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Frothers For Mineral Processing
Frothers For Mineral Processing
Mineral Processing
Frothers
Development and testing
by :
Levi Guzman Rivera
Moly-Cop Adesur S.A
Introduction
Froth flotation is a highly
interactive
system including
water
chemistry,
pH,
hidrodynamic, particle size, etc.
The answer appears to be that
changing frother chemistry
structure
could
improve
metallurgical performance
Moly-Cop Adesur S.A has
been involved in developing
new frother chemistry.
Moly-Cop Adesur
Experience
Overview
A long experience with the frother
business, due to since 1987 to 1992
was the exclusive representative of
Ore Prep Chemicals.
In 1992
was formed Mineral
Reagents
International
Inc.,
Moly-Cop Adesur S.A. was chosen
to be one of the pilot business unit for
testing and developing new frothers
under Dr. Richard Klimpel direction.
Moly-Cop Adesur
Experience
Overview
In 1994 Armco signed an agreement
with
Dow
Chemical
Co.
to
commercialize
Dowfroth
mining
products
and
manufacture
new
chemical products for mining industry
In 1998 Moly-Cop Adesur S.A. built
its own blending facility in Callao
Lima.
In 2002 Moly-Cop
relocated its blending
Anita Lima.
Adesur S.A.
facility To Sta
Naturally Derived
materials as:
Inexpensive to
Pine oil
Very variable in
Cresilic acid
Xilenol
moderately priced
quality
Environmentally
regulated
Alcohols
Inexpensive to
Glycols
moderately priced
Polyglycols methyl
ether
Consistent in quality
Modified Alcohols
Environmentally not
Carbonyl materials
regulated
Inexpensive to
moderately priced
Consistent in quality
Effective used alone
Low dosage
Environmentally not
regulated
Main Frother
Families
Alkoxys
group
Polyglycols
group
The alcohol
group
The alcohol
group
The alkoxys
group
Polyglycol group
Polyglycol group
FROTHER REQUIREMENTS
Frothers
Requirements
Environmentally Safe
Frothers
Clasification
FROTHER CLASIFICATION
By Kinetics rate
using DFI and CCC
DF-400
DF-1012
DF-250
HEXANOL
DF-200
MIBC
20
30
50
100
70
Particle size, (microns)
200
300
500
we can notice that each specific frother is related to an effective particle size
ranges of particles, so we can deduct that no one frother structure can generally
float the broadness of particle size distribution in flotation process.
% Recuperacion en Peso
15,00
13,00
11,00
9,00
7,00
5,00
10
35
60
85
110
135
160
185
210
235
% Cu Recovery
DF250
MIBC
H212
10
100
1000
12
11
Calculated HLB
10
Glycero
l(PO)
n
T402
CH (C
3 3 H O)
6 n OH
DF400
DF1012
DF1263
T411
MIBC
E
W
O
U
RF
MIBC-2PO
Hexanol-2PO
-Terpineol
Hexanol
5
4
100
200
300
400
500
600
Molecular Weight
700
800
900
1000
By Kinetics Rate
1
Ri = R 1 (
) [1 exp( Kt ) ]
Kt
By Kinetics Rate
100
90
% Cu recovery
80
C-800
F-501
70
H-225
60
H-425
50
H-525
40
H-530
H-602
30
20
0
10
12
14
16
18
By Kinetics Rate
(%) Pb recovery
H425
TPG
H212
DF250
flotation time(min)
10
By Kinetics Rate
95
%Cu Recovery
85
H-530
H-525
H-520
H-515
H-501
75
65
55
45
35
25
0
10
Flotation Time (min)
15
20
C C 0
V
rt =
Q
Frother
MIBC
HEX
DEMPH
DEH
MPDEH
(PO)1
(PO)2
DF-200
DF-250
DF-1012
DFI
s.L/mol
34,000
33,000
290,000
94,000
170,000
5,700
35,000
196,000
208,000
267,000
CCC
mmol/L
0.11
0.079
0.013
0.031
0.016
0.52
0.17
0.089
0.033
0.015
DFI x CCC
S
3.74
2.61
3.77
2.91
2.72
2.96
5.95
18.44
6.86
4.0
1.5
CCC for MIBC
0.5
CCC for
DF1012
CCC for
DF250
0
0
0.1
0.2
Concentration (mmol/L)
0.3
0.4
300000
DEMPH
DFI (s.L/mol)
DF1012
DF250
200000
DF200
MPDEX
100000
DEH
HEX MIBC
(PO)1
(PO)2
0
0
0.2
0.4
CCC (mmol/L)
0.6
Conclusions
Moly-Cop Adesur S.A. research is based in giving to
the frother different properties as kinetics, selectivity,
grain size floatability, froth stability, these ones are
combined to obtain the best metallurgical performance
for each application.
The broad of products developed by Moly-Cop
Adesur S.A., allows to address specific mineral
processing problems by providing the best hydrophobic
frother solution.
Conclusions
In research work, there were
identified some trends in
order to improve the frother
capability, as follows:
To float slimes and coarse
particles
Larger flotation cells require
more stronger frother
Alternative
equipments
(column cells, Flash Flotation,
etc)
More complex ores systems
(Oxides)
Improve Kinetics rate
........ many others
Conclusions
Moly-Cop
Adesur
S.A.
Conclusions
Need to blending frothers in order
to improve particle size flotability
Making
frothers
more
hydrophobic, it is possible to
float coarser particles
Conclusions
Lab testing gives good approach for
new raw materials an to analyze froth
(persistance, breakage, etc)