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Practical Techniques For Cathodic Protection Potential Measurement
Practical Techniques For Cathodic Protection Potential Measurement
In order to determine the adequacy of a cathodic protection system applied on a certain structure, its
polarized potential has to be measured. The polarized potential is the summation of corrosion
potential and the amount of polarization that the structure has, excluding the soil IR drop.
Polarized potential is the potential across the structure-to-electrolyte interface. Below, we will talk
about the practical techniques that can be used to measure a structure's polarized potential.
Positive Spiking
When the current is interrupted, a positive spike occurs in the measured potential due to the
inductive and capacitive effects of the pipeline, which doesn't represent the true potential of
the pipeline. The duration of this spike may be 0.3 seconds. So, the instant OFF potential
reading, which represents the polarized one, should be recorded after this time has passed.
Recirculating Currents
Recirculating currents are post-interruption currents that are generated between highly
polarized locations and lesser polarized locations. Due to these currents, the measured
potential at highly polarized locations is more positive than the true one, while at less
polarized locations the measured potential is more electronegative than the true one. The
error in measured potential due to these currents is 150 mv.
3. External CP Coupons
CP coupons are intended to simulate a small portion of a well-coated pipeline like a holiday; they are
manufactured from the same alloy as the protected structure, and they are typically 10 to 100 cm in
surface area.
CP coupons should be buried near the protected structure in the same electrolyte, subjected to the
same CP current and connected electrically to the protected structure.
CP coupons can be used to determine the corrosion rate of the structure or to monitor the adequacy
of the applied CP system.
In order to determine the corrosion rate, the coupon needs to be weighed beforehand and then
buried and connected to the structure. After a certain time, the coupons should be removed and
weighed. The corrosion rate is the weight loss per time.
For monitoring of CP potential, the connection between the coupon and the pipeline needs to be
interrupted instantaneously and the reference electrode should be placed in a soil tube to eliminate
any IR drop in the soil. So, the polarized potential of the coupon can be measured with respect to the
reference electrode placed in the soil tube. If the polarized potential of the coupon is -850 mv/cse or
more negative, any holiday of the same size or smaller will be equally well protected.
The above techniques are the most practical ones used for potential measurements, but in order to
obtain correct measurements, proper instruments have to be used. These techniques are very
important for any structure-to-electrolyte potential survey.
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