Table B.

2 Heat Capacities"
Form 1: Cp[kJ/(mol-0C)] or [kJ/(mol-K)] = a + bT + cT2 + dT3
Form 2: Cp[kJ/(mol-C)] or [kJ/(mol-K)j = a + bT + cT~2
Example: (Cp)acetone(g) = 0.07196 + (20.10 X MT5)r - (12.78 X 10~8)r2 + (34.76 X lQ-12)r3, where T is in C.
Note: The formulas for gases are strictly applicable at pressures low enough for the ideal gas equation of state to apply.

Compound

Formula

Mol.
Wt.

Acetone

CH3COCH3

58.08

Acetylene
Air

C2H2

Ammonia
Ammonium sulfate
Benzene

NH3
(NH4)2S04

Isobutane
-Butane
Isobutene
Calcium carbide
Calcium carbonate
Calcium hydroxide
Calcium oxide
Carbn
Carbn dioxide
Carbn monoxide
Carbn tetrachloride
Chlorine
Copper

C4H10
C 4 Hio
C4HX
CaC2
CaCO3
Ca(OH)2
CaO
C
C02

co

CC14
C12
Cu

26.04
29.0
17.03
132.15
78.11
58.12
58.12
56.10
64.10
100.09
74.10
56.08
12.01
44.01
28.01
153.84
70.91
63.54

State
1
g
g
g
g
g
c
1
g
g
g
&
c
c
c
c
c

g
g
1
g
c

Temp.
Form Unit
1
1
1
1
1
1
1
1
1
1
1
1
2
2
1
2
2
1
1
1
1
1

C
C
C

K
C
K
C

c
c
c
K

K
K
K

K
C

c
K
C
K

cXlO8

d X 1012

flXlO3

b x 105

123.0
71.96
42.43
28.94
28.09
35.15
215.9
126.5
74.06
89.46
92.30
82.88
68.62
82.34
89.5
41.84
11.18
36.11
28.95
93.39
33.60
22.76

18.6
20.10
6.053
0.4147
0.1965
2.954

-12.78
-5.033
0.3191
0.4799
0.4421

34.76
18.20
-1.965
-1.965
-6.686

23.4
32.95
30.13
27.88
25.64
1.19
4.975

-25.20
-18.91
-15.47
-17.27
-8.66 X 1010
-12.87 X 10'

77.57
49.87
34.98
50.50

2.03
1.095
4.233
0.4110
12.98
1.367
0.6117

-4.52 X 101
-4.891 X 1010
-2.887
0.3548
-1.607

7.464
-2.220
6.473

Range
(Units
or)
-30-60
0-1200
0-1200
0-1500
273-1800
0-1200
275-328
6-67
0-1200
0-1200
0-1200
0-1200
298-720
273-1033
276-373
273-1173
273-1373
0-1500
0-1500
273-343
0-1200
273-1357

"Adapted in part from D. M. Himmelblau, Basic Principies and Calculations in Chemical Engineering, 3rd Edition, 1974, Table E.l. Adapted by
permission of Prentice-Hall, Inc., Englewood Cliffs, NJ.
(continued)

X)

&

fr

TableB.2 (Continued)

CgHn

Cumene
(Isopropyl benzene)
Cyclohexane
Cyclopentane
Ethane
Ethyl alcohol
(Ethanol)

Formula

Compound

CgHi2
CsHio
C2H6
C2H5OH

Mol.
Wt.
120.19
84.16
70.13
30.07
46.07

98.18
84.16
63.02
30.01

C7H14
CeH^
NH03
NO

32.04

CH3OH

Methyl alcohol
(Methanol)
Methyl cyclohexane
Methyl cyclopentane
Nitric acid
Nitric oxide

H2
HBr
HC1
HCN
H2S
MgCl2
MgO
CH4

Hydrogen
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen sulfide
Magnesium chloride
Magnesium oxide
Methane

C2H4
Fe2O3
CH2O
He
CfiHu

Ethylene
Ferric oxide
Formaldehyde
Helium
n-Hexane

28.05
159.70
30.03
4.00
86.17
2.016
80.92
36.47
27.03
34.08
95.23
40.32
16.04

State Form
g
g
g
g
1
1
g
g
c
g
g
1
g
g
g
g
g
g
c
c
g
g
1
g
g
g
1
g

!<

1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
1
1

Ternp.
Unit
C
C
C
C

c
c
c
c
K

c
c
c
c
c
c
c
c
c
K
K
C
K
C

c
c
c
c
c

aXlO3
139.2
94.140
73.39
49.37
103.1
158.8
61.34
+40.75
103.4
34.28
20.8
216.3
137.44
28.84
29.10
29.13
35.3
33.51
72.4
45.44
34.31
19.87
75.86
42.93
121.3
98.83
110.0
29.50

b x 105
53.76
49.62
39.28
13.92

15.72
11.47
6.711
4.268

40.85
0.00765
-0.0227
-0.1341
2.908
1.547
1.58
0.5008
5.469
5.021
16.83
8.301
56.53
45.857
0.8188

c X 108

-39.79
-31.90
-25.54
-5.816

-8.749
-6.891
-17.72 X 1010
0.0000

-23.92
0.3288
0.9887
0.9715
1.092
0.3012
-8.732 X 1010
0.3661
1.268
-1.87
-37.72
-30.44

d x io12
120.5
80.63
68.66
7.280

19.83
17.66

-8.694

57.66
-0.8698
-4.858
-4.335
-3.292

-11.00
-11.00

-8.03
"-- 100.8
83.81

-0.2925

0.3652

Range
(Units
of T)

xj
T3
a
O.
x"
W

0-1200
0-1200
0-1200
0-1200
0
100
0-1200
0-1200
273-1097
0-1200
0-1200
20-100
0-1200
0-1500
0-1200
0-1200
0-1200
0-1500
273-991
273-2073
0-1200
273-1500
0-65
0-700
0-1200
0-1200
25
0-3500

Nitrogen
Nitrogen dioxide
Nitrogen tetraoxide
Nitrous oxide
Oxygen
n-Pentane

N2
NO2
N204
N2O
02

Propane
Propylene
Sodium carbonate
Sodium carbonate
decahydrate
Sulfur

Sulfuric acid
Sulfur dioxide
Sulfur trioxide
Toluene

C3H8
, 44.09
C3H6
42.08
Na2CO3 , 105.99
Na2CO3' 286.15
10H2O
S
32.07
c
(Rhombic)
c
(Monoclinic)
1
98.08
H2S04
64.07
SO2
r
g
SO3
80.07
g
92.13
1
C7H8

Water

H2O

QHi2

28.02
46.01
92.02
44.02
32.00
72.15

18.016

g
g
g
g
g
1
g
g
g
c
c

0.2199
3.97
12.5
4.151
1.158
43.68
34.09
22.59
17.71

K
K

15.2

2.68

273-368

18.3

1.84

368-392

1
1

C
C
C
C

139.1
38.91
48.50
148.8
94.18
75.4
33.46

15.59
3.904
9.188
32.4
38.00

1
1
1
1
1

1
1

1
1
1
1

C
C
C

c
c
c
c
c
c

c
c
c

0.6880

0.5723
2.88
-11.3
-2.694
-0.6076

-2.871
7.87

-18.99
-13.11
-10.17

42.26
31.71
24.60

0-1500
0-1200
0-300
0-1200
0-1500
0-36
0-1200
0-1200
0-1200
288-371
298

29.00
36.07
75.7
37.66
29.10
155.4
114.8
68.032
59.580
121
535.6

1
1

-3.104
-8.540
-27.86
0.7604

10.57
1.311

8.606
32.40
80.33
-3.593

10-45
0-1500
0-1000
0-110
0-1200
0-100
0-1500

hd
c?

o'
^-t
O
O>