problem statement

1-profile of

A k1 B k 2 C k 3 D

k 1=k 2=k 3

For A:
dC A
=k 1 C A , C A =C A C A CA =1 , k 1 t=t
dt

CA

dC A
dC A
dC A
CA

C A
=k 1 C A C A
=k 1 C A =k 1 dt ln =k 1 t
dt
dt

CA
CA
C
0

A0

( )
0

k 1 t

C A =1ln C A =k 1 t C A =e
0

=e

For B:
dC B
=k 1 C A k 2 C B ,C B =C A C B
dt
0

dC B
dCB
dC B

CA
=k 1 C A C A k 2 C A C B
=k 1 C A k 2 C B k 1 =C A CB
dt
dt

dt
0

C B=

1
et

For C:

( et e t d t +C ) @t =0 C B =0 CB=t . et

dCC
=k 2 C B k 3 CC , CC =C A C C
dt
0

dC C
dC C
dC C

CA
=k 2 C A C B k 3 C A C C
=k 2 C B k 3 C C k 2 =C B CC
dt
dt
dt

CC =

1
et

( t et e t d t +C ' ) @ t =0 C C=0 C C= 12 .t 2 . et

For D:
dC D
=k 3 C C , C D =C A C D
dt
0

dC D
dC D
dC
t 2 et
CA
=k 1 C A C C
=k 3 C C k 3 D =C C dCD=
dt
dt
2
dt
dt

CD

2 t

C = t 2e t et et +C } {
0

{C} ^ {

C
t . et
( o)B = = 2 t
C
t e
t et et +1
2

S
dCB

d t C A C B
( p)B= =
dC D
C C
d t

2 t

t e
=1 C =
t et et + 1

S
( o)C =

1 2 t
.t .e
2

C
= 2 t
C
t e
t et et + 1
2

dCC

C C
dt
( p)C = = B C
dC D
CC

dt

1
0.8

point selectivity of C

0.6
0.4
0.2
0
-0.2
-0.4
-0.6
-0.8
-1

5
time

10

0.4
0.35

overall selectivity of C

0.3
0.25
0.2
0.15
0.1
0.05
0

5
time

10

1
0.8

point selectivity of B

0.6
0.4
0.2
0
-0.2
-0.4
-0.6
-0.8
-1

5
time

10

0.7

overall selectivity of B

0.6
0.5
0.4
0.3
0.2
0.1
0

0.1

0.2

0.3

0.4

0.5
time

0.6

0.7

0.8

0.9

1
0.9
0.8

concentration

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0

5
time

10