Fase heterognea (1er orden)

Balance de materia

d 2
2
r N Ar ) + K C A r =0
(
dr
A B
N Ar =N Br
N Ar=J Ar +Y A (N Ar + N Br)
d
2
2
r D Ac d C A ) =k C A r
(
dr
1 d 2 dCA
K
r
=
C (1)
2
dr
D Ac A
r dr

Condiciones de frontera

r=0

dCA
=0 ( I )
dr

r=R C A =C As ( II )

Cambio de variable

C A f (r) d C A
f ' (r ) f (r )
=
,
=C As [
2 ]
C As
r
dr
r
r

dCA
f ' (r ) f ( r)
=C As [
2 ]
dr
r
r
'

''
'
'
2
2
d CA
f ( r ) . rr f ( r ) f ( r ) .r r f ( r )
=C As [

]
2
4
dr
r
r
2

d CA
f ' ' (r ) f ' (r ) f ' (r ) 2 f ' (r )
=C As [
2 2 + 3 ]
dr
r
r
r
r
Reemplazando en la ecuacin (1) y simplificamos
2

d f (r ) K
d f (r )
=
. f (r )
=m2 . f (r)
2
D Ae
dr
dr 2
r=R , f ( r )=R

r=0 , f ' ( r ) =0
f ( r ) =C1 e mr +C2 emr
m=

K
D Ae

f ( r ) =C1 senh ( mr ) +C 2 cosh ( mr)

C A C1
C
= senh ( mr ) + 2 cosh ( mr)
C As r
r
CA=

C1 .C As
C .C
senh ( mr ) + 2 As cosh ( mr)
r
r

CA=

C1
C
senh ( mr )+ 2 cosh ( mr ) ( )
r
r

d C A C1 mr . cosh ( mr )C1 senh (mr) C 2 mr . senh ( mr )C 2 cosh (mr )

=
+
( )
dr
r2
r2
Reemplazando de II en

CA=

C1
C
senh ( mR ) + 2 cosh ( mR ) (1 )
R
R

Reemplazando de I en

0=

De

()

( )

C1 senh (0) C2 cosh (0)

+
C2=0 (2 )
0
0

(2 ) y

C As=

Cf=

(1 )

C1
R
senh ( mR ) C 1=C As .
R
senh ( mR )

C As R
1
R senh(mr )
. senh ( mr ) C A =C As
.
r senh( mR)
senh ( mR ) r

( )

Densidad de flujo molar

N Ar r=R =D Ae .

dC A

dr r =R

'

'

senh ( mr ) r senh (mr)

dC A
C As R
=
.
dr senh ( mR )
dC A
C As R
senh ( mR )
m
=
.[ .cosh ( mR )
]
dr senh ( mR ) R
R2
1
N AR r=R =D Ae .C As [mctgh ( mR ) ]
R
N AR r=R =

mR=

D Ae . C As
. [R . mctgh ( mR )1]
R

K
2
. R =
D Ab

N AR r=R =

D Ae . C As
. [ . ctgh ( )1]
R

Flujo molar real

W R=N AR r= R . 4 R 2=4 R 2 .

D Ae .C As
.[ . ctgh ( ) 1]
R

Calculo de factor de efectividad

n=

WR
4
,W T =K C As R3
WT
3
4 R2 .

n=

D Ae . C As
.[ . ctgh ( )1]
R
4
K C As R 3
3

Simplificando

n=

3
.[ . ctgh ( ) 1]
2

d CA 2 dCA
K
+ .
=
.C
2
r dr
D AB A
dr

Resolviendo por mtodos numricos

r=0,

d2C A
dr

K
. C =0
3 D AB A

K
K
2
K
2
2
2
. R =
. R 2=
D Ab
D Ab
D
R
AB

d 2 C A 2
2 .C A =0
dr 2
3R