
variations in the subsurface or the boundaries of a conductive plume.
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dependent upon soil composition, the depth to groundwater, and the properties
of the contaminant of concern. Common uses of soil gas surveys are:
!
!
!
!
!
!
5.8.1
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Soil air permeability is greatest in dry, coarse grained, high porosity soils with a
low organic content. Soils with low air permeabilities (clays and silts) will
significantly increase the difficulty of sample acquisition.
5.8.2 SOIL VAPOR SURVEY SAMPLING STRATEGIES
Soil vapor sampling locations can be selected by the judgment, statistical, or
hybrid strategies. The sampling depth interval may depend upon the water table
depth. Soil vapor survey design should take into account the following:
!
!
!
!
!
!
!
!
!
Sample location,
Date and time,
Pre-sampling instrument response,
Sample purge volume and flow rate,
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! Difficulty in purging,
! Presence of water in the probe, and
! Peak instrument response during purging.
5.8.4 SOIL VAPOR SAMPLE ANALYSIS
Soil vapor surveys can generate either qualitative or quantitative data depending
on the method of analysis selected. The sample analysis method selected must
be capable of detecting the contaminants of concern or their break down products
at the desired detection levels. Common field analytical instruments include:
!
!
!
!
!
!
!
Photoionization Detector,
Flame Ionization Detector,
Field Gas Chromatograph,
Combustible Gas Indicator,
Detector Tubes,
Oxygen Meter, and
Carbon Dioxide Meter.
Table 5.1 in this guideline contains detailed information about these field
analytical instruments. Soil vapor samples may also be collected in bags,
syringes, or canisters, and sent to an off-site laboratory for analysis. The
concentration of contaminants in soil vapor cannot be correlated with a volume
or concentration of contaminants in soil or ground-water because it is an indirect
measurement. Therefore, the results should be used as a screening tool to assist
in the evaluation of an area requiring further investigation.
Use of an oxygen meter or carbon dioxide meter serves a dual purpose. Typically,
oxygen levels are slightly depressed and carbon dioxide levels are slightly elevated
in soil vapor relative to ambient air (21% O2 and 0.5 % CO
2 in ambient air).
Vapors entering the probing rod may be from leaks or ambient air migrating down
the boring. Including an oxygen and/or carbon dioxide survey with the VOC
screening can help distinguish between ambient air and soil vapors. At locations
where aerobic biodegradation is occurring, oxygen levels will be greatly depressed
and carbon dioxide will be highly elevated.
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cover (i.e., pavement, buildings, vegetation), and the current or future use of the
property. In addition, surface soil sampling is typically focused on locations where
groundwater seeps are observed, stains or discoloration are present, or stressed
vegetation is observed.
A combined judgmental and statistical approach is often taken. However, if a
presumptive remedy such as a cap is being considered, the amount of surface soil
sampling needed may be very limited.
For the purposes of this guidance document, a surface soil sample is any sample
that can be gathered using sampling equipment such as a spoon, shovel, trowel
or spade. Surface soil is typically described as being from the surface to six
inches below ground surface (bgs). Surface soil samples should be tested for the
following parameters, at a minimum.
! Priority Pollutant Metals (13 elements),
! Polynuclear Aromatic Hydrocarbons (EPA Method 8270), and
! Polychlorinated Biphenyls (EPA Method 8080).
Because volatile organic compounds would not be expected to persist in the top
six inches in soil, this parameter is not typically tested for in surface soil, unless
existing data or knowledge infer that they may be present.
5.11 SURFACE WATER AND SEDIMENT SAMPLE COLLECTION
Because surface water and sediment may be affected by migrating contaminants
originating within the site, surface water and sediment samples should be
collected if there are surface water bodies (i.e., ponds, streams, ditches, lakes)
within the perimeter of the site or immediately adjacent to it.
5.11.1
SURFACE WATER SAMPLING
Conditions that may make surface water sampling necessary include:
! A river channel or former river channel cuts through the area of concern.
! A river channel or other surface water body is adjacent to the area of
concern and groundwater is suspected of being contaminated.
! Leachate seeps are observed at the riverbank or the margin of another type
of surface water body.
! Surface drainage passes over the area of concern and leads to a surface
water body.
Methods for surface water sampling vary from simple grab sampling using
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suitable sample containers to more complex methods that enable the investigators
to collect samples from discrete depth intervals. Several types of discrete interval
samplers are available, including Kemmerer bottles and Alpha and Beta bottles.
Surface water samples are typically collected up gradient and down gradient of
any known groundwater/drainage seeps. It is critical to identify other possible up
gradient or historical sources of contamination (i.e., industrial or municipal
sources). If intermittent streams are present on or adjacent to the site, it may be
necessary to conduct stream sampling during or immediately following a heavy
rainfall. In addition, on-site ponds or adjacent lakes may be impacted by surface
water runoff and/or groundwater seeps from the dump site. It is also possible
that contaminated groundwater could recharge to nearby ponds or lakes. Surface
water samples should be tested for the following parameters, at a minimum.
! Priority Pollutant Metals (13 elements), and
! Surface Water Quality Parameters (see section 5.15.4 for a list of surface
water quality parameters).
5.11.2 SEDIMENT SAMPLING
Sediment sampling may be necessary when any of the following conditions are
observed:
!
!
!
Sediment sampling methods generally include two categories: grab sampling and
core sampling. Grab samplers, such as Ponar and Ekman dredges, are useful for
collecting samples of surface sediments only. While these are generally easy to
collect, they are only useful for characterizing relatively recent impacts reflected
in the youngest sediments.
Core samplers are required for collecting deeper sediments when historical
deposition data is needed. There are a variety of types available, including vibrocorers, piston corers, and gravity corers.
As with surface water samples, sediment samples are typically collected up
gradient and down gradient of any known groundwater/drainage seeps. The other
factors affecting the selection of surface water sampling locations pertain to
sediment sampling as well. Sediment samples should be tested for the following
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parameters, at a minimum.
!
!
!
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The excavation of each test pit should be conducted slowly and with utmost care
for safety. Site activities should be conducted in accordance with a health and
safety plan prepared for activities at each specific site. A complete description and
field sketch of the test pit should be recorded and should include the following
information:
!
!
!
!
!
!
!
Location,
Approximate surface elevation,
Test pit dimensions,
Soil descriptions (refer to soil descriptions below),
Presence or absence of groundwater,
Results of air monitoring or soil sampling screening results, and
A detailed description of the type(s) and distribution of waste(s).
All test pits should be abandoned in a manner that prevents them from acting as
future conduits or infiltration points for contaminated surface water. As a general
rule, the test pit should be backfilled with material that is at least an order of
magnitude less permeable than the material that was excavated. Typically, a
mixture of soil (i.e., the material that was excavated) and bentonite is used for
backfilling. If significant amounts of waste material or hazardous substances (e.
g., drums containing liquid waste) are encountered during the excavation of the
test pits, disposal and/or treatment of excavated material at a licensed facility will
be required.
The advantages and disadvantages of excavating test pits are outlined in Table
5.6. To minimize health and safety concerns during the excavation of test pits and
to ensure a proper surface seal following completion of the test pit, this activity
should be specifically addressed in the health and safety plan and only
experienced personnel should conduct and direct the excavation.
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DISADVANTAGES
Cost effective
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soil borings may be required due to the size of the dump site or the presence of
several hot spots located in separate areas of the dump site.
The purpose of drilling soil borings within the interior portion of the dump is to
evaluate:
Types and distribution of waste material,
The potential presence of leachate,
Soil composition,
Cap thickness and characteristics (soil classification, grain size distribution,
density and permeability),
! The potential presence of groundwater, and
! The potential for contaminant migration.
!
!
!
!
The purpose of drilling soil borings beyond the boundary of the dump in the
natural soil layers is to evaluate:
!
!
!
!
Soil stratigraphy;
Confirmation of dump boundaries;
The potential presence of groundwater; and
The potential for contaminant migration.
The abandoned dump should be carefully evaluated before drilling the boring to
ensure that the boring is drilled at a preferred location, and potential health and
safety concerns are minimized. Site activities should be conducted in accordance
with a health and safety plan prepared for activities at each specific site.
Soil borings can be drilled using numerous methods. However, southeastern
lower Michigan is dominated by unconsolidated Pleistocene glacial and glaciallacustrine deposits that may be as thick as 400 feet. Therefore, soil borings to be
drilled at abandoned dumps within the River Rouge Watershed should be drilled
using a drill rig equipped with hollow-stem augers or with a Geoprobe.
Either method of drilling has several advantages and disadvantages. At some
sites, both methods of drilling may be used. Table 5.7 lists several advantages
and disadvantages for each drilling method.
For the purpose of minimizing the number of soil borings installed at a site,
several common scenarios can be addressed.
Table 5.8 presents
recommendations for location and minimum number of soil borings for four
common scenarios. In addition, the diagrams presented in Figure 5-8 show
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Disadvantages
Advantages
Disadvantages
Capable of installing
2-inch monitoring well
with larger diameter
filter pack
Cannot be drilled
quickly
Not capable of
installing monitoring
wells larger than 1inch in diameter; well
would not be adequate
for hydraulic testing
Higher profile
installation
procedures (i.e.,
larger vehicles and
noise levels)
Typically generates
more waste soil
that may require
special handling
and disposal if soil
is contaminated
Table 5.8
Soil Boring Recommendations for Four Scenarios
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SCENARIO
RECOMMENDATION
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Figure 5-8
Recommended Soil Boring Locations for Nine Scenarios
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Figure 5-8
Recommended Soil Boring Locations for Nine Scenarios (Continued)
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Figure 5-8
Recommended Soil Boring Locations for Nine Scenarios (Continued)
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the depths at which the lower clay unit is encountered within each recognized
geologic unit in the Rouge River -Drainage Basin.
Table 5.9
Depth to Lower Clay Unit, Rouge River Watershed
GEOLOGIC UNIT
Moraine Unit
Sandy Clay Unit
7 to 20
Sand Unit
5 to 34
10 to 30
10 to 30
Isolated Units
3 to 18
Recent
5 to 60
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SCENARIO
RECOMMENDED ABANDONMENT
PROCEDURE
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!
!
!
!
It is recommended that each soil sample collected be retained for future potential
chemical or physical testing. Sample preservation and holding times must be
observed for samples that are submitted for laboratory testing.
5.13.6 SUBSURFACE SOIL SAMPLE COLLECTION
A three-dimensional representation of the distribution of contaminants must be
developed to begin to understand the human health and ecological risk at an
abandoned dump. Therefore, subsurface soil samples should be collected and
submitted for laboratory testing to confirm and/or quantify contaminants at a site.
For soil samples collected from soil borings drilled within the interior portion of the
dump, the following minimum number of soil samples from soil borings should be
submitted for laboratory analysis:
! Where waste/fill material is encountered and ground-water is not
encountered: 1.) the worst-case fill or waste sample based on a visual
inspection and screening results, and 2.) a sample collected from beneath
the waste/fill material.
! Where waste/fill material is encountered and ground-water is also
encountered: 1.) the worst-case fill or waste sample based on a visual
inspection and screening results, and 2.) the sample collected from
immediately above the capillary fringe.
! Where waste/fill material is not encountered but groundwater is
encountered: the soil sample collected from immediately above the capillary
fringe.
! Where waste/fill material and groundwater are not encountered: the soil
sample collected from the bottom of the borehole.
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For soil borings drilled beyond the boundary of the dump, the following minimum
number of soil samples should be submitted for laboratory analysis:
! Where groundwater is encountered and contamination is not observed or
detected during inspection and screening: the soil sample collected from the
capillary fringe.
! Where groundwater is encountered and contamination is not observed or
detected during inspection and screening: the soil sample collected from the
bottom of the borehole assuming the boring is terminated beneath the zone
of saturation.
! If contamination is observed or suspected based on visual inspection or
field screening results: the soil sample that represents the worst-case
sample.
5.13.7 SOIL SAMPLE LABORATORY PARAMETERS
Soil samples should be submitted to a laboratory and tested for the following
parameters, at a minimum.
!
!
!
!
If chemicals are known to be present in soil that are not included in the above
parameter list, the test parameters should include these chemicals.
5.14 GEOTECHNICAL SAMPLING
At some sites, soil samples may be collected for geotechnical testing. Geotechnical
testing is conducted for the purpose of evaluating treatment options and evaluating
contaminant fate and transport. The geotechnical tests that may be conducted
include:
! Mositure content and dry density according to ASTM Method D2216,
! Grain size distribution according to ASTM Method D422, and,
! Coefficient of permeability using ASTM Method D5084 (falling head
method).
Soil samples collected for geotechnical testing should be collected in Shelby tubes.
Because samples cannot be visually inspected in Shelby tubes, it is necessary to
drill specific soil borings for geotechnical testing only. Soil borings for geotechnical
testing should be drilled after initial soil borings are drilled so that optimal
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Table 5.11
Advantages and Disadvantages of Monitoring Well Installation Methods
GEOPROBE MONITORING WELLS
Advantages
Disadvantages
Monitoring well
may be 2-inches
in diameter
Can conduct
hydrologic testing
Lower profile
installation
procedures (i.e.,
smaller vehicles and
noise levels)
Typically generates
less waste soil that
may require special
handling or disposal if
soil is contaminated
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Table 5.12
Advantages and Disadvantages of Permanent
and Temporary Monitoring Wells
PERMANENT MONITORING
TEMPORARY MONITORING WELLS
WELLS
Advantages
Disadvantages Advantages
Disadvantages
Available for sampling
and monitoring for
several years
More expensive
Less expensive
Must be resurveyed to
ensure accuracy
Could potentially be
used for remediation
extraction well
Typically cannot be
used for remediation
extraction well
Less susceptible to
environmental
disturbance (e.g.,
freeze and thaw cycles)
More susceptible to
environmental
disturbance (e.g.,
freeze and thaw cycles)
Could be more
susceptible to
tampering
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!
!
!
!
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Chemical compounds that are capable of sinking through the water column (i.e.,
dense nonaqueous phase liquids [DNAPLs]) may be present but are not expected
to be present at high concentrations in deeper portions of aquifers present with the
Rouge River Watershed for the following reasons:
! Saturated zones within the Watershed are generally thin; and
! The sediments within the zone of saturation in the sand unit coarsen
upward, which represents a stratigraphic control on the potential downward
migration of DNAPL compounds that may be present within the unit (Rogers
1996)
An exception may be aquifers within the moraine unit (including subunits) located
in the western and northern portions of the Watershed. Aquifers within the
moraine unit may be thick (greater than 25 feet) and may not exhibit a coarsening
upward sequence. Therefore, at abandoned dump sites located within the moraine
unit, it may be necessary to install nested wells or another acceptable method to
gather data on the vertical distribution of hazardous substances or the hydrology
of thick aquifers.
If installation of fully penetrating monitoring wells is necessary, the location of the
bentonite seal or plug that is placed above the filter pack should not be placed at
a distance greater than 1.5 to 2.0 feet above the well screen because groundwater
located above the screen and below the bentonite seal can enter the monitoring
well during development and sampling. Therefore, the effective length of the well
is equal to the length of the screen plus the distance between the top of the well
screen and the bottom of the bentonite plug. This effective length is termed the
effective well screen length.
When evaluating groundwater chemistry or hydraulic characteristics of a relatively
thick aquifer (saturated thickness generally greater than 20 feet), installation of
nested wells should be considered. Nested monitoring wells are multiple wells
installed at the same location that are screened at different vertical locations within
the zone of saturation.
Therefore, it is anticipated that the only geologic unit within the watershed that
may require the installation of nested wells is the moraine unit, because aquifers
within the moraine unit:
! May be thicker than 20 feet;
! Are not well understood hydrologically, and
! Are sources of potable water.
5.15.2
MONITORING WELL DEVELOPMENT
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in groundwater within the monitoring well to a depth not to exceed the top of the
bailer. This can be detected by noting the buoyancy force on the bailer once the
bailer is completely submerged. This minimizes the suspension of fine-grained
sediments that may accumulate on the bottom of the monitoring well. Employing
sampling techniques that reduce turbidity within the aquifer will increase sample
quality (Puls and Barcelona, 1996)
A groundwater sample can be collected after: 1.) purging the monitoring well by
evacuating at least three times the initial volume of groundwater in the well; 2.)
once purging at least three casing volumes of groundwater from the well is
completed, monitoring the groundwaters temperature, pH, and conductivity until
at least two of the three parameters have stabilized, or; 3.) purging the well dry.
Once a sufficient quantity of groundwater seeps into the monitoring well after
purging, a sample can be collected using a Teflon bailer. When sampling
groundwater for VOCs, it is recommended that the bailer be equipped with a lowflow Teflon VOC sampler.
Purge water collected from the monitoring wells should be contained in MDOT
approved 55-gallon drums until analytical results are obtained. The drums should
be placed at a secured location on-site and shall be labeled with: 1.) the monitoring
well identification code; 2.) the date sampled, and; 3.) special handling
instructions, until appropriate disposal alternatives are evaluated.
If no
contaminants are detected in the groundwater samples, the purge water can be
disposed of in a secure manner. If contaminants are detected in one or more
groundwater samples, then purge water shall be properly characterized and
disposed of at a licensed facility or can be returned to the well provided there is no
likelihood that contamination will spread.
5.15.4
GROUNDWATER SAMPLE LABORATORY PARAMETERS
Groundwater samples should be submitted to a laboratory and tested for the
following parameters, at a minimum.
! Priority Pollutant Metals (13 elements)
! Volatile Organic Compounds (EPA Method 8260)
! Surface Water Quality Parameters
In areas where groundwater may be used for drinking water analytical methods
must may be required to attain a greater sensitivity (lower MCL). In Michigan,
MDEQs Operational Memorandum #6 provides guidance on analytical methods
and detection limits.
Surface water quality parameters may include nitrate, nitrite, ammonia, total
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!
!
!
!
!
!
!
!
Hydrogeology
! Regional geological and hydrogeological setting
! Site geology and hydrogeology
! Groundwater flow direction and estimated rate
! Geological cross-sectional maps
! Soil boring logs and well construction diagrams and logs
Analytical Results
! Soil analytical results
! Groundwater analytical results
! Analytical results from other media (i.e., leachate surface water, sediment
! Tables summarizing analytical results
Nature and Extent of Contamination
! Soil
! Groundwater
! Maps depicting extent of hazardous substances in each affected media
! Sources of contamination
Conclusions and Recommendations
5.17 REFERENCES
Bensen, R., R. Glaccum, and M. Noel, 1988. Geophysical Techniques for Sensing
Buried Wastes and Waste Migration. National Water Well Association. Dublin, Ohio.
p.236
Gibbons, R.D. 1994. Statistical Methods for Groundwater Monitoring. John Wiley
& Sons, Inc. New York, New York.
Gilbert, R.O. 1987. Statistical Methods for Environmental Pollution Monitoring. Van
Nostrand Reinhold, New York, New York.
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American Chemical
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USEPA. 1995a. Test methods for Evaluating Solid Waste, Physical Chemical
Methods. United States Environmental Protection Agency Publication SW-846.
USEPA. 1995b. Guidelines Establishing Test Methods and Procedures for the
Analysis of Pollutants. United States Environmental Protection Agency 600 Series.
40 CFR 136
USEPA. 1986. RCRA Groundwater Monitoring Technical Enforcement Guidance
Document. Office of Solid Waste and Emergency Response. OSWER-9950.1.
Washington, D. C. 317p.
USEPA. 1989. Guidance Document on the Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities. Interim Final Guidance. Office of Solid Waste,
Waste Management Division. Washington, D. C.
USEPA, 1991. Removal Program Representative Sampling Guidance, Volume 1 - Soil.
OSWER Publication 9360.4-10.
USEPA, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA
Facilities. Addendum to Interim Final Guidance. Office of Solid Waste, Waste
Management Division. Washington, D. C.
Zohdy, A. A., G.P. Eeaton, and D. R. Mabey. 1974. Application of Surface
Geophysics to Ground-Water Investigations. Techniques of Water-Resources
Investigations of the United State Geological Survey, Chapter D1. p.116
USEPA. 1990. A Guide to Selecting Superfund Remedial Actions. Office of Solid
Waste and Emergency Response. OSWER-9355.0-27FS. Washington, D.C., 6p.
USEPA. 1991a. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites.
Office of
Emergency and Remedial Response.
EPA/540/P-91/001. Washington, D.C., 294p.
USEPA. 1993. Remediation Technologies Screening Matrix and Reference Guide.
Office of Solid Waste and Emergency Response. EPA 542-B-93-005. Washington,
D. C. 141p.
USEPA. 1994. Physical/Chemical Treatment Technology Resource Guide. Office
of Solid Waste and Emergency Response, Technology Innovation Office. EPA 542B-94-008. 43p.
USEPA. 1994. GroundWater Treatment Technology Resource Guide. Office of Solid
Guidelines for Closure of
Abandoned Dump Sites
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Waste and Emergency Response, Technology Innovation Office. EPA 542-B-94009. 29p
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The work plan should include the selected methods for investigation (i.e., test pits,
soil borings, monitoring wells), media to be sampled (i.e., soil, groundwater,
sediment), sampling locations and quantities, and analytical parameters for
laboratory testing. The work plan should maintain flexibility and should be
revised during the investigation, if necessary.
Statistical analysis may be useful at several stages of a site investigation. The
application and suitability of using statistical methods should be evaluated.
Detailed information on the application of statistical methods is found in Chapter
5.
If necessary, revisions should be made to the field and management personnel
list, health and safety plan, FSPs, and SOPs.
6.5 PREPARATION FOR FIELD WORK
This step includes obtaining site access and utility clearance, preparation of field
equipment and supplies, mobilization, and scheduling field activities. Details are
provided in Section 4.4.3, above.
6.6 CONDUCTING THE FIELD INVESTIGATION
The investigation will be conducted according to the work plan. However, as
additional site information and data are collected, the project manager and other
technical staff should continually compare the scope of work to the objectives of
the investigation and reduce or expand the scope if site data clearly indicate such
a change is warranted. When the scope of work is revised, the project manager
must submit the revised scope and workplan to the site manager. See Section
4.4, above, for additional details.
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example, a landfill with the following characteristics would not require fate and
transport modeling:
! The landfill is old (over 20 years) and site investigation results indicate there
has been little, if any, leachate generation in the landfill at any time of the
year over a period of several years.
! The landfill has a clay cap that is functioning well. As a result, there is no
foreseeable change in leachate generation characteristics nor is there
significant probability of leachate escape through potential surface seeps.
! The concentration of contaminants in the landfill leachate is below riskbased criteria.
! The landfill is situated in lacustrine clays with very low hydraulic
conductivity and limited secondary porosity. There are no interbedded
lenses of sand or other material for transport of contaminants.
At the opposite extreme, a landfill in a sandy aquifer immediately adjacent to or
near (within 2 miles) the Rouge River with a large volume of leachate would
require a detailed study to evaluate whether there is a risk of exposure and, if so,
to what extent. It is likely that many cases will fall somewhere in between these
two scenarios.
6.7.2 MODEL PREPARATION
This is the first stage of model development. It involves evaluation of the existing
site information to determine the type of model necessary to simulate contaminant
fate and migration. Typically, relatively simple analytical models are used to
simulate fate and transport characteristics during this stage to evaluate the effects
of such limiting parameters as groundwater flow, contaminant retardation, and
general source conditions.
Often, the need for additional information to develop a more accurate model is
identified in this stage, in which case, additional investigation may be needed.
When the supplemental data is acquired, more detailed simulations are
conducted. This iterative modeling and investigation process is repeated until a
reliable site model is produced.
6.7.3 CALIBRATION
In this stage, simulations of fate and transport are performed and compared to the
observed field conditions. This can be conducted using the simple model
described in the preparation stage if it is determined that this model is adequate
to perform the exposure assessment. In other cases, additional site information
and/or a more complex model are used to perform the calibration simulations.
Calibration simulations are performed using the available site information and,
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migration from landfills (Mulkey, et al., 1992) and can save a significant amount
of time and effort without sacrificing confidence in model results. For example,
Mulkey, et al., (1992) used the chemicals listed in the left hand column of the
following table to simulate the fate and migration of contaminants with similar
characteristics as shown in the right hand column of the following table.
Table 6.1
Chemical-Specific Fate and Transport Parameters
CHEMICAL
PARAMETER
CHARACTERISTICS
Toluene
2,3,4,6-Tetrachlorophenol (TeCP)
Toxaphene
1,2-Dichlorethane (DCA)
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Except for the first pattern (constant leachate concentrations), each pattern of
leachate generation involves some type of temporal change in the amount and/or
concentration of leachate produced by a landfill. Models have been developed to
simulate these patterns (Mulkey, et al., 1992). However, collecting sufficient
monitoring data to adequately define these types of source patterns can take a
significant amount of time and effort. In cases where it is determined these short
term temporal changes will significantly affect the risk of exposure, it will be
necessary to collect the data or assume a worst case scenario.
In some cases, initial model runs and sensitivity analysis may indicate that the
temporal variations in leachate generation will not affect the exposure scenario.
This, in fact, has been demonstrated in conceptual modeling already. For
example, Mulkey, et al., (1992) discovered that modeling temporal changes in
leachate generation did not produce results that were significantly different from
modeling constant source conditions when there was a significant amount of time
involved in contaminant migration (> 20 years). When the time required for
contaminant migration to a point of exposure is short relative to the temporal
changes in the leachate generation cycle, it may be necessary to model the
temporal changes in leachate generation to adequately estimate the concentration
of leachate at a given point of exposure.
The chances of this latter condition occurring are greatest when a landfill is
situated in a highly transmissive aquifer and is very close to the river. The
potential need for modeling temporal changes in leachate generation is further
increased if the landfill is in an early stage in its leachate generation life cycle (i.e.,
it is in a stage where it is most likely to generate leachate with the highest
concentration of contaminants in its life cycle).
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Conversely, the need for modeling temporal changes in landfill leachate generation
are greatly reduced, or possibly eliminated, if the landfill is old, distant from the
river, is located in an aquifer with low transmissivity, and its leachate contains
only chemicals that are very sorptive and readily undergo decay.
6.8 MODEL SELECTION AND USE
Models are simply tools to perform quantitative assessments with a set of input
parameters. Numerous models have been developed with a wide range of
capabilities. It is very likely that models are available that can perform the types
of simulations necessary to model the fate and transport scenarios associated with
the waste disposal sites near the Rouge River. The particular model chosen for
a given site should be selected based on the specific modeling needs. Generally,
however, the models should be selected based on the following criteria:
! The model should be as simple as possible (especially during the
preparation stage of model development)
! The code of the selected model should be well documented.
! The model should have been validated through calibration with field studies
and/or modeled results from models that have been through a generally
accepted validation process.
! If possible, models should be used that are widely accepted by regulatory
agencies and the professional community.
There are two types of model generally used: analytical models and numerical
models. Numerical models can be further subdivided into finite difference models
and finite element models. Analytical models are simple to use and are capable
of simulating contaminant fate and transport only under simplified conditions.
Numerical models are capable of simulating very complex conditions in two or
three dimensions, although recent software developments have made numerical
models easier to use.
Depending on site conditions, either type of model may be adequate for
conducting an exposure assessment. When numerical models are used, however,
it is often best to keep them as simple as possible despite their complex
capabilities. This reduces the chance of error in model simulations and can help
clarify the limiting factors in contaminant migration, increasing confidence in the
model results, an important consideration in performing exposure assessments.
It is beyond the scope of this guidance document to summarize all the models that
are available that may be appropriate for conducting exposure assessments on
waste sites near the Rouge River. However, numerous models that meet these
criteria are summarized in Mulkey, et al., (1992).
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Using this and any other necessary information, the MDEQ will calculate the
extent to which flow in the surface water body dilutes the contaminant plume as
it enters the surface water body. Based on this information, the MDEQ will
calculate a monthly average and daily maximum allowable concentration for the
contaminants of concern at the GSI compliance points (i.e., a mixing zone-based
GSI criteria will be established).
Obviously, the extent to which the surface water body dilutes the venting
groundwater plume will be a key factor (and perhaps the major factor) in
calculating a mixing zone-based GSI criteria. As a general guidance, the MDEQ
states the following:
! Dilution Ratio <10 - For dilution ratios less than 10, the mixing zone-based
GSI criteria may be up to two times the generic GSI criteria. An accurate
calculation of the discharge rate of the venting groundwater plume will be
critical in making mixing zone determinations.
! Dilution Ratio 10-100 - Sites with a dilution ratio between 10 and 100 are
in a transitional range for calculating mixing zone-based GSI criteria. The
mixing zone-based GSI criteria may be in the range of two to 20 times the
generic GSI criteria. An accurate calculation of the discharge rate of the
venting groundwater plume will be critical in making mixing zone
determinations.
! Dilution Ratio 100-400 - Mixing zone-based GSI criteria may be 20 to 45
times the generic GSI criteria when the dilution ratio is 100-400. It is
important to calculate the discharge rate of venting groundwater plume to
the surface water body. In addition, contaminant concentrations which
exceed 100 times the generic GSI criteria will likely require groundwater
treatment or control. This is because the dilution ratio will not affect the
daily maximum concentration criteria which must not be exceeded in the
discharge of the venting groundwater plume.
! Dilution Ratio >400 - Mixing zone-based GSI criteria for situations where
dilution ratios exceed 400 generally will not be greater that 45 times the
generic GSI criteria. Once again, this is because the daily maximum
limitations are likely to become a controlling factor in the acceptable
discharge concentration of the contaminant plume. For this same reason,
contaminant concentrations which exceed 100 times the generic GSI criteria
will likely require treatment.
Although an estimate can be developed for the dilution ratio of a mixing zone,
MDEQ will typically make the determination and/or approval as to the
applicability and details of a mixing zone at a site unless there is a circumstance
where Part 201 requirements are not applicable.
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In addition to the dilution factor, the level of precision and certainty in models
that predict the quantity and concentration of contaminant discharges to a
surface water body will be key factors in calculating the mixing zone-based GSI
criteria, emphasizing the need for fate and transport models that simulate field
conditions with a high degree of confidence.
6.10 SPECIAL INVESTIGATION REQUIREMENTS
Investigation methods for defining most geological and hydrogeological conditions
that can affect contaminant migration have been described in Chapter 5. In some
cases, additional effort may be necessary to define important variables in
developing models for exposure assessments. For example, a pump test may be
needed to accurately define the transmissivity of an aquifer if initial evaluations
and sensitivity analysis so indicate. In some cases, the fraction of organic carbon,
groundwater pH, the presence or absence of ligands, or the quantification of other
parameters may also be important for calculating the migration rate of certain
contaminants. The need for this information will be recognized on a site specific
basis, often as a result of the preparation and calibration stages of the modeling
process.
6.11 FATE AND TRANSPORT MODELING IN GROUNDWATER
The study of the fate and transport of contaminants in the subsurface
environment involves the evaluation and/or prediction of contaminant behavior
in unsaturated and saturated media within a specific geologic environment. The
accurate prediction of the fate and transport of a specific contaminant at a site
requires a thorough understanding of the physical chemistry of the hazardous
substances and the geologic features of the environment into which the hazardous
substances are released.
Of these two fundamental factors, the geologic environment into which the
contaminant is released is typically the least understood. Therefore, to develop
a generic process for investigation and closure of sites of environmental
contamination within a region, it is crucial to understand the fate and transport
of contaminants on a regional basis and at each specific site. A discussion of the
behavior of contaminants in the Rouge River Watershed is found below in Section
6.12.
Predicting the fate and transport of the contaminants may be necessary to
evaluate the potential for human or ecological exposure when groundwater
contamination is present at a site. This is important when the underlying
groundwater discharges to a surface water body or to the ground surface through
springs or seeps. In these circumstances, groundwater models can be useful tools
for simulating the quantity and concentration of contaminants at the points of
potential exposure. Based on the modeling results, the risk of impact to human
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transport scenarios to evaluate risk at the site. Finally, the simulated scenarios
are compared to ongoing monitoring results to confirm the validity of the modeled
results.
Field monitoring results that consistently confirm the conditions predicted by the
modeling efforts add confidence to the validity of the modeled scenarios. Under
the appropriate circumstances, this pattern can justify reducing or eliminating the
ongoing monitoring requirements at a site.
6.12
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with increased distance traveled through time (Bedient et al. 1996, and USEPA
1990).
6.12.2 UNSATURATED FLOW
Flow and transport mechanisms affecting contaminant behavior in the
unsaturated zone (i.e., vadose zone or zone of aeration) are much more complex
than those mechanisms in the saturated zone. These flow and transport
mechanisms include porosity, capillary forces, and moisture content. The
unsaturated zone is defined as that portion of the soil column where the amount
of water present is less than the porosity of the soil and where the soil water
pressure is negative. The capillary fringe ( i.e., the tension-saturated zone) is
defined as the area above the water table where the soil pores are saturated but
the pressure head is less than atmospheric (Freeze and Cherry 1979). In an
unsaturated porous medium, a portion of the pore space contains air and a
portion contains water. The total porosity within the unsaturated zone equals the
sum of the two. The moisture content is defined as the ratio of the volume of the
water to the total volume of the porous media.
6.13
Specific gravity
Vapor pressure
Vapor density
Solubility
Adsorption potential
!
!
!
!
!
Degradability
Biodegradability
Reactivity
Corrosivity
Ignitability
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slightly soluble in water, tend to adhere to the soil particles; and do not readily
migrate through the soil.
6.13.4 METALS
Rates of migration for metals released in the subsurface environment are strongly
influenced by soil type. In general, chemically-reduced metals exhibit low mobility
in clays, silty clays, and clayey loams due to adsorption and fixation to clay
minerals, and most are only slightly soluble in water. Therefore, uncompounded
(non-ionic) metals released into a subsurface environment with a high clay content
will not migrate far from the point of release.
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Approximately 14,500 years ago the glaciers that occupied the region began to
melt. As the glaciers retreated, a series of moraines, lakes, and rivers formed.
However, the ice did not retreat uniformly, as many as 20 distinct stages of retreat
and an occasional readvance of ice have been identified (Farrand 1982 and 1988).
The resulting terminal and lateral moraines became effective natural dams and
were ideal for the development of glacial lakes.
Several significant glacial lake stages have been identified within the Rouge River
Watershed (Bergquist and MacLachlan 1951, Leverett 1911, Leverett and Taylor
1915, Spencer 1888, Sherzer 1913, Taylor 1897 and 1899). Deposits from these
ancient glacial lakes were first observed and mapped in 1838 and 1840 (Hubbard
1840). These deposits extend to the north of the Rouge River Watershed to Imlay
City, Michigan, and to the south through northern Ohio to an area east of
Cleveland, Ohio (Sherzer 1913).
The Pleistocene deposits within the Watershed are composed of: 1.) moraine
sediments of glacial origin, and 2.) lake sediments of glacial-lacustrine origin.
These sediments typically have varied and complex lithologies that include coarse
gravels, fine-grained sands, and clays (Bergquist and MacLachlan 1951, Mozola
1969, and Rieck 1981).
The Defiance Moraine forms the north and western boundaries of the Watershed
and reaches a maximum elevation of approximately 950 feet. To the east are the
lake deposits associated with the retreating ice. The elevations of these deposits
range from 580 to 800 feet.
The occurrence of groundwater in the Pleistocene deposits is influenced by: 1.) the
hydrology of the region, and 2.) the nature, horizontal and vertical extent, and
composition of the sediments. According to Mozola (1954), the depth to
groundwater in the upper unconfined waterbearing zone, horizontal and vertical
extent of groundwater, and the amount of groundwater present can vary from
location to location.
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Moraine Unit
Sandy Clay Unit
Sand Unit
Sandy and Silty Clay Unit
Upper Clay Unit
Isolated Units
Reworked River Sediments
Lower Clay Unit
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Table 6.2
Probability of Hydrogeological Conditions in Geologic Units of the Rouge
River Watershed
CONDITION
CLAY
SANDY
CLAY
SANDY
SILTY
CLAY
SAND
MORAINE
RIVER
DEPOSIT
Groundwater
Presence
Low
Medium
High
High
Medium
High
Groundwater
in Aquifer
Low
High
Low
High
High
Transport/
Connection to
Aquifer
Low
Medium
Low
High
High
Transport to
Surface
Water
Low
Low
Medium
High
Medium
High
Low
Low
Low
Low
Low
Low
High
Low
Drinking
Water Use:
- On-site
- In vicinity
of site
Notes:
?=Unknown-insufficient information available
The direction of groundwater flow, at those sites where a flow direction could be
established, was generally toward surface water. Groundwater within the unit has
not been used as a source of potable water, most likely because of insufficient
water yield. Groundwater encountered within the sandy clay unit may be
hydraulically connected to the sand unit and to surface water.
Therefore, contaminants detected within the unit may have the potential to
migrate to surface water or to groundwater present within the sand unit,
especially at those locations along the sandy clay unit and sand unit margin.
The sandy clay unit is not an effective aquitard in most cases because the unit
is generally thin (i.e., less than six feet) and most likely contains a significant
amount of vertical hairline fractures. These hairline fractures tend to act as
pathways for contaminants to migrate both horizontally and vertically. Therefore,
because the sandy clay unit is generally thin and is not an effective aquitard,
contaminants released at sites located within the unit may migrate relatively
quickly into the upper portion of the moraine unit (which has been characterized
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as a sensitive unit), or may migrate to the sand unit. Table 6.2 contains a rating
of the probabilities of encountering certain hydrogeological conditions in each
geologic unit of the Rouge River Watershed.
Sand Unit - A sand unit is located east of the sandy clay unit. The sand unit
ranges in elevation from approximately 690 to 720 feet at its western margin to
approximately 640 feet at its eastern margin. This unit is characterized as a
moderate yellowish-brown to light olive-gray, fine- to coarse-grained quartz sand.
The sand becomes less coarse with increasing depth. The composition and
mineralogy of the sand has been historically described as containing 90 percent
or more quartz (Sherzer 1917).
At many locations, the sand unit is stratified and has well-developed
crossbedding, ripple marks, and scour and fill features. In addition, localized
evidence of reworking and eolian deposition are present within the upper portion
of the unit. Clay rip-up clasts are present in the lower 0.5 feet of the unit, which
indicates that the contact between the sand unit and the unit beneath it (the
Lower Clay Unit) is an erosional contact.
The width of the sand unit ranges from approximately three to five miles. The
thickness of the unit is 10 to 20 feet in the southern portion of the Watershed and
increases northward into the western portions of Livonia, where the thickness may
exceed 30 feet. North of the city of Livonia, the unit thins significantly and may
only be five feet thick in the city of Farmington. North of Farmington, the unit
thickens and may be 10 to 15 feet thick in the northern portion of the Watershed.
From west to east, the thickness of the sand unit increases significantly from one
to 20 feet over a horizontal distance of only 400 feet along its western margin near
the city of Plymouth. In areas east of Plymouth and through the city of Livonia,
the unit gradually thins and becomes intercalated with the sandy and silty clay
unit in the township of Redford.
Groundwater encountered within the sand unit is unconfined. The direction of
groundwater flow within the unit is generally toward surface water. Groundwater
encountered within the unit is regional in extent. The unit occupies approximately
25 percent of the Watershed. The saturated thickness within the unit ranges from
just a few feet (near Farmington) to more than 20 feet (in portions of Livonia).
Groundwater within the unit has been observed to discharge into the Rouge River
at numerous locations.
The degree and nature of urbanization within the Watershed has also affected the
rate and direction of groundwater flow within the sand unit. The construction of
roads (i.e., Hines Drive and I-96), storm sewers, retention basins, and ditches
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within the unit act as points for groundwater to discharge to surface water.
Therefore, the residence time for groundwater in the aquifer has most likely
decreased as a result of urbanization.
In addition, urbanization has resulted in a decrease of recharge to the aquifer
because impervious cover (i.e., roads, paved parking areas, buildings, and
landscaping) and stormwater runoff controls divert runoff from storm events
directly to the Rouge River and its tributaries.
Recharge of groundwater within the sand unit is most likely from surface
precipitation because of the surficial nature of the unit.
In portions of Livonia, Hines Drive has cut into the sand unit at many locations.
This has resulted in numerous seepage points along the north side of Hines Drive.
From the seepage points, groundwater has been observed to seep from the ground,
flow along ditches, and discharge into the Middle Rouge River.
In addition to Hines Drive affecting the direction and rate of groundwater flow on
a local scale, I-96 through portions of Livonia has also created the same effect.
Several groundwater seepage points are located along I-96 in Livonia where the
highway has cut into portions of the saturated zone within the sand unit,
especially near underpasses where the highway was excavated deeper for the
overpass and surface water drainage.
The sand unit is a heterogeneous aquifer. It is a multi-layered lacustrine deposit
with highly variable grain size distribution between the individual layers. In
addition, because of the fluctuating glacial shorelines and the general regressive
history of the glacial lakes, the grain size distribution horizontally within the unit
is also highly variable and complex. Therefore, the heterogeneous configurations
of the unit include both layered heterogeneity and trending heterogeneity (Freeze
and Cherry 1979).
The hydraulic conductivity of the sand unit decreases significantly with depth.
The upper portion of the saturated zone within the unit is characterized as a
medium- to coarse-grained sand, which has a hydraulic conductivity ranging from
1 x 10-1 to 10+1 cm/s. The lower portion of the saturated zone within the unit is
characterized as a very fine-grained sand, which has a hydraulic conductivity
ranging from 1 x 10-4 to 1 x 10 -2 cm/s (Rogers 1996).
Recovery wells installed in the sand unit at sites of environmental contamination
have pumped groundwater at rates that range from 0.5 to 50 gallons per minute.
The wide range in yield depends upon: 1.) the saturated thickness of the sand,
which ranges from less than three feet to more than 20 feet, 2.) the range in grain
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size, and 3.) the diameter of the recovery well. The average yield from the
saturated zone within the sand unit ranges from five to 10 gallons per minute.
The decrease in hydraulic conductivity represents a stratigraphic control that
minimizes the vertical migration of contaminants within the unit, especially
contaminants that have a specific gravity greater than water, such as DNAPLs.
Therefore, contaminants are more likely to be concentrated within the upper
portion of the unit.
The composition and mineralogy of the sand unit has historically been described
as 90 percent or more quartz and little or no silt or clay. The absence of
significant amounts of silt or clay within the unit is significant when evaluating
contaminant migration within the unit. Contaminants present within the unit
that typically adsorb strongly to clayey soil particles (e.g., PNAs, PCBs, most
VOCs, and metals) may migrate a greater distance than otherwise predicted.
However, there are localized exceptions where the unit is stratified and has welldeveloped crossbedding, ripple marks, and scour and fill features.
The scour and fill features typically have been filled with a significant amount or
clay-size organic matter that may provide isolated pockets where higher
contaminant concentrations may be present.
In summary, contaminants detected in groundwater within the sand unit will
migrate to surface water if they are not controlled, captured, or degraded. In
addition, the sand unit has historically been a source of potable water. Therefore,
the sand unit is a geologic unit that is especially sensitive to urbanization and
industrial development. Table 6.2 contains a rating of the probabilities of
encountering certain hydrogeological conditions in each geologic unit of the Rouge
River Watershed.
Sandy and Silty Clay and Upper Clay Units - A sandy and silty clay unit and
upper clay unit are located east of the sand unit. The sandy and silty clay and
upper clay units range in elevation from approximately 640 feet on their western
margin to approximately 580 feet on their eastern margin. Due to the degree of
interbedding between the sandy and silty clay and upper clay units, the precise
boundary between the two units is interpolated.
The sandy and silty clay unit is characterized as a medium- to light-olive gray,
mottled, well rounded-pebble bearing, sandy to silty clay. Discontinuous finegrained sand lenses may also be present within the unit especially along its
western margin. The width of the unit ranges from approximately three to five
miles. The thickness of the unit ranges from 10 to 20 feet. In general, the unit
has more sand content along the western portion of the unit.
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Well-developed varves have been observed within the sandy and silty clay unit and
upper clay unit. The varves appear to be more numerous along the western
margin of the sandy and silty clay unit, where they are interbedded and beneath
the sand unit. The individual varves range in thickness from approximately 0.1
to 0.25 inches and have been observed to extend for more than two feet vertically
within the unit. The upper clay unit is located east of the sandy and silty clay
unit. The upper clay unit forms the eastern boundary of the watershed and
ranges in elevation from 620 feet along its western margin to 580 feet at its
eastern margin. The upper clay unit is characterized as a bluish to light-olive
gray, mottled, clay with trace amounts of well-rounded pebbles.
Vertical hairline fractures may be present within the upper portion of both clay
units. These hairline fractures are caused by stress changes from wetting and
drying cycles and/or freezing and thawing (Freeze and Cherry, 1979). The
occurrence of the fractures decreases with increasing depth within each unit. In
addition, root fragments may also be present within the upper portion of any of
the near-surface geologic units. A mottled appearance and/or zones of oxidation
indicate the presence of fractures within the clay units.
The presence of vertical hairline fractures and discontinuous sand lenses within
the two clay units located east of the sand unit has resulted in a hydraulic
conductivity that is slightly higher that what would have been otherwise predicted.
The hydraulic conductivity for these two clay units ranges from 1 x 10-6 to 1 x 10 -2
cm/s.
The upper clay unit appears to be uniformly deposited in the north-south
direction within the Watershed and thickens from west to east. Along its western
margin, the upper clay unit is approximately 10 feet thick and may be more than
30 feet thick along its eastern margin near the Detroit River.
Groundwater encountered in the sandy and silty clay and upper clay units is
unconfined to semi-confined. When groundwater was encountered within the
units, it was present 1) within discontinuous sand lenses, and/or 2) at the contact
with the lower clay unit. Groundwater that is present within each of these clay
units is generally discontinuous and is not present in large volumes that could be
pumped from the ground at a sustained rate. However, groundwater encountered
within the sandy and silty clay unit may be hydraulically connected to the sand
unit, but groundwater within the sandy and silty clay unit is hydraulically down
gradient.
A groundwater flow direction was determined at some sites of environment
contamination located within the two clay units. The direction of groundwater
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flow at those sites was toward the east-southeast. This flow is in the general
direction of the dip of the units and toward surface water.
Groundwater within the sandy and silty clay and upper clay units has not been
used as a source of potable water. Table 6.2 contains a rating of the probabilities
of encountering certain hydrogeological conditions in each geologic unit of the
Rouge River Watershed.
Isolated Units - The discontinuous and isolated units consist of two subunits:
! Discontinuous sand subunits, and
! Discontinuous sandy and silty clay subunits.
The discontinuous and isolated units are located in two primary regions of the
Watershed which are along the boundary between:
! The moraine unit and the sandy clay unit, and
! The sandy and silty clay unit and the clay unit.
The discontinuous sand units are generally described as fine-grained sand, less
than five feet thick, and less than 0.5 miles wide. However, the discontinuous
sand unit extending north of Ferndale through Royal Oak is more than 18 feet
thick. Historically, these units have been described as sand ridges (Sherzer 1913,
and 1916 and Leverett 1917). However, urbanization has obscured most evidence
that this unit is currently in the form of a sand ridge.
The discontinuous sandy and silty clay units are described as a bluish- to
medium- to light-olive gray, mottled, well-rounded pebble-bearing, sandy to silty
clay. The units are generally less than five feet thick and less than 0.5 miles wide.
These discontinuous sandy and silty clay units are located along the boundary
between the sandy and silty clay and clay units.
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sand deposit may be reworked river sediments from the Detroit River and not from
the Rouge River. The deposit has been described as being as thick as 40 feet
(Sherzer 1917). Groundwater present within the reworked rivers deposits most
likely is hydraulically connected to the Rouge River. Table 6.2 contains a rating
of the probabilities of encountering certain hydrogeological conditions in each
geologic unit of the Rouge River Watershed.
6.15 HYDRAULIC CONDUCTIVITY AND AVERAGE LINEAR VELOCITY
The hydraulic conductivities at evaluated sites where groundwater was present
ranged from 1.0 x 10-6 to 1.0 x 10+1 cm/s [Rogers 1996]. Table 6.3 presents the
range in hydraulic conductivities for each geologic unit.
The range in hydraulic conductivities was greatest for those sites located in the
moraine unit. Sites with groundwater in the sand unit generally had a high
hydraulic conductivity. Sites located in the clay unit generally had a low hydraulic
conductivity.
Table 6.3
Probability of Encountering Groundwater and Hydraulic Conductivities in
the Rouge River Watershed
GEOLOGIC UNIT
PROBABILITY
OF
ENCOUNTERING
GROUNDWATER
ESTIMATED
HYDRAULIC
CONDUCTIVITY
(CM/S)
Moraine Unit
35%
14%
1.0 x 10-4
Sand Unit
97%
30%
22%
Discontinuous and
Isolated Units
81%
50.9%
Total
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The presence of fractures or mottling, with the exception of the contact with the
near-surface units, within the lower clay unit have not been observed. The lack
of hairline fractures and mottling within the lower clay unit is most likely the
result of the unit being at a sufficient depth beneath the surface, which has
insulated the unit and prevented or minimized the potential development of
fractures.
The thickness, horizontal distribution, and low and uniform hydraulic
conductivity of the lower clay unit has influenced near-surface groundwater flow
on a regional basis. The presence of the lower clay unit has prevented
groundwater from migrating to lower aquifers. Instead, groundwater in nearsurface aquifers discharges to surface water.
6.17 AIR MODELING
Toxicity data indicate that risks from exposure to some chemicals via inhalation
far outweigh the risks via ingestion (USEPA, 1996). Therefore, if concentrations
of hazardous substances are elevated in surface or subsurface soil, it may be
necessary to conduct air modeling to estimate the concentration of soil
contaminants in ambient air. Air modeling can be conducted for both volatiles
and fugitive dusts.
Inhalation from fugitive dusts results from particle entrainment from the soil
surface; thus contaminant concentrations in the surface soil horizon (i.e., the top
two centimeters) are of primary concern for this pathway. On the other hand, the
entire column of contaminated soil can contribute to volatile emissions at a site.
However, the top two centimeters are likely to be depleted of volatile contaminants
at most sites. Therefore, contaminant concentrations in subsurface soils, which
are measured using core samples, are of primary concern for quantifying the risk
from volatile emissions.
For volatiles, the soil-to-air volatilization factor (VF) is used to define the
relationship between the concentration of the contaminant in soil and the flux of
the volatilized contaminant to air. VF is calculated using chemical-specific
properties and either site-measured or default values for soil moisture, dry bulk
density, and fraction of organic carbon in soil (USEPA, 1996). VF can be
calculated based on the assumption of an infinite source of contamination or a
known mass of contaminant using a finite source model.
The particulate emission factor relates the concentration of contaminant in soil
to the concentration of dust particles in the air. Dust from open sources is
typically termed fugitive because it is not discharged into the atmosphere in a
confined flow stream (i.e., discharge from a point source or stack emission). Wind
moving across an open site with erodible areas of exposed surface soil can create
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an emission flux. Other sources of fugitive dusts that may lead to higher
emissions due to mechanical disturbances include unpaved roads, tilled
agricultural soils, and construction operations (USEPA, 1996).
Several models can be used to estimate the air concentration of volatiles and
fugitive dusts. For fugitive dusts, USEPA currently uses the unlimited reservoir
model from Cowherd et al. (1985) to estimate particulate emissions due to wind
erosion. The unlimited reservoir model is most sensitive to the threshold friction
velocity, which is a function of the mode of the size distribution of surface soil
aggregates. The mode soil aggregate size determines how much wind is needed
before dust is generated at a site. This parameter has the greatest effect on the
emissions and resulting concentration.
For volatiles, USEPA currently uses the infinite source Jury model because this
model was shown to most accurately predict the available measured soil
contaminant volatilization rates and considers the influence of the liquid phase
on the local equilibrium partitioning. Other than the initial soil concentration, airfilled soil porosity is the most significant soil parameter affecting the final steadystate flux of volatile contaminants from soil (USEPA, 1996). The higher the airfilled soil porosity, the greater the emission flux of volatile contaminants.
To calculate the concentration of potential surface soil emissions in air, a
dispersion model is used. An air dispersion model for fugitive dust or volatile
emissions from a site should have the following characteristics (USEPA, 1996):
! Dispersion modeling from a ground-level area source on-site receptor
! A long-term/annual average exposure point concentration
! Algorithms for calculating the exposure point concentration for area sources
of different sizes and shapes
USEPA is currently using the Industrial Source Complex Model (ISCST3) to
estimate dispersion of airborne contaminants.
6.18 FINAL RISK EVALUATION
Once the sampling and data collection has been completed, the data must be
reevaluated with respect to potential risks posed by the site. The final risk
evaluation should include a description of the receptors, exposure pathways, and
whether concentrations of hazardous substances exceed the applicable risk-based
clean-up criteria. A detailed description of the risk assessment process is
presented in Chapter 7.
6.19 PREPARATION OF FINAL REPORT
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Keller, K. C., Van Der Kamp, G., and J. A. Cherry. 1989. A Multiscale Study of
the Permeability of a Thick Clayey Till. Water Resources Research. Vol. 25. No. 11.
p. 2299-2317.
Leverett, F. B. 1911. Map of the Surface Formations of the Southern Peninsula of
Michigan. Geological Survey of Michigan, Publication 25, Lansing, Michigan.
1:1,000,000. 1sheet.
Leverett, F. B. 1917. Surface Geology and Agricultural Conditions of Michigan.
Annual Report of the Board of Geology Survey of Michigan. Lansing, Michigan.
223p.
Leverett, F. B. & Taylor, F B. 1915. The Pleistocene of Indiana and Michigan and
the History of the Great Lakes, U. S. Geo. Survey, Monograph 53, 529p.
Martin, H. 1957. Geologic Map of Michigan. Michigan Department of Conservation.
Lansing, Michigan. 1 sheet.
MDEQ. 1996. Interim Environmental Response Division Operational
Memorandum #17: Instructions for Obtaining Definitions on Mixing Zone-Based
Groundwater Surface Water Interface Criteria for Inclusion in Remedial Action Plans
and Monitoring Compliance with Criteria for Discharges of Groundwater
Contaminants to Surface Water. Michigan Department of Environmental Quality.
Interoffice Communication. April 12, 1996.
Mozola, A. J. 1954. A Survey of the Groundwater Resources in Oakland County,
Michigan. Michigan Geological Survey. Publication 48, Part II. Lansing, Michigan.
Mozola, A. J. 1969. Geology for Land and Groundwater Development in Wayne
County, Michigan. Michigan Geological Survey. Lansing, Michigan.
Mulkey, L. A., Donigian, Jr., A.S., Allison, T.L., and Raju, C.S. 1992. Evaluation
of Source Term Initial Conditions for Modeling Leachate Migration from Landfills.
EPA/600/R-92/233. Office of Research and Development. U.S. Environmental
Protection Agency. Athens, GA.
Rieck, R. L. 1981. Map. Glacial drift thickness, Southern Peninsula. Plate 15.
Hydrogeologic Atlas of Michigan. Western Michigan University. Kalamazoo,
Michigan.
Rogers, D.T. 1996. Environmental Geology of Metropolitan Detroit.
Environmental Consultants, Inc. Novi, Michigan.
Clayton
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Sherzer, W. H. 1913. Geology of Wayne County, Geo. Survey of Mi., Pub. 12:
Lansing, Michigan.
Sherzer, W. H., 1916. Geologic Atlas of the United States, Detroit Folio No.E205,
U. S. Geo. Survey, Reston, Virginia, 1:62,500, 4 Sheets.
Spencer, W. 1888. The Iroquois Beach, Science, Vol. XI, 49p.
Taylor, F.B. 1897. Correlation of Erie-Huron Beaches with Outlets and Moraines in
Southeastern Michigan. Bulletin of the Geological Society of America. Vol. VIII, 52p.
Taylor, F.B. 1899. The Great Ice-Dams of Lakes Maumee, Whittlesey, and Warren.
American Geologist. Vol. XXIV. 23p.
United States Environmental Protection Agency (USEPA). 1990. A Guide to
Selecting Superfund Remedial Actions. Office of Solid Waste and Emergency
Response. OSWER-9355.0-27FS. Washington, D.C., 6p.
USEPA. 1996. Soil Screening Guidance: Technical Background Document. Office
of Solid Waste and Emergency Response. EPA/540/R-95/128. PB96-963502.
(May 1996).
USEPA. 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites.
Office of
Emergency and Remedial Response.
EPA/540/P-91/001. Washington, D.C., 294p.
USEPA, 1993. Remediation Technologies Screening Matrix and Reference Guide.
Office of Solid Waste and Emergency Response. EPA 542-B-93-005. Washington,
D. C. 141p.
USEPA, 1994a. Physical/Chemical Treatment Technology Resource Guide. Office
of Solid Waste and Emergency Response, Technology Innovation Office. EPA 542B-94-008. 43p.
USEPA, 1994b. Groundwater Treatment Technology Resource Guide. Office of
Solid Waste and Emergency Response, Technology Innovation Office. EPA 542-B94-009. 29p
USEPA. 1990b. Groundwater. Volume I. Groundwater and Contamination, United
States Environmental Protection Agency. Washington, D. C. 144p.
USEPA. 1991.
Groundwater.
Volume II.
Methodology,
Environmental Protection Agency. Washington, D. C. 144p.
Guidelines for Closure of
Abandoned Dump Sites
United States
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USEPA. 1992a. Estimating the Potential for the Occurrence of DNAPL at Superfund
Sites. Environmental Protection Agency Quick Reference Sheet. United States
Environmental Protection Agency Publication 9355.4-7FS. Washington, D. C.
USEPA. 1992b. Dense Nonaqueous Phase Liquids (DNAPLs): A Workshop
Summary. EPA Groundwater Issue Paper. United States Environmental
Protection Agency Publication EPA/600-R+92/030. Washington, D. C.
Van der Heijde, Paul K. M.; Aly I. El-Kadi, and Stan A. Williams, Groundwater
Modeling: An Overview and Status Report, United States Environmental
Protection Agency, December 1988. Document No. EPA/600/2-89/028.
Wiedemeier T. H., D. C. Downey, J. T. Wilson, D. H. Kampbell, R. N. Miller, and
J. E. Hansen., Technical Protocol for Implementing the Intrinsic Remediation with
Long-term Monitoring Option for Natural Attenuation of Dissolved-Phase Fuel
Contamination in Groundwater. United States Air Force Center for Environmental
Excellence, Brooks AFB, San Antonio, TX, March 1994.
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A list of the potential exposure pathways and conditions should be developed and
may include one or more of the following:
Hazardous Substance Sources
! Abandoned substances not yet dispersed and free phase liquids (i.e. drums,
tanks, lagoons, buried materials, free product, etc.)
Groundwater Contamination
! Drinking water usage;
! Dermal exposure (i.e. direct contact with hazardous substances in soil,
water, etc.);
! Indoor air hazards; and
! Hazards to surface waters.
Soil Contamination
! Direct contact hazards (i.e. ingestion, dermal adsorption);
! Ambient air inhalation hazards;
! Indoor air inhalation hazards;
! Injury to drinking water use of aquifer (i.e. leaching of hazardous
substances from soil to groundwater);
! Dermal exposure to groundwater affected by hazardous substances in soil
(i.e. by leaching from soil); and
! Exposure to surface water impacted by leachate-contaminated groundwater
! Contaminated soil runoff to surface water.
Other Pathways/Conditions
! Acute toxic impacts and physical hazards, and
! Ecological and aesthetics impacts
Once the exposure pathways have been identified, the applicable cleanup criteria
can be chosen. It is important to note that it is critical to verify that the cleanup
criteria are appropriate to the site, considering such things as land use and
activity patterns anticipated at the site. Since many abandoned dumps are
located on sites with current or proposed recreational land use and generic
cleanup criteria for recreational land use have not yet been established by the
MDEQ, generic recreational soil cleanup criteria have been developed for this
abandoned dump closure process. These cleanup criteria and a description of the
data and methods used to develop the criteria can be found in Appendix A.
Generic cleanup criteria are calculated using generic exposure assumptions (i.e.
hours of exposure, number of days exposed, etc.); these exposure assumptions
may or may not reflect actual conditions at a specific site. If it is determined that
the generic cleanup criteria do not accurately reflect site-specific exposure
Guidelines for Closure of
Abandoned Dump Sites
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have not been included in Table 8.1 because they have not been used in landfill
situations enough to be considered candidates. Those remediation methods not
shown include bioventing, biosparging, air sparging, and soil flushing, as well as
numerous ex-situ processes.
8.2 IMPLEMENTATION OF REMEDIAL ACTIONS
Once a feasibility study has identified suitable remedial actions for a site,
implementation of the selected remedial action is the next step. Whether the
approach involves a presumptive remedy or other remediation strategy, the
requirements are comparable.
8.2.1 REMEDIAL ACTION PLANS AND MICHIGANS PART 201
As described in Chapter 2.0, the state of Michigan has adopted specific statutes
and rules regarding the completion, review, and approval of RAPs, and has
formulated comprehensive sets of cleanup criteria for a variety of closure options.
The relevant resources are as follows:
! Address:
!
!
!
!
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Table 8.1
Summary of Remediation Technologies Potentially Appropriate for
Abandoned Dump Sites
REMEDIAL ACTION
CATEGORY
ADVANTAGES
DISADVANTAGES
Slurry Walls
Soil Cover
Clay Cap
Easy
to
implement,
depending on the source of
clay;
greater
exposure
protection than soil cover
Composite Barrier
Cap
Maximum
protection
e xposure
Solidification/
Stabilization
Excavation
M, R
Natural Attenuation
M, R
Readily available;
moderate cost
to
Requires
extensive
site
characterization,
simulation
modeling, and ongoing monitoring;
regulatory
and
community
acceptance may be low
Passive Treatment
Walls
M, R
Groundwater
Recovery and
Treatment (Pump
& Treat)
M, R
Not
effective
at
eliminating
contamination over a short time;
effectiveness
limited
in
heterogeneous geologic settings
Bioremediation
Soil Vapor
Extraction
Proven,
effective
reliable,
low
cost
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Part 201 also specifies that any land use or resource use restrictions are to be
described in a restrictive covenant, filed with the county register of deeds. The
requirement for a restrictive covenant applies to all remedial actions that require
any type of containment or exposure barrier. The statute allows for application
of institutional controls to be applied in cases where a restrictive covenant will be
impractical or ineffective at limiting exposure to hazardous chemicals.
According to Part 201 the remedial action plan will include the following:
! A description of the remedial action, including a description of compliance
with the applicable statute and rules;
! All applicable technical submittals, including remedial investigation report,
feasibility study, risk assessment, closure report, etc.;
! An operation and maintenance plan;
! A monitoring plan;
! An explanation of any land use or resource use restrictions, as well as a
plan for the monitoring and enforcement of these restrictions; and,
! a schedule for implementation of the RAP.
If a RAP is submitted to achieve closure under commercial, industrial, or
recreational criteria, the operation and maintenance plan, monitoring plan, and
financial assurance plan must be submitted if they will be required to ensure
compliance with applicable criteria outside the boundary of the property that is
the source of the release.
8.3 PRESUMPTIVE REMEDIES
As described in Chapter 1, USEPA has developed presumptive remedies to
accelerate cleanup of some sites. The USEPA has identified containment as the
presumptive remedy for CERCLA municipal landfill sites. Containment methods
applicable to abandoned dump sites include capping, source area ground water
control, leachate collection and treatment, gas treatment, and institutional
controls.
8.3.1 CAPPING
Capping is typically required when contaminated materials are to be left in place
at a site. It is commonly used when the underground contamination is so
extensive that it prohibits excavation and removal. It may also be used if the
removal of wastes from the site would pose a greater threat to human health and
the environment than simply leaving them in place. The purposes of a cap may
include any of the following:
! Preventing direct contact with landfill contents (i.e. exposure barrier);
Guidelines for Closure of
Abandoned Dump Sites
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SOURCE
COMMENTS
Groundwater Discharge
Exemption
State of Michigan
Soil Erosion
County or Municipality
Dust Control
Municipality
Stormwater
County or Municipality
Floodplain
State or County
Tree Removal
Municipality
State or County
Wetlands
Well Drilling
Local Municipality
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consists of various types of landfill waste and/or liquid waste, there will likely be
special handling and disposal considerations and requirements.
8.6 LONG TERM OPERATIONS AND MAINTENANCE
The following are aspects of operations and maintenance that must be considered
in the years following remedial action implementation.
! Permanent markers to describe restricted areas of the site and the nature
of any restrictions.
! Monitoring of the effectiveness and integrity of the remedial action
! Operation and maintenance of the remedial action
! Continued financial responsibility is the establishment of financial
mechanisms by which a party ensures continued funding of remediation
measures.
8.7 REFERENCES
USEPA. 1998. Memorandum. Subject: Findings and Recommendations of the
Working Group Reviewing Landfill Cover Requirements and Decision-Making by
Region 5 Superfund Program. From: James N. Mayka, Chief, Remedial Response
Branch #2 and Wendy Carney, Chief, Remedial Response Branch #1; To:
Superfund RPMs. April 14, 1998.
USEPA. 1992. EPA Facts About Capping. Compiled from: Superfund Innovative
Technology Evaluation (November 1990). June 1992.
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The second step, preliminary public contact, opens the public involvement
dialogue and helps the team to determine the list of potential stakeholders.
During this phase, preliminary information about the proposed closure process
is provided to stakeholders in anticipation that the stakeholders will provide the
project manager with meaningful feedback and express their concerns. This step
is complete when the project planners understand the issues that the
stakeholders have raised and have determined both the level of public interest and
the significance of those issues.
After all significant issues have been identified, a detailed public involvement plan
can be prepared which integrates the issues raised into the decision-making
process. The following key factors should be considered when choosing public
involvement tools for an abandoned dump situation:
!
!
!
!
!
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successful public involvement program when certain lands are viewed by the
public as locally unwanted land uses. Because residents feel strongly about their
property and the health and safety of their families, policy decisions involving
locally unwanted land uses can trigger serious disagreements between
communities and their local governments. The issues pertaining to locally
unwanted land uses that are typically of greatest concern to public stakeholders
are:
! health and environmental risks,
! risks to the most sensitive population groups such as children and the
aged,
! the value of property located near a potentially contaminated site, and
! trust in the governing regulatory agencies and the parties responsible for
site cleanup.
The solutions to community opposition engendered by citizen participation
programs include establishing public comment and review periods, holding public
hearings, and setting up active, influential citizen advisory boards. The success
of these participation mechanisms depends on local politics, the composition of
the affected public, and the receptivity of decision makers to citizen input.
Consensus is not guaranteed simply because an open process in used. For these
complex risk-based policy making decisions, a more democratic format may
facilitate a more effective two-way exchange of ideas, power, and influence
between officials and citizens.
9.1 PRINCIPLES OF PUBLIC INVOLVEMENT
This section of the guidance document describes a generic public involvement
plan which a local unit of government can use to develop a specific plan that is
appropriate for its situation. There are a number of key principles that serve as
the foundation for a successful public involvement program. In developing such
a program, all interested parties should keep these concepts in mind:
! It is essential to let people know about and contribute in a meaningful way
to decisions that may affect their health, the environment, their lives, and
the communities in which they reside. The public not only needs to be
informed, but often has the right, by law or regulation, to be informed of
plans that may affect it made by an organization, public or private.
! To participate effectively, the public must have access to accurate and
timely information about the site and any plans for action at the site. It is
essential to continuously maintain access to information. To the extent
possible, the closure team should use commonly used terms when
discussing technical matters. A complete file of project activities, including
technical information, should be readily accessible to the public through
Guidelines for Closure of
Abandoned Dump Sites
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9-4
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9-5
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9-6
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9.
10.
11.
12.
13.
14.
15.
16.
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As this step is completed, the project team should have a better understanding of
the major issues and areas of concern that stakeholder groups and other
individuals have raised, the level of public interest, the significance of the issues
and concerns, and the key stakeholder groups and community public opinion
leaders interested in the project.
9.3.3 PREPARATION OF A DETAILED PUBLIC INVOLVEMENT PLAN FOR AN
ABANDONED DUMP SITE
The detailed public involvement plan integrates public input into the decisionmaking process. Because this step is vital to maintaining a well-managed and
cost-effective investigation and closure project, the following elements should be
included in each PI plan:
!
!
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identify key points in the site investigation process when the public
involvement plan will be reviewed, evaluated, and updated based on
additional project information or issues that may have arisen.
Clarification and evaluation of options - There may be several options
available for providing safe closure of an abandoned dump site. Options
may include presumptive remedies (i.e., exposure barrier), limited closure
based upon land use, or waste and contaminated soil removal. Each of
these options has different social, environmental and economic impacts
that must be evaluated. Involving the public during this stage promotes
a high level of public buy-in for the final solution.
9.4
IMPLEMENTING THE PUBLIC INVOLVEMENT PLAN
The length and cost of the implementation phase will depend on the complexity
of the issues and the level of interest of the stakeholders. If the stakeholders have
little or moderate interest in the proposed site investigation, then a notice of the
proposed activity sent to stakeholders and the media, and a series of periodic
media interviews and written stakeholder updates may be sufficient to keep the
public informed. However, in this case, the project manager must be certain that
all interested stakeholders have been identified or informed of the project. At the
other extreme, an angry community with a potentially highly toxic abandoned
dump site in its midst may require:
!
!
!
!
!
!
!
!
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9.5
PUBLIC MEETING RECOMMENDATIONS
This section contains recommendations for conducting a public meeting.
9.5.1 PUBLIC NOTICE
Because it is essential to properly notify those citizens who are locally affected by
the site and actions proposed by the team, the public should be appropriately
notified of the meeting date, time, and location. The notice should appear in local
newspapers as well as in the larger metropolitan papers, and should be broadcast
a number of times on a major market radio station.
9.5.2 MEETING FORMAT
The following recommendations are made for organizing the format of the public
meeting:
Introductions - The following should be a part of the introduction phase at the
initial public meeting:
!
!
!
!
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!
!
The lead agency should start the information phase of the meeting by
presenting the following information:
- The agenda for the meeting
- A brief definition of the problem
- A summary of the strategies and remedies that may be used to resolve
the situation
- Processes (sampling needs, etc.)
- A proposed schedule
- Cost estimates
The team manager should identify any anticipated project delays (i.e.,
analytical results, weather delays). This will eliminate surprises and
disappointments.
The information that is presented should be appropriate to the members
of the audience. Each presenter should give a brief overview of the
information he or she is going to discuss and indicate how it addresses the
publics concerns.
Since the primary concerns of the residents will generally relate to
potential health effects, property values, and the well-being of their
children, these issues must be addressed during the meeting and are more
important than volumes of technical information that they may not
understand. The investigation team should attempt to adopt the publics
perspective and provide information that would reassure residents living
near the dump site that the major issues are being adequately addressed
and appropriately handled.
At the end of the meeting, the lead agency should outline its future plans.
A date for the next public meeting should be set, if appropriate, to assure
the public that the investigation will be moving forward and that its
progress can be monitored.
When asking questions or making statements, citizens should be
videotaped only if they have given written permission. Being on camera
intimidates many people; using such practices may inhibit the trust of the
public.
Adequate time should be provided during the meeting for questions and
answers.
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!
!
!
Handouts - Handouts are very useful and appreciated by the public. The
following recommendations are offered on the types and content of handouts that
are most valuable to the public.
!
A fact sheet should be distributed to the public at each meeting. The fact
sheet should include the following items:
- A summary of the problem and the proposed remedial activities.
- Any facts known at the time such as sampling results for contaminants
at the site, risk exposure analysis data, potential hazards (physical, etc.),
routes of exposure, location of site, owner of site, responsible parties.
- How the site may affect the public.
- What resources may be impacted (water, land, air, etc.).
- Which agency is in charge of the remediation.
- A contact list, including agency contacts for all those involved (name,
addresses, and phone numbers). A local contact person should be
identified so citizens do not have to call long distance.
- The location of a complete repository of information pertaining to the site
at the local library or other public building. Placing only selected
information in this file should be avoided. It also would be helpful if a
complete copy of the project file was also available at the government
office where the site is located. Each file should include a table of
contents to ensure that it is complete and that documents have not been
removed.
- A description of what is not known about the site and which activities
will be conducted to make those determinations.
- A project organization chart, showing who is in charge and how other
agencies fit into the picture.
- The law or policy under which the investigation and remedial activities
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!
!
are authorized.
- A glossary of the most commonly-used terms and acronyms.
An example of a fact sheet is presented in Figure 9-2.
A written agenda should be prepared for each meeting and furnished to
the public.
If a risk assessment will be used to assist the team in making decisions,
the public should be made aware of which models will be used and how
they are qualified.
Meeting minutes should be made readily available to the public as soon as
possible after the meeting.
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Figure 9-2
Example EPA Fact Sheet
United States
Environmental Protection
Agency
EPA Fact Sheet
Region 5
77 West Jackson Blvd.
Chicago, Illinois 60604
Illinois, Indiana,
Michigan, Minnesota,
Ohio, Wisconsin
SITE HISTORY
The Nankin Township Dump Site is located near the intersection of Conan and Warren Roads in
Westland, Wayne County, Michigan. The site consists of approximately 12 acres of land along
Tonquish Creek: a wooded portion that is part of a county-owned nature preserve known a William
P. Holiday Park, and an overgrown open field that is owned by Crestwood Development, a local real
estate development firm. From the 1950s to the 1970s, this land was used as a dump for
industrial and municipal wastes. A former facility of the Minnesota Mining and Manufacturing
Company (3M), located in Wayne, Michigan, was one of the sources of the industrial waste that was
dumped at the site. The United States Environmental Protection Agency (U.S. EPA) received
information about the site in late winter 1993 during an investigation of three other hazardous
waste sites in southeast Michigan.
U.S. EPA ACTIONS AT THE SITE
U.S. EPA conducted a preliminary site assessment of the Nankin Township Dump site on April 14,
1993. During the assessment, investigators observed partially buried drums, exposed solid waste,
and partially buried scraps of metal in the wooded area along the south bank of Tonquish Creek
and in the open field. On May 17 and 18, 1993, U.S. EPA conducted a survey over an area of the
site measuring 200 feet square, including an area where partially buried drums were visible at the
ground surface. This survey was conducted using a magnetometer--an instrument capable of
detecting the presence of metallic objects by measuring the intensity of the objects magnetic fields.
Magnetometer results indicated the presence of metal objects, possibly drums, buried at depth over
a large portion of the surveyed area.
On June 7, 1993, U.S. EPA representatives collected five samples of waste from partially buried,
deteriorated drums. Chemical analysis of the samples detected a number of hazardous substances
in various samples, including chromium, lead, zinc, toluene, and ethylbenzene. Analysis of one
sample indicated that the material is readily ignitable at the relatively low temperature of 140
degrees Fahrenheit.
In July 1993, U.S. EPA received information from a former waste hauler who had transported
industrial waste to the site from operator of the dump at this site, who reported that waste from
the 3M facility had been dumped at the site. On July 27, 1993, U.S. EPA notified 3M, Wayne
County, and Crestwood Development of their potential liability as Potentially Responsible Parties
(PRPs)--the parties considered liable for the contamination.
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RECENT ACTIONS
Representatives of U.S. EPA and the three PRPs entered into negotiations for a consensual
agreement concerning further investigation and cleanup of the site. The negotiations were
concluded on December 17, 1993, without reaching an agreement.
On January 5, 1994, the Director of U.S. EPAs Region 5 Waste Management Division approved
an Action Memorandum which documented the determination that the Nankin Township Dump
site poses a threat to human health and the environment. The determination was based on the
accessibility of the site, the hazardous nature of the materials found at the site, the deteriorated
condition of the partially buried metal drums containing some of the wastes, and evidence from
the site investigations which indicted the possible presence of additional buried waste. Further
concerns cited were the dump=s location near residential developments, and the proximity of some
wastes to Tonquish Creek, which is a tributary to the Middle Branch of the Rouge River. In
addition, seasonal flooding of the creek may be contributing to the erosion of contaminated soil and
containers of waste from the bank of the creek.
The Action Memorandum further stated that conditions at the Nankin Township Dump site
warranted the initiation of an immediate removal action. On January 7, 1994, U.S. EPA issued
a Unilateral Administrative Order (UAO) to 3M, Wayne County, and Crestwood Development,
requiring these PRPs to conduct cleanup activities. Specific activities to be conducted include
securing the site to prevent public access; excavating and properly disposing of hazardous
substances and contaminated soil; and conducting an extent-of-contamination (EOC) study to
determine the full extent to which the soil, sediment, ground water, and surface water may have
become contaminated as a result of the burial of hazardous materials at the site.
NEXT STEPS
The UAO provides an opportunity for the PRPs to meet with U.S. EPA or submit comments on the
UAO to U.S. EPA prior to the effective date of the UAO. If the PRPs comply with the UAO, the PRPs
will conduct the cleanup activities required at the site, to be overseen by U.S. EPA representatives.
If the PRPs do not comply with the UAO, U.S. EPA can request that a U.S. District Court enforce
the UAO, or U.S. EPA can conduct the cleanup and recover the costs of the cleanup from the PRPs.
Representatives of U.S. EPA Region 5 plan to conduct an informal public meeting in February to
provide an opportunity for members of the community to obtain further information about the site
and the proposed cleanup. Additional fact sheets will be issued in the coming months to keep the
community informed of events concerning the site.
FOR MORE INFORMATION
For more information about the Nankin Township Dump site, you may contact the following U.S.
EPA representatives:
Heidi Valetkevitch (P-19J)
Community Relations Coordinator
U.S. EPA Region 5 Office of Public Affairs
77 West Jackson Boulevard
Chicago, IL 60604-3590
312-886-1303
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9.5.3
GENERAL SUGGESTIONS
The following suggestions are offered to improve the effectiveness of public
meetings.
! The agencies and consultants making presentations should endeavor to
furnish all available factual information to the public and avoid the
perception that the government is attempting to hide adverse information
or data. If a question cannot be answered or information cannot be
released during a meeting, the public should be made aware of the
legitimate reason (i.e., litigation). If the public determines that an agency
was dishonest or evasive, that agencys credibility may be permanently
impaired.
! The Chairperson and presenters should be thoroughly familiar and
conversant with the information being provided and be capable of answering
most questions regarding the material. If a speaker does not know the
answer to a question posed by a member of the public, he or she should
admit that he does not know, rather than guess, and indicate that he/she
will try to determine an accurate answer for discussion at the next meeting.
Leaving questions unanswered creates a poor impression of the project
team.
! The public is often able to discern hidden agendas among the participants
and does not trust individuals who bring them to the meeting.
! The public should not be perceived as uninformed. Residents will lose
respect for the project team if they think they are being patronized.
! Roundtable discussions held early in the process and involving members of
the public, responsible parties, and participating agencies, often help
prevent adverse public reactions later in the project.
9.6 PUBLIC INVOLVEMENT METHODS
There are many ways to provide information to and foster communication with the
public regarding abandoned dump sites. The public involvement methods chosen
will depend on:
! the characteristics of the individual site,
! gaps in the information base which need to be filled,
! the degree of formality desired,
! contentiousness of the issue,
! available resources (i.e., funds),
! the project schedule, and
! the degree of entrenchment of stakeholder positions.
Several public involvement methods are listed below. In addition, Table 9.1
Guidelines for Closure of
Abandoned Dump Sites
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Much of the success of a panel is determined by the appropriate mix and balance
of its members.
Conference - A conference is a meeting, lasting one or more days, at which
experts and spokespersons outline their views and discuss predetermined topics.
Conferences may have free or paid admissions. The emphasis is on educating,
clarifying views, or fostering an agreement on an issue or project. Conferences
may lead to a climate of opinion; they frequently bring forward leading-edge
knowledge and views. They are a valuable source of stories and perspective for
reporters. Opinions have also been known to change on a conference floor due to
persuasive new knowledge or points of view.
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Public Meeting
Open House
Focus Groups
Community
Visits
Electronic
Bulletin Board
Panels
Town Meeting
Conferences
Public
Seminar
Task Force
Workshops
Public
Hearings
Advisory
committees
Legend:
- = Low
0 = Medium
+ = High
+
+
0
0
+
+
0/+
-/0
-/+
-
0
+
+
+
0
0
+
0
0
+
0/+
0/+
+
0
0
0
+
+
0
+
+
+
0
0
9-19
+
0
+
0
0
+
0/+
0
0
0
0
0/+
0/+
0
0/+
0
0/+
0
0/+
0/+
-/0
0/+
0
+
+
+
+
+
+
0
+
+
+
0
0
0
+
-
Public
Range of Issues Degree of
Number of
Time
Cost of
Potential for
Expertise
Involvement
that can be
Interaction People Who Commitment
Running
Public/Media Required to
Mechanism Accommodated
among
can
to Plan and Mechanism
Visibility
Run
Participants Participate
Implement
Mechanism
Table 9.1
Choosing the Right Public-Involvement Mechanisms
-/0
0/+
-/+
-
-/+
-/+
/0
-/0
Ability to
Accommodate
Different
Levels of
Participation
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Public Hearings - Public hearings are special, highly formal public meetings at
which a problem is presented, a wide range of possible solutions outlined, and
reaction received from the public. Experts can be called to verify assumptions.
The moderator, like a judge, firmly controls the proceeding. The hearing takes
place in three parts: first, a summary of the main points of the project is
presented. Second, the range of solutions, including the recommended solution,
if one exists, is presented. The final part of the hearing consists of the competing
interests reactions to the proposed course of action. In most cases, a permanent
record is kept at the hearing and becomes part of the public record.
Dissemination of Information - There are many methods that can be employed
by project proponents and stakeholders groups to disseminate information about
the issues and to request feedback:
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9.7 REFERENCES
Duffield, J.J., and Depoe, Dr. S.P., 1997. Lessons From Fernald: Revising
NMBYism, Through Democratic Decision-Making. Risk Policy Report. Pp. 31-34.
February 21, 1997.
Applegate, J.S., and Sarao, D.J., 1996. Coping With Complex Facts and Multiple
Parties in Public Disputes. Consensus: [Harvard-MIT Public Disputes Program].
31pp. 1, 12. July 1996.
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