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    Detailed Information On Carbonyl IR

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    ismailhussain22
    This document provides a summary of characteristic infrared absorption frequencies of common organic functional groups. It lists the typical ranges and intensities of absorptions for functional groups including alcohols, alkanes, alkenes, alkyl halides, alkynes, amines, aromatics, carbonyls, ethers, nitriles, nitro compounds, and various carbonyl-containing functional groups such as acids, aldehydes, amides, anhydrides, esters, ketones. References for more detailed information on interpreting infrared spectra are also provided.

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    Detailed Information On Carbonyl IR

    Uploaded by

    ismailhussain22
    27 views2 pages
    This document provides a summary of characteristic infrared absorption frequencies of common organic functional groups. It lists the typical ranges and intensities of absorptions for functional groups including alcohols, alkanes, alkenes, alkyl halides, alkynes, amines, aromatics, carbonyls, ethers, nitriles, nitro compounds, and various carbonyl-containing functional groups such as acids, aldehydes, amides, anhydrides, esters, ketones. References for more detailed information on interpreting infrared spectra are also provided.

    Original Description:

    FTIR Frequencies

    Original Title

    IR Frequencies

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    This document provides a summary of characteristic infrared absorption frequencies of common organic functional groups. It lists the typical ranges and intensities of absorptions for functional groups including alcohols, alkanes, alkenes, alkyl halides, alkynes, amines, aromatics, carbonyls, ethers, nitriles, nitro compounds, and various carbonyl-containing functional groups such as acids, aldehydes, amides, anhydrides, esters, ketones. References for more detailed information on interpreting infrared spectra are also provided.

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    © All Rights Reserved
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    27 views2 pages

    Detailed Information On Carbonyl IR

    Uploaded by

    ismailhussain22
    This document provides a summary of characteristic infrared absorption frequencies of common organic functional groups. It lists the typical ranges and intensities of absorptions for functional groups including alcohols, alkanes, alkenes, alkyl halides, alkynes, amines, aromatics, carbonyls, ethers, nitriles, nitro compounds, and various carbonyl-containing functional groups such as acids, aldehydes, amides, anhydrides, esters, ketones. References for more detailed information on interpreting infrared spectra are also provided.

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    of 2

    1/29/2016

    IRfrequencies

    CharacteristicIRAbsorptionFrequenciesofOrganicFunctionalGroups
    Functional Typeof
    Characteristic
    Intensity
    Group
    Vibration Absorptions(cm1 )
    Alcohol
    (stretch,H
    OH
    32003600
    strong,broad
    bonded)
    (stretch,
    OH
    35003700
    strong,sharp
    free)
    CO
    (stretch)
    10501150
    strong
    Alkane
    CH
    CH
    Alkene
    =CH
    =CH
    C=C
    Alkyl
    Halide
    CF
    CCl
    CBr
    CI
    Alkyne
    CH

    stretch
    bending

    28503000
    13501480

    strong
    variable

    stretch
    bending
    stretch

    30103100
    6751000
    16201680

    medium
    strong
    variable

    stretch
    stretch
    stretch
    stretch

    10001400
    600800
    500600
    500

    strong
    strong
    strong
    strong

    stretch
    stretch

    3300
    21002260

    strong,sharp
    variable,notpresentinsymmetricalalkynes

    NH

    stretch

    33003500

    CN
    NH

    stretch
    bending

    10801360
    1600

    medium(primaryamineshavetwobandssecondary
    haveoneband,oftenveryweak)
    mediumweak
    medium

    Aromatic
    CH
    C=C

    stretch
    stretch

    30003100
    14001600

    medium
    mediumweak,multiplebands

    Amine

    AnalysisofCHoutofplanebendingcanoftendistinguishsubstitutionpatterns
    Carbonyl
    DetailedInformationonCarbonylIR
    C=O
    stretch
    16701820
    strong
    (conjugationmovesabsorptionstolowerwavenumbers)
    Ether
    stretch

    10001300(1070
    1150)

    strong

    CN
    Nitro

    stretch

    22102260

    medium

    NO

    stretch

    15151560&1345
    1385

    strong,twobands

    CO
    Nitrile

    IRAbsorptionFrequenciesofFunctionalGroupsContainingaCarbonyl(C=O)
    Functional
    Typeof
    CharacteristicAbsorptions(cm
    Intensity
    Group
    Vibration
    1)
    http://www2.ups.edu/faculty/hanson/Spectroscopy/IR/IRfrequencies.html

    1/2

    1/29/2016

    IRfrequencies

    Carbonyl
    C=O

    stretch
    16701820
    (conjugationmovesabsorptionstolowerwavenumbers)

    strong

    Acid
    C=O

    stretch

    17001725

    strong

    OH

    stretch

    25003300

    strong,verybroad

    CO
    Aldehyde

    stretch

    12101320

    strong

    C=O

    stretch

    17401720

    strong

    =CH
    Amide

    stretch

    28202850&27202750

    medium,twopeaks

    C=O

    stretch

    16401690

    strong

    NH

    stretch

    31003500

    unsubstitutedhavetwo
    bands

    NH
    Anhydride

    bending

    15501640

    C=O

    stretch

    18001830&17401775

    twobands

    Ester
    C=O

    stretch

    17351750

    strong

    CO

    stretch

    10001300

    twobandsormore

    Ketone
    acyclic

    stretch

    17051725

    strong

    cyclic

    stretch

    3membered1850
    4membered1780
    5membered1745
    6membered1715
    7membered1705

    strong

    ,unsaturated

    stretch

    16651685

    strong

    arylketone

    stretch

    16801700

    strong

    Agoodgeneralreferenceformoredetailedinformationoninterpretationofinfraredspectra(aswellas
    otherspectroscopictechniques)isSilverstein,R.M.Bassler,G.C.andMorrill,T.C.Spectrometric
    IdentificationofOrganicCompounds.4thed.NewYork:JohnWileyandSons,1981.QD272.S6S55
    Amorecompletelistingoffunctionalgroupabsorptionfrequenciesmabefoundin:Nakanishi,Koji
    InfraredAbsorptionSpectroscopy.QD95.N383

    http://www2.ups.edu/faculty/hanson/Spectroscopy/IR/IRfrequencies.html

    2/2

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