SA 15 16 XII XII Chemistry Unit-2 Section-A

Organic Chemistry
UNIT
Section - A : Straight Objective Type

1.
2.
Answer (1)
Fluorine cannot be detected due to its more electronegativity.
Answer (3)
WBaSO 4
32
%S = 233 W
100
compound
...
18.5 =
32
6.48
100
233
W
3.
W = 4.81 gram
Answer (2)
4.
32
100 42%
76
Answer (2)
%S =
5.
6.
7.
O2 + 2C 2CO
5 CO + I2O5 I2 + 5 CO2
Answer (1)
Nitrogen is detected by Duma and Kjeldahl method only.
Answer (4)
These substances cannot give NH3 gas.
Answer (3)
Na2S + Na2 [Fe(CN)5NO] Na4 [Fe(CN)5 NOS]

Answer (3)
HCN and H2S are vapourised.
9. Answer (1)
PbCrO4 absorbs SO2 to form PbSO4.
10. Answer (3)
Boiling point decreases with decrease in vapour pressure.
11. Answer (4)
These are solid polar organic compounds.
12. Answer (2)
8.
%C =
WCO2
12
100
44 Wcompound
%H=
WH2O
2
100
18 Wcompound
13. Answer (4)

These all methods are for halogens.
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112
Organic Chemistry
Success Achiever (Solutions)
14. Answer (1)
WMg2P2O7
62
%P = 222 W
100
compound
14a.
Answer (2)
[JEE (Main)-2014]
As per question
H2SO4
NaOH
Normality Volume
N
60 mL
5
N
20 mL
10
(ngeq )H2SO4 (ngeq )NaOH (ngeq )NH3

1
60
1
20
(ngeq )NH3
5 1000 10 1000
6
1
(ngeq )NH3
500 500
(ngeq )NH3
5
1
500 100
(nmol )N (nmol )NH3 (ngeq )NH3

(Mass)N
14
0.14 g
100
Percentage of "N"
14b.
1
100
0.14
100 = 10%
1.4
Answer (1)
[JEE (Main)-2015]
Percentage of Br
=
Weight of AgBr
Mol. mass of Br
100
Mol. mass of AgBr Weight of O.C.
141 80
100 = 24%
188 250
15. Answer (1)
Mass of Platinichloride 195 410

Mass of platinum
Molar mass of base =

basicity
2
16. Answer (2)
weight of silver salt
108 107 = 45
108 107 =
Equivalent weight of acid =
0
.
7
weight
of
silver
basicity =
Molar mass
90
=
=2
Equivalent mass
45
17. Answer (4)

Dumas method can be used in all nitrogen containing compounds.
18. Answer (1)
It can combine with all Cl, Br, I, P, S, N elements due to high reactivity.
Organic Chemistry
113
19. Answer (4)

Information based.
20. Answer (4)
All can be converted to vapour state directly from solid state.
21. Answer (1)
Cryoscopic and ebullioscopic methods are for non-volatile solutes.
22. Answer (4)
NaOH
FeSO 4
Fe OH
green
NaCN
2
Fe2(SO4)3
Na 4 Fe CN
Fe 4 Fe CN
blue
6 3
23. Answer (1)

P
Na 3PO 4
H3PO 4
(NH4 )2 MoO4
NH4
HNO 3
PO 4 .12MoO 3
24. Answer (4)

Cd OAc
H2 S
CdS
(yellow ppt.)
25. Answer (2)
1 mass of Pt salt
195 410
2 mass of Pt
26. Answer (3)

Equivalent weight of acid =
0.76
108
0.54
107
45
Molar mass of ester = 2 45 2 + 2 45 = 178

27. Answer (2)
2
2
4
3
2
1
28. Answer (3)
1
2 | 1
29. Answer (3)

It is aromatic
30. Answer (1)
It is aromatic
30a.
Answer (2)
(AIEEE 2009)
CCl3 > C6H5 CH2 > (CH3)2 CH > (CH3)3 C

31. Answer (3)
(1, 1) (1, 2) (1, 3) (1, 4) (1, 5) (2, 2) (2, 3) (2, 4) (3, 3) dihaloderivatives are possible.
114
Organic Chemistry
32. Answer (1)
CH3 O C H2 CH3 O CH2

33. Answer (2)
Maximum electron density containing nitrogen.
34. Answer (1)
n-octane > n-nonane > n-hexane > n-heptane.
35. Answer (4)
Just attached elements contain lone pair of electrons.
36. Answer (3)
All given groups show +R effect.
37. Answer (4)
OH is weaker nucleophile than NH2.

38. Answer (3)
More will be negative charge on less electronegative carbon atom, more will be basic character.
39. Answer (4)
There are only functional isomers.
39a.
Answer (4)
[JEE (Main)-2014]
Cl
CN
(b)
(a)
(c)
Cl
CN
=0
=0
(d)
40. Answer (2)

It contains 10 electrons.
41. Answer (3)
+
CH CH2
is formed as a most stable carbocation.
42. Answer (2)

R H + x R + HX
43. Answer (3)
Butanone cannot form any other type of Ketone.
44. Answer (1)
Both have different carbon chain length.
45. Answer (2)
It can form most stable conjugate base.
46. Answer (2)
It forms most stable carbocation.
Organic Chemistry
115
47. Answer (1)

In forms most stable carbocation.
48. Answer (3)
Property of SN1 mechanism.
49. Answer (2)
+
CH2
|
is most stable carbocation.

50. Answer (1)
It is antiaromatic
51. Answer (1)
It is antielimination.
52. Answer (1)
Antielimination is not possible.
53. Answer (1)
Benzene is more reactive than iodobenzene towards SE reaction.
54. Answer (1)
Rate determining step is removal of H, D or T.
55. Answer (4)
Factual.
56. Answer (2)
Due to resonance, Cl is partially double bonded.
57. Answer (3)
CH3 C CH3
|
It can form most stable radical
58. Answer (4)
Numbering will be started from COOH. It is (2S, 3E) configuration
59. Answer (3)
*
*
60. Answer (4)

In hetero cyclic aromatic compounds at least one atom of ring is different.
61. Answer (3)
Initially left ring is less reactive towards nitration due to R effect but after first nitration on other ring it becomes
more reactive.
62. Answer (3)
After removal of 3rd H, it becomes aromatic
63. Answer (2)
CH3
|
+
CH3 C CH2
|
CH3
(CH3 shifting)
CH3
|
CH3 C CH2 CH3
+
116
Organic Chemistry
64. Answer (4)

Fullurenes are allotrope of carbon.
65. Answer (4)
NO2 has strongest electron withdrawing ability.
66. Answer (3)
Due to the presence of vacant d-orbital of appropriate energy in Si atom, it behaves as electron withdrawing
group through mesomerism.
67. Answer (3)
Because charge separated structure is most contributing where negative charge in five-membered ring and
positive charge in seven-membered ring.
68. Answer (2)
In III, aromatic ring is present, hence it has lowest enthalpy of combustion.
69. Answer (2)
70. Answer (2)
(2) is resonance stabilized where delocalization of positive charge is maximum due to resonance.
71. Answer (2)
Planar six-membered ring formation.
72. Answer (1)
Charge separated resonating structure has negligible contribution towards resonance hybrid in option (1).
73. Answer (4)
Structure (4) has maximum number of covalent bonds.
74. Answer (2)
Conjugate base is not stabilized by resonance.
H
O
Unstable
75. Answer (2)

Bond between sp3 sp3 hybridised carbons
76. Answer (1)
It has sp3 hybridised carbon (25% S charater)
77. Answer (2)
In both SN1 and SN2 mechanism reactivity order of haloacids is same.
77a.
Answer (2)
(AIEEE 2010)
Formation of carbocation is rate determining step in SN1 reaction. Hence alkyl halide which gives more
stable carbocation is more reactive towards SN1 reaction
Me
Me
Br
> Me
Br
> Me
Br
decreasing order of SN1 reactivity

78. Answer (2)
Adsorption extent of ethyne on surface of catalyst is maximum.
Organic Chemistry
117
79. Answer (3)

Due to rearrangement, conjugated diene is formed.
80. Answer (4)
It is S type optical isomer.
81. Answer (2)
I and II carbon atoms are of R and S configurations and it is symmetrical molecule.
82. Answer (4)
Acetaldehydeoxime shows and syn-anti isomerism.
83. Answer (1)
2n number of stereomers = 22 = 4
84. Answer (3)
H
CH3C*CH = C
C2H5
CH3
H
Two enantiomeric pairs for each cis and trans. So the combination gives 4-diastereomeric pairs.
85. Answer (4)
CH3
C2H5CCl
H
KOH
DMF
SN2
CH3
HOCC2H5
H
Inversion of
configuration
86. Answer (3)

87. Answer (2)
OH
CH3
CH3
CH3
H5C2CCl
C3H7
aq. KOH
SN1
C Cl
C3H7
C2H5
CH3
C2H5COH + HOCC2H5
C3H7
(A)
C3H7
(B)
The concentration of B > A

88. Answer (3)
Pairs are not enantiomers
89. Answer (2)
The similar groups are on the same side in the fischer projection formula.
90. Answer (1)
Number of double bond are 3 and the polyene contains different groups at the terminals. So geometrical isomer
= 23 = 8
91. Answer (4)
92. Answer (1)
Br
H
Cl (1, 2) axial-equatorial is cis in nature
H
118
Organic Chemistry
93. Answer (3)

94. Answer (3)
95. Answer (2)
NH CH3 is maximum electron donating group among all given groups.
96. Answer (2)
(CH3)3COK is a bulky base and it gives Hoffmann elimination.
97. Answer (3)
Both have 6 valance electrons.
98. Answer (1)
D
CH3
C2H5
Chiral centre
Since it has chiral centre therefore it will show optical isomerism.

99. Answer (4)
C2H5
+
MgBr + H
C2H5 H + R O MgX
Conjugate Conjugate
base of ROH
acid of
CH3 CH2
Protonolysis due to proton transfer.
100. Answer (3)

Even number of carbon containing hydrocarbon has higher melting point.
101. Answer (1)
CH3 CH3
+ CH3 C
CH3
Pd /
+ CH3
CH3
CH3
CH
CH
CH3
102. Answer (2)

TPH [Ph3SnH], TPH can reduce 1, 2 and 3 RX while NaBH4 can reduce 2 and 3 RX only.
While RedP and ZnHg/HCl cant reduce alkyl chloride.
103. Answer (3)
Wolf Kishner reduction is used for the preparation of alkane by using hydrazine (NH2NH2) + sodium alkoxide.
104. Answer (1)
2Na + 2H2O 2NaOH + H2
RX Soluble in ether, insoluble in water.
105. Answer (4)
CH3
Cl +2Na + C2H5
Cl
Ether
CH3
CH3 + CH2
CH3
C2H5
C2H5
CH2
C2H5
106. Answer (3)

3 Alkyl halide preferred dehydrohalogenation and form alkene.
Organic Chemistry
119
107. Answer (4)

At anode
2e
2CH3
2CH3COO
O
C
O
CH3
CH3 + CH3
CH3 + CO2
(Free radical)
C2H6 (Alkane)
108. Answer (1)
109. Answer (1)

1-Alcohol follow E2 mechanism while 2 and 3-alcohol follow E1 mechanism.
109a. Answer (2)
(AIEEE 2010)
H
OH
CH3
CH2CHCH
H
O
CH3
CH2CHCH
CH3
CH3
CH3
CHCH C
H (A)
CH3
CH = CHCH
(B) H CH3
(A)
CH3
Extension of conjugation
(More stable)
Major product
CH3
(B)
CH2CH = C
CH3
(Minor)
110. Answer (2)

Due to intra molecular hydrogen bonding gauche is more stable in glycol.
111. Answer (3)
Birch reduction
112. Answer (3)

On increase in surface area of alkene boiling point increases and cis form is more polar hence cis-3-Hexene
has highest boiling point.
120
Organic Chemistry
113. Answer (3)

CH3 CH
CH3 CH
CH2
Cl
OH
OH Nucleophile
Cl+ Electrophile
114. Answer (3)
OH
OH
1% KMnO4/OH
Cold
115. Answer (3)

4
1
3
Right way
of numbering
Wrong way
of numbering
116. Answer (1)

OsO4 is used to perform cis-dihydroxylation reaction on alkene.
117. Answer (2)
H3C
H3C
C = CH CH3
Saytzev's product
118. Answer (4)
Br
Anti-Markonikoff's addition
(Peroxide effect)
119. Answer (2)
HCCH
Hg2+, H3O+
H2C = CH
H
O
Tautomerization
O
H3C C H
120. Answer (3)
Fact.
121. Answer (2)
Most substituted alkene will have lowest molar heat of hydrogenation.
122. Answer (3)
Factual
123. Answer (3)
Br2
Br
Br
Organic Chemistry
121
124. Answer (1)

h
Initiation : R O O R
R O
Propagation :
R O + H Br
R OH + Br
125. Answer (4)

Presence of electron withdrawing group in -complex increases potential energy of the system.
126. Answer (4)
Five double bonds, one triple bond and cyclopropyl ring will absorb H2 at higher temperature.
127. Answer (2)
CH3 CH
CH3 CH2 CH2
(Electrophile)
H
H
128. Answer (4)
CH
CH
HgSO4
CHO
CH3
H2SO4
LiAlH4
OH
CH3 CH2
129. Answer (2)
CH
CH
CHO
(i) B2H6
(ii) H2O2/NaOH CHO
The alkynes which has terminal hydrogen always gives aldehyde. While non-terminal alkynes gives ketone.
130. Answer (2)
CH2
CH
CH
CH
CH
CH2
(i) O3
(ii) Zn/H2O
2HCHO + 2
CHO
CHO
131. Answer (1)

No. of geomaterical isomer is = 2n where n = No. of double bond. When both end are non identical.
131a. Answer (1)
(AIEEE 2012)
132. Answer (3)
CH2 CH2
OsO4
CH2
CH2
O
Os
O
NaHSO3
CH2
CH2
OH
OH
133. Answer (4)

NaNH 2
Hg 2 hv
CH3 CBr2 CH3 CH3 C CH CH3 C CH3
(1) NaIO
+
H2O/H
CH3COOH
122
Organic Chemistry
134. Answer (2)
O
CH3
CH3
Tautomerism
OH
C
CH3
CH2
NaNH2
ONa
C CH2
(A)
n
Add CH CH
CH3
ONa
CH3
CH3
C CH
(B)
135. Answer (1)
C CH 2Br + Mg
CH
Ether
CH
(A)
CH2MgBr
(B)
Since compound B has acidic (terminal) H, hence it reacts further with (A) and forming propyne
CH
CH2 MgBr + CH
CH2Br
CH
CH3 + BrMgC
C CH2Br
136. Answer (4)

C2H6, CH2 = CH2, CH
sp3(25%)
sp2(33.33%)
CH
sp(50%)
Greater the s.character more will be bond dissociation energy (C H)

137. Answer (1)
Greater the number of terminal hydrogen more will be acidic character.
138. Answer (3)
A pair of electron is easily available for protonation.
138a. Answer (1)
(AIEEE 2010)
R COO HC C NH2 R
increasing basic strength

As sp3 C is less electronegative than sp3 N alkyl carbanion R is more basic than NH2 . However
sp hybridized carbon is more electronegative than sp3 N. Hence NH2 is more basic than HC C
139. Answer (3)
R
H + R' MgBr
MgBr + R'H
This reaction of terminal alkynes with Grignard reagent is extremely rapid and goes to completion and example
of transmetallation.
Transmetallation A reaction in which a metal is transferred from one carbon to another.
140. Answer (3)
KMnO4 hydroxylate C
C bond and C
C bond.
141. Answer (2)
3CH
hot Fe
CH Tube
Benzene
Organic Chemistry
142. Answer (3)
CH3
CH3
CH3
Na/C2H5OH
123
H
CH3
D2/Pt
CH3
CH3
D H
(Recemic mixture)
143. Answer (1)
Degree of unsaturation =
(2 carbon 2) hydrogen
2
(2 7 2) 12
2
D.U. = 2
D.U.
144. Answer (4)
C2H5
+ CH2
CH2
AlCl3/HCl
368 K
145. Answer (4)

All of these are example of stereospecific reaction only particular isomer is formed.
146. Answer (1)
Nucelophilic substitution is not possible in benzene nucleus under ordinary condition, but under high
temperature and pressure SN reaction is made possible.
147. Answer (1)
Cl
Cl
H
+
NH
CH3
CH3
CH3
+ Cl
Benzyne
148. Answer (1)
Due to more prominent +R effect of F .
149. Answer (2)
CH3
CH3
Cl
CH3
CH3
CH3
CH3
resonance
stable
carbocation
It will be faster towards SN1 mechanism

150. Answer (1)
It is aromatic because it is planner, conjugated and contains 6 electrons.

151. Answer (4)
In NH2 lone pair of electron is easily available for delocalisation because it is planar and NR2 is nonplannar
124
Organic Chemistry
152. Answer (2)

It is example of anti-elimination
O
153. Answer (4)
||
Reductive ozonolysis of all can form H C
O
||
O
||
C C H
[JEE (Main)-2015]
153a. Answer (2)

5-keto-2-methylhexanal is
O
H
O3
Zn
154. Answer (3)
Cl
CH2Cl
Cl2
Cl
155. Answer (4)
+
CH2
CH3
+
is more stable,
is aromatic
156. Answer (1)

There is no H-atom at anti-position.
157. Answer (3)
Natural polymer is degradable.
158. Answer (4)
SO3 is not primary pollutant.
159. Answer (1)
Exosphere is the uppermost region of atmosphere.
160. Answer (1)
Statosphere.
161. Answer (2)
Fact.
162. Answer (1)
BOD5 means dissolved oxygen consumed in 5 days.
163. Answer (1)
Ozone layer is destroyed by chlorofloro carbon.
164. Answer (1)
Los Angels smog is photochemical smog.
165. Answer (4)
MIC gas released in Bhopal gas tragedy.
166. Answer (4)
Due to very decrease in temperature.
Organic Chemistry
125
167. Answer (2)

Due to hole in ozone layer, U.V. rays reaches on earth which cause skin cancer.
168. Answer (4)
CO is primary pollutant.
169. Answer (3)
PAN is a secondary pollutant.
170. Answer (2)
Chlorination of water is done to kill germ.
171. Answer (1)
Fact.
172. Answer (4)
NO2.
173. Answer (1)
N2 is not an air pollutant.
174. Answer (3)
SO3 is not dissociated in smog formation
175. Answer (4)
Seconal is tranquilliger
[JEE (Main)-2015]
175a. Answer (3)

Phenelzine is not antacid, it is anti-depressant.
176. Answer (3)
Reaction of alcohol with SOCl2 in presence of dry ether is an example of SNi. In this reaction retention of
structure take place.
177. Answer (1)
OH
Br
H SO
NBS
4
2
CH3
178. Answer (1)
170 C
CH3
CH3
Nucleophilic substitution by SN2 mechanism on a stereogenic centre give only one product that may be
dextrorotatory or leveorotatory.
179. Answer (1)
Et 2O
Br CH2CH2CH2Br + Mg
180. Answer (3)
Covalent character in AgCN due to high polarising power of Ag+ due to its Pseudo noble electronic configuration
so C of CN is not allowed to attack and hence N of CN act as nucleophile.
181. Answer (2)
Alkyl fluoride always give alkene that is less substituted which is governed by Hoffman rule.
182. Answer (1)
Function of Red P is to remove I2 as PI3 otherwise I2 react again with C2H6 to form C2H5I.
183. Answer (4)
Stronger base favour elimination while weaker base favour substitution.
The order of basic strength is
RO > OH > C6H5O > CH3COO
126
Organic Chemistry
184. Answer (4)

Better will be leaving group faster will be rate of reaction.
Leaving group is in order I > Br > Cl > F.
185. Answer (1)
CH3CH
CHCOOH + HBr
CH3CHCH2COOH
Br
CH3CHCH2COOH
Br
NO2 in a strong electron withdrawing so, CH3 CH2 C H NO 2 is highly unstable.

186. Answer (1)
HBr
CHCH3
|
OH
CHCH3
|
OH
|
H
CH3
*
CHCH3
ring
expansion
CH3
Br
187. Answer (4)

At high temperature, Cl show allylic substitution.
188. Answer (2)
CaOCl2 + H2O Ca(OH)2 + Cl2
Hydrolysis
(ii) CH3CH2OH + Cl2 CH3CHO + 2HCL
Oxidation
(iii) CH3CHO + 3Cl2 CCl3CHO + 3HCl
Halogenation
(i)
(iv) 2CCl3CHO + Ca(OH)2 2CHCl3 + (HCOO)2Ca Alkaline hydrolysis

189. Answer (4)
Wiliamson synthesis is a nucleophilic substitution and R'O act as nucleophile.
190. Answer (4)
C2H5O + CH3CHBrCH3
E2
H
C
H
CH3
H
Br
C2H5O
H
H
CH3
+ C2H5OH
C=C
H
191. Answer (2)

192. Answer (1)
Fact.
193. Answer (3)
Organic Chemistry
127
194. Answer (3)
CH3
CH3
Br
CH3
CHOH + PBr
Br
CH3
Br
CHOP
H
Br
SN2
Br
CH3
CH3
CHBr + HOP
Br
Br
195. Answer (1)
Br
CH3CH2CCH3
O
O=S=O
CH3CH2COH + ClS
CH3
CH3
Br
SN2
(OTs)
CH3
CH3CH2CCH3
H
196. Answer (3)

196a. Answer (3)
[JEE (Main)-2014]
Ethylene
CH3COOH
LiAlH4
CH3CH2OH
'A'
PCl5
CH3CH2Cl
'B'
Alc. KOH
CH2 = CH2
'C'
197. Answer (4)

1
CH3CHCH2CHCH3
CH3
CH3
Only three different position available
198. Answer (2)
Here the order of base strength is also the order of rate.
199. Answer (1)
200. Answer (3)
DCCl2CF3
OH/HOH
OD
D2O
CCl2CF2
F
CCl2 = CF2
CCl2CF3
HOH
HCCl2CF3
128
Organic Chemistry
201. Answer (1)
CH3 O is a strong base and good nucleophile and the substrate is 1 alkyl halide so SN2
202. Answer (4)
More stable will be carbocation, higher will be chance to show SN1 reaction.
203. Answer (2)
204. Answer (4)
This is Ullmann reaction.
205. Answer (2)
O
OH
||
|
To give iodoform test, compound should have either CH3 C or CH3 CH as general formula.
206. Answer (2)

Benzyne is the intermediate of this reaction
207. Answer (3)
More will NO2 group more stable will be intermediate and easy will be aromatic substitution.
208. Answer (4)
All form azodyes.
209. Answer (1)
This is Sand Mayer reaction.
210. Answer (1)
Fact.
211. Answer (3)
CH3
Cl
CH3
212. Answer (4)

This is an example of isomerisation reaction and elimination reaction.
213. Answer (1)
Cl
N
214. Answer (3)
Benzene is more reactive than chlorobenzene.
215. Answer (4)
Br is weaker nucleophile than I.
Organic Chemistry
129
216. Answer (1)
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl2/Fe
Cl
Cl
Cl
217. Answer (2)
CH2
CH3
CH3
CH3
|
|
|
Re arrangemen t
CCHCH
CH
CCH
CH
3
CH
3
3
3
CHCCH3 + H2O
| |
|
|
|
OH CH3
OH CH3
CH3
(more stable)
218. Answer (1)
ONa
OH
OH
COONa
4 7 atm
CO 2
125C
COOH
H / H2 O
Salicylic acid
CO
+C O
(E)
O
218a. Answer (2)
(AIEEE 2009)
OH
OH
CO2
COOH
NaOH
Salicylic acid
219. Answer (2)
RNH2 HONO ROH N2 H2O
2HNO2 N O H2 O NO 2
(Electrophi le )
220. Answer (1)

( CH COO ) Hg / H O
NaBH4
3
2
2
CH3 CH CH2
CH3 CH CH3
CH3 CH CH2
THF
|
|
OH
|
OH
OH HgOOCCH
( 2 Alcohol )
3
130
Organic Chemistry
221. Answer (4)

222. Answer (1)
(i) O
3
CH3 CH CH CH CH3
CH3 CH CHO CH3 CHO
(ii)Zn / H2O
|
|
CH3
CH3
Oxidation
CH3 CH COOH CH3 COOH

|
CH
3
222a. Answer (4)
CH3
CH
(AIEEE 2010)
CH
CH3
(i) O3
(ii) Zn-H2O
CH3
CHO
44 amu
223. Answer (1)

HOCl OH Cl
(Nu )
CH 3CH
CH 2 + OH
CH3CHCH2 + Cl
|
OH
+1
CH3 CH CH2Cl
|
OH
224. Answer (2)
Cl
H
623 K
300 atm
OH
OH
Benzyne
(Intermediate)
225. Answer (1)
OH
OK
OH
CHO
343 K
KOH CHCl3
CHO
dil HCl
(major)
226. Answer (4)
O
||
The compound which has CH3 C or CH3 CH group gives iodoform test.
|
OH
226a. Answer (3)
(AIEEE 2012)
227. Answer (1)
OCH2CH CH2 CH2 CHCH2
OH
475 K
Organic Chemistry
131
228. Answer (2)

Due to sp2 hybridisation of bonded carbon atoms.
229. Answer (4)
Br
Conc . H2SO 4
excess of Alc KOH
2
C 3H7 OH
CH3 CH CH2
CH3 CH CH2
CH3 C CH
160 180 C
|
|
( Alkene)
(Z )
OH OH
230. Answer (4)

For the preparation of Di-tertiarybutylether, tert-butylether is required which undergoes elimination reaction and
form alkene.
231. Answer (1)
CH3 O CH(CH3 )2 HI CH3I CH3 CH OH

|
CH3
( 2 Alcohol & more stable )
232. Answer (3)

In phenol, phenoxide ion is resonance stable compound.
233. Answer (4)
Due to + R effect of benzene, C6H5COOH is less acidic than HCOOH.
234. Answer (2)
It is an example of SNi mechanism in which 100% retention takes place.
235. Answer (3)
In Claisen rearrangement, if ortho positions are blocked, allyl group migration para position with same carbon.
236. Answer (4)
It forms most resonance stabilised aromatic carbocation.
237. Answer (2)
CH3
CH3
C
CH3
OH
Cu
573 K
CH2 = C
CH3
O3
CH3
Zn H2O
HCHO + CH3 C CH3

(C)
(B)
NaNH2
CH3 C CH2Na
238. Answer (1)

First ester (A) will form ketone which will further reacts with grignard reagent and form 3Alcohol which reacts
faster with Lucas reagent.
239. Answer (1)
O
|
HCOOC2H5 + CH3MgBr HCOC2H5
|
CH3
OMgBr
O
OH
|
||
|
CH3MgBr
H / H2 O
H C CH3 C 2H5 OMgBr
CH3CCH3
CH3 CH CH3
Acetaldehy de
|
2 propanol
H
132
Organic Chemistry
240. Answer (3)

This method is used for the preparation of aldehyde (expect formaldehyde) only.
241. Answer (4)
Fact.
242. Answer (1)
243. Answer (3)
3 allyl radical is formed
244. Answer (3)
OH
is formed
OH
245. Answer (1)
246. Answer (1)
O
O
is formed by H2SO4
247. Answer (2)
OH
OCOONa
(i) NaOH
(ii) CO2
OH
OH
COONa
COOH
248. Answer (1)

Attack of BH3 fellows Markovnikovs addition.
249. Answer (1)
3 cation is formed.
250. Answer (2)
It gives alkene
251. Answer (2)
HO
CH
COONa
HO
CH
COOK
252. Answer (4)

Both give same test
Organic Chemistry
252a. Answer (2, 4)
133
(AIEEE 2011)
Both formaldehyde and acetaldehyde will give this test
[ Ag(NH3 )2 ]
HCHO
Ag Organic compound
Silver mirror
[ Ag(NH3 )2 ]
CH3 CHO
Ag Organic Compound
Silver mirror
253. Answer (1)

By using strong oxidising such as conc. HNO3, ketones gives carboxylic acids
254. Answer (2)
255. Answer (2)
CuO (Cupric oxide) (blue colour) of Fehling solution converted into cuprous oxide (red colour) on the the
reaction with aldehyde.
256. Answer (2)
O
OH
||
|
H
CH3 C HCN
CH3 C CH3
|
|
CH3
CN
Cyanohydrine
257. Answer (1)
O
|
In Cannizzaros reaction due to transfer of hydride ion D C OH (Alcohol) is formed.
|
D
258. Answer (3)
Only C has - carbon
259. Answer (4)
All of these do not have hydrogen
259a. Answer (2)
(AIEEE 2011)
Cl
Cl
ClCCHO
NaOH
Cannizaros reaction
Cl
ClCCOONa
Cl
Cl
ClCCH2OH
2 1
Cl
2, 2, 2-trichloroethanol
260. Answer (1)

(i ) CO2
CH3MgBr
CH3 COOH Mg

(ii)H / H2O
Acetic acid
Br
OH
261. Answer (4)

This is laboratory method of preparation of formic acid.
134
Organic Chemistry
262. Answer (2)

COOH
CH2
COOH
263. Answer (3)

(A) is carboxylic acid and (B) is anhydride
264. Answer (3)
It is Schimdt reaction
265. Answer (4)
C2H5
C2H5
CH3
and
CH3
cannot give HCHO
266. Answer (1)

LiAlH4 can be kept in alcohol due to its greater reducing power.
267. Answer (4)
Five membered product is more stable then seven membered.
268. Answer (2)
HI/P
HO
COOH
CH3
269. Answer (2)

According to alphabetic order
270. Answer (4)
All can form benzaldehyde
271. Answer (1)
CH3
CH3
O
C
CH
CH
CH3
CH3
272. Answer (2)
Ring expansion takes place
CHCl3
KOH
Cl
N
H
273. Answer (4)
CHO is deactivating group and OH and NH2 have acidic H
274. Answer (3)
Cl
OH
I
I
H O
CH3 C Cl (aq) NaOH CH3 C OH 2 CH3 COOH
|
|
( Carboxylic acid)
Cl
OH
( unstable )
Organic Chemistry
135
275. Answer (3)

Due to greater acidic character.
276. Answer (4)
Conc. H SO
2
4
HCOOH
CO H2O
277. Answer (4)

Tollens reagent gives silver mirror with formic acid.
278. Answer (2)
Due to greater +I-effect
278a. Answer (4)
(AIEEE 2011)
O
CH3CH2CHCOH
Cl
Presence of electron withdrawing group nearest to the carboxylic group increase the acidic strength to
maximum extent.
279. Answer (2)
The value of vant Hoff factor (i) can be determined on dimerisation of benzoic acid and i gives information
about molecular mass.
280. Answer (3)
Sequence of acetic strength = II > III > I.
So pKa sequence will be opposite.
281. Answer (1)
It is Wittig reaction
282. Answer (2)
It is aldol condensation reaction.
283. Answer (2)
CH3 COCl (CH3 )2 Cd CH3 COCH3 CdCl2
284. Answer (1)
The carbonyl carbon of HCHO has greater positive charge.
285. Answer (2)
2
LiAlH4
P / Br2
Hg / H
CH CH
CH3 CHO
CH3 CH2 OH
CH3 CH2 Br
H2 O
(A)
285a. Answer (4)
(B )
(C)
[JEE (Main)-2014]
CHCl /KOH
3
R CH2 NC
R CH2 NH2
C2H5OH
286. Answer (1)

This is iodoform test
287. Answer (1)
Fact
136
Organic Chemistry
288. Answer (3)

Phenyl ethanal does not have CHO group directly attached to phenyl group, therefore it is not a aromatic
aldehyde.
289. Answer (4)
633 K
Na CO 2
COONa
COONa
HCl
COOH
COOH
+ NaCl
290. Answer (1)
CN
| + H2O
CN
HCl
COOH
|
COOH
(A) cyanogen
291. Answer (1)
O
||
CH2CH2COOH
573 K
CH2CH2COOH
+H2O + CO2
(CH3CO)2O
Adipic acid (A)
292. Answer (1)

CHCOOH KMnO4 CH(OH)COOH
||
|
CHCOOH
CH(OH)COOH
293. Answer (1)
H
|
C12H22O11 H2O CH3 C COOH
|
Lactose
OH
Lactic acid
294. Answer (2)

NaNO / HCl
RCONH2 2 RCOOH
295. Answer (4)
O
NH2
NOH
NH2OH
LiAlH
HNO
CH2OH
296. Answer (3)
O
O
O
||
|| . .
||
H O / H
R C Cl + N3H R C N3 R C N : RNCO 2 RNH2
Acylazide
297. Answer (2)
CH3
CH3COH
CH3
NH3
CH2
C
CH3
HCN/H
CH3
CH3
CH3CNH2 (Ritter reaction)

CH3
Organic Chemistry
137
298. Answer (1)
O
||
CH3CH2 C N
CH3
C 2H 5
O
||
H O/H
2 CH3CH2 COH + CH3NHC2H5
299. Answer (4)
CH2
COOH
P2 O5
COOH
CaO/
O = C = C = C = O + 2H2O
Carbon suboxide
CH2 = C = O + H2O + CO2

Ketene
300. Answer (3)
OH COOH
OH CH2OH
O
+
301. Answer (4)
O
CHO
(C2H5 O)3Al
C O CH2
COOH +
CH2OH
302. Answer (3)

Amide forms amine. Acetone and acetophenone give haloform test.
303. Answer (2)
CH2
HOOC (CH2)4 COOH

304. Answer (2)
NO2
NO
Fe / H O
305. Answer (2)
O
||
LiAlH4
CH3CH2CH2NH2
CH3CH2 CNH2
306. Answer (4)
Due to maximum molecular mass.
307. Answer (3)
More is the +I effect, higher is the basicity of amine in gaseous phase.
138
Organic Chemistry
307a. Answer (1)

Among C6H5NH2, CH3NH2, (CH3)2NH,
(CH3)3N . C6H5NH2 is least basic due to resonance.
+
NH2
NH2
[JEE (Main)-2014]
NH2
NH2
NH2
Out of (CH3)3N, CH3NH2, (CH3)2NH . (CH3)2NH is most basic due to +I effect and hydrogen bonding in
H2O.
+I effect
CH3
N
H3C
+I effect
H
O
Hydrogen
bonding
308. Answer (1)

Due to maximum resonance stabilised nitrogen atom.
309. Answer (4)
Nitrobenzene does not respond to Friedel Craft acylation.
310. Answer (3)
More -hydrogen on alkyl group, more repelling power.
311. Answer (2)
CH3
CH3
KNH
CH3
NH
NH2
Cl
312. Answer (2)
Hofmann elimination (Least substituted alkene is formed).
313. Answer (1)
It is Gabriel synthesis used for preparation of primary amine only.
314. Answer (3)
Zn dust and NaOH are strong reducing agent.
315. Answer (2)
CH3
CH3
|
|
HNO 2
CH3 C CH2 CH3 (followed by rearrangement)
CH3 C CH2 NH2
|
|
CH3
OH
Organic Chemistry
139
316. Answer (2)

NO
|
HNO 2

R C R
|
NO 2
R CH R
|
NO 2
NaOH

Blue colour
317. Answer (3)

Dipole moment of alkyl cyanides are very high.
318. Answer (2)
It can form most stable carbocation.
319. Answer (1)
NaNO / HCl
NH2 2 NaO3S
HO3S
N2Cl
N(CH3) 2
NaO3S
N=N
N(CH3)2
Methyl orange
320. Answer (3)
NH2
NC
H O / H
+ HCOOH
321. Answer (2)
CH3 N CH CH3
|
|
CH3 CH3
O
|
H2 O 2
CH3 N CH CH3 CH3CH = CH2 + (CH3)2NOH
|
|
CH3 CH3
322. Answer (2)

HNO 2
R2NNO.
This test is only for secondary amines R2NH
323. Answer (3)

H SO
(C2H5)2 NOH
(C2H5)2 NH 2
324. Answer (2)

Fact.
325. Answer (1)
It is Hinsberg test
O
||
S Cl + RNH2
||
O
O
||
KOH
S NH R
||
O
O
||

S NK R
||
O
140
Organic Chemistry
326. Answer (3)

NaOH
N2Cl
327. Answer (2)
OH
CH2 OH
HO
OH
328. Answer (3)

Approximately 52% p-nitro aniline.
329. Answer (3)
Migration of CH 3O
is easier than
OCH3
330. Answer (4)
N2Cl
NH2
N
NH2
(yellow dye)
331. Answer (3)

Due to maximum e density on N.
332. Answer (2)
Cl > OCOC2H5 > OC2H5 > NH2
333. Answer (1)
O
H
CH3
CH3
is formed
334. Answer (4)

Migration of CH3 on N takes place
335. Answer (1)
CH
N(CH3)2
N(CH3)2
(Malachite)
336. Answer (4)

All form complexes
337. Answer (1)
Hg(NHC2H5)2 is formed.
Organic Chemistry
141
338. Answer (2)

C 8H18
cannot migrate due to Bulkier group.
339. Answer (4)
NH2
NO2
W.A
S.B.
H2N
NH2
Benzidine
340. Answer (4)

It is due to polar protic medium.
341. Answer (1)
CH3 CN
CH3 COOH + NH3, CH3 NC
CH3 NH2 + HCOOH
HCOOH reduces tollens reagent while CH3COOH does not reduce tollens reagent.
342. Answer (2)
Diazo salt is an electrophile & Phenoxide is more reactive than phenol towards SE reaction.
343. Answer (2)
344. Answer (4)
345. Answer (4)
H2N C C OH + H NH C C OH
H
H
H2O
H2N C C NH C OH
H
H
Peptide linkage
346. Answer (1)
CH C
CH C
H HN
HO
C CH
OH
NH H
R
H2O
NH
HN
CH CH
O
347. Answer (3)

348. Answer (1)
349. Answer (2)
350. Answer (2)
142
Organic Chemistry
351. Answer (4)

352. Answer (3)
353. Answer (2)
354. Answer (3)
354a. Answer (1)
[JEE (Main)-2014]
DNA contains ATGC bases

A Adenine
T Thymine
G Guanine
C Cytocine
So quinoline is not present.
355. Answer (3)
The typical elastomeric properties of natural rubber are attributed to its almost complete cis configuration and
nature of gutta percha is attributable to its trans structure.
356. Answer (3)
Nylon-66 is fibres, in which the interparticles forces are strongest these forces are either H-bonds or dipole dipole attractions.
357. Answer (4)
Buna-S is copolymer of butadiene and styrene.
358. Answer (4)
In condensation polymerisation a large number of monomers combine together usually with the loss of simple
molecules like water, alcohol etc. and they are also called step growth polymers, monomers of terylene are
ethylene glycol and terephthalic acid.
359. Answer (4)
Zeigler Natta catalyst is TiCl4 + (C2H5)3 Al.
360. Answer (2)
Polyamide and polyester are examples of condensation polymers.
361. Answer (3)
NH2
N
NH2 N
NH2
N
NH2
Melamine
+ HCHO
NH2OH
N
NH2
Resin intermediate
NH
Polymerisation
N
N
NH2CH2
N
NH
|
Melamine polymer
362. Answer (1)

Formaldehyde is used in the formation of Bakelite (phenol + formaldehyde) and melamine resin.
363. Answer (2)
Thermoplastic polymers softon and melt on heating PVC is an example of thermoplastic.
Organic Chemistry
363a. Answer (1)
143
[JEE (Main)-2014]
Dacron is polyester formed by condensation polymerisation of terephthalic acid and ethylene glycol.
HOOC
COOH + HOCH2CH2OH
CO
CH2CH2O
n
Dacron
Acrylonitrile, Neoprene and Teflon are addition polymers of acrylonitrile, isoprene and tetrafluoro ethylene
respectively.
364. Answer (3)
Bakelite is condensation polymer of phenol + formaldehyde, glyptal is condensation polymer of ethylene glycol
+ phthalic acid, caprolactum is monomer of nylon-6, Buna-S is co-polymer of butadiene + styrene.
364a. Answer (2)
(AIEEE 2009)
Acrylonitrile + 1, 3-butadiene Buna-N

(Bu = Butadiene, na Sodium, a polymerising agent, N = Nitrile)
365. Answer (1)
(PAN) Polyacrylonitrite
nCH2= CH
|
CN
Peroxide
|
CN
(PAN)
366. Answer (4)

367. Answer (1)
368. Answer (4)
369. Answer (1)
370. Answer (1)
371. Answer (3)
372. Answer (2)
373. Answer (1)
374. Answer (2)
375. Answer (3)
376. Answer (4)
377. Answer (2)
378. Answer (2)
Kelvar is an polyamide which is obtained by condensation of terephathalic acid and P-phenylenediamine.
379. Answer (4)
Free radical of the compound C6H5CH=CH2 is most stable amongst the given compound therefore it will give free
radical polymerisation with ease.
144
Organic Chemistry
380. Answer (4)

The cation of the compound CH3C=CH2 is most stable amongst the given compound.
CH3
381. Answer (2)
CN
CH CH
HCN
Ba(CN)2
CH2=CHCN
Polymerisation
Peroxide
CH2CH
n
Orlon
(Polyacrylonitrite)
(PAN)
382. Answer (2)
O
C
H2SO4
N
CH2
Beckmann's
rearrangement
CH2
NOH
NH2OH
Cyclohexanone
oxime
CH2
CH2
O
260-270C
H2O
CNH(CH2)5
Nylon-6
CH2
Caprolactum
383. Answer (4)

PTFE, polyethylene and PVC are homopolymers so their molecular mass is a whole number multiple of mol.
mass of monomer but terylene is condensation polymer.
384. Answer (1)
Polymethyl methylacrylate (PMMA) is known as plexiglass.
385. Answer (3)
Vulcanisation is a process of heating of rubber with 3-5% sulphur. It introduces cross links of sulphur atoms
between the polymeric chains thereby increasing the elasticity, tensile strength etc.
386. Answer (2)
NOH
O
C
NH2OH
H2SO4
N
CH2
H2O
Beckmann's
rearrangement
CH2
CH2
CH2
CH2
Caprolactum
387. Answer (3)
O
[O]
NOH
NH2OH
(i) PCl5
(ii) Polymerisation
Nylon-6
388. Answer (1)

The anion formed by CH2 =CHCH3 is least stable amongst the given alkene therefore is least reactive toward
anionic polymerisation.
Organic Chemistry
145
389. Answer (4)

Neoprene is not a biopolymer and it is thermoplastic polymer and is a synthetic rubber.
390. Answer (4)
Neoprene, PVC and Polyethylene are the addition homopolymers.
391. Answer (2)
In condensation polymerisation a series of condensation reactions between the (generally two) monomers
containing at least two functional group each occur with loss of a small molecule such as H2O, CH3OH or HX,
Terylene is a condensation polymer of ethylene glycol and Terephthalic acid. It is also called step growth polymer.
392. Answer (4)
Because it contains alcoholic group in its side chain HOCH2CH2NH2COOH.
393. Answer (2)
In Greek, tyros means cheese.
394. Answer (2)
Amylose
CH2OH
O
H
H
H
O
OH H
H
O
, 1, 4
CH2OH
O
H
H
H
H OH
OH
OH
OH
395. Answer (1)

Cellulose
CH2OH
O
H
H
O
OH H
H
CH2OH
O
H
H
O
O
H H
OH
H
, 1, 4
H
OH
OH
396. Answer (4)

A - Adenine pairs with T (Thymine)
G - Guanine pairs with C (Cytosine)
397. Answer (3)
Tertiary structure aims at giving more stability to the structure of protein as compared to other 2 hence variety
of bonds.
398. Answer (3)
Hair waving involves heat treatment and application of a gel which behaves as a reducing agent breaking
n-bonds of helix of hair protein to -pleat parallel.
399. Answer (3)
Raw fish contains thiaminase an antienzyme for Vit. B1 or Thiamine.
400. Answer (1)
Vit. A, C, E prevent formation of free radicals hence antioxidising.
Vit. D prevents rachitis hence antirachitic vitamin.
Vit. B1 prevents neuritis hence antineuritic vitamin.
Vit. E prevents ageing hence beauty vitamin.
146
Organic Chemistry
401. Answer (2)

402. Answer (2)
Deptite-2 amino acids linked by a peptide bond.
403. Answer (4)
Fact.
404. Answer (2)
Fact.
405. Answer (1)
Fact.
406. Answer (1)
Fact.
407. Answer (2)
Amino group attached to -carbon.
408. Answer (1)
Fact.
409. Answer (1)
In sucrose carbonyl group glucopyranose and fructo-furanose are used in glycosidic linkage hence loss of
reducing property.
410. Answer (1)
Isoelectric point =
pK a pK b 2.34 4.40
3.37
2
2
411. Answer (2)

Only aldose decolourises the Br2-water.
412. Answer (2)
Glycogen is stored sugar of animal body as starch in plants.
413. Answer (2)
The sugar present in D.N.A. is 2-deoxy D() ribose.
414. Answer (3)
B2 is soluble in H2O but insoluble in fat
Vitamin H is insoluble in H2O and fat both
Vitamin A is soluble only in fat
Vitamin C is soluble in H2O
414a. Answer (1)
[JEE (Main)-2015]
Vitamin C is water soluble vitamin.

415. Answer (1)
Nylon-2-Nylon-6
(Step growth polymer)
Organic Chemistry
147
416. Answer (4)
N
N
and
are aromatic
417. Answer (2)

HC CH
CH2 = CH C CH
CH2 = CH C = CH2
|
Cl
CH2 CH = C CH2
n
Cl
Neoprene
418. Answer (3)

Tranquilizers These medicines act on central nervous system and help in reducing anxiety and relieve tension
on the nerves.
419. Answer (1)
It is chloroxylenol and is a component of dettol.
420. Answer (2)
Indigo is blue dye while alizarin is red dye.
421. Answer (1)
Heroin is morphine diacetate and is a narcotic drug.
422. Answer (2)
The sweetness of glucose is about 75% of cane sugar.
Sweetness of glucose = 100
75
75 .
100
423. Answer (1)

Reserpine is obtained from this plant which lowers the blood pressure.
424. Answer (2)
The sodium salts of azo dyes containing sulphonic acid (SO3H) and carboxylic acid (CO2H) groups are called
acid dyes.
425. Answer (1)
SLV-3 is indian rocket in which composite solid propellant is used.
426. Answer (4)
Factual.
427. Answer (4)
The chemicals which are used to bring down the body temperature during high fever are called antipyretics.
428. Answer (1)
Aspirin used as both antipyretics and analgesic.
429. Answer (2)
Sulphapyridine is used for the treatment of pneumonia.
148
Organic Chemistry
430. Answer (4)

Bipropellants consists of two liquids one of which acts as a fuel while other acts as the oxidizer.
431. Answer (1)
Mordant dyes are applied to the fabric after treating them with a metal ion (mordant) which acts as a binding
agent between the dye and the fabric.
432. Answer (3)
Malachite green is an example of triphenyl methane dye
433. Answer (3)

OH
COOCH3
Methyl salicylate.
434. Answer (4)
O
||
OCCH3
COOH
Aspirin
435. Answer (1)
Leibigs method is used for the estimation of carbon and hydrogen.
436. Answer (2)
Na2S + (CH3COO)2 Pb PbS + 2CH3COONa
437. Answer (2)
All nitrogen is converted to NH3.
438. Answer (2)
Beilstein test is used for the detection of halogen in organic compound.
439. Answer (1)
Kjeldahl method cannot be used for those compound in which nitrogen is present in ring.
440. Answer (3)
Phenol is acidic and gives violet coloured complex with FeCl3.
441. Answer (3)
n=
60
Molecular weight
=
=2
30
Empirical weight
So, molecular formula = C2H4O2

Organic Chemistry
149
442. Answer (2)

KOH is used to absorb CO2.
443. Answer (3)
PbS is insoluble in CH3COOH.
444. Answer (1)
Li is very less reactive while K is very highly reactive.
445. Answer (3)
Aldehyde gives positive test with Tollen reagent.
446. Answer (1)
If 42 g silver is present the weight of organic compound = 58
If 1 g silver is present the weight of organic compound =
58
42
58 108
= 149.14
42
So molecular weight of organic compound = 149.14 + 1 = 150.14 ~ 150
If 108 g silver is present the organic compound =
447. Answer (2)

Blood red colour is due to CH3 C NO 2 .
||
N ONa
448. Answer (1)
COOH group gives brisk effervences with NaHCO3.
449. Answer (2)
In Hofmann method diethyl oxalate is used.
450. Answer (1)
In thin layer chromatography, stationary phase is solid.
451. Answer (3)
Complex is [Fe(H2O)5NO]SO4.
452. Answer (3)
Black ppt are of Hg + Hg(NH2)Cl.
Black ppt
453. Answer (4)

All these metal ions belong with IIA group (groups belong with qualitative classification).
454. Answer (1)
NiS is black coloured and soluble in aqua regia.
455. Answer (1)
Cu+2 is coloured due to d-d transition.
456. Answer (4)
Except Be and Mg, all s block elements give flame test.
457. Answer (3)
Sodium metal does not form nitride.
150
Organic Chemistry
458. Answer (1)

As size of halogen increase, covalent character increase, so solubility decrease.
459. Answer (4)
MnS + 2HCl
MnCl2 + H2S
MnCl2 + 2NaOH
Mn(OH)2 + 2NaCl
Br2 + H2O
2HBr + (O)
Mn(OH)2 + O
MnO2
Black ppt
+ H2O
460. Answer (2)
Al(OH)3
gelatinous white ppt
NaAlO 2 + H2O
+ NaOH
So luble
Al(OH)3 + NaCl + NH3

NaAlO2 + NH4Cl + H2O
461. Answer (4)
NO2
NH2
NH2
N2Cl
N(CH3) 2
NaNO2/HCl
NaOH
SO3H
NaSO3
N=N
N(CH3)2
SO3H
462. Answer (2)

O
OH
O +
OH
OH
OH
Alizarin
463. Answer (1)
NHCOCH3
NH2
SO2NH2
Sulphonilamide
463a. Answer (4)
[JEE (Main)-2014]
PCC is mild oxidising agent, it will convert R CH2 OH

R CHO

SA 15 16 XII XII Chemistry Unit-2 Section-A

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SA 15 16 XII XII Chemistry Unit-2 Section-A

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Organic Chemistry

Section - A : Straight Objective Type

Na2S + Na2 [Fe(CN)5NO] Na4 [Fe(CN)5 NOS]

13. Answer (4)

Success Achiever (Solutions)

14. Answer (1)

(ngeq )H2SO4 (ngeq )NaOH (ngeq )NH3

(nmol )N (nmol )NH3 (ngeq )NH3

15. Answer (1)

Mass of Platinichloride 195 410

Molar mass of base =

16. Answer (2)

weight of silver salt

17. Answer (4)

Success Achiever (Solutions)

19. Answer (4)

23. Answer (1)

24. Answer (4)

25. Answer (2)

26. Answer (3)

Molar mass of ester = 2 45 2 + 2 45 = 178

29. Answer (3)

CCl3 > C6H5 CH2 > (CH3)2 CH > (CH3)3 C

Success Achiever (Solutions)

32. Answer (1)

CH3 O C H2 CH3 O CH2

OH is weaker nucleophile than NH2.

40. Answer (2)

is formed as a most stable carbocation.

42. Answer (2)

Success Achiever (Solutions)

47. Answer (1)

is most stable carbocation.

60. Answer (4)

Success Achiever (Solutions)

64. Answer (4)

75. Answer (2)

decreasing order of SN1 reactivity

Success Achiever (Solutions)

79. Answer (3)

86. Answer (3)

The concentration of B > A

Success Achiever (Solutions)

93. Answer (3)

Since it has chiral centre therefore it will show optical isomerism.

Protonolysis due to proton transfer.

100. Answer (3)

102. Answer (2)

106. Answer (3)

Success Achiever (Solutions)

107. Answer (4)

108. Answer (1)

109. Answer (1)

110. Answer (2)

112. Answer (3)

Success Achiever (Solutions)

113. Answer (3)

115. Answer (3)