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Microstructure Evolution and Change in Hardness in Type 304hstainless Steel During Long-Term Creep.
Microstructure Evolution and Change in Hardness in Type 304hstainless Steel During Long-Term Creep.
Microstructure Evolution and Change in Hardness in Type 304hstainless Steel During Long-Term Creep.
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Abstract
The microstructural evolution and the change in hardness have been investigated for 18Cr 8Ni (type 304H) stainless steel
during long-term creep. Creep and creep-rupture tests were carried out at temperatures between 550 (823) and 750C (1023 K) for
up to 180 000 h. The hardening behavior during creep depends on the stress level, as well as the precipitation of M23C6 carbides
and s phase. At a high stress of 177 MPa, the hardening during creep is much larger than the age hardening, indicating that the
hardening during creep is mainly caused by the strain hardening due to creep deformation. At a later stage of creep, the softening
occurs due to the recovery of excess dislocations, which becomes more significant with decreasing stress and increasing test
duration. The strain hardening disappears with decreasing stress level and increasing test duration. At a low stress of 61 MPa or
less, the hardening during creep can be approximately given by the age hardening under no stress, except for the final stage of
creep. 2001 Elsevier Science B.V. All rights reserved.
Keywords: Microstructural evolution; Type 304H; Long-term creep
1. Introduction
Austenitic stainless steels, such as type 304 (l8Cr
8Ni), 316 (l8Cr l2Ni Mo), 321 (18Cr 10Ni Ti) and
347 (18Cr 12Ni Nb) steels, are widely used as hightemperature components, such as boilers, superheaters
and chemical reactors, which require good mechanical
properties and corrosion resistance at temperatures up
to 650 700C. It is well known that long-term exposure
of the steels to stress at these temperatures can cause
microstructure evolution and creep deformation leading
ultimately to creep-rupture. Of the steels, the type 304
steel exhibits the simplest microstructure where only
M23C6 carbides and s phase precipitate at high temperatures, while the microstructure of the other steels are
complicated [1]. Several investigations have dealt with
the microstructure evolution in the type 304 steel during
thermal aging and creep [2,3]. But these studies are
limited to specimens tested in periods not exceeding
60 000 h, while high-temperature components are usually operating for long periods exceeding 100 000 h. At
* Corresponding author. Tel.: + 81-298-592219; fax: +81-298592201.
E-mail address: hide@nrim.go.jp (H. Tanaka).
present, little is known about the microstructure evolution during long-term creep for up to 100 000 h or more.
The present authors and co-workers have investigated
comprehensively the microstructure evolution during
creep and its effect on long-term creep strength for type
304H steel, where the term H means high carbon
concentration, using specimens tested in the NRIM
Creep data sheet project [1,4 6]. A number of micrographs for the type 304H steel were recently published
in Metallographic Atlas of Long-term Crept Materials
[7]. In the present research, the relationship between the
microstructure evolution and the change in hardness has
been investigated for the type 304H steel during creep
for up to 180 000 h at high temperature. The measurement of hardness is frequently used for estimating
materials degradation and remaining life for high-temperature components.
2. Experimental procedure
The material used was the commercially produced
heat ABE of 18Cr 8Ni steel (304H TB) in the NRIM
Creep Data Sheet No. 4B [8], where the creep rupture
data were presented for nine heats of 18Cr 8Ni steel.
0921-5093/01/$ - see front matter 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 9 2 1 - 5 0 9 3 ( 0 1 ) 0 1 0 1 2 - 7
789
Fig. 1. Stress versus time to rupture for the heat ABE of type 304H
steel.
790
Fig. 4. Creep curves of type 304h steel at 177, 118 and 61 MPa at
650C.
Fig. 5. Vickers hardness during creep as functions of (a) time and (b)
normalized time t/tr at 650C.
791
than 100 000 h, indicating a low stress condition presumably much less than 61 MPa at 650C. Therefore,
for estimating materials degradation or remaining life
for type 304 austenitic steel components, the hardness
can be approximated by the age hardening under no
stress and the results shown in Fig. 2a can be used as
reference or standard data. By comparing the hardness
of the components with the data shown in Fig. 2a and
by observing microstructure, we can also estimate the
operating conditions, such as operating temperature
and time, for the components.
4. Conclusions
During thermal aging under no stress, the precipitation of M23C6 carbides and s phase causes the age
hardening at short times below 1000 h and at long
times above about 10 000 h, respectively, at around
650C.
The hardening behavior during creep at 650C depends on stress levels as well as the precipitation of
M23C6 carbides and s phase. At a high stress of 177
MPa, the hardness increases for up to t/tr=0.7, then
decreases slightly and again increases just before creeprupture. The hardening during creep is much larger
than the age hardening, indicating that the hardening
during creep is mainly caused by the strain hardening.
The strain hardening disappears with decreasing stress
level and increasing test duration.
For estimating materials degradation or remaining
life for type 304 austenitic steel components, which are
usually operated under stresses presumably less than 61
MPa, the hardness can be approximated by the age
hardening under no stress, except for the final stage just
before creep-rupture.
References
[1] H. Tanaka, M. Murata, F. Abe, K. Yagi, Mater. Sci. Eng.
A234 236 (1997) 1049.
[2] Y. Minami, H. Kimura, Y Ihara, Mater. Sci. Technol. 2 (1986)
795.
[3] V.A. Biss, V.K. Sikka, Metall. Trans. 12A (1981) 1360.
[4] N. Shinya, J. Kyono, H. Tanaka, M. Murata, S. Yokoi, TetsuTo-Hagane 69 (1983) 1668 in Japanese.
[5] H. Tanaka, M. Murata, M. Kaise, N. Shinya, Tetsu-To-Hagane
74 (1988) 2009 in Japanese.
[6] M. Murata, H. Tanaka, E. Abe, H. Irie, Proceedings of the
Eighth. International Conference on Creep and Fracture of Engineering Materials and Structures, Key Eng. Mater. 171 174
(1999) 513.
[7] National Research Institute for Metals Creep Data Sheet, Metallographic Atlas of Long-Term Crept Materials, National Research Institute for Metals, Japan, No. M-1 (1999).
[8] National Research Institute for Metals Creep Data Sheet, National Research Institute for Metals, Japan, No. 4B (1986).