Professional Documents
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CP System
CP System
Arindam Samanta
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Mechanism Of Corrosion
Corrosion is loss of metal by electrochemical reaction of metal with its
environment.
Almost always electrochemical reactions occur in aqueous solutions.
In all aqueous electrolytes such as soil, water, metal atoms go into solution as
metal ions.
For corrosion (electrochemical) reaction to proceed the following conditions
must be satisfied
i.
Setting up a galvanic cell in the same metal or between two different metals
resulting in a potential difference in the cell and current flow.
ii.
Corrosion Reactions
AT ANODE
M M +z + Ze
AT CATHODE
(Acid)
2 H + +2e H2
(Acidic solutions)
(Neutral
or Basic solutions)
O 2+ 2H2O+ 4e 4OH
For Iron
Fe Fe+++2e
Fe ++ + 2OH Fe (OH)2
4Fe (OH)2 + O2 + 2H2 O 4Fe (OH)3
Fe(OH)3 FeOOH+H2O (Hydrated Ferric oxide, Red Rust)
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Corrosion Rate
Corrosion rate expressed as mm/yr or mils/year (mpy) or Mg/dm2/day(mdd).
The above units represent average rate of metal penetration or weight loss of
metal excluding any adherent or non adherent corrosion products.
= It a / nF tA
=ia/nF
The above relationship gives proportionality between mass loss per unit area per
unit time ( mg/dm2/day) and current density( A/cm2).The constant includes
factor a/nF and conversion factor for units
Corrosion rate expressed in penetration per unit time
a) corrosion rate in mils per year (mpy) = 0.129 x a i /n d
where d= density of the metal ( gm/cm3)
i = a/cm2
b) corrosion rate in mm/yr = 0.00327 x a i/n d
For FeFe++ + 2e ,
1a/cm2= 0.0116mm/yr
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a)
b)
c)
d)
Cathodic Protection
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Sacrificial Anode
Cathodic Protection
Impressed
Current Cathodic Protection
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Al Al +++ + 3e
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Protection Criteria
Plain carbon steel and low alloy ferrous materials exposed to soil, fresh water
and sea water are fully cathodically protected when their interface potential to
electrolyte when measured with a coppercopper sulfate reference electrode is
minimum 0.850 volts for soil / freshwater and 0.800 volts w.r.t. Ag / Agcl in
seawater.
Measurement taken by placing the electrode in the electrolyte and measuring
the potential between structure and electrode with a high resistance voltmeter
(see figure).
Above potentials are at electrolyte metal interface temperature upto 40C. For
temp > 40C, protection potential shall be0.950 Volt (Cu / Cuso4) in soil / fresh
water and 0.900Volt (Ag / Agcl) in sea water.
For large bare structure drawing high current, minimum 100 mv potential shift
is recommended as protection criteria
Shift = Instant offpotential (Cu/CuSO4) Natural Potential (Cu/CuSO4)
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For effective cathodic protection ,all anodic process must be stopped i.e. all
anodic current shall be zero and there would not be solvation of metal atom.
To satisfy above condition potential of metal should be equal to reversible
potential of that metal electrode
Fe Fe++ + 2e in its own ions
Excessive current leads to very high cathode potential which has following
detrimental effects----
High pH
Wastage of energy.
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For existing structures, a current requirement test will provide the actual current
requirement at the time of the test. Allowance should be made in the design for
future degradation of coatings or structure additions that will increase the current
requirement.
Ceramic anodes are made in a variety of shapes, such as, wires, rods, tubes,
strips, disks, and mesh.
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The number of anodes or length of anode wire required is determined from the
total current required and the manufacturer's published current rating for a given
life.
The number calculated will determine the minimum number of anodes or anode
wire length required.
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The total circuit resistance (RT) consists of the anode-to electrolyte resistance (RN)
plus the interconnecting wire resistance (RW) plus the structure-to-electrolyte
resistance (RC).
RT = RN + RW + RC
A criterion of 2-ohm maximum ground bed resistance is often used to limit the
rectifier output voltage and the associated hazards of overprotection. When the
total required current is low, a higher total resistance is often acceptable. As the
required current increases, the total resistance should be reduced.
The anode-to-electrolyte resistance for a single anode is given by RA. For a single
vertical anode:
If the anode dimensions are different, another empirical expression may be used:
Wire resistance (RW) is the sum of both the rectifier-to anode lead and the rectifierto-protected-structure lead.
where LW is the length of wire in thousands of feet and RMFT is the resistance of
the wire in ohms per 1000 ft.
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where RS is the coating resistance in ohm-square feet and A is the total surface
area. If the structure surface is bare, negligible resistance is assumed (RC = 0).
g. Calculate required rectifier voltage and current.
The required rectifier voltage (VREC and maximum current rating should include at
least an extra 20 percent to allow for variations in calculations from actual
conditions and for changes in the system over the system's life.
where I is the total current required and RT is the total circuit resistance as
calculated above and IREC is the minimum current rating for a rectifier for this
particular application.
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Anodes
Cables
Backfill
Junction boxes
Potential recorder
DC Power Source
PSP Feedback
facility TR Unit Drawing
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Anodes
Sacrificial Anodes:--1.
Zinc
2.
Aluminum Alloy
3.
Magnesium
1. Graphite
2. Silicon-chromium-iron alloy
3. Metal oxide coated titanium
4. Platinised titanium
5. Platinised niobium
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Sacrificial Anodes
Sacrificial anodes generate their own DC Charges and require no external DC
Power source.
Sacrificial anodes are made of metals which are more electronegative in E.M.F
series than protected metal
They have fixed driving voltage to protected metal which is in range of 0.60.25 volts.
They are not pure metals but alloys . Alloying elements have several functions
which are :i. Giving a fine grained structure to give uniform corrosion.
ii. Reduce self corrosion by local cell action.
iii. Prevent passivation due to formation of insoluble corrosion products on anode
surface
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Element
% wt
Aluminium
5.3-6.7
Zinc
2.5-3.5
Manganese
0.15-0.7
Silicon
0.3 Max
Copper
0.05 Max
Nickel
0.003 Max
Iron
0.003 Max
Others ( total )
0.3 Max
Magnesium
Remainder
Note -Heavy metals( Cu, Ni, Fe, Pb ) should never exceed specified values since they
lower efficiency due to local cell formation.
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Type II
Element
% wt
% wt
Iron
0.005 max
0.0014 max
Lead
0.006 max
0.003 max
Copper
0.005 max
0.002 max
Aluminium
0.1-0.5
0.005max
Cadmium
0.025-0.07
0.003 max
Others ( total )
0.1 max
----
Zinc
remainder
remainder
Note: 1) Cu ,Fe ,Pb should not exceed specified limit as they passivate the anode
2) Al and Cd are for grain refinement and prevent passivation
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Alanode
Element
wt %
wt %
Iron
0.12 max
0.13 max
Silicon
0.08-0.2
0.10 max
Copper
0.006
Zinc
2.0-4.0
0.5-5.0
Indium
0.01-0.02
0.005-0.05
0.02 max
Aluminum remainder
remainder
Note: Heavy metal (iron, copper and others i.e. Nickel, lead should not exceed
specified limit)
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Magnesium
Zinc
Aluminium
-1.1 v
-1.05 v
-1.05 v
780
2500-2700
d) Current efficiency
95%
50%
-1.1 v
95%
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These are made of metals/alloys having very low wear rate (gms/a-yr.)
Can have life of 30 years at large current discharge and therefore often termed as
permanent anodes.
They need not be of more negative electro-chemical potential than protected metal.
These anodes are used for impressed current C.P. System using external DC Power source.
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1.5mmor3mmdiaTitaniumsolidwirecoatedwithoxides
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Backfill of Anode
Anodes in soil application are always used in combination with backfill.
Anodes are usually supplied prepacked with backfill.
The function of the backfill are--
Prevent anode to come into contact with harmful ions in soil and contaminants
which can passivate the anode (Phosphates ,carbonates, nitrates).
b) Density 2.1gms/cm3,
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Reference Electrode
Stable non-polarizable electrodes with stable electrode potential
Consists of high purity metal element in the solution of its own salt.
Most commonly used electrodes are
Saturated Copper-copper Sulfate (Cu/CuSO4)
Silver-silver Chloride/Sea Water ( Ag / Agcl)
Silver-silver Chloride / Saturated KCl (Ag/AgCl/KCl)
High purity zinc
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Reference Electrode
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Test Station
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Coupons are installed to measure instant off potential measurement and are
placed at critical locations as follows :
Interference location
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OR
PDB
3Cx25 Sq.mm Al
TO T/R UNITS
T/R UNIT
-- -+
--
1Cx95 Sq.mm Al
CJB
CJB
QTY - 14 Nos
CLASSIFIED / NON CLASSIFIED
1Cx50 Sq.mm Cu
(DRAINAGE CABLE)
TANKS
NAPHTHA BULK STORAGE
NAPHTHA DAY TANK
NPDU
1Cx95 Sq.mm Al
AJB
AJB
AJB
1000 x 20 x 3 MM - 69 Nos
2000 x 20 x 3 MM - 133 Nos
MATERIAL - MMO (MIXED METAL OXIDE)
COATED TITANIUM
HORIZONTAL
BED AT 1.5 MTR
DEPTH
ANODE BED
DEEP W ELL
BED AT 16 MTR
DEPTH
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thanksYou
Thank
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