TOPICS in CHEMISTRY and MATERIAL SCIENCE

volume 1

ADVANCED
MICRO- AND MESOPOROUS
MATERIALS
edited
K.

Hadjiivanov, V. Valtchev,

HERON PRESS

by
S.

Mintova, G. Vayssilov

SOFIA. MMVW

Advanced Micro- and Mesoporous Materials

eds. K. Hadjiivanov, V. Valtchev, S. Mintova, G. Vayssilov
Heron Press, Sofia, 2008

Contents

L.G. Gordeeva, Yu.l. Aristov

Nanocomposite

Sorbents "Salt inside Porous Matrix":

Composition and Sorption

L.F. Petrik, Z.G.

Properties,

Godongwana,

P.

Practical

Ndungu,

Design of Phase
1

Applications

V.M. Linkov, S. Liao

LPG Synthesis of Carbon Analogue of HMS

11

K. Bachari, A. Saadi, D. Halliche, O. Cherifi

Study

of the

Benzylation

of Aromatics

on

Nickel-Containing Mesoporous

Materials

20

G. Busca, E. Finocchio, M.

Infrared Studies
B.B.

Pejova,

on

the

Bevilacqua,

T. Montanari

Localization of Acid Sites on Microporous Materials

I.S. Grozdanov

Semiconducting Bismuth(m) Sulfide Quantum Dots

A

Study of Photophysical Properties

and

in Thin Film Form:

Photoconductivity Relaxation Dynamics

Lj. Pejov, I. Petreska, M. La Rosa, Lj. Kocarev

Dynamics of the Central Phenylene Ring Torsional Motion in Phenylene
Ethynylene Oligomers: a Quantum-theoretical Study of Single-Molecule
Switching Phenomena
Z.

B.

Abdessadek, F. Touahra, K. Bachari, A. Saadi, O. Cherifi, D. Halliche

Synthesis, Characterization and Application of Ni/Mg/Al(La) Hydotalcites in
Methane Dry Reforming
Cekova, D. Kocev, E. Kolcakovska
Obtaining Co2+ Form Using Ionic Exchange
Solution of

V.

Stengl,

S.

Ti02/ZnS

31

41

50

60

of Zeolite 4A with Water

Co(N03)2

68

Bakardjieva, V. Houskova, N. Petrova, Yu. Kalvachev

Nanocomposites Characterization and 'Visible-Light Photocatalytic
-

'.

74

Preparation and Characterization ofTitanosilicate Ag-ETS-10

87

Activity
I. Tiscornia, S. Irusta, M.E. Venturini, D. Blanco, C. Tellez,
J. Santamari'a, J. Coronas

S.M. Hashemianzadeh, A.A. Rafati, Z.B. Nojini

Host-Guest Inclusion Complexes of the Local Anesthetic Drugs
Procaine

Hydrochloride and Butacaine Hydrochloride

/3-Cyclodextrins: Semi-Empirical Studies

with

a-

and
97

CONTENTS
Y. Ghadarghadr, H. Karimi, S.M.
Monte Carlo Simulation of

Single

Hashemianzadeh, A.H.

Hydrogen

Amin
and Methane Mixture
Storage

on

Walled Carbon Nanotubes

N. Petrova, R.

110

Petrova, Ts. Stanimirova, R. Titorenkova,

S.

Bakardjieva

Synthesis and Characterization of Mg-Al Layered Double Hydroxides

Containing Squarate

or

119

Hydrogensquarate Anions

S. Walspurger, J. Sommer, B. Louis

Design

of Metallic Sites in Solid Acid

128

Catalysts

H. Iglev, M. Schmeisser, A. Laubereau

Ultrafast Temperature and Pressure Changes in H-bonded
S.

Zanardi,

A. Carati, C.

Rizzo,

R. Millini, M.C Dalconi

Structural Characterization of the Hydrated and

Ion-Exchanged

137

Systems

Dehydrated Forms

of
146

Stannosilicate EMS-2

V.I. Isaeva, O.R Tkachenko, I.V. Mishin, A.A.

Kostin,

T.R. Brueva,

K.V. Klementiev, L.M. Kustov

Preparation and
Zn Ions and

L.A.

Correia,

R.

Zaleski,

155

Carboxylate Ligands

E.W.

Mechanical

Characterization of MOF-5 Modifications Derived from

Y.C. van Delft

Schuring,

Testing of Adherence of Stacked Layers in Tubular Geometry

163

J. Goworek

Positron Porosimetry Study of Ordered Mesoporous Materials

170

S.M. Hashemianzadeh, B. Sohrabi, B.T. Ahmadabad

The

Study of PEG Effects

S. Habib, J.-D.

Comparot,

on Nanostructures Size in Ionic Surfactants

F.

Launay,

S.

179

Laforge, Y. Millot,

J.-L. Paillaud, C. Faust, P. Magnoux, A. Gedeon

Synthesis and Characterization of Micro/Mesoporous

Prepared from ZSM-5 Zeolite
L.

Capek, J. Adam, G. Kosova-Kucerova,

P.

Knotek,

Molecular Sieves
186
R. Bulanek

of Vanadium Based Mesoporous Materials in Oxidative

High Activity
Dehydrogenation of Ethane

200

L. Juhasz, A. Vass-Varnai, C. Dominkovics, V. Timar-Horvath

Porous

AI2O3 Layers for Capacitive RH Sensors

209

M. Manouchehri Nezhad, S.N. Ashrafizadeh, A. Malekpour

Synthesis

and Characterization of Silicalite-1 Based Membranes for

Aromatic

Separation

221

M. Anbia, S.N. Ashrafizadeh

Non-Thermal

Synthesis of Nanoporous Lanthanum Tungstate as a Novel

Heavy Metal Cations and Organic Pollutants from

Sorbent for the Removal of

234

Wastewater Streams

A. Borowka, J. Goworek
Meso- and

viii

"Microporosity"

of MCM-41 Silicas

243

CONTENTS

V.

Cauda, R. Mortera, S. Fiorilli, B. Onida, F. Baino, E. Verne,

Brovarone, G. Croce, D. Viterbo, E. Garrone

C. Vitale

Ordered

Mesoporous Silica inside Bioactive Scaffolds for Local Drug Release.. 251

C. Resini, M.C.H. Delgado, S. Presto, L.J. Alemany, R Riani,

R. Marazza, G. Busca
Evaluation of Surface Activity and Its Modification during
Reforming over YSZ-Supported Ni-Co Alloy

Ethanol Steam
259

V. Pashkova, K. G6ra-Marek, L. Lityriska-Dobrzyriska, M. Derewiriski

Preparation of New Acid-Type Catalysts Containing Nanoclusters of

Zeolites (FAU, BEA) Dispersed in the Amorphous Porous Matrix
V.

Tsukala, V. Nikolakis, S.N. Yannopoulos

Encapsulation of Selenium in Silicalite-1 Crystals

270

278

A. Burkat-Dulak, L. Litynska-Dobrzyriska, M. Derewiriski

286

Preparation of Bifunctional Catalysts

E. Ivanova, M.
FUR

Exchanged
R.

Mihaylov,

K.

Hadjiivanov,

H.

Knozinger

Study of Low-Temperature CO Adsorption on

Kefirov,

M.

EMT Zeolite

with Alkali-Earth Cations

Mihaylov,

M.

Che,

K.

295

Hadjiivanov

FTIR Study of the Interaction of Ni(CO)4 with H-ZSM-5 and

Ni-H-ZSM-5 Zeolites

A.

304

Stefanov, K. Hadjiivanov, S. Dzwigaj, M.

Study by XPS and
Spectroscopy of Adsorbed CO and NO

Mihaylova,

P.

Che

Cobalt Ions in Siliceous BEA Zeolite:

FTIR

E.-P.

Ng,

S. Mintova

Nanoporous Materials
G.J.

313

as

High

Selective Water Sorbents in Lubricants

Majano, S. Mintova
Sorption of Hydrocarbons on

Selective

Zeolite Beta

322

330

V. Gurin, I. Tuzovskaya, N. Bogdanchikova, A. Pestryakov,

M. Avalos, M.H. Farfas
Stabilization of Gold in Zeolites with Various Structural and Ionic

Properties...

Kox, B.M. Weckhuysen

Catalytic Behavior of Zeolite Crystals as Revealed by
Optical and Fluorescence Micro-Spectroscopy

337

E. Stavitski, M.H.F.
Non-Uniform
In-Situ

Dogu, G. Dogu, S. Damyanova

Dry Reforming of Methane

346

C. Sener, K. Arishtirova, R.N. Nikolov, T.

MCM-41-Supported Ni Catalysts
M.R.

Mihalyi,

for

I.N. Kolev, V.P. Mavrodinova, M.

355

Kollar, T. Koranyi,

Ch.l. Minchev
Effect of the Partial Substitution of Al

the

Selectivity

and

Catalytic Activity

by

B in MCM-22 Zeolite on

in Toluene

Disproportionation

363

M. Jaber, J. Piovan, V. Valtchev

Nanoporous Zinc-Silicate Rods: Synthesis

and Characterization

372

ix

CONTENTS

M.

Hureau,

A.

Moissette, C. Bernard,

H. Vezin

Long Lived Radical Cation-Electron Pair Induced by Spontaneous

Ionization of t-Stilbene in Medium Pore Ferrierite Zeolite
Author Index

379
...390