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I. Chem. E. Symposium Series No. 85
I. Chem. E. Symposium Series No. 85
85
Thomas*
INTRODUCTION
The protection of chemical plant from over-pressurisation entails satisfying
the contradictory requirements of preventing the emission of hazardous
products and ensuring that the plant cannot suffer catastrophic failure. The
systems described below have been developed over the past ten years primarily
on emulsion polymerisation plant producing vinyl acetate - ethylene - vinyl
chloride copolymers in vessels with design pressures up to 100 bar. However,
basically the same principles can be applied to many other processes.
With hazardous feed stocks such as ethylene or vinyl chloride, emphasis has
been on minimising the emission of unreacted materials to atmosphere, the
dispersion of any such emissions to prevent flammable cloud formation, and the
containment of the liquid phase within the plant. The same principles will
apply to many processes within the chemical industry where protection of the
environment is paramount.
In the examples of systems described in the paper, operating levels of the
various stages of protection are expressed as a percentage of the system
design pressure, rather than in engineering pressure units. This is intended
to illustrate the principles of operation and to assist in their application
to equipment with differing pressure ratings.
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2)
A non-pressure vent tank meant that the venting of gas through the
flame arrestor could not be controlled, owing to the risk of damage
to the tank.
3)
4)
System 2
This system incorporates much that has been learnt from the early system and
is shown schematically in Fig. 2.
The major difference is the adoption of a dual parallel bursting disc system
with a relief valve mounted over the primary disc. The vent tank is now a
pressure vessel and is equipped with a number of pressure protection devices;
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the vent gases are now carried to a 40 metre high vent stack with oxygen
analysis and automatic nitrogen purging.
In operation, the vent tank is kept under vacuum at a pressure of about 0.15
bar absolute. In the event of a high pressure alarm, the operator manually
shuts all feeds to the reaction vessel, and via a pressure control valve vents
the gas space to the vent tank. The vent tank remains closed until the
pressure rises to above atmospheric, when the vent valve opens allowing gas to
pass through to the high-level vent stack. A foam alarm on the vent tank top
prevents liquids being entrained with the gas to the vent stack by closing the
vent valve. When the pressure in the vent tank rises to 75% of its burstingdisc rating, the inlet valve closes, preventing further pressurisation until
the foam alarm clears and venting resumes. With vent tank capacity three
times that of the reactor and the vent tank normally evacuated during the
process, the reaction vessel pressure can be reduced considerably before a
combination of vent tank pressure and high foam level causes the inlet valve
to close.
In the event of the pressure continuing to rise the reaction vessel extra-highpressure alarm system can still vent to atmosphere. If this system fails
then the bursting disc under the relief valve will rupture giving a controlled
discharge via the relief valve. Ultimate vessel safety is ensured should all
the foregoing fail, by a single high pressure disc set to burst at 1.3 times
the vessel design pressure. It is now thought that the refined system 2
offers the most effective method of containing the products of overpressurisation while preventing catastrophic plant failure.
THE EFFECTS OF SAFETY DEVICES ON WORKING PRESSURES
The system described above, with it's four stages of pressure relief, requires
discreet pressure steps between each stage. Codes of Practice for vessel
protection lay down guide lines for the rating of pressure relief devices
in relation to the design pressure of equipment, and the limitations on safety
devices also contribute to a general lowering of actual maximum working
pressures.
In satisfying the conditions of the vessel design code BS 55OO relating to
pressure relief devices and the application of BS 2915, the relevant
paragraphs are as follows:BS.5500
J.8.1.
BS.550O
J.8.5.
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BS.2915
5.7.
BS.2915
5.8.
BS.2915
5.9.
It is significant that J.8.5. states that the bursting disc will be rated at
atmospheric temperature to burst at a pressure not greater than 1.3 times
the design pressure, as opposed to BS.2915, 5.9. which merely states "at the
disc operating temperature". Thus in a vessel designed for a working temperature of 100C, the primary relief system can be specified to operate at
100C, but the secondary relief system must operate no higher than 1.3 times
the design pressure at ambient temperature, to satisfy BS.5500. This can
lead to a significant loss of pressure rating if the vessel works at
elevated temperatures due to the temperature co-efficient of the disc material.
Additionally, both BS.5500 and BS.2915 specify that the maximum burst pressure
of the safety disc is not greater than either the design pressure for the
primary disc, or 1.3 times the design pressure for the secondary disc. This
definition of maximum burst pressure can also seriously affect the working
pressure of the vessel, since bursting discs are typically rated 5% on burst
pressure; thus the rated pressure of the primary disc can be no more than
95.2% of vessel design pressure, while manufacturing tolerance allows disc
failure as low as 90.5% with a maximum of 10O%. Similarly, at ambient temperature the secondary disc rating would be 123.8%, with a burst range of
117.6 - 13O%. Luckily, disc manufacturers can offer some assistance by
supplying discs with a smaller tolerance above the rated pressure than below,
or by providing 2% discs which significantly reduce the possibility of
overstressing the secondary disc before failure of the primary disc.
The choice of disc construction can have a pronounced effect on maximum
working pressure. Conventional (pressure-under-the-dome) bursting discs
typically have a lower tolerance to pressurisation close to the burst pressure
than reverse-buckling or tear-out discs. Cycling of pressure also affects
bursting disc rating adversely, leading to creep on conventional discs with
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required. The operator may now be watching more than one control station,
with the computer carrying out all the control and sequencing functions. It
is also felt that it could be hazardous to give computer control to a single
device such as an automatic vent valve, since computer failure can occasionally
have a positive control action causing the valve to open. Hard-wired devices
can be more effectively constructed to give safe failure on signal, air or
electrical breakdown.
For this reason the computer system has a number of extra steps. The recipe
for each product contains information on the normal process pressure attained
during the cycle; this is used to trigger a process deviation alarm should the
pressure rise significantly above this figure, typically between 5 and 10%.
This first alarm will alert the operator to consult the computer, but will not
necessarily trigger any further action. If the pressure continues to rise,
the normal vessel high-pressure alarm operates, shutting off feeds to the
vessel, suspending the sequences of operation and raising a hard-wired alarm
as well as a computer alarm. Pressure increase to the high state will cause
the computer to vent via a block and control valve to the vent tank, which is
equipped with the same safety devices as System 2; hard-wired and computer
alarms will also be activated. Should the computer fail to reduce the
pressure correctly, manual control of the venting system is possible, with
finally a separate key switch vent valve allowing the operator to vent
directly to atmosphere, so reducing the vessel pressure and averting bursting
disc failure.
To ensure the integrity of the system, dual pressure sensing units are
employed, and the computer will suspend sequences if the two elements indicate
different pressures.
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SUMMARY
The systems described represent an effective and tested method of applying
multi-stage over-pressure protection to high-pressure chemical plant, with
the emphasis on containment prior to the final stages of pressure relief. The
systems can be effectively applied to lower pressure plant, although problems
can arise from the smaller pressure changes between each step. The systems
require the employment of accurate and repeatable measuring elements for the
operation of each stage.
Finally, it is our firm belief that bursting discs should never be called upon
to burst under process conditions; the safety of the plant should be ensured
by the preliminary pressure relief systems, and relief to atmosphere should be
a secondary element within those systems.
ACKNOWLEDGEMENTS
The author wishes to acknowledge that the development of the systems described
has been a joint effort by members of the engineering department at Vinyl
Products Limited, and would like to thank the following for their assistance
in the preparation of this paper.
Mr. A.T. Anderson
Project Engineer
Dr. R. Straus
Miss. C. Tappenden
References
BS.550O
1976
BS.2915
1974
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Fig. 2
Refined System 2 Design
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