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Povoden-Karadeniz - HTMC2016 - Poster - Ni - A1 - With MARKS PDF
Povoden-Karadeniz - HTMC2016 - Poster - Ni - A1 - With MARKS PDF
and Technology
Computational Materials Engineering
erwin.povoden-karadeniz@tuwien.ac.at
Doppler Laboratory for Early Stages of Precipitation, Institute of Materials Science and Technology, Vienna University of Technology, Vienna, Austria
2University of Technology Graz, Austria
3Institute of Materials Science and Technology, Vienna University of Technology, Vienna, Austria
Interfacial energies
In the nucleation simulation of coherent precipitates their interfacial energies resulting from
generalized nearest-neighbour broken-bond model (NNBB) are decreased when the
interface between matrix and precipitate is diffuse [1]. In a computation simulation of
continuous cooling of Ni-base single-crystal superalloy PWA 1480 the interfacial energy at
the initial stages of (Ni,Co)3(Al,Ti,X) gamma precipitation close to the its thermodynamic
solvus is reduced significantly due to diffuse interface during nucleation of fully-coherent
gamma.
Figure 1: Thermal
evolution
of
interfacial energy
factor
due
to
diffuse
interface
calculated
with
Tcrit=2003K, based
on [1]
Thermodynamics
Figure 2: Thermodynamic
solvi of g calculated with
MatCalc Engineering
database, rel1.0 and
experimental data.
Precipitation simulation
Figure 4: g formation
accompanied by
pronounced
exothermal DSC peak.
Figure 3: Calculated
equilibrium phase fractions
of PWA 1480 (lines) and
experimental results
(symbols).
10K/s
1K/s
1K/s
10K/s