Gepiga, Hanah Mae

BSChE-4A
Quiz in CHE 324
13. Assuming C

O2

to be an ideal gas, calculate the work done by 10 g of C

O2

expanding

isothermally and reversibly from a volume of 5 litres to 10 litres at 27C. What are q, E, and H
for the process?
mC O

Given:

= 10 g

MW= 44.0098
V1

=5L

V2

= 10 L

g
mol

T= 27C + 273.15 = 300.15 K

Required: W, E, and H
Solution:
m

n= mw
10 g

n= 44.0098 g

mol

n= 0.2272221187 mol
V2

W=Q=

pdV
V1

W=Q= nRT ln

V2
V1

cal
10 L
W=Q= (0.2272221187 mole) (1.987 mol . K ) (300.15 K) (ln 5 L )

W=Q= 93.93172131 Cal

20. Eight grams of

O2

at 27C and under a pressure of 10 atm are permitted to expand

adiabatically and reversibly until the final pressure is 1 atm. Find the final temperature and the
work done in the process. Assume that

cp

Given:
mO

=8g

MW = 31.9988

g
mol

T 1 = 27C + 273.15 = 300.15 K

P1

= 10 atm

P2

= 1 atm

cp

O
Required:

7
2

= 1.4
T2

Solution:
m

n= mw

and

Wm

7
2

R for

O2

8g

n= 31.9988 g

mol

n= 0.2500093754 mole
T1
( )
T2

P1
= ( P21

300.15 K
T2

10 atm 1.41
)
1atm

1.4(log 300.15 log

T2

= 155 C 273

T2

= -118 K

Wm

=-

T2

T2

Cv

dT

Cv

T2

) = 0.4

Wm

=-n

T1

Wm

cal
= - (0.2500093754 mole) (4.9675 mol . K ) (-118 K 300.15K)

Wm

= 179.6 Cal

22. For a certain ideal gas

cp

1
= 8.58 Cal mole

degree1 . What will be the final

volume and temperature when 2 moles of the gas at 20C and 15 atm are allowed to expand
adiabatically and reversibly to 5 atm pressure?
Given:
cp

1
= 8.58 Cal mole

degree1

n = 2 moles
T1

= 20C + 273.15 = 293.15 K

P1

= 15 atm

P2

= 5 atm

= 1.3

Required:

V2

T2

Solution:
V2
P1
( )
V1
P2 = (

W/r:

V1

nRT
P

V2
P1
nRT
( )
P2 = (
P

1.3

15
5

V2
(
)
2 x 0.08206 x 293.15
15

1.3
V2
(
)
3.207451867

3=
V2

= 7.45 litres

T1
( )
T2

P1
= ( P21

293.15 K
T2

15 atm 1.31
(
)
5 atm

1.3(log 293.15 K log

T2

T2

) = 0.3

= -46

48. From the data of Table 7-2 calculate the heats of the following reactions at 25 .

Fe2 O3(s)

a. Given:

Required:

+ CO(g) = CO2(g) + 2Fe O(s )

H 25

Solution:
H 25

= n H f (products) - n H f (reactants)

H 25

= -94,050-2(64,300)-(-196,500-26,420)

 H 25

b. Given: 2N
Required:

= -270 Cal

O2(g )

= 2N

O( g)

O2(g )

H 25

Solution:
H 25

= n H f (products) - n H f (reactants)

H 25

= 21,600 x 2 - 2 x 8,090

H 25

= 27, 020 Cal

c. Given: 3
Required:

C2 H 2(g )

C6 H 6(l )

H 25

Solution:
H 25

= n H f (products) - n H f (reactants)

H 25

= 11,720 3 x 54,190

H 25

= 150,850 Cal

51. From the data in Table 7-4 determine at 25 the amount of heat which will be liberated
when 2 moles of

H 2 SO 4(l )

H 2 SO 4(l )

Given: 2 moles of
Required:

are dissolved in 30 moles of

H 25

Solution:
H 25

= 2 x (-16990)

H 25

= -33980 Cal

H 2 O(l )