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Iitjee Chemistry Sample Paper - I: Solutions
Iitjee Chemistry Sample Paper - I: Solutions
com
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(b)
2.
(a)
H3BO3 + 2H2O
3.
(d)
k1
k2
[B(OH)4] + H3O+
K
3B ;
k1
[B]3
; [B] =
[A]
k2
k1
k2
k1
where k =
k2
1/ 3
Ae
E
4.
(a)
5.
(d)
A1e
A 2e
E / RT
E1
3
E2
3
E1 / RT
E 2 / RT
1/ 3
[A]1 / 3
1/ 3
k3
1/ 3
A 3e
E 3 / RT
E3 = 70.0 kJ.
HA; more is hydrolysis of A ions and hence more is the pH. Hence Ka is least for the
acid HZ.
S nC V ln
T2
T1
nR ln
V2
V1
C V (ln 2)
R ln
1
2
C V ln 2 R ln 2 ln 2(C V
R)
6.
(d)
7.
(c)
CH3CH2CH=CH2
NBS
CH3CHCH=CH2
Br
8.
(a)
CH3CH2Br + Mg
(X)
dry ether
alc. KOH
CH2=CHCH=CH2
(X)
(Y)
CH3CH2MgBr
(Y)
CH3CH2MgBr + HCH
(Z)
CH3CH2CH2OMgBr
H3O+
CH3CH2CH2OH
SECTION II
Reasoning Type
9.
(b)
2NO2(g) ; Q C
N2O4(g)
[ NO 2 ] 2
[N 2O 4 ]
When inert gas is added under the condition of constant pressure, volume increases.
Hence, QC decreases and reaction moves in forward direction to achieve equilibrium.
10.
(a)
11.
(a) Statement-1 and statement-2 both are correct and statement-2 is the correct explanation
of the statement-1. Protection by acetylation makes the ring less prone to oxidation as
electron density in the ring decreases.
12.
(c)
SECTION III
Linked Comprehension Type
PassageI
13.
(d) Bromine water being a weak oxidising agent cant oxidize ketones.
14.
103 = 102
C=O
HCOH
HOCH
HOCH
CH2OH
L Fructose
1 molecule will require 5 molecules of HIO4. Hence 102 moles will require 5
HIO4.
15.
102 moles of
(d) On oxidation with HNO3, fructose yields a mixture of tartaric acid and glycollic acid, both
containing fewer carbon atoms than six.
PassageII
h
.
e
V0
h
e
h
e
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18.
(d) 2E E
4E
3
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= h eV0
is higher for B
V0
hc
E hc
3
3hc
3
E
hc
E
SECTION IV
Matrix Match Type
1.
2.
1.
Equivalent weight =
2.
V
RT
n
15 10 3
58
PV
8 V
=
RT
R T
10 V
R T
15 10 3
58 10
8 15 10 3
58 10
206.89
12.0 kg
A B