Professional Documents
Culture Documents
Sol Aits Jeea FT IV Paper 2
Sol Aits Jeea FT IV Paper 2
JEE(Advanced)-2013
FIITJEE
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top
100, 75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
Q. No.
1.
PHYSICS
C
CHEMISTRY
C
MATHEMATICS
A
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
A, B, C
A,C
A, B
16.
A, B, C
A,C
A, B, C, D
17.
A, D
B,D
A, B, C
18.
A, B, D
B,D
C, D
19.
A, C, D
A, B, D
A, C
20.
C, D
B, C, D
A, C
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
Physics
PART I
SECTION A
1.
2.
3 R) 2
BV0R
2
[R ] =
2
force = (P P0) A = Ma
by P1V1 = P2V2
P0hA = P(h x) A
P0h
P=
hx
Ph
A
=a
So force = 0 P0
h
M
a=
P0 Ax
P Ax
0
; (for small x)
M(h x)
Mh
T = 2
3.
Mh
P0 A
L
2
L
L KL
L
sin
+ K sin +
4
4 2
2
2
3mg 5KL
restoring = 2 + 16 ( : small)
3mg 5kL2
+
1
2
16
frequency of oscillation) =
2
mL2 4mL2
=
where = mL2 +
3
3
4.
5.
The EMF will be induced in the loop, only when there is a change in the flux through the loop.
When the loop was completely inside the field region, for some time (say t1) there is no change in
the flux, hence that time would not be included in the calculation.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
b b 2b
+ =
v v
v
6.
That wire will break first whose stress reaches the breaking stress (for that
material) first.
F
F
=
Stress =
where F is the tension in the wire. F is same in both the wires.
A r 2
1
Thus stress 2 for the wire of smaller radius, the stress is more.
r
Thus the wire with smaller radius will break first.
If rA < rB, then wire A will break first.
If rA > rB, then wire B will break first.
If rA = rB, either of them could break.
8.
As the magnetic field is uniform and the particle is projected in a direction perpendicular to the
field, it will describe a circular path. The particle will not hit the yz-plane if the radius of the circle is
mv
= d.
smaller than d. For the maximum value of v, the radius is just equal to d. Thus
Bq
Bqd
v=
m
9.
F = A
u u0
y
F
y + u0
A
1
y + 1 = 100 y + 1
u = 2
10 1
u =
10.
The velocity of upper plate is same as that of the layer in contact with the plate i.e. layer at y = 2
cm.
u = 100 (0.02) + 1 = 3 m/s
11.
T2 r3 (Kepler's law)
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
TA2
TB2
12.
rA3
rB3
r3
3
(4r)
T
1
1
Get A =
64
TB 8
4 2 3
r = T03 or T = T0
GM
13-14. =
k
k
, =
=
M
M+m
2500
= 10 rad/sec
25
M
M+m
x1 = A sin 1
1 2 1
kx1 = M2 sin2 1
2
2
Let v and v be the velocity of system just before collision and just after collision, so using COLM
Mv
MA cos
v =
=
(M + m )
(M + m )
1 2 1(
kx1 + M + m ) v 2
2
2
2
2
M + msin
1
1 2 M + m sin
= MA 2 2
= kA
=8J
2
M+m
2
M+m
M + m sin2
1(
1
M + m ) A 2 2 = MA 2 2
M+m
2
2
15.
Imax (a1 + a2 )2
=
Imin (a1 a2 )2
a1
I
= 1 =
a2
I2
4 2
=
9 3
Imax
= 25
Imin
If an identical paper is pasted across second slit shifted C.B.F. will back in central point.
tD
shift = ( 1)
d
n D
fringe width =
d
shift
( 1)t
n=
=
= 15 .
fringe width
16.
The change in magnetic flux is zero, hence the current in the ring will be zero.
17.
18.
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
n(n 1)
=6 n=4
2
If the initial state were n = 3, in the emission spectrum, no wavelengths
shorter than 0 would have occurred. This is possible if initial state were n = 2
(A), (B) and (D)
n=4
3
2
1
19.
2GM
R
(A), (C) and (D) are correct.
20.
v=
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
Chemistry
PART II
SECTION A
pKa1 + pKa2 4 + 9
=
= 6.5
2
2
1.
pH at isoelectric point =
2.
5.
2+
6.
H3C
O
CH2
(i) EtO
CH2 CH3
O
(ii) H
H3C
H3C
CH C
CH2 O
CH
H3C
CH2 CH3
CH2 CH3
CH
CH2 CH3
CH2 OH
H3C
CH C
CH3
O
H3C
(Michael)
CH 2
, OH2
O
C
CH2 CH3
CH2
EtO
OH
O
C
CH3
CH2 CH3
O
C
Et
Li /
O
C
CH2 CH3
+ H2O + CO2 + Et OH
7.
FeSO4
Fe2O3 + SO3 + SO2
8.
Energy of e in H-atom = - E
Energy of e in Li+2 = - 9E
1
Energy supplied by photon = IE + mv 2
2
IE = E
Ep = 9E +
v=
1
mv 2
2
2 (Ep 9E )
m
9.
In reverse osmosis water moves from more concentrated to less concentrated solution
10.
= iCRT, (i=2)
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
7
11.
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
PbEDTA 2 H+
Keq =
2
x
x = 103
12.
14.
+
aq.K 2 CO3
H /H2 O
HCN
P + Q
R
S
heat
H2 O
H /H2 O
heat
OH
OH
OH
CN
OH
OH HO
(S)
HCN
O
O
+
aq. K 2 CO3
(P )
H
OH
(Q)
(R )
15.
Cl
KCN
Cl
Cl
H Pt
Cl
CN
NH2
H O+
CF CO H
HIO4
3
3
3
epoxide
diol
2CH3CHO
16.
Trans-2-butene
17.
18.
19.
Radius of cation is smaller than parent atom and that of anion is more than parent atom
O
(A)
O
H 2C
I
CH
C
O
O
CH2
I2 will attack the double bond to form a cyclic halonium ion. It then undergoes on intramolecular
reaction. Formation of five membered ring is favoured because (i) attack by a nucleophile on a
halonium ion normally takes place at the more substituted site.
(ii) Formation of five membered ring is more probable.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
(B)
Br
O
H3C
Br
O
CH2
(C)
C
Option(C)gives
O
C
(D)
Option(D)gives
1, 4 and 1,5-dicarboxylic acids give anhydrides whereas 1,6 and 1, 7-diacids give ketones when
heated with P2O5.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Mathematics
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
PART III
SECTION A
1.
2.
Given x + y + z = 5 (1)
and x2 + y2 + z2 = 9 (2)
1
2
We have yz = ( y + z ) y 2 + z2
2
1
2
= ( 5 x ) 9 x 2 (using) (1) & (2))
2
= x2 5x + 8
y, z must be the roots of the equation
(
(
u2 ( 5 x ) u + x 2 5x + 8 = 0 ( 3 )
2 sin2x + sin2 2x = 2
2(1 sin2 x) + 4 sin2 x cos2 x = 0
cos2 x.cos 2x = 0 (1)
sin 2x + cos 2x = tan x
2 sin x cos2 x + cos 2x cos x = sin x
sin x cos 2x + cos 2x cos x = 0
cos 2x (sin x + cos x) = 0 (2)
Common roots of (1) and (2) are given by cos 2x = 0
( 2n 1)
,n N
x=
4
n
In [0, 4] we have x =
, where n = 1, 3, 5,,15 (3)
4
Now, 2 sin2 x + sin x 0
2 sin2 x sin x 0
(sin x) (2 sin x 1) 0
1
sin x [1, 0] or sin x 1 (4)
2
5 7 13 15
Among the 8 values given by (3), only 4 values, i.e., x =
, ,
,
satisfy (4)
4 4 4
4
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
10
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
4.
1
z
Take z = ei ( |z| = 1).
We have w = ei + ei = 2cos
We know that w is real and | w | 2
We have w = z +
x2 1
5.
2x + 1
3x 2 + 2
x2 + 4
= x 1 2x 1 2x + 1
x +4
3x + 2
x +1
3x + 2
= x 1 2x 1 2x + 1
5x 2
x +4
3x + 2
x2 + 1
(using C3 C3 + C2 + C1)
5x + 7
= x 2 1 2x 2 1 2x 2 + 3
2
3 x 2 1
2 x2 1
5x
)(
5x 2
(using C2 C2 2C1)
5x + 7
= x 2 1 15x 4 + x 2 + 21
We have f ( x ) = a xn
1/ n
so that
n
= a a x
g ( x ) = f f .....f ( x ) = x
f f ( x ) = f a xn
1/ n
1/ n
1/ n
( (
))
1/ n
= a a xn
2m times
dx
(g ( x ))
(1+ (g ( x )) )
n 1/ n
dx
n
1 t 1/ n+1
1
=
1 + x n
+c =
n 1
1 n
+ 1
n
7.
(1 + x )
n
1
n
1/ n
dx
n +1
(1 + x )
n
1/ n
dt
nt
1/ n
(using t = 1 + xn)
+c
Given y = f ( x ) ,z = g ( x ) we have
d2 y
d f dx
dy dy / dx f ( x )
gf f g 1
=
.
=
and
=
=
2
dz dz / dx g ( x )
dx
g
dz
dz
( g)2 g
8.
f ( x ) is continuous at x = 3
( )
( )
f 3 = f ( 3 ) = f 3+
( )=
Now f 3
lim
x 3
a | x2 x 6 |
6+xx
= lim
x 3
a x 2 x 6
6+xx
)=a
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
11
( )
f 3 + = lim+
x 3
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
x [x]
x3
= lim+
=1
x 3 x 3
x3
x 2 + tdt
x
x tdt 0
3
f ( 3 ) = b lim 3
= 9b
form = b lim
x 3
x 3
1
x 3 0
1
a = 9b = 1 b =
and a = 1
9
9.
Vn =
r = n (n + 1)
Sr = 2
r =1
lim
10.
Vn
n
r =1
= lim
n +1
=1
n
(ii) Qn =
1
1
=
S
S
4
r =1 r r +1
1
1
=
r
r
1
4
+
)
r =1 (
r r + 1 = 4 1 n + 1
1
r =1
We have
2a x ,
x<0
f (x) =
x
x
a + a , x 0
Clearly, f(x) is continuous in R.
a2x 1
log a
For x > 0, f ( x ) = a x loge a + a x loge a = ( a x a x) loge a =
a x e > 0 for x > 0
12.
Required area =
2a
dx +
(a
x
2a
dx =
loge a
x
x
a + a
+
loge a
3a 2a 1
1
1 1
2 ( 2a ) +
+ a 0 =
aloge a
loge a
loge a a
15.
+a
2 2
a3
1
b3
Consider the parabola y2 = 4ax
2 1
a3 b3
m=
a 3
1
, c = a 3 b 3
b3
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
12
AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
a
=
m
a 3
1
3
ab
1
= a 3 b 3 = c
a3
b3
Condition for tangency for the parabola y2 = 4ax is satisfied
The given line touches y2 = 4ax
Similarly the line touches x2 = 4by
16.
( x + iy ) 5
= a + ib
( A ) sin2k =
k =0
(B)
cos
2k
k =0
(C)
tan2k =
k =0
1
1 sin2
= s ec 2
1
2
1 cos
1
1 tan2
= cosec 2
cos2
cos2 sin2
. Hence,
4
19.
3y = 9 3x 9 3x > 0 x < 2
Similarly, y < 2
20.
Area ( T ) =
cot
2k
cos2
cos 2
k =0
c.c 2 c 3
=
2
2
c
c3
Area (R ) =
x 2 dx
2
c
c
c
=
2
3
6
Area ( T )
c3 6
lim+
= lim+ . 3 = 3
c 0 Area (R )
R 0 2 c
=
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com