Refercia

6
7

12

5
4
8

11
3
3

10
9
2
1

Sistema

Inibdor (%massa)

Etano
Etano
Etano
Etano
Etano
Propano (97%) + Butano (3%)
Metano
Metano
Metano
Metano
Metano
Metano
Metano
Etano (85%)+Propano(15%)
Metano (96%) + Butano (4%)
Metano (89,5%) + Etano (10,5%)
Metano (89,5%) + Etano (10,5%)
Metano (88%)+Propano (12%)
Metano (91%) + Etano (9%)
Propano
Propano
Propano
Propano
Propano
Metano (97%)+Propano(7%)

TEG (10%)
Etilenoglicol (15%)
Metanol (20%)
Metanol (10%)
Metanol (35%)
Metanol (20%)
Metanol (10%)
TEG (10%)
Etanol (15%)
Etilenoglicol (10%)
Metanol (20%)
Metanol (10%)
Metanol (15%)
TEG (15%)
Etilenoglicol (15%)
Metanol (10%)
Metanol (5%)
-

120%
100%
80%
60%

Column J

40%
20%
0%
0

10000

20000

30000

40000

50000

60000

70000

Experimental ou Calculada?

Faixa Temperatura (/K)

Menor Presso (/kPa)

277 - 282
271,73 - 282,72
263,53 - 275,69
268,28 - 281,41
273,68 - 285,48
273,15 - 274,15
260,25 - 270,05
278,65 - 289
276 - 286
274,6 - 276
273,3 - 284,7
270,24 - 287,1
274,25 - 284,76
276,66 - 283,32
276,91 - 285,95
266,99 - 278,07
268,66 - 284,87
276,89 - 289,81
278,71 - 295,52
272,3 - 276,1
271,42 - 273,79
268,3 - 272,1
272,12 - 274,79
273,55 - 277,32
278,09 - 297,53

1000
510
550
417
499
171.7
6810
16800
5630
3170
3378
2420
2920
825
2150
2110
1400
1365
2254
180
210.1
185
234
186
1416

Column J

60000

70000

Maior Presso (/kPa)

Nmero de pontos

Erro mdio (%)

1800
2600
2650
2800
2297
228.2
20510
57600
18820
3870
13665
15610
8550
1936
8160
8340
8420
17834
23198
450
426.7
984
468
425
24363

2
5
5
5
6
2
5
5
4
2
5
4
15
6
4
4
5
3
8
5
3
5
4
3
7

13%
13%
13%
11%
8%
3.43%
37%
15%
6%
3%
3%
3%
1%
3%
57%
23%
6%
32%
25%
98%
59%
34%
15%
2%
17%

Year:
1985
Authors:

Ng, H.-J.[Heng-Joo], Robinson, D. B.[Donald B.]

Source:
@Fluid Phase Equilib.@ $21$, 145-155
Title:

HYDRATE FORMATION IN SYSTEMS CONTAINING METHANE, ETHA

Year:
1983
Authors:

Ng, H.-J.[Heng-Joo], Robinson, D. B.[Donald B.]

Source:

@D. B. Robinson Equilibrium phase composition and hydrating c

Title:

Equilibrium phase composition and hydrating conditions in syste

Year:
1983
Authors:

Ng, H.-J.[Heng-Joo], Robinson, D. B.[Donald B.]

Source:

@D. B. Robinson Equilibrium phase composition and hydrating c

Title:

Equilibrium phase composition and hydrating conditions in syste

Year:
1951
Authors:

Kobayashi, R.[Riki], Withrow, H. J.[Harold J], Williams, B.[Brymer],

Source:

@30th Annual Convention Natural gasoline Association of Ameri

Title:
Gas Hydrate Formation with Brine and Ethanol Solutions

Year:
1992
Authors:

Ross, M. J.[Martin J.], Toczylkin. L. S.[Leonard S.]

Source:
@J. Chem. Eng. Data@ $37$, 488-91
Title:

Hydrate dissociation pressures for methane or ethane in the pres

Year:
1992
Authors:

Ross, M. J.[Martin J.], Toczylkin. L. S.[Leonard S.]

Source:
@J. Chem. Eng. Data@ $37$, 488-91
Title:

Hydrate dissociation pressures for methane or ethane in the pres

Year:
2000
Authors:

Majumdar, A. J., Mahmoodayhdam, E.[Elham], Bishnoi, P. R.[P. Ra

Source:
@J. Chem. Eng. Data@ $45$, 20-22
Title:
Equilibrium Hydrate Formation Conditions for Hydrogen Sulfide,

Year:
1986
Authors:

Robinson, D. B.[Donald B.], Ng, H.-J.[Heng-Joo]

Source:
@J. Can Petrol Tech@ $25$, 26 ( - 30)
Title:

Hydrate formation and inhibition in gas or gas condensate stream

Year:
2002
Authors:

Mahmoodayhdam, E.[Elham], Bishnoi, P. R.[P. Raj]

Source:
@J. Chem. Eng. Data@ $47$, 278-281
Title:

Equilibrium Data for Methane, Ethane, and Propane Incipient Hyd

Year:
1997
Authors:

10

Servio, P. [Phillip], Englezos, P.[Peter]

Source:
@J. Chem. Eng. Data@ $1997$(42), 800-1
Title:

Incipient Equilibrium Propane Hydrate Formation Conditions in A

Year:
1976

Authors:

11

Ng, H.-J.
[Heng-Joo],
Robinson, D.
B.[Donald B.]
Source:
@AIChE J.@
$22$(4), 656661
Title:
The Role of nButane in
Hydrate
Formation
Year:
1989
Authors:

12

Paranjpe, S. G., Patil, S. L., Kamath, V. A., Godbole, S. P.

Source:
@Spe Reservoir Engineering@, 446-454
Title:

Hydrate Euilibria for Binary and Ternary Mixtures of Methane, Pro

[Donald B.]

CONTAINING METHANE, ETHANE, PROPANE, CARBON DIOXIDE OR HYDROGEN SULFIDE IN THE PRESENCE OF METHANO

[Donald B.]

composition and hydrating conditions in systems containing methanol, light hydrocarbons, carbon dioxide and hydrogen sulfide@ RR-66

hydrating conditions in systems containing methanol, light hydrocarbons, carbon dioxide and hydrogen sulfide

[Donald B.]

composition and hydrating conditions in systems containing methanol, light hydrocarbons, carbon dioxide and hydrogen sulfide@ RR-66

hydrating conditions in systems containing methanol, light hydrocarbons, carbon dioxide and hydrogen sulfide

arold J], Williams, B.[Brymer], Katz, D. L.[Donald L.]

gasoline Association of America@, pp 27-31

and Ethanol Solutions

[Leonard S.]

methane or ethane in the presence of aqueous solutions of triethylene glycol

[Leonard S.]

methane or ethane in the presence of aqueous solutions of triethylene glycol

E.[Elham], Bishnoi, P. R.[P. Raj]

ditions for Hydrogen Sulfide, Carbon Dioxide, and Ethane in Aqueous Solutions of Ethylene Glycol and Sodium Chloride

.[Heng-Joo]

gas or gas condensate streams

noi, P. R.[P. Raj]

ne, and Propane Incipient Hydrate Formation in Aqueous Solutions of Ethylene Glycol and Diethylene Glycol

ate Formation Conditions in Aqueous Triethylene Glycol Solutions

V. A., Godbole, S. P.

nary Mixtures of Methane, Propane, Isobutane, and n-Butane: Effect of Salinity

n sulfide@ RR-66

n sulfide@ RR-66

Temperatura
(/K)
274.25
275.25
276.22
277.24
278.24
279.23
280.24
281.24
281.73
282.23
282.73
283.25
283.74
284.26
284.76

Presso
Experimental
(/kPa)
2920
3220
3550
3920
4330
4790
5310
5890
6200
6530
6880
7250
7650
8100
8550

Presso
Calculada
(/atm)
28.65
32
35
38.56683
42.5999
47.1893
52.3995
58.1884
61.3011
64.7435
68.1724
72.3223
76.3272
81
85.5856

Presso
Calculada
(/kPa)

Erro
(%)
2903
3204
3528
3908
4316
4781
5309
5896
6211
6560
6908
7328
7734
8194
8672

0.59
0.49
0.61
0.31
0.31
0.18
0.01
0.10
0.18
0.46
0.40
1.08
1.10
1.16
1.43

0.56

CH4+H2O+Metanol(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
20%
20%
20%
20%
20%

278.65
282.15
285.25
288.45
289

16800
24000
35900
57000
57600

122.4299
199.1719
313.8372
492.2952
528.9578

CH4+H2O+Metanol(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
35%
35%
35%
35%
35%

260.25
264.55
267.75
268.45
270.05

6810
10160
13680
17220
20510

39.9679
64.1938
93.923
101.5206
125.8628

ambda=0,36)
Presso
Calculada
(/kPa)
12405.21
20181.09
31799.55
49881.81
53596.65
Mdia

CH4+H2O+Metanol(lambda=0,36)
Erro
(%)
26%
16%
11%
12%
7%
15%

ambda=0,36)
Presso
Calculada
(/kPa)
4049.747
6504.437
9516.748
10286.57
12753.05
Mdia

Erro
(%)
41%
36%
30%
40%
38%
37%

Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
10%
10%
10%
10%

276
280
284
286

5630
9070
13320
18820

52.0711
80.7208
131.4717
171.628

ambda=0,36)
Presso
Calculada
(/kPa)
5276.104
8179.035
13321.37
17390.21
Mdia

Erro
(%)
6%
10%
0%
8%
6%

CH4+H2O+Etilenoglicol(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
10%
10%
10%
10%

270.24
273.49
280.19
287.1

2420
3400
6530
15610

23.392
32.2171
64.5434
146.9085

l(lambda=0,36)
Presso
Calculada
(/kPa)
2370.194
3264.398
6539.86
14885.5
Mdia

Erro
(%)
2%
4%
0%
5%
3%

270,24 - 287,1
2420 - 15610
3%
4

CH4+H2O+TEG(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
10%
10%

274.6
276

3170
3870

32.0522
36.8671

mbda=0,36)
Presso
Calculada
(/kPa)
3247.689
3735.559
Mdia

Erro
(%)
2%
3%
3%

274,6 - 276
3170 - 3870
3%
2

C2H6+H2O (lambda=0.36)
Temperatura
(/K)
273.68
274.7
275.64
278.66
282.66
285.48

Presso
Presso
Presso
Experime
Calculada Calculada
ntal
(/atm)
(/kPa)
(/kPa)
499
565
635
926
1546
2297

4.514245
5.114305
5.740086
8.353128
13.98376
21

457.4059
518.207
581.6142
846.3807
1416.904
2094.772

Erro
(%)
8%
8%
8%
9%
8%
9%

8%

C2H6+H2O+Metanol(lambda=0,36)
Presso
Frao Temperat
Presso
Presso
Experime
inibidor
ura
Calculada Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
(/kPa)
10%
10%
10%
10%
10%

268.28
272.1
276.01
280.4
281.41

417
731
1160
2160
2800

4.5087
7.278
12.0412
18.0507
20.908

456.844
737.4434
1220.075
1828.987
2118.503
Mdia

0,36)

C2H6+H2O+Metanol(lambda=0,36)
Erro
(%)
10%
1%
5%
15%
24%
11%

Presso
Frao Temperat
Presso
Presso
Experime
inibidor
ura
Calculada Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
(/kPa)
20%
20%
20%
20%
20%

263.53
264.86
268.81
271.75
275.69

550
614
1030
1520
2650

5.1108
6.0478
10.055
10.952
17.6989

517.8518
612.7933
1018.823
1109.711
1793.341
Mdia

0,36)
Erro
(%)
6%
0%
1%
27%
32%
13%

C2H6+H2O+Etilenoglicol(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
15%
15%
15%
15%
15%

271.73
277.13
279.4
282.38
282.72

510
1090
1540
2430
2600

5.9746
10.7724
13.3822
20.3368
21.3985

ol(lambda=0,36)
Presso
Calculada
(/kPa)
605.3763
1091.513
1355.951
2060.626
2168.203
Mdia

Erro
(%)
19%
0%
12%
15%
17%
13%

271,73 - 282,72
510 - 2600
13%
5

C2H6+H2O+TEG(lambda=0,36)
Presso
Frao Temperat
Presso
Presso
Experime
inibidor
ura
Calculada Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
(/kPa)
10%
10%

277
282

1000
1800

9.2613 938.4012
14.2435 1443.223
Mdia

36)
Erro
(%)
6%
20%
13%

C3H8+H2O(lambda=0.36)
Presso
Temperat
Presso
Presso
Experime
ura
Calculada Calculada
ntal
(/K)
(/atm)
(/kPa)
(/kPa)
273.55
275.47
277.32

186
1.82 184.6115
291 2.764079 280.0703
435 4.164864 422.0048

Erro
(%)
1%
4%
3%

2%

C3H8+H2O(lambda=0.36)
Frao
mssica
metanol
(%)
5%
5%
5%
5%

Presso
Temperat
Presso
Presso
Experime
ura
Calculada Calculada
ntal
(/K)
(/atm)
(/kPa)
(/kPa)
272.12
272.58
273.28
274.79

Erro
(%)

234
2.75 278.4898
259 3.043119 308.344
316 3.557787 360.4928
468
5 508.2635

19%
19%
14%
9%
Mdia

C3H8+H2O(lambda=0.36)
Frao
mssica
metanol
(%)
10%
10%
10%
10%
10%

Presso
Temperat
Presso
Presso
Experime
ura
Calculada Calculada
ntal
(/K)
(/atm)
(/kPa)
(/kPa)
268.3
270.93
271.07
271.82
272.1

Erro
(%)

185 2.503559 253.6731

360 4.52396 458.3902
352 4.68319 474.5242
434 5.589485 566.3546
984 5.982216 606.148

37%
27%
35%
30%
38%
Mdia

272,12 - 274,79
234 - 468

15%

268,3 - 272,1
185 - 984

34%

Propano+H2O+Etilenoglicol(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
15%
15%
15%

271.42
272.46
273.79

210.1
303
426.7

3.620972
4.595172
6.296013

col(lambda=0,36)
Presso
Calculada
(/kPa)
366.895
465.6058
637.9435
Mdia

Erro
(%)
75%
54%
50%
59%

271,42 - 273,79
210,1 - 426,7
59%
3

Propano+H2O+TEG(lambda=0,36)
Presso
Frao Temperat
Presso
Experime
inibidor
ura
Calculada
ntal
(%massa)
(/K)
(/atm)
(/kPa)
15%
15%
15%
15%
15%

272.3
272.6
273.9
275
276.1

180
215
275
370
450

3.722989
3.971392
5.360823
6.95965
9.167552

ambda=0,36)
Presso
Calculada
(/kPa)
377.2319
402.4013
543.1854
705.1865
928.9022
Mdia

Erro
(%)
110%
87%
98%
91%
106%
98%

272,3 - 276,1
180 - 450
5%
98%

CH4+C2H6
Frao
Metano
(%mol)
90.47%
90.47%
90.47%
90.47%
90.47%
90.47%
90.47%
90.47%

Frao
Etano
(%mol)
9.53%
9.53%
9.53%
9.53%
9.53%
9.53%
9.53%
9.53%

Presso
Temperat
Presso
Experime
ura
Calculada
ntal
(/K)
(/atm)
(/kPa)
278.21
279.6
283.69
288.12
290.44
292.97
294.63
295.52

2254
2628
4191
7208
9992
14849
19891
23198

26
31
49.46075
88.88941
126.839
192.009
252.3891
290.823

Presso
Calculada
(/kPa)
2680.067
3128.794
5011.61
9006.719
12851.96
19455.31
25573.33
29467.64

Erro
(%)
18.90268
19.0561
19.5803
24.95449
28.62251
31.02102
28.56732
27.02664

Erickson
(/atm)

Erickson
(/kPa)

25.7552
29.8816
47.0084
80.7642
111.2663
160.4091
200.5421

2609.646
3027.753
4763.126
8183.433
11274.06
16253.45
20319.93

Erro
(%)
16%
15%
14%
14%
13%
9%
2%

Hidrato de Metano + Etano

35000
28000

Presso de dissociao (/kPa)

21000

Experimental

14000

Modelo Proposto

7000
0
270 280 290 300
Temperatura

CH4+C2H6+CH4O
Frao
mssica
metanol
(%)
10%
10%
10%
10%
10%

Frao
Metano
(%mol)
89.50%
89.50%
89.50%
89.50%
89.50%

Frao
Etano
(%mol)
10.50%
10.50%
10.50%
10.50%
10.50%

Presso
Temperat
Presso
Experime
ura
Calculada
ntal
(/K)
(/atm)
(/kPa)
268.66
273.63
277.14
280.45
284.87

1400
2320
3280
4780
8420

13
23
34.1916
50.8493
94.3301

CH4+C2H6+CH4O
Frao
mssica
metanol
(%)
20%
20%
20%
20%

Frao
Metano
(%mol)
89.5%
89.5%
89.5%
89.5%

Frao
Etano
(%mol)
10.5%
10.5%
10.5%
10.5%

Presso
Temperat
Presso
Experime
ura
Calculada
ntal
(/K)
(/atm)
(/kPa)
266.99
272.27
275.19
278.07

2110
3760
5490
8340

16.476
29.597
41.6121
60.4544

Presso
Calculada
(/kPa)
1365.03
2330.799
3464.464
5152.305
9557.997
Mdia

Presso
Calculada
(/kPa)
1669.431
2998.916
4216.346
6125.542
Mdia

Erro
(%)
2.497848
0.465484
5.623898
7.788814
13.51541
5.978291

268,66 - 284,87
1400 - 8420
5.98%

Erro
(%)
20.88006
20.2416
23.19953
26.55225
22.71836

266,99 - 278,07
2110 - 8340
22.72%

CH4+C3H8 (lambda=0.36)
Frao
Metano
(%mol)

Frao
Propano
(%mol)

97%
97%
97%
97%
97%
97%
97%

3%
3%
3%
3%
3%
3%
3%

Presso
Temperat
Presso
Presso
Experime
ura
Calculada Calculada
ntal
(/K)
(/atm)
(/kPa)
(/kPa)
278.09
283.52
288.8
292.87
295.33
296.59
297.53

1416
2640
5080
9196
14966
19814
24363

12.85639
25.17103
51.28767
104.6929
192.0226
257.1862
311.7503

1302.674
2550.455
5196.723
10608.01
19456.69
26059.39
31588.1

Erro
(%)
8.003269
3.391871
2.2977
15.35459
30.00595
31.5201
29.65603

0.171756

C2H6+C3H8(lambda=0.36)
Frao
Etano
(%mol)
85%
85%
85%
85%
85%
85%

Frao
Propano
(%mol)
15%
15%
15%
15%
15%
15%

Presso
Temperat
Presso
Experime
ura
Calculada
ntal
(/K)
(/atm)
(/kPa)
276.66
278.92
279.11
281.38
281.49
283.32

825
1089
1115
1495
1513
1936

7.771472
10.35919
10.61138
14.26613
14
18.7076

0.36)
Presso
Calculada
(/kPa)
787.4444
1049.645
1075.198
1445.516
1467.27
1895.548

Erro
(%)
4.552194
3.613873
3.569679
3.309992
3.022465
2.089485

3%

CH4+C3H8 (lambda=0.36)
Frao
Metanol
(%massal)

Frao
Metano
(%mol)

Frao
Propano
(%mol)

Temperat
ura
(/K)

15%
15%
15%

88%
88%
88%

12%
12%
12%

276.89
288.57
289.81

(lambda=0.36)
Presso
Presso
Presso
Experime
Calculada Calculada
ntal
(/atm)
(/kPa)
(/kPa)
1365
12640
17834

Erro
(%)

13.13 1330.732 2.510504

68.65 6955.909 44.96908
90.56
9176.19 48.54665

Metano + Butano(lambda=
Frao
Metano
(%mol)
96.09%
96.09%
96.09%
96.09%

Frao
Butano
(%mol)
3.91%
3.91%
3.91%
3.91%

Temperatura
(/K)
276.91
279.74
283.12
285.95

tano + Butano(lambda=0.36)
Presso
Experimental
(/kPa)
2150
3140
5090
8160

Presso
Calculada
(/atm)

Presso
Calculada
(/kPa)

Erro
(%)

39.0232 3954.026 83.90817

52.0904 5278.06 68.09108
74.7242 7571.43 48.75107
103.2242 10459.19 28.17637
Mdia
57.23167

Erickson
(/atm)
25.8025
36.3267
56.3271
85.0064

Erickson
(/kPa)
2614.438
3680.803
5707.343
8613.273

12000
10000
8000
6000
4000
2000
0
276

278

280

Erro
(%)
22%
17%
12%
6%

Column H
LCVM
Erickson

278

280

282

284

286

288

Propano + Butano(lambda=
Frao
Propano
(%mol)
96.90%
96.10%

Frao
Butano
(%mol)
3.10%
3.90%

Temperat
ura
(/K)
273.15
274.15

ano + Butano(lambda=0.36)
Presso
Presso
Presso
Experime
Calculada Calculada
ntal
(/atm)
(/kPa)
(/kPa)
171.7
228.2

Erro
(%)

1.73197 175.4919
2.21
2.147431 217.5884 4.650111
Mdia
3.43

273,15 - 274,15
171,7 - 228,2
3.43%

273.15

273.15

273.15

273.15

273.15

273.15

273.15

273.15

273.15

10

274.15

11

274.15

12

274.15

13

274.15

14

274.15

15

275.15

169.6

171.7

0.969

177.9

0.953

183.4

0.938

193.1

0.895

208.2

0.864

220.6

0.828

227.5

0.788

244.1

0.725

219.3

228.2

0.961

240.6

0.933

244.8

0.906

269.6

0.817

269.6

0.996

C2H6+C3H8
Frao
Metano
(%mol)
58%
69%
71%

Frao
Etano
(%mol)
42%
31%
29%

C2H6+C3H8(lambda=0.36)
Presso
Temperat
Presso
Presso
Experime
ura
Calculada Calculada
ntal
(/K)
(/atm)
(/kPa)
(/kPa)
274.2
274.2
274.2

883
958
972

Erro
(%)

8.0458 815.2407 7.673762

9.6371 976.4792 1.928931
10.0156 1014.831 4.406448

274.2

274.2

274.2

883

0.581

958

0.69

972

0.708